CN101438869A - Shoes with antibiotic antistatic/conductive function and method for producing the same - Google Patents
Shoes with antibiotic antistatic/conductive function and method for producing the same Download PDFInfo
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- CN101438869A CN101438869A CNA2008101871644A CN200810187164A CN101438869A CN 101438869 A CN101438869 A CN 101438869A CN A2008101871644 A CNA2008101871644 A CN A2008101871644A CN 200810187164 A CN200810187164 A CN 200810187164A CN 101438869 A CN101438869 A CN 101438869A
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- footwear
- silver
- zirconium phosphate
- carbon fiber
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Links
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 37
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 36
- 239000004917 carbon fiber Substances 0.000 claims abstract description 36
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims abstract description 34
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 32
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000004332 silver Substances 0.000 claims abstract description 29
- 229910052709 silver Inorganic materials 0.000 claims abstract description 29
- 239000003381 stabilizer Substances 0.000 claims abstract description 20
- 239000000314 lubricant Substances 0.000 claims abstract description 16
- 239000004014 plasticizer Substances 0.000 claims abstract description 16
- 239000002245 particle Substances 0.000 claims abstract description 9
- 239000011159 matrix material Substances 0.000 claims description 25
- 239000004604 Blowing Agent Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- 230000002421 anti-septic effect Effects 0.000 claims description 8
- -1 azo nitrile compound Chemical class 0.000 claims description 8
- 239000000344 soap Substances 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
- 238000002347 injection Methods 0.000 claims description 6
- 239000007924 injection Substances 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 6
- 108091007643 Phosphate carriers Proteins 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 5
- 239000008188 pellet Substances 0.000 claims description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 4
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 4
- 125000005498 phthalate group Chemical group 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 3
- 238000000967 suction filtration Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 239000003242 anti bacterial agent Substances 0.000 abstract description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 4
- 239000000758 substrate Substances 0.000 abstract 4
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 2
- 235000010216 calcium carbonate Nutrition 0.000 abstract 2
- 239000004088 foaming agent Substances 0.000 abstract 2
- 239000000047 product Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 230000003068 static effect Effects 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000002688 persistence Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229940088710 antibiotic agent Drugs 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000002860 competitive effect Effects 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000722917 Cacosmia Species 0.000 description 1
- 208000012898 Olfaction disease Diseases 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 235000019546 parosmia Nutrition 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 210000004927 skin cell Anatomy 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Landscapes
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention relates to a shoe which can effectively discharge electrostatic charge released by a human body and has an antibiotic function and antistatic/conductive functions as well as a manufacturing method thereof. The shoe comprises a substrate, a carbon fiber conductive network distributed in the substrate and silver-loaded zirconium phosphate particles distributed in the substrate. Materials of the substrate comprise PVC, a plasticizer, a stabilizer, a foaming agent, a lubricant, and CaCO3; the weight ratio of each material is as follows: 20-50% of the PVC, 15-30% of the plasticizer, 0.1-2% of the stabilizer, 0.1-1% of the foaming agent, 0.1-5% of the lubricant, 1-10% of the CaCO3, 1-20% of the carbon fiber and 1-15% of the silver-loaded zirconium phosphate. The manufacturing method can help cause the shoe to have good antibiotic efficacy because of the silver-loaded zirconium phosphate, and different resistance values can be realized by changing an addition amount of the carbon fiber as required for manufacturing the antistatic shoe/conductive shoe.
Description
Technical field
The present invention relates to a kind of footwear, more particularly, relate to a kind of electrostatic charge that can discharge the human body generation effectively, have the manufacture method of footwear and these footwear of antibacterial functions simultaneously again.
Background technology
Footwear are our known daily necessitiess, and structure comprises sole and upper of a shoe, and wherein sole is made by insulating materials such as rubber, plastics usually, and this just makes people and the earth mutually insulated.At present, chemical ﹠ blended fabric is also more in the clothing materials that people wear on one's body, therefore will make human body have static through friction when air is dry, because the insulating effect of sole can not discharge electric charge automatically, and makes that current potential is more and more higher.This has not only destroyed normal biological of human body, makes people's mood agitation, weak and sickly that becomes, and the electric charge of high potential also forms spark discharge easily, becomes a kind of potential safety hazard.Particularly in electron trade, the existence meeting of static causes damage to electronic component, endangers very big.In addition, wear the shoes of especially above-mentioned rubber overshoes and synthetics sole, because of gas permeability official post shoe temperature increases, people's pin is perspired easily.Pin sweat provides moisture, is fit to growth of microorganism, adds that a large amount of dead skin skin cell mass of sole provides nutritious materials such as protein, and microorganism is bred rapidly, and its metabolite cacosmia is incomparable.
