CN104263111A - 一种耐候型硬质涂料 - Google Patents

一种耐候型硬质涂料 Download PDF

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CN104263111A
CN104263111A CN201410451817.0A CN201410451817A CN104263111A CN 104263111 A CN104263111 A CN 104263111A CN 201410451817 A CN201410451817 A CN 201410451817A CN 104263111 A CN104263111 A CN 104263111A
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孙巨福
张萍
戴宇钧
祝盆鑫
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Tianchang Julong Car and Ship Coating Co Ltd
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Abstract

本发明公开了一种耐候型硬质涂料，它是由下述重量份的原料组成的：聚双环戊二烯2-3、偏钒酸铵1-2、硫酸氢钾1-2、甲基膦酸二甲酯2-3、二茂铁甲酸0.7-1、单丁基氧化锡0.6-1、丙烯酸异辛酯2-3、纳米硅藻土10-14、2-巯基苯并咪唑0.3-1、氟化钙2-3、苯乙烯140-200、丙烯酸甲酯150-200、丙烯酸10-20、过硫酸铵4-6、OP-106-8、粘结助剂4-5、油酸聚氧乙烯酯1-2、去离子水500-600；本发明的涂料耐候性好，对环境适应性强，耐高低温性强，涂膜与基材的粘结性强，抗剥离抗黄变性好，涂层表面硬度高，抗磨抗冲击性好，耐擦拭。

