CN104264496A - Synthetic leather for clothes and production method of synthetic leather - Google Patents
Synthetic leather for clothes and production method of synthetic leather Download PDFInfo
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- CN104264496A CN104264496A CN201410448326.0A CN201410448326A CN104264496A CN 104264496 A CN104264496 A CN 104264496A CN 201410448326 A CN201410448326 A CN 201410448326A CN 104264496 A CN104264496 A CN 104264496A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
- D06N3/08—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products with a finishing layer consisting of polyacrylates, polyamides or polyurethanes or polyester
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
- D06N3/005—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by blowing or swelling agent
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1642—Hardnes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention discloses synthetic leather for clothes. The synthetic leather for clothes comprises a base cloth layer, a PVC foaming layer and a PU surface layer, wherein the surface layer is prepared from the following raw materials in parts by weight: 80-100 parts of waterborne polyurethane resin, 0.2-1 part of coconut oil fatty acid diethanol amide, 0.2-0.5 part of sodium lauryl sulfate, 0.5-1.5 parts of spearmint oil, 2-6 parts of oleic acid macrogol ester, 0.2-1 part of sorbitol, 3-8 parts of beta-cyclodextrin, 1-3 parts of peanut shell powder, 1-2 parts of wood flour, 1-2 parts of microcrystalline cellulose, 1-3 parts of a performance additive and 1-2 parts of pigment. The synthetic leather for clothes is good in appearance, softness and mouthfeel, is moderate, harmless, has lasting fresh flavor, and is suitable for clothes materials.
Description
Technical field
The present invention relates to synthetic leather processing technique field, be specifically related to a kind of synthetic leather for clothes and production method thereof.
Background technology
Polyurethane (PU) synthetic leather has cold-resistant, feel and presentation quality is good, intensity is high, sucting wet air permeability is good, the soft and features such as the phenomenon of sticky hand without the hard summer in polyvinyl chloride (PVC) artificial leather winter, becomes the optimal selection of alternative natural leather.
Summary of the invention
The object of this invention is to provide a kind of synthetic leather for clothes.
The present invention is achieved by the following technical solutions:
A kind of synthetic leather for clothes, comprises base cloth layer, PVC foam layer and PU surface layer, wherein:
PU surface layer is obtained by the raw material of following weight parts:
Waterborne polyurethane resin 80-100, cocoanut fatty acid diethanolamide 0.2-1, laruyl alcohol sodium sulfovinate 0.2-0.5, spearmint oil 0.5-1.5, Polyethylene Glycol Oleate 2-6, sorbierite 0.2-1, beta-schardinger dextrin-3-8, peanut hull meal 1-3, wood powder 1-2, microcrystalline cellulose 1-2, modified additive 1-3, colorant 1-2;
PVC foam layer is obtained by the raw material of following weight parts:
PVC SG-1 30-60, PVC SG-5 20-40, tributyl 2-acetylcitrate 50-80, palm oil 3-8, linseed oil 2-4, urea 0.2-1, sodium succinate 0.5-1, precipitated calcium carbonate 20-40, zeolite powder 10-20, tapioca 5-10, brucite fiber 1-2, polyoxyethylene nonylphenol ether 0.2-0.5, Tween 80 0.1-0.3, cetostearyl alcohol 4-8, AC blowing agent 2-5, liquid barium zinc stabilizer 1-3;
Wherein modified additive is made up of the raw material of following weight portion:
Feather meal 10-20, kaolin 10-20, sweet mellow wine 1-2, citric acid 0.2-1, ammonium chloride 2-4, titanate coupling agent 0.5-1, oleic acid 2-6;
The preparation method of modified additive is:
Feather meal is mixed with kaolin, suitable quantity of water and ammonium chloride is added after 500-600 DEG C of calcining 1-2h, filter after stirring, add propylene glycol and citric acid, then add suitable quantity of water grinding 15-30min, titanate coupling agent is added after drying, 100-150 DEG C, 200-400r/min stirs 10-20min, add oleic acid, under similarity condition, stir 30-60min, be ground to 600-800 order after drying, obtain final product;
A production method for synthetic leather for clothes, comprises the following steps:
(1) PU face stock is taken, first spearmint oil is dissolved in a small amount of ethanol, 50-60 DEG C, be added dropwise to the 10-15% beta-schardinger dextrin-aqueous solution under 600-800r/min condition and stir 30-60min, stir 10-15min under adding Polyethylene Glycol Oleate and sorbierite similarity condition, after spraying dry, obtain active powder; Active powder mixed with all the other face stock, 1000-1500r/min is evenly coated in release liners after stirring 10-20min, dries rear forming surface for 100-150 DEG C;
(2) PVC foam layer raw material is taken, first precipitated calcium carbonate, zeolite powder, tapioca are mixed with palm oil, linseed oil and 200-400r/min, 50-60 DEG C stir 30-60min, mix with all the other raw materials, 1000-1500r/min stirs 30-60min, obtains PVC foam slurry again; Evenly be coated on polyurethane cover by the PVC foam slurry prepared, at 160-200 DEG C, foaming forms PVC foam layer again;
(3) in foaming layer, apply aqueous polyurethane binding paste, rear 130-160 bonding with base cloth layer DEG C is dried;
(4) remove release liners, obtain synthetic leather finished product.