When people wore shoes usually, these two problems of static and bacterium existed simultaneously.Therefore, we need a kind of footwear, and it can discharge the electrostatic charge that human body produces effectively, can have antibacterial effect again simultaneously.
Summary of the invention
The technical problem to be solved in the present invention is, bacterial content is many and have the defective of static when wearing at the footwear of prior art, provides a kind of and can discharge the electrostatic charge that human body produces effectively, has the footwear of antibacterial functions simultaneously again.
The technical solution adopted for the present invention to solve the technical problems is: construct a kind of footwear with antibiotic antistatic/conductive function, comprise sole and upper of a shoe, described sole comprises matrix, be distributed in the electric conduction of carbon fiber network in the described matrix and be dispersed in silver-loaded zirconium phosphate particle in the described matrix.
The present invention solves another technical scheme that its technical problem adopts: construct a kind of footwear with antibiotic antistatic/conductive function, comprise with integrated sole of same material and upper of a shoe, it is characterized in that described sole and upper of a shoe comprise matrix, be distributed in the electric conduction of carbon fiber network in the described matrix and be dispersed in silver-loaded zirconium phosphate particle in the described matrix.
In the footwear with antibiotic antistatic/conductive function of the present invention, the material of described matrix comprises PVC, plasticizer, stabilizing agent, blowing agent, lubricant and CaCO
3Wherein the weight ratio of various materials is:
PVC：20～50％；
Plasticizer: 15～30%;
Stabilizing agent: 0.1～2%;
Blowing agent: 0.1～1%;
Lubricant: 0.1～5%;
CaCO
3：1～10％；
Carbon fiber: 1～20%;
Silver-loaded zirconium phosphate: 1～15%.
In the footwear with antibiotic antistatic/conductive function of the present invention, described plasticizer is phthalate, phosphoric acid ester or polyesters; Described stabilizing agent is metallic soap class, organic tin or compound stabilizer class; Described blowing agent is azo nitrile compound, azo-carboxylic acid's derivative class or benzene sulphur hydrazine compound class; Described lubricant is metallic soap class or paraffin class.
In the footwear with antibiotic antistatic/conductive function of the present invention, the shared weight ratio of described carbon fiber is 1～10%, and described footwear are anti-static shoes.
In the footwear with antibiotic antistatic/conductive function of the present invention, the shared weight ratio of described carbon fiber is 11～20%, and described footwear are conductive shoes.
The present invention solves another technical scheme that its technical problem adopts: a kind of manufacture method with footwear of antibiotic antistatic/conductive function is provided, comprises: distribution electric conduction of carbon fiber network and scatter the silver-loaded zirconium phosphate particle in the matrix material of footwear.
In the manufacture method of the footwear with antibiotic antistatic/conductive function of the present invention, described in the matrix material of footwear distribution electric conduction of carbon fiber network and scatter the silver-loaded zirconium phosphate particle, technological process comprises:
A, manufacturing inorganic antiseptic silver-loaded zirconium phosphate (Ag-ZrP): zirconia, oxalic acid, phosphoric acid three are mixed, react back suction filtration, washing, remove foreign ion, obtain the basic zirconium phosphate carrier; The basic zirconium phosphate carrier is mixed control exchange temperature with silver nitrate〉60 ℃, the time〉4h, obtain containing Ag thereby wash out foreign ion
+Inorganic antiseptic silver-loaded zirconium phosphate (Ag-ZrP);
B, prepare burden by the weight ratio prescription of following various materials:
PVC：20～50％；
Plasticizer: 15～30%;
Stabilizing agent: 0.1～2%;
Blowing agent: 0.1～1%;
Lubricant: 0.1～5%;
CaCO
3：1～10％；
Carbon fiber: 1～20%;
Silver-loaded zirconium phosphate: 1～15%; And
Double-screw extruding pelletizing;
C, the resulting pellet injection mo(u)lding of step B is got antibiotic antistatic/conductive footwear or sole.
Implement the footwear with antibiotic antistatic/conductive function of the present invention, have following beneficial effect: because the existence of silver-loaded zirconium phosphate in the footwear material makes this footwear material have the excellent antibiotic effect; Owing to contain carbon fiber in the footwear material, it forms conductive network in the footwear material simultaneously, can discharge the static that human body produces.The volume resistance value of footwear of the present invention and sheet resistance value are not influenced by humiture, have strengthened the stability and the persistence of properties of product effectively.
