CN104277356A - Antistatic PVC foamed sole material and manufacturing method thereof - Google Patents
Antistatic PVC foamed sole material and manufacturing method thereof Download PDFInfo
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- CN104277356A CN104277356A CN201410449087.0A CN201410449087A CN104277356A CN 104277356 A CN104277356 A CN 104277356A CN 201410449087 A CN201410449087 A CN 201410449087A CN 104277356 A CN104277356 A CN 104277356A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an antistatic PVC foamed sole material, which comprises the following raw materials in parts by weight: 40-50 parts of PVC, 5-15 parts of graphite nanosheets, 30-40 parts of plasticizer, 0.5-2 parts of foaming agent, 1-2 parts of stabilizer, 4-6 parts of calcium carbonate, 0.5-1 parts of antioxidant, and 0.2-1 parts of stearic acid. The invention further discloses a manufacturing method of the antistatic PVC foamed sole material. The PVC foamed sole material is good in antistatic property.
Description
Technical field:
The present invention relates to a kind of material for sole of shoe, particularly relate to a kind of anlistatig PVC foam material for sole of shoe and manufacture method thereof.
Background technology:
PVC foam material for sole of shoe is basic raw material with PVC, adds a kind of material for sole of shoe that softening agent, whipping agent and other auxiliary agents are obtained, have good mechanical property, comfortable and easy to wear, occupying certain market at material for sole of shoe.But, PVC foam material for sole of shoe surface resistivity is higher, and antistatic effect is poor, and surface very easily produces electrostatic because of friction, when electrostatic accumulation to a certain extent time can produce spark discharge, and then may cause the burning of inflammable gas, blast and electronic devices and components malfunctioning.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of anlistatig PVC foam material for sole of shoe, and its antistatic property is better.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of anlistatig PVC foam material for sole of shoe, its weight part consists of:
Preferably, softening agent of the present invention is dibutyl phthalate, dioctyl phthalate (DOP) or dimixo-octyl phthalate.
Preferably, whipping agent of the present invention is AC whipping agent.
Preferably, stablizer of the present invention is tribasic lead sulfate.
Preferably, oxidation inhibitor of the present invention is antioxidant 1010.
Another technical problem that the present invention will solve is to provide the manufacture method of above-mentioned anlistatig PVC foam material for sole of shoe.
For solving the problems of the technologies described above, technical scheme is:
A manufacture method for anlistatig PVC foam material for sole of shoe, comprises the following steps:
(1) graphite nanosheets is added in mixed acid solution, mixed acid solution is that the vitriol oil of 3:1 and concentrated nitric acid form by volume ratio, with being placed in ultrasonic cleaner supersound process 3 hours, by mixing solutions vacuum filtration, with deionized water wash to neutral, the filter cake obtained is placed in baking oven at 90 DEG C dry 1 hour, obtains acidifying graphite nanosheets;
(2) the acidifying graphite nanosheets that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 1.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 120 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains anlistatig PVC foam material for sole of shoe.
Therefore compared with prior art, the present invention has following beneficial effect:
Graphite nanosheets is a kind of novel flake nano structural carbon material, there is very excellent antistatic property, its flaky nanometer structure is conducive to it and forms conductive path in PVC matrix, reduces the volume resistance of PVC, effectively improves the antistatic property of PVC foam material for sole of shoe; Interface bonding state between graphite nanosheets and PVC is not good, disperse uneven, therefore the present invention has carried out ultrasonic wave dispersion treatment by nitration mixture to graphite nanosheets, after process ,-the OH ,-COOH content on graphite nanosheets surface obviously increases, the hydrogen bond action that can occur to a certain degree with PVC, improve interface bonding state between the two, make graphite nanosheets to be scattered in PVC matrix equably, to give full play to its antistatic property.
Embodiment:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1
A kind of anlistatig PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) graphite nanosheets is added in mixed acid solution, mixed acid solution is that the vitriol oil of 3:1 and concentrated nitric acid form by volume ratio, with being placed in ultrasonic cleaner supersound process 3 hours, by mixing solutions vacuum filtration, with deionized water wash to neutral, the filter cake obtained is placed in baking oven at 90 DEG C dry 1 hour, obtains acidifying graphite nanosheets;
(2) the acidifying graphite nanosheets that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 1.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 120 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains anlistatig PVC foam material for sole of shoe.
Embodiment 2
A kind of anlistatig PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) graphite nanosheets is added in mixed acid solution, mixed acid solution is that the vitriol oil of 3:1 and concentrated nitric acid form by volume ratio, with being placed in ultrasonic cleaner supersound process 3 hours, by mixing solutions vacuum filtration, with deionized water wash to neutral, the filter cake obtained is placed in baking oven at 90 DEG C dry 1 hour, obtains acidifying graphite nanosheets;
(2) the acidifying graphite nanosheets that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 1.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 120 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains anlistatig PVC foam material for sole of shoe.
Embodiment 3
A kind of anlistatig PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) graphite nanosheets is added in mixed acid solution, mixed acid solution is that the vitriol oil of 3:1 and concentrated nitric acid form by volume ratio, with being placed in ultrasonic cleaner supersound process 3 hours, by mixing solutions vacuum filtration, with deionized water wash to neutral, the filter cake obtained is placed in baking oven at 90 DEG C dry 1 hour, obtains acidifying graphite nanosheets;
(2) the acidifying graphite nanosheets that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 1.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 120 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains anlistatig PVC foam material for sole of shoe.
