CN104194595A - Acrylic polyurethane alkyd resin orange peel coating - Google Patents
Acrylic polyurethane alkyd resin orange peel coating Download PDFInfo
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- CN104194595A CN104194595A CN201410435953.0A CN201410435953A CN104194595A CN 104194595 A CN104194595 A CN 104194595A CN 201410435953 A CN201410435953 A CN 201410435953A CN 104194595 A CN104194595 A CN 104194595A
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- synolac
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- maleic anhydride
- acroleic acid
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Abstract
The invention relates to an acrylic polyurethane alkyd resin orange peel coating which is prepared from the following raw materials in parts by weight: 100 parts of alkyd resin, 5-15 parts of diethylene glycol, 35-45 parts of methyl methacrylate, 20-30 parts of propylene glycol, 25-45 parts of benzoyl peroxide, 30-40 parts of maleic anhydride, 25-35 parts of sunflower seed oil, 15-35 parts of isopropanol, 20-30 parts of pigments and filler, 1-10 parts of methyl ethyl ketone, 5-25 parts of trimethylolpropane, 10-30 parts of silicone, 30-40 parts of flexibilizer, 5-15 parts of maleic anhydride, 10-20 parts of phthalic anhydride and 15-25 parts of hydroquinone. The glossiness of the film is 98-100, the hardness is 0.8-1, the flexibility is 1mm, the adhesive force is level 1, the tack-free time is 0.1-0.3 hour, the hard dry time is 0.4-1.4 hours, and the water resistance is 10-20 days. The coating can be widely produced and continuously replaces existing materials.
Description
Technical field
The application belongs to paint field, relates in particular to a kind of acroleic acid polyurethane Synolac tangerine line coating.
Background technology
Coating, in China, tradition name is called paint.So-called coating is to be coated in protected or decorated body surface; and can form with coated article the continuous film of firm attachment; normally take resin or oil or emulsion as main; add or do not add color stuffing, filler; add corresponding additive, with organic solvent or the formulated thick liquid of benzoyl peroxide.China's coating circle more authoritative < < coating process > > mono-book is definition like this: " coating is a kind of material; this material can be coated in article surface by different construction technologies, forms and adheres to firmly, has some strength, continuous solid film.The film common name forming is like this filmed, and claims again paint film or coating." paint finishing can and form the material of complete and tough and tensile protective membrane with the fine bonding of body material in body surface, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, introduces after China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.Coating refers to the general name that is applied to body surface and can forms the material of tough and tensile protective membrane, and building coating is an important class in coating, in China, generally will be for inner wall of building, and exterior wall, ceiling, ground, the coating of toilet is called building coating.
Coating, is to be applied to body surface can form and have protection, decoration or property a solid-state class I liquid I of filming of (as insulation, anticorrosion, sign etc.) or the general name of solid material, comprises oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint is to take machine solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is that used water is dissolved or with the coating of water-dispersion.Coating is as one of main material of house decoration, and the large percentage accounting in decorations is bought the whether qualified environment that directly has influence on whole finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.
So-called acroleic acid polyurethane Synolac tangerine line coating is comprised of inconsistent two phase compositions, and wherein a phase dispersion medium is external phase, and another is disperse phase mutually, during application, by disposable spray finishing, just can obtain luxurious, attractive in appearance, colorful pattern.Acroleic acid polyurethane Synolac tangerine line coating is again acroleic acid polyurethane Synolac tangerine line paint, acroleic acid polyurethane Synolac tangerine line paint; Acroleic acid polyurethane Synolac tangerine line coating is the coating variety with special usefulness consisting of speciality coating; it is a kind of industrial finish; the same with other coating; this coating is coated in to body surface and can plays the provide protection to various objects; after different are its coating film forming; painting face meeting self-assembling formation and the natural various beautiful patterns of appearance, as mallear stria, wrinkle, tangerine line, bag, speckle, crystallized, crackle, wood grain etc.And universal along with humanity concept, and the formation of novel harmonious society, designs that a kind of glossiness is high, fast drying and hardness and the good acroleic acid polyurethane Synolac tangerine line coating of snappiness is very important.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of acroleic acid polyurethane Synolac tangerine line coating, the technical problem such as solve existing acroleic acid polyurethane Synolac tangerine line coating gloss degree, hardness and snappiness is low, dry slow, sticking power is low.