Footwear processing technology of the present invention is simple, excellent performance.And can in footwear material production process,, realize different resistance values, thereby obtain the performance of anti-static shoes/conductive shoes as required by changing the carbon fiber addition.Footwear of the present invention are specially adapted to the toilet.The footwear that adopt the technology of the present invention to produce have very big competitive advantage in like product, market prospects are wide.
Description of drawings
The invention will be further described below in conjunction with drawings and Examples, in the accompanying drawing:
Fig. 1 is the structural representation of sole of an embodiment of footwear of the present invention.
The specific embodiment
Fig. 1 is the structural representation of sole of an embodiment of footwear of the present invention.As shown in Figure 1, comprise carbon fiber 1 in the sole matrix, it is the crisscross net distribution that is in the sole matrix material; Also comprise silver-loaded zirconium phosphate 2 in the sole matrix, it is graininess and is scattered and is distributed in the sole matrix.
According to embodiments of the invention, matrix material comprises PVC, plasticizer, stabilizing agent, blowing agent, lubricant and CaCO
3Wherein, the prescription (weight ratio) of various compositions is as follows in the footwear material:
PVC：20～50％；
Plasticizer: 15～30%;
Stabilizing agent: 0.1～2%;
Blowing agent: 0.1～1%;
Lubricant: 0.1～5%;
CaCO
3：1～10％；
Carbon fiber: 1～20%;
Silver-loaded zirconium phosphate: 1～15%.
As selection:
Above-mentioned plasticizer can be phthalate, phosphoric acid ester, polyesters etc.;
Stabilizing agent can be metallic soap class, organic tin, compound stabilizer class etc.;
Blowing agent can be azo nitrile compound, azo-carboxylic acid's derivative class, benzene sulphur hydrazine compound class etc.;
Lubricant can be metallic soap class, paraffin class etc.
The present invention mainly adopts in footwear material raw material production process, adds a certain amount of anti-biotic material and conductive material extruding pelletization.With the injection mo(u)lding of gained pellet, get final product the antibiotic antistatic/conductive footwear.
Among the present invention, the production procedure of PVC antibiotic antistatic/conductive footwear is as follows:
(1) zirconia, oxalic acid, phosphoric acid three mix, and react back suction filtration, washing, remove foreign ion, obtain the basic zirconium phosphate carrier.It is mixed control exchange temperature with silver nitrate〉60 ℃, the time〉4h, wash out foreign ion, obtain containing Ag
+Inorganic antiseptic silver-loaded zirconium phosphate (Ag-ZrP).
(2), in process of production, in the matrix material raw material of footwear, add silver-loaded zirconium phosphate and carbon fiber, double-screw extruding pelletizing by above prescription.
(3) resulting pellet injection mo(u)lding is got the antibiotic antistatic/conductive footwear.
What deserves to be explained is that in the present invention, what use above-mentioned pellet injection mo(u)lding can be sole, also can be integrated footwear (comprising sole and upper of a shoe), for example slippers, water shoes or beach shoes etc.Relevant this point it will be understood by those skilled in the art that so do not show with accompanying drawing.
In sum, according to the present invention, prepared footwear have antibiotic and antistatic/conductive function simultaneously, and anti-biotic material is the synthetic silver-loaded zirconium phosphate that obtains, and conductive material is a carbon fiber.Because the electric conduction of carbon fiber function admirable is added carbon fiber and is cross-linked in material for sole of shoe, constitutes a conductive network, so this antistatic/conductive footwear function admirable.In use this antistatic/conductive sole makes and wears the static that personnel's health produced and reach sole by conductive fiber because the carbon fiber that contains is conductive network and interconnects, and imports the earth then.The volume resistance value of this product and sheet resistance can be controlled by the amount of adding carbon fiber.In one embodiment, when being 1～10% weight portion, amount of carbon fiber can reach the resistance value 10 of anti-static shoes requirement
6To 10
9Ohm.In another embodiment, when amount of carbon fiber is 11～20% weight portions, can reach the volume resistance value 10 of conductive shoes requirement
3To 10
5Ohm.And volume resistance value and sheet resistance value are not influenced by humiture, have strengthened the stability and the persistence of properties of product effectively.The existence of silver-loaded zirconium phosphate in the footwear material, make this footwear material have the excellent antibiotic effect simultaneously, the antibiotic antistatic/conductive footwear that make by this technology are owing to adopt the fibre structure material, in material for sole of shoe, be network structure, difficult drop-off, in use can on the floor, not stay blackly, can in the toilet of high request, use.