Advantage of the present invention is:
Synthetic leather outward appearance of the present invention, pliability and feel are good, gentle harmless, and containing natural perfume material spearmint oil, have lasting pure and fresh fragrance, be applicable to garment material.
Detailed description of the invention
Non-limiting examples of the present invention is as follows:
Embodiment 1
A kind of synthetic leather for clothes, comprises base cloth layer, PU surface layer and PVC foam layer, wherein:
PU surface layer is obtained by the raw material of following weight parts:
Waterborne polyurethane resin 90, cocoanut fatty acid diethanolamide 0.5, laruyl alcohol sodium sulfovinate 0.4, spearmint oil 1, Polyethylene Glycol Oleate 4, sorbierite 0.6, beta-schardinger dextrin-6, peanut hull meal 2, wood powder 1.5, microcrystalline cellulose 1.5, modified additive 2, colorant 1.5;
PVC foam layer is obtained by the raw material of following weight parts:
PVC SG-1 40, PVC SG-5 30, tributyl 2-acetylcitrate 65, palm oil 6, linseed oil 3, urea 0.5, sodium succinate 0.6, precipitated calcium carbonate 30, zeolite powder 15, tapioca 7, brucite fiber 1, polyoxyethylene nonylphenol ether 0.4, Tween 80 0.2, cetostearyl alcohol 6, AC blowing agent 3, liquid barium zinc stabilizer 2;
Wherein modified additive is made up of the raw material of following weight portion:
Feather meal 15, kaolin 10, sweet mellow wine 2, citric acid 0.5, ammonium chloride 3, titanate coupling agent 0.8, oleic acid 4;
The preparation method of modified additive is:
Feather meal is mixed with kaolin, suitable quantity of water and ammonium chloride is added after 600 DEG C of calcining 1h, filter after stirring, add propylene glycol and citric acid, then add suitable quantity of water grinding 15min, titanate coupling agent is added after drying, 120 DEG C, 200r/min stirs 10min, add oleic acid, under similarity condition, stir 30min, be ground to 600 orders after drying, obtain final product;
A production method for synthetic leather for clothes, comprises the following steps:
(1) PU face stock is taken, first spearmint oil is dissolved in a small amount of ethanol, 55 DEG C, be added dropwise to the 15% beta-schardinger dextrin-aqueous solution under 800r/min condition and stir 45min, stir 10min under adding Polyethylene Glycol Oleate and sorbierite similarity condition, after spraying dry active powder; Active powder mixed with all the other face stock, 1200r/min is evenly coated in release liners after stirring 10min, dries rear forming surface for 120 DEG C;
(2) take PVC foam layer raw material, first precipitated calcium carbonate, zeolite powder, tapioca are mixed with palm oil, linseed oil and 400r/min, 60 DEG C stir 50min, then mix with all the other raw materials, 1300r/min stirs 40min, obtains PVC foam slurry; Evenly be coated on polyurethane cover by the PVC foam slurry prepared, at 180 DEG C, foaming forms PVC foam layer again;
(3) in foaming layer, apply aqueous polyurethane binding paste, dry for bonding with base cloth layer latter 150 DEG C;
(4) remove release liners, obtain synthetic leather finished product.