Embodiment 4
A kind of anlistatig PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) graphite nanosheets is added in mixed acid solution, mixed acid solution is that the vitriol oil of 3:1 and concentrated nitric acid form by volume ratio, with being placed in ultrasonic cleaner supersound process 3 hours, by mixing solutions vacuum filtration, with deionized water wash to neutral, the filter cake obtained is placed in baking oven at 90 DEG C dry 1 hour, obtains acidifying graphite nanosheets;
(2) the acidifying graphite nanosheets that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 1.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 120 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains anlistatig PVC foam material for sole of shoe.
Embodiment 5
A kind of anlistatig PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) graphite nanosheets is added in mixed acid solution, mixed acid solution is that the vitriol oil of 3:1 and concentrated nitric acid form by volume ratio, with being placed in ultrasonic cleaner supersound process 3 hours, by mixing solutions vacuum filtration, with deionized water wash to neutral, the filter cake obtained is placed in baking oven at 90 DEG C dry 1 hour, obtains acidifying graphite nanosheets;
(2) the acidifying graphite nanosheets that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 1.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 120 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains anlistatig PVC foam material for sole of shoe.
Embodiment 6
A kind of anlistatig PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) graphite nanosheets is added in mixed acid solution, mixed acid solution is that the vitriol oil of 3:1 and concentrated nitric acid form by volume ratio, with being placed in ultrasonic cleaner supersound process 3 hours, by mixing solutions vacuum filtration, with deionized water wash to neutral, the filter cake obtained is placed in baking oven at 90 DEG C dry 1 hour, obtains acidifying graphite nanosheets;
(2) the acidifying graphite nanosheets that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 1.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 120 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains anlistatig PVC foam material for sole of shoe.
By the examination criteria of anlistatig PVC foam material for sole of shoe obtained for embodiment 1 to 6 according to GB GB21148-2007, test its volume resistance respectively, result is respectively 3.2 × 10
6Ω cm, 2.7 × 10
6Ω cm, 8.3 × 10
5Ω cm, 7.7 × 10
5Ω cm, 5.4 × 10
6Ω cm, 1.5 × 10
6Ω cm, antistatic property is all better.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (6)
1. an anlistatig PVC foam material for sole of shoe, is characterized in that: its weight part consists of:
2. the anlistatig PVC foam material for sole of shoe of one according to claim 1, is characterized in that: described softening agent is dibutyl phthalate, dioctyl phthalate (DOP) or dimixo-octyl phthalate.
3. the anlistatig PVC foam material for sole of shoe of one according to claim 1, is characterized in that: described whipping agent is AC whipping agent.
4. the anlistatig PVC foam material for sole of shoe of one according to claim 1, is characterized in that: described stablizer is tribasic lead sulfate.
5. the anlistatig PVC foam material for sole of shoe of one according to claim 1, is characterized in that: described oxidation inhibitor is antioxidant 1010.
6. the manufacture method of a kind of anlistatig PVC foam material for sole of shoe according to Claims 1 to 5 any one, is characterized in that: comprise the following steps:
(1) graphite nanosheets is added in mixed acid solution, mixed acid solution is that the vitriol oil of 3:1 and concentrated nitric acid form by volume ratio, with being placed in ultrasonic cleaner supersound process 3 hours, by mixing solutions vacuum filtration, with deionized water wash to neutral, the filter cake obtained is placed in baking oven at 90 DEG C dry 1 hour, obtains acidifying graphite nanosheets;
(2) the acidifying graphite nanosheets that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 1.5 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 35 minutes, temperature is 120 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains anlistatig PVC foam material for sole of shoe.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410449087.0A CN104277356A (en) | 2014-09-04 | 2014-09-04 | Antistatic PVC foamed sole material and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410449087.0A CN104277356A (en) | 2014-09-04 | 2014-09-04 | Antistatic PVC foamed sole material and manufacturing method thereof |
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| CN104277356A true CN104277356A (en) | 2015-01-14 |
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| CN201410449087.0A Pending CN104277356A (en) | 2014-09-04 | 2014-09-04 | Antistatic PVC foamed sole material and manufacturing method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109486059A (en) * | 2018-11-07 | 2019-03-19 | 高邮市强杰塑料制品有限公司 | A kind of manufacturing method of sandals soles |
| CN109503989A (en) * | 2018-11-07 | 2019-03-22 | 高邮市强杰塑料制品有限公司 | A kind of manufacturing method of PVC sole |
| CN109535590A (en) * | 2018-11-07 | 2019-03-29 | 高邮市强杰塑料制品有限公司 | A kind of production technology of moulded from foam slipper sole |
| CN109527698A (en) * | 2018-11-07 | 2019-03-29 | 高邮市强杰塑料制品有限公司 | A kind of production method of wear-resistant sole |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109486059A (en) * | 2018-11-07 | 2019-03-19 | 高邮市强杰塑料制品有限公司 | A kind of manufacturing method of sandals soles |
| CN109503989A (en) * | 2018-11-07 | 2019-03-22 | 高邮市强杰塑料制品有限公司 | A kind of manufacturing method of PVC sole |
| CN109535590A (en) * | 2018-11-07 | 2019-03-29 | 高邮市强杰塑料制品有限公司 | A kind of production technology of moulded from foam slipper sole |
| CN109527698A (en) * | 2018-11-07 | 2019-03-29 | 高邮市强杰塑料制品有限公司 | A kind of production method of wear-resistant sole |
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