In this invention, synthesized silver-loaded zirconium phosphate as antiseptic, in footwear material raw material production process, add this antiseptic, add carbon fiber, injection mo(u)lding simultaneously.Content by the control carbon fiber can obtain antistatic or conductive shoes material, and the adding of antiseptic makes this footwear that antibiotic effect be arranged, and has obtained having simultaneously antibiotic and the functional shoe dual usefulness of antistatic/conductive.
Processing technology of the present invention is simple, excellent performance.The existence of silver-loaded zirconium phosphate in the footwear material, make this footwear material have the excellent antibiotic effect, the product that adopts this technology to produce has controllability, can be as required, by changing the carbon fiber addition, realize different resistance values, thus the performance of control anti-static shoes/conductive shoes, when the shared weight ratio of carbon fiber is 1～10%, can reach the resistance value 10 of anti-static shoes requirement
6To 10
9Ohm when the shared weight ratio of carbon fiber is 11～20%, can reach the volume resistance value 10 of conductive shoes requirement
3To 10
5Ohm, antistatic/conductive footwear excellent performance.Overcome simultaneously antistatic/conductive footwear of the prior art stay black, the problem that can not use in the toilet.And volume resistance value and sheet resistance value are not influenced by humiture, have strengthened the stability and the persistence of properties of product effectively, and the product that adopts this technology to produce has very big competitive advantage in like product, and market prospects are wide.
Claims (10)
1, a kind of footwear with antibiotic antistatic/conductive function comprise sole and upper of a shoe, it is characterized in that, described sole comprises matrix, be distributed in the electric conduction of carbon fiber network in the described matrix and be dispersed in silver-loaded zirconium phosphate particle in the described matrix.
2, the footwear with antibiotic antistatic/conductive function according to claim 1 is characterized in that, the material of described matrix comprises PVC, plasticizer, stabilizing agent, blowing agent, lubricant and CaCO
3Wherein the weight ratio of various materials is:
PVC：20～50％；
Plasticizer: 15～30%;
Stabilizing agent: 0.1～2%;
Blowing agent: 0.1～1%;
Lubricant: 0.1～5%;
CaCO
3：1～10％；
Carbon fiber: 1～20%;
Silver-loaded zirconium phosphate: 1～15%.
3, the footwear with antibiotic antistatic/conductive function according to claim 2 is characterized in that, described plasticizer is phthalate, phosphoric acid ester or polyesters; Described stabilizing agent is metallic soap class, organic tin or compound stabilizer class; Described blowing agent is azo nitrile compound, azo-carboxylic acid's derivative class or benzene sulphur hydrazine compound class; Described lubricant is metallic soap class or paraffin class.
4, the footwear with antibiotic antistatic/conductive function according to claim 2 is characterized in that, the shared weight ratio of described carbon fiber is 1～10%, and described footwear are anti-static shoes.
5, the footwear with antibiotic antistatic/conductive function according to claim 2 is characterized in that, the shared weight ratio of described carbon fiber is 11～20%, and described footwear are conductive shoes.
6, a kind of footwear with antibiotic antistatic/conductive function, comprise with integrated sole of same material and upper of a shoe, it is characterized in that described sole and upper of a shoe comprise matrix, be distributed in the electric conduction of carbon fiber network in the described matrix and be dispersed in silver-loaded zirconium phosphate particle in the described matrix.
7, the footwear with antibiotic antistatic/conductive function according to claim 6 is characterized in that, the material of described matrix comprises PVC, plasticizer, stabilizing agent, blowing agent, lubricant and CaCO
3Wherein the weight ratio of various materials is:
PVC：20～50％；
Plasticizer: 15～30%;
Stabilizing agent: 0.1～2%;
Blowing agent: 0.1～1%;
Lubricant: 0.1～5%;
CaCO
3：1～10％；
Carbon fiber: 1～20%;
Silver-loaded zirconium phosphate: 1～15%.
According to the described footwear of claim 7, it is characterized in that 8, described plasticizer is phthalate, phosphoric acid ester or polyesters with antibiotic antistatic/conductive function; Described stabilizing agent is metallic soap class, organic tin or compound stabilizer class; Described blowing agent is azo nitrile compound, azo-carboxylic acid's derivative class or benzene sulphur hydrazine compound class; Described lubricant is metallic soap class or paraffin class.