Through properties of product test, it is 18N that warp-wise tears load, and broadwise tears the requirement that load is 15N, realistic application.
Claims (2)
1. a synthetic leather for clothes, comprises base cloth layer, PVC foam layer and PU surface layer, it is characterized in that:
Described PU surface layer is obtained by the raw material of following weight parts:
Waterborne polyurethane resin 80-100, cocoanut fatty acid diethanolamide 0.2-1, laruyl alcohol sodium sulfovinate 0.2-0.5, spearmint oil 0.5-1.5, Polyethylene Glycol Oleate 2-6, sorbierite 0.2-1, beta-schardinger dextrin-3-8, peanut hull meal 1-3, wood powder 1-2, microcrystalline cellulose 1-2, modified additive 1-3, colorant 1-2;
Described PVC foam layer is obtained by the raw material of following weight parts:
PVC SG-1 30-60, PVC SG-5 20-40, tributyl 2-acetylcitrate 50-80, palm oil 3-8, linseed oil 2-4, urea 0.2-1, sodium succinate 0.5-1, precipitated calcium carbonate 20-40, zeolite powder 10-20, tapioca 5-10, brucite fiber 1-2, polyoxyethylene nonylphenol ether 0.2-0.5, Tween 80 0.1-0.3, cetostearyl alcohol 4-8, AC blowing agent 2-5, liquid barium zinc stabilizer 1-3;
Described modified additive is made up of the raw material of following weight portion:
Feather meal 10-20, kaolin 10-20, sweet mellow wine 1-2, citric acid 0.2-1, ammonium chloride 2-4, titanate coupling agent 0.5-1, oleic acid 2-6;
The preparation method of described modified additive is:
Feather meal is mixed with kaolin, suitable quantity of water and ammonium chloride is added after 500-600 DEG C of calcining 1-2h, filter after stirring, add propylene glycol and citric acid, then add suitable quantity of water grinding 15-30min, titanate coupling agent is added after drying, 100-150 DEG C, 200-400r/min stirs 10-20min, add oleic acid, under similarity condition, stir 30-60min, be ground to 600-800 order after drying, obtain final product.
2. the preparation method of a kind of synthetic leather for clothes according to claim 1, is characterized in that, comprise the following steps:
(1) PU face stock is taken, first spearmint oil is dissolved in a small amount of ethanol, 50-60 DEG C, be added dropwise to the 10-15% beta-schardinger dextrin-aqueous solution under 600-800r/min condition and stir 30-60min, stir 10-15min under adding Polyethylene Glycol Oleate and sorbierite similarity condition, after spraying dry, obtain active powder; Active powder mixed with all the other face stock, 1000-1500r/min is evenly coated in release liners after stirring 10-20min, forms surface layer after 100-150 DEG C of oven dry;
(2) PVC foam layer raw material is taken, first precipitated calcium carbonate, zeolite powder, tapioca are mixed with palm oil, linseed oil and 200-400r/min, 50-60 DEG C stir 30-60min, mix with all the other raw materials, 1000-1500r/min stirs 30-60min, obtains PVC foam slurry again; Evenly be coated on polyurethane cover by the PVC foam slurry prepared, at 160-200 DEG C, foaming forms PVC foam layer again;
(3) in foaming layer, apply aqueous polyurethane binding paste, rear 130-160 bonding with base cloth layer DEG C is dried;
(4) remove release liners, obtain synthetic leather finished product.