Technical scheme:
An acroleic acid polyurethane Synolac tangerine line coating, the raw materials by weight portion proportioning of described acroleic acid polyurethane Synolac tangerine line coating is as follows: 100 parts of Synolac; Glycol ether 5-15 part; Methyl methacrylate 35-45 part; Propylene glycol 20-30 part; Benzoyl peroxide 25-45 part; MALEIC ANHYDRIDE 30-40 part; Sunflower seed oil 25-35 part; Virahol 15-35 part; Color stuffing 20-30 part; Methylethylketone 1-10 part; TriMethylolPropane(TMP) 5-25 part; Silicone 10-30 part; Toughner 30-40 part; MALEIC ANHYDRIDE 5-15 part; Phthalic anhydride 10-20 part; Resorcinol 15-25 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described acroleic acid polyurethane Synolac tangerine line coating is as follows: 100 parts of Synolac; 10 parts of glycol ethers; 40 parts of methyl methacrylates; 25 parts of propylene glycol; 35 parts of benzoyl peroxides; 35 parts of MALEIC ANHYDRIDE; 30 parts of sunflower seed oils; 25 parts of Virahols; 25 parts of color stuffings; 5 parts of methylethylketones; 15 parts of TriMethylolPropane(TMP)s; 20 parts of silicone; 35 parts of toughner; 10 parts of MALEIC ANHYDRIDE; 15 parts of phthalic anhydrides; 20 parts of Resorcinol.
As a preferred technical solution of the present invention: described color stuffing adopts carbon black, lemon yellow or iron oxide red.
As a preferred technical solution of the present invention: described toughner adopts styrene-butadiene-styrene.
Beneficial effect:
A kind of acroleic acid polyurethane Synolac tangerine line coating of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, coating film gloss degree 98-100, hardness 0.8-1; 2, snappiness 1mm, adhesion 1 grade; 3, surface drying 0.1-0.3h, does solid work 0.4-1.4h; 4, water tolerance 10-20d, can the not division of history into periods of widespread production replace current material.
Embodiment
Embodiment 1:
An acroleic acid polyurethane Synolac tangerine line coating, its raw materials by weight portion proportioning is as follows: 100 parts of Synolac; 5 parts of glycol ethers; 35 parts of methyl methacrylates; 20 parts of propylene glycol; 25 parts of benzoyl peroxides; 30 parts of MALEIC ANHYDRIDE; 25 parts of sunflower seed oils; 15 parts of Virahols; 20 parts of carbon blacks; 1 part of methylethylketone; 5 parts of TriMethylolPropane(TMP)s; 10 parts of silicone; 30 parts of styrene-butadiene-styrenes; 5 parts of MALEIC ANHYDRIDE; 10 parts of phthalic anhydrides; 15 parts of Resorcinol.
Under normal temperature, Synolac, glycol ether, methyl methacrylate and propylene glycol are added in reactor, after stirring 10min, add benzoyl peroxide, MALEIC ANHYDRIDE and sunflower seed oil, after stirring 20min, be warming up to 90 ℃ and add surplus stock, after stirring, drop into sand mill and grind 30min, cooling and filter after both finished product.
Coating film gloss degree 98, hardness 0.8; Surface drying 0.3h, does solid work 1.4h, water tolerance 10d.
Embodiment 2:
An acroleic acid polyurethane Synolac tangerine line coating, its raw materials by weight portion proportioning is as follows: 100 parts of Synolac; 15 parts of glycol ethers; 45 parts of methyl methacrylates; 30 parts of propylene glycol; 45 parts of benzoyl peroxides; 40 parts of MALEIC ANHYDRIDE; 35 parts of sunflower seed oils; 35 parts of Virahols; 30 parts of lemon yellows; 10 parts of methylethylketones; 25 parts of TriMethylolPropane(TMP)s; 30 parts of silicone; 40 parts of styrene-butadiene-styrenes; 15 parts of MALEIC ANHYDRIDE; 20 parts of phthalic anhydrides; 25 parts of Resorcinol.
Under normal temperature, Synolac, glycol ether, methyl methacrylate and propylene glycol are added in reactor, after stirring 10min, add benzoyl peroxide, MALEIC ANHYDRIDE and sunflower seed oil, after stirring 20min, be warming up to 90 ℃ and add surplus stock, after stirring, drop into sand mill and grind 30min, cooling and filter after both finished product.
Coating film gloss degree 99, hardness 0.9; Surface drying 0.2h, does solid work 0.8h, water tolerance 15d.