9, a kind of manufacture method with footwear of antibiotic antistatic/conductive function is characterized in that, comprising: distribution electric conduction of carbon fiber network and scatter the silver-loaded zirconium phosphate particle in the matrix material of footwear.
10, the manufacture method with footwear of antibiotic antistatic/conductive function according to claim 9 is characterized in that, described in the matrix material of footwear distribution electric conduction of carbon fiber network and scatter the silver-loaded zirconium phosphate particle, technological process comprises:
A, manufacturing inorganic antiseptic silver-loaded zirconium phosphate: zirconia, oxalic acid, phosphoric acid three are mixed, react back suction filtration, washing, remove foreign ion, obtain the basic zirconium phosphate carrier; The basic zirconium phosphate carrier is mixed control exchange temperature with silver nitrate〉60 ℃, the time〉4h, obtain containing Ag thereby wash out foreign ion
+The inorganic antiseptic silver-loaded zirconium phosphate;
B, prepare burden by the weight ratio prescription of following various materials:
PVC：20～50％；
Plasticizer: 15～30%;
Stabilizing agent: 0.1～2%;
Blowing agent: 0.1～1%;
Lubricant: 0.1～5%;
CaCO
3：1～10％；
Carbon fiber: 1～20%;
Silver-loaded zirconium phosphate: 1～15%; And
Double-screw extruding pelletizing;
C, the resulting pellet injection mo(u)lding of step B is got antibiotic antistatic/conductive footwear or sole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101871644A CN101438869B (en) | 2008-11-14 | 2008-12-11 | Shoes with antibiotic antistatic/conductive function and method for producing the same |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810217468 | 2008-11-14 | ||
| CN200810217468.0 | 2008-11-14 | ||
| CN2008101871644A CN101438869B (en) | 2008-11-14 | 2008-12-11 | Shoes with antibiotic antistatic/conductive function and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101438869A true CN101438869A (en) | 2009-05-27 |
| CN101438869B CN101438869B (en) | 2010-07-14 |
Family
ID=40723593
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008101871644A Expired - Fee Related CN101438869B (en) | 2008-11-14 | 2008-12-11 | Shoes with antibiotic antistatic/conductive function and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101438869B (en) |
Cited By (22)
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| CN102634131A (en) * | 2012-04-11 | 2012-08-15 | 深圳市新纶科技股份有限公司 | Low-density PVC (Poly Vinyl Chloride) injection-molded shoe material and preparation method thereof |
| CN103275504A (en) * | 2013-06-21 | 2013-09-04 | 苏州新区特氟龙塑料制品厂 | Conductive plastic |
| CN103304919A (en) * | 2013-05-31 | 2013-09-18 | 苏州市景荣科技有限公司 | Fold resisting PVC (Polyvinyl Chloride) foaming sole material |
| CN103304924A (en) * | 2013-06-21 | 2013-09-18 | 苏州市景荣科技有限公司 | PVC (Polyvinyl Chloride) sole material with thermal stability |
| CN103467880A (en) * | 2013-08-23 | 2013-12-25 | 吴江市天源塑胶有限公司 | Anti-bacterial PVC plastic |
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| CN103589087A (en) * | 2013-10-15 | 2014-02-19 | 苏州市景荣科技有限公司 | Antibacterial odor-resistant PVC (Polyvinyl Chloride) sole material |
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| CN104262864A (en) * | 2014-10-22 | 2015-01-07 | 苏州市景荣科技有限公司 | Conductive PVC (polyvinyl chloride) shoe sole material and manufacturing method thereof |
| CN104277375A (en) * | 2014-10-22 | 2015-01-14 | 苏州市景荣科技有限公司 | PVC (Polyvinyl Chloride) shoe material with antibacterial function and manufacturing method thereof |
| CN104277356A (en) * | 2014-09-04 | 2015-01-14 | 苏州市景荣科技有限公司 | Antistatic PVC foamed sole material and manufacturing method thereof |
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| CN112741395A (en) * | 2019-10-30 | 2021-05-04 | 李王玉寒 | Human body static electricity discharging shoes with built-in conductive medium |
| CN111187425A (en) * | 2020-02-17 | 2020-05-22 | 吉林化工学院 | Antibacterial silver metal azo coordination polymer |
| WO2022039686A1 (en) * | 2020-08-19 | 2022-02-24 | Sevim Funda | Anti-corona virus footwear |
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