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CN201410448326.0A CN104264496A (en) | 2014-09-04 | 2014-09-04 | Synthetic leather for clothes and production method of synthetic leather |
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CN201410448326.0A CN104264496A (en) | 2014-09-04 | 2014-09-04 | Synthetic leather for clothes and production method of synthetic leather |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104594063A (en) * | 2015-01-12 | 2015-05-06 | 安徽玉堂雨具有限公司 | High-performance PU sofa leather and production method thereof |
CN104594061A (en) * | 2015-01-12 | 2015-05-06 | 安徽玉堂雨具有限公司 | Energy-saving and environment-friendly PU synthetic leather and production method thereof |
CN105239415A (en) * | 2015-08-26 | 2016-01-13 | 安徽冠宜箱包有限公司 | Artificial leather luggage having refreshing fragrance and preparation method thereof |
CN105297468A (en) * | 2015-10-27 | 2016-02-03 | 芜湖市鸿坤汽车零部件有限公司 | Delicate-fragrance type synthetic leather and production method thereof |
CN105862446A (en) * | 2016-06-22 | 2016-08-17 | 程志刚 | Anti-bacterial mould-proof PU synthetic leather and production method thereof |
CN105887504A (en) * | 2016-06-22 | 2016-08-24 | 程志刚 | Imitated PU (polyurethane) synthetic leather and production method thereof |
CN107099125A (en) * | 2017-06-23 | 2017-08-29 | 安徽金钻智能科技有限公司 | A kind of synthetic leather processing soft reinforcing agent and preparation method thereof |
CN107435248A (en) * | 2016-05-27 | 2017-12-05 | 丰田纺织株式会社 | Synthetic leather |
CN109235053A (en) * | 2018-11-30 | 2019-01-18 | 重庆长安汽车股份有限公司 | A kind of Fragrant artificial leather and its preparation method and application |
CN109577020A (en) * | 2018-12-05 | 2019-04-05 | 东台市吉中汽车内饰件有限公司 | A kind of production technology with fragrance surface cover |
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CN103352375A (en) * | 2013-07-03 | 2013-10-16 | 六安三希皮革制品有限公司 | Twist-resisting PVC synthetic leather fabrics and preparation method thereof |
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CN102199882A (en) * | 2011-04-02 | 2011-09-28 | 江苏国信合成革有限公司 | TPU modified high performance PVC ball leather and its preparation method |
CN102995445A (en) * | 2012-10-23 | 2013-03-27 | 合肥市安山涂层织物有限公司 | Diatomite modified polyvinyl chloride synthetic leather and manufacturing method thereof |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104594063A (en) * | 2015-01-12 | 2015-05-06 | 安徽玉堂雨具有限公司 | High-performance PU sofa leather and production method thereof |
CN104594061A (en) * | 2015-01-12 | 2015-05-06 | 安徽玉堂雨具有限公司 | Energy-saving and environment-friendly PU synthetic leather and production method thereof |
CN105239415A (en) * | 2015-08-26 | 2016-01-13 | 安徽冠宜箱包有限公司 | Artificial leather luggage having refreshing fragrance and preparation method thereof |
CN105297468A (en) * | 2015-10-27 | 2016-02-03 | 芜湖市鸿坤汽车零部件有限公司 | Delicate-fragrance type synthetic leather and production method thereof |
CN107435248A (en) * | 2016-05-27 | 2017-12-05 | 丰田纺织株式会社 | Synthetic leather |
CN105862446A (en) * | 2016-06-22 | 2016-08-17 | 程志刚 | Anti-bacterial mould-proof PU synthetic leather and production method thereof |
CN105887504A (en) * | 2016-06-22 | 2016-08-24 | 程志刚 | Imitated PU (polyurethane) synthetic leather and production method thereof |
CN107099125A (en) * | 2017-06-23 | 2017-08-29 | 安徽金钻智能科技有限公司 | A kind of synthetic leather processing soft reinforcing agent and preparation method thereof |
CN107099125B (en) * | 2017-06-23 | 2019-04-09 | 安徽金钻智能科技有限公司 | A kind of synthetic leather processing soft reinforcing agent and preparation method thereof |
CN109235053A (en) * | 2018-11-30 | 2019-01-18 | 重庆长安汽车股份有限公司 | A kind of Fragrant artificial leather and its preparation method and application |
CN109577020A (en) * | 2018-12-05 | 2019-04-05 | 东台市吉中汽车内饰件有限公司 | A kind of production technology with fragrance surface cover |
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