CN104250441A - 一种pa66用阻燃增韧剂及由其制备的阻燃增韧pa66材料 - Google Patents
一种pa66用阻燃增韧剂及由其制备的阻燃增韧pa66材料 Download PDFInfo
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- CN104250441A CN104250441A CN201410304436.XA CN201410304436A CN104250441A CN 104250441 A CN104250441 A CN 104250441A CN 201410304436 A CN201410304436 A CN 201410304436A CN 104250441 A CN104250441 A CN 104250441A
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- 229920002302 Nylon 6,6 Polymers 0.000 title claims abstract description 71
- 239000000463 material Substances 0.000 title claims abstract description 47
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 25
- 239000012745 toughening agent Substances 0.000 title abstract 4
- 239000012757 flame retardant agent Substances 0.000 title abstract 3
- 239000003063 flame retardant Substances 0.000 claims abstract description 81
- 239000002994 raw material Substances 0.000 claims abstract description 19
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 38
- 239000011521 glass Substances 0.000 claims description 38
- 239000002131 composite material Substances 0.000 claims description 35
- 239000000843 powder Substances 0.000 claims description 35
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 25
- 229910052799 carbon Inorganic materials 0.000 claims description 25
- 229910052802 copper Inorganic materials 0.000 claims description 25
- 239000010949 copper Substances 0.000 claims description 25
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 24
- 238000007710 freezing Methods 0.000 claims description 22
- 230000008014 freezing Effects 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000003963 antioxidant agent Substances 0.000 claims description 19
- 230000003078 antioxidant effect Effects 0.000 claims description 19
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 18
- 235000019353 potassium silicate Nutrition 0.000 claims description 14
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 14
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 12
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 12
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 claims description 10
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 10
- VUTSITSGGYCKFP-UHFFFAOYSA-J [C+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O Chemical compound [C+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VUTSITSGGYCKFP-UHFFFAOYSA-J 0.000 claims description 10
- 239000002041 carbon nanotube Substances 0.000 claims description 10
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 10
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 10
- 239000002048 multi walled nanotube Substances 0.000 claims description 10
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 8
- -1 Polyoxyethylene nonylphenol Polymers 0.000 claims description 8
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical compound [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 claims description 8
- 239000003365 glass fiber Substances 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 239000013078 crystal Substances 0.000 claims description 5
- 229960004756 ethanol Drugs 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 abstract 2
- 231100000053 low toxicity Toxicity 0.000 abstract 2
- 230000000694 effects Effects 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 238000011056 performance test Methods 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000005452 bending Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 229960001866 silicon dioxide Drugs 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- 231100000518 lethal Toxicity 0.000 description 3
- 230000001665 lethal effect Effects 0.000 description 3