Description

一种耐候型硬质涂料
技术领域
    本发明主要涉及涂料领域，尤其涉及一种耐候型硬质涂料。
背景技术
    涂于物体表面能形成具有保护、装饰或特殊性能(如绝缘、防腐、标志等)的固态涂膜的一类液体或固体材料的总称，包括油(性)漆、水性漆、粉末涂料。漆是可流动的液体涂料，包括油(性)漆及水性漆。油漆是以有机溶剂为介质或高固体、无溶剂的油性漆。水性漆是可用水溶解或用水分散的涂料。涂料作为家庭装修的主材之一，在装饰装修中占的比例较大，购买涂料的合格与否直接影响到整体装修效果和居室的环境，有时甚至会对人体的健康产生极大的危害。目前随着各种各样涂料的产生，对涂料的品质要求也不断提高，而不断提高涂料质量对于建筑、生活都可以起到很大的帮助作用。
发明内容
本发明目的就是提供一种耐候型硬质涂料。
本发明是通过以下技术方案实现的：
一种耐候型硬质涂料，其特征在于它是由下述重量份的原料组成的：
聚双环戊二烯2-3、偏钒酸铵1-2、硫酸氢钾1-2、甲基膦酸二甲酯2-3、二茂铁甲酸0.7-1、单丁基氧化锡0.6-1、丙烯酸异辛酯2-3、纳米硅藻土10-14、2-巯基苯并咪唑0.3-1、氟化钙2-3、苯乙烯140-200、丙烯酸甲酯150-200、丙烯酸10-20、过硫酸铵4-6、OP-10 6-8、粘结助剂4-5、油酸聚氧乙烯酯1-2、去离子水500-600；
所述的粘结助剂是由下述重量份的各原料组成的：
铝溶胶20-30、硫酸铝铵1-3、羊毛脂1-2、聚乙二醇二甲基丙烯酸酯0.6-1、无水乙醇3-4、丙烯酸甲酯2-4、过硫酸钾2-3、乳化剂OP-100.5-1、香樟木微粉2-4、去离子水15-20；
将无水乙醇加热到70-75℃，加入羊毛脂，搅拌均匀，得醇脂溶液；
将香樟木微粉加入到铝溶胶中，加入聚乙二醇二甲基丙烯酸酯，升高温度为55-60℃，100-200转/分搅拌分散3-5分钟，得分散液；
将过硫酸钾与丙烯酸甲酯混合，在60-70℃下搅拌混合2-3分钟，加入分散液，搅拌至常温，加入上述醇脂溶液，60-100转/分搅拌混合5-10分钟，加入剩余各原料，200-400转/分搅拌分散3-5分钟，即得所述粘结助剂。
一种耐候型硬质涂料的制备方法，其特征在于包括以下步骤：
（1）取上述苯乙烯重量的80-90%、丙烯酸甲酯重量的80-90%、丙烯酸异辛酯、丙烯酸混合，得单体a；
（2）取OP-10，加入上述去离子水重量的30-40%，搅拌均匀，得预乳液；
（3）取过硫酸铵，加入剩余去离子水重量的10-20%，搅拌均匀，得引发剂溶液；
（4）取上述单体a、预乳液重量的40-50%、引发剂溶液重量的50-60%，混合，加入硫酸氢钾，在75-80℃下保温搅拌10-20分钟，得预混单体；
（5）将剩余的苯乙烯、丙烯酸甲酯混合，搅拌均匀后加入油酸聚氧乙烯酯、单丁基氧化锡，在50-60℃下保温搅拌10-20分钟，冷却至常温，得改性单体；
（6）将上述改性单体与剩余的预乳液、剩余的引发剂溶液混合，70-90℃下保温搅拌30-50分钟，滴加上述预混单体，滴加时间为2-3小时，滴加完毕后在80-85℃下保温2-3小时，降低温度至40-50℃，调节pH 值至7-8，用200-250 目过滤筛过滤；
（7）将上述步骤（6）得到的物料与剩余各原料混合，800-1200转/分搅拌分散20-30分钟，即得所述耐候型硬质涂料。
本发明的优点是：
    本发明的涂料耐候性好，对环境适应性强，耐高低温性强，涂膜与基材的粘结性强，抗剥离抗黄变性好，涂层表面硬度高，抗磨抗冲击性好，耐擦拭。本发明的粘结助剂中加入的香樟木微粉具有良好的抗磨性、热稳定性好化学稳定性，铝溶胶与硫酸铝铵、羊毛脂、丙烯酸异辛酯、过硫酸钾混合，具有优异的粘结性能，可以增强涂层表面抗性和稳定性。
具体实施方式
实施例1
一种耐候型硬质涂料，其特征在于它是由下述重量份的原料组成的：
聚双环戊二烯2-3、偏钒酸铵1-2、硫酸氢钾1-2、甲基膦酸二甲酯2-3、二茂铁甲酸0.7-1、单丁基氧化锡0.6-1、丙烯酸异辛酯2-3、纳米硅藻土10-14、2-巯基苯并咪唑0.3-1、氟化钙2-3、苯乙烯140-200、丙烯酸甲酯150-200、丙烯酸10-20、过硫酸铵4-6、OP-10 6-8、粘结助剂4-5、油酸聚氧乙烯酯1-2、去离子水500-600；
所述的粘结助剂是由下述重量份的各原料组成的：
铝溶胶20-30、硫酸铝铵1-3、羊毛脂1-2、聚乙二醇二甲基丙烯酸酯0.6-1、无水乙醇3-4、丙烯酸甲酯2-4、过硫酸钾2-3、乳化剂OP-100.5-1、香樟木微粉2-4、去离子水15-20；
将无水乙醇加热到70-75℃，加入羊毛脂，搅拌均匀，得醇脂溶液；
将香樟木微粉加入到铝溶胶中，加入聚乙二醇二甲基丙烯酸酯，升高温度为55-60℃，100-200转/分搅拌分散3-5分钟，得分散液；
将过硫酸钾与丙烯酸甲酯混合，在60-70℃下搅拌混合2-3分钟，加入分散液，搅拌至常温，加入上述醇脂溶液，60-100转/分搅拌混合5-10分钟，加入剩余各原料，200-400转/分搅拌分散3-5分钟，即得所述粘结助剂。
一种耐候型硬质涂料的制备方法，其特征在于包括以下步骤：
（1）取上述苯乙烯重量的90%、丙烯酸甲酯重量的90%、丙烯酸异辛酯、丙烯酸混合，得单体a；
（2）取OP-10，加入上述去离子水重量的40%，搅拌均匀，得预乳液；
（3）取过硫酸铵，加入剩余去离子水重量的20%，搅拌均匀，得引发剂溶液；
（4）取上述单体a、预乳液重量的50%、引发剂溶液重量的60%，混合，加入硫酸氢钾，在80℃下保温搅拌20分钟，得预混单体；
（5）将剩余的苯乙烯、丙烯酸甲酯混合，搅拌均匀后加入油酸聚氧乙烯酯、单丁基氧化锡，在60℃下保温搅拌20分钟，冷却至常温，得改性单体；
（6）将上述改性单体与剩余的预乳液、剩余的引发剂溶液混合，90℃下保温搅拌50分钟，滴加上述预混单体，滴加时间为2小时，滴加完毕后在85℃下保温3小时，降低温度至50℃，调节pH 值至8，用250 目过滤筛过滤；
（7）将上述步骤（6）得到的物料与剩余各原料混合，1200转/分搅拌分散20-30分钟，即得所述耐候型硬质涂料。
性能测试：
延伸率：≥300％ ；
不透水性：0.3MPa( 一个小时不透水)。

Claims (2)