- 239000002990 reinforced plastic Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 206010016275 Fear Diseases 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000001246 bromo group Chemical class Br* 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 1
- 230000000176 photostabilization Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
性质 | 方法 | 单位 | 数据 |
比重 | ASTMD792 | — | 1.28 |
模收缩 | ASTMD955 | % | 0.1-0.7 |
延伸率 | ASTMD638 | % | 30 |
拉伸强度 | ASTMD638 | Mpa | 92 |
弯曲强度 | ASTMD790 | Mpa | 98 |
弯曲模数 | ASTMD790 | Mpa | 3500 |
缺口冲击强度(1/8") | ASTMD256 | KJ/M2 | 12 |
热变形温度(1.8Mpa) | ASTMD648 | ℃ | 60 |
热变形温度(0.45Mpa) | ASTMD648 | ℃ | 75 |
耐燃性 | UL94 | (1/16") | V0 |
干燥时间 | — | HR | 4 |
熔融温度 | — | ℃ | 230-270 |
建议模温 | — | ℃ | 120 |
性质 | 方法 | 单位 | 数据 |
比重 | ASTMD792 | — | 1.28 |
模收缩 | ASTMD955 | % | 0.1-0.7 |
延伸率 | ASTMD638 | % | 30 |
拉伸强度 | ASTMD638 | Mpa | 73 |
弯曲强度 | ASTMD790 | Mpa | 87 |
弯曲模数 | ASTMD790 | Mpa | 2590 |
缺口冲击强度(1/8") | ASTMD256 | KJ/M2 | 8 |
热变形温度(1.8Mpa) | ASTMD648 | ℃ | 60 |
热变形温度(0.45Mpa) | ASTMD648 | ℃ | 75 |
耐燃性 | UL94 | (1/16") | V0 |
干燥时间 | — | HR | 4 |
熔融温度 | — | ℃ | 230-270 |
建议模温 | — | ℃ | 120 |
性质 | 方法 | 单位 | 数据 |
比重 | ASTMD792 | — | 1.28 |
模收缩 | ASTMD955 | % | 0.1-0.7 |
延伸率 | ASTMD638 | % | 30 |
拉伸强度 | ASTMD638 | Mpa | 62 |
弯曲强度 | ASTMD790 | Mpa | 76 |
弯曲模数 | ASTMD790 | Mpa | 2500 |
缺口冲击强度(1/8") | ASTMD256 | KJ/M2 | 8 |
热变形温度(1.8Mpa) | ASTMD648 | ℃ | 60 |
热变形温度(0.45Mpa) | ASTMD648 | ℃ | 75 |
耐燃性 | UL94 | (1/16") | HB |
干燥时间 | — | HR | 4 |
熔融温度 | — | ℃ | 230-270 |
建议模温 | — | ℃ | 120 |
性质 | 方法 | 单位 | 数据 |
比重 | ASTMD792 | — | 1.28 |
模收缩 | ASTMD955 | % | 0.1-0.7 |
延伸率 | ASTMD638 | % | 30 |
拉伸强度 | ASTMD638 | Mpa | 73 |
弯曲强度 | ASTMD790 | Mpa | 88 |
弯曲模数 | ASTMD790 | Mpa | 2590 |
缺口冲击强度(1/8") | ASTMD256 | KJ/M2 | 7 |
热变形温度(1.8Mpa) | ASTMD648 | ℃ | 60 |
热变形温度(0.45Mpa) | ASTMD648 | ℃ | 75 |
耐燃性 | UL94 | (1/16") | V0 |
干燥时间 | — | HR | 4 |
熔融温度 | — | ℃ | 230-270 |
建议模温 | — | ℃ | 120 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410304436.XA CN104250441B (zh) | 2014-06-30 | 2014-06-30 | 一种pa66用阻燃增韧剂及由其制备的阻燃增韧pa66材料 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410304436.XA CN104250441B (zh) | 2014-06-30 | 2014-06-30 | 一种pa66用阻燃增韧剂及由其制备的阻燃增韧pa66材料 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104250441A true CN104250441A (zh) | 2014-12-31 |
CN104250441B CN104250441B (zh) | 2017-12-01 |
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CN201410304436.XA Active CN104250441B (zh) | 2014-06-30 | 2014-06-30 | 一种pa66用阻燃增韧剂及由其制备的阻燃增韧pa66材料 |
Country Status (1)
Country | Link |
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CN (1) | CN104250441B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110148813A (zh) * | 2019-04-30 | 2019-08-20 | 苏州宇量电池有限公司 | 一种应用于锂电池的安全防护材料 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101104736A (zh) * | 2006-07-11 | 2008-01-16 | 上海普利特复合材料有限公司 | 一种阻燃增强型pa66组合物 |
CN101475707A (zh) * | 2009-01-22 | 2009-07-08 | 北京华腾工程新材料有限责任公司 | 用于pa66工程塑料制备中的无卤阻燃体系以及一种pa66复合材料及其制备方法 |
US20090318594A1 (en) * | 2006-08-25 | 2009-12-24 | Sachtleben Chemie Gmbh | Barium sulfate-containing composite |
-
2014
- 2014-06-30 CN CN201410304436.XA patent/CN104250441B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101104736A (zh) * | 2006-07-11 | 2008-01-16 | 上海普利特复合材料有限公司 | 一种阻燃增强型pa66组合物 |
US20090318594A1 (en) * | 2006-08-25 | 2009-12-24 | Sachtleben Chemie Gmbh | Barium sulfate-containing composite |
CN101475707A (zh) * | 2009-01-22 | 2009-07-08 | 北京华腾工程新材料有限责任公司 | 用于pa66工程塑料制备中的无卤阻燃体系以及一种pa66复合材料及其制备方法 |
Non-Patent Citations (1)
Title |
---|
邵会菊等: "接枝POE增韧尼龙6的性能", 《塑料》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110148813A (zh) * | 2019-04-30 | 2019-08-20 | 苏州宇量电池有限公司 | 一种应用于锂电池的安全防护材料 |
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