1.一种耐候型硬质涂料，其特征在于它是由下述重量份的原料组成的：
聚双环戊二烯2-3、偏钒酸铵1-2、硫酸氢钾1-2、甲基膦酸二甲酯2-3、二茂铁甲酸0.7-1、单丁基氧化锡0.6-1、丙烯酸异辛酯2-3、纳米硅藻土10-14、2-巯基苯并咪唑0.3-1、氟化钙2-3、苯乙烯140-200、丙烯酸甲酯150-200、丙烯酸10-20、过硫酸铵4-6、OP-10 6-8、粘结助剂4-5、油酸聚氧乙烯酯1-2、去离子水500-600；
所述的粘结助剂是由下述重量份的各原料组成的：
铝溶胶20-30、硫酸铝铵1-3、羊毛脂1-2、聚乙二醇二甲基丙烯酸酯0.6-1、无水乙醇3-4、丙烯酸甲酯2-4、过硫酸钾2-3、乳化剂OP-100.5-1、香樟木微粉2-4、去离子水15-20；
将无水乙醇加热到70-75℃，加入羊毛脂，搅拌均匀，得醇脂溶液；
将香樟木微粉加入到铝溶胶中，加入聚乙二醇二甲基丙烯酸酯，升高温度为55-60℃，100-200转/分搅拌分散3-5分钟，得分散液；
将过硫酸钾与丙烯酸甲酯混合，在60-70℃下搅拌混合2-3分钟，加入分散液，搅拌至常温，加入上述醇脂溶液，60-100转/分搅拌混合5-10分钟，加入剩余各原料，200-400转/分搅拌分散3-5分钟，即得所述粘结助剂。
2.一种如权利要求1所述的耐候型硬质涂料的制备方法，其特征在于包括以下步骤：
（1）取上述苯乙烯重量的80-90%、丙烯酸甲酯重量的80-90%、丙烯酸异辛酯、丙烯酸混合，得单体a；
（2）取OP-10，加入上述去离子水重量的30-40%，搅拌均匀，得预乳液；
（3）取过硫酸铵，加入剩余去离子水重量的10-20%，搅拌均匀，得引发剂溶液；
（4）取上述单体a、预乳液重量的40-50%、引发剂溶液重量的50-60%，混合，加入硫酸氢钾，在75-80℃下保温搅拌10-20分钟，得预混单体；
（5）将剩余的苯乙烯、丙烯酸甲酯混合，搅拌均匀后加入油酸聚氧乙烯酯、单丁基氧化锡，在50-60℃下保温搅拌10-20分钟，冷却至常温，得改性单体；
（6）将上述改性单体与剩余的预乳液、剩余的引发剂溶液混合，70-90℃下保温搅拌30-50分钟，滴加上述预混单体，滴加时间为2-3小时，滴加完毕后在80-85℃下保温2-3小时，降低温度至40-50℃，调节pH 值至7-8，用200-250 目过滤筛过滤；
（7）将上述步骤（6）得到的物料与剩余各原料混合，800-1200转/分搅拌分散20-30分钟，即得所述耐候型硬质涂料。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105968999A (zh) * 2016-03-01 2016-09-28 阜阳市金木工艺品有限公司 一种木器乳化涂料及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102268208A (zh) * 2011-06-02 2011-12-07 沈阳顺风新城建筑材料有限公司 一种纳米硅溶胶改性外墙乳胶漆及其制备方法
CN102399483A (zh) * 2011-12-22 2012-04-04 华南理工大学 有机/无机复合型隔热保温水性建筑涂料及其制备方法
CN102604003A (zh) * 2012-03-14 2012-07-25 大连工业大学 一种自分层有机-无机纳米复合乳液及其制备方法
CN102993792A (zh) * 2012-10-15 2013-03-27 怀远县巨龙机械制造有限公司 一种高光泽金属防锈漆及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102268208A (zh) * 2011-06-02 2011-12-07 沈阳顺风新城建筑材料有限公司 一种纳米硅溶胶改性外墙乳胶漆及其制备方法
CN102399483A (zh) * 2011-12-22 2012-04-04 华南理工大学 有机/无机复合型隔热保温水性建筑涂料及其制备方法
CN102604003A (zh) * 2012-03-14 2012-07-25 大连工业大学 一种自分层有机-无机纳米复合乳液及其制备方法
CN102993792A (zh) * 2012-10-15 2013-03-27 怀远县巨龙机械制造有限公司 一种高光泽金属防锈漆及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105968999A (zh) * 2016-03-01 2016-09-28 阜阳市金木工艺品有限公司 一种木器乳化涂料及其制备方法

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