Embodiment 3:
An acroleic acid polyurethane Synolac tangerine line coating, its raw materials by weight portion proportioning is as follows: 100 parts of Synolac; 10 parts of glycol ethers; 40 parts of methyl methacrylates; 25 parts of propylene glycol; 35 parts of benzoyl peroxides; 35 parts of MALEIC ANHYDRIDE; 30 parts of sunflower seed oils; 25 parts of Virahols; 25 parts of iron oxide reds; 5 parts of methylethylketones; 15 parts of TriMethylolPropane(TMP)s; 20 parts of silicone; 35 parts of styrene-butadiene-styrenes; 10 parts of MALEIC ANHYDRIDE; 15 parts of phthalic anhydrides; 20 parts of Resorcinol.
Under normal temperature, Synolac, glycol ether, methyl methacrylate and propylene glycol are added in reactor, after stirring 10min, add benzoyl peroxide, MALEIC ANHYDRIDE and sunflower seed oil, after stirring 20min, be warming up to 90 ℃ and add surplus stock, after stirring, drop into sand mill and grind 30min, cooling and filter after both finished product.
Coating film gloss degree 100, hardness 1; Surface drying 0.1h, does solid work 0.4h, water tolerance 20d.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, rather than restriction, therefore in the implication suitable with claims of the present invention and any change in scope, all should think to be included in the scope of claims.
Claims (4)
1. an acroleic acid polyurethane Synolac tangerine line coating, is characterized in that the raw materials by weight portion proportioning of described acroleic acid polyurethane Synolac tangerine line coating is as follows: 100 parts of Synolac; Glycol ether 5-15 part; Methyl methacrylate 35-45 part; Propylene glycol 20-30 part; Benzoyl peroxide 25-45 part; MALEIC ANHYDRIDE 30-40 part; Sunflower seed oil 25-35 part; Virahol 15-35 part; Color stuffing 20-30 part; Methylethylketone 1-10 part; TriMethylolPropane(TMP) 5-25 part; Silicone 10-30 part; Toughner 30-40 part; MALEIC ANHYDRIDE 5-15 part; Phthalic anhydride 10-20 part; Resorcinol 15-25 part.
2. a kind of acroleic acid polyurethane Synolac tangerine line coating according to claim 1, is characterized in that the raw materials by weight portion proportioning of described acroleic acid polyurethane Synolac tangerine line coating is as follows: 100 parts of Synolac; 10 parts of glycol ethers; 40 parts of methyl methacrylates; 25 parts of propylene glycol; 35 parts of benzoyl peroxides; 35 parts of MALEIC ANHYDRIDE; 30 parts of sunflower seed oils; 25 parts of Virahols; 25 parts of color stuffings; 5 parts of methylethylketones; 15 parts of TriMethylolPropane(TMP)s; 20 parts of silicone; 35 parts of toughner; 10 parts of MALEIC ANHYDRIDE; 15 parts of phthalic anhydrides; 20 parts of Resorcinol.
3. a kind of acroleic acid polyurethane Synolac tangerine line coating according to claim 1, is characterized in that: described color stuffing adopts carbon black, lemon yellow or iron oxide red.
4. a kind of acroleic acid polyurethane Synolac tangerine line coating according to claim 1, is characterized in that: described toughner adopts styrene-butadiene-styrene.
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CN201410435953.0A CN104194595A (en) | 2014-08-29 | 2014-08-29 | Acrylic polyurethane alkyd resin orange peel coating |
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CN201410435953.0A CN104194595A (en) | 2014-08-29 | 2014-08-29 | Acrylic polyurethane alkyd resin orange peel coating |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1092445A (en) * | 1993-03-15 | 1994-09-21 | 河南省新乡市建筑材料科学研究所 | A kind of multi colour stereo pattern paint |
CN103468106A (en) * | 2013-09-26 | 2013-12-25 | 天津灯塔涂料工业发展有限公司 | Alcohol acid ripple finish and preparation method thereof |
CN103627307A (en) * | 2013-11-22 | 2014-03-12 | 广州贝客音涂料有限公司 | Coating capable of achieving orange grain/ripple effect and preparation method of coating |
-
2014
- 2014-08-29 CN CN201410435953.0A patent/CN104194595A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1092445A (en) * | 1993-03-15 | 1994-09-21 | 河南省新乡市建筑材料科学研究所 | A kind of multi colour stereo pattern paint |
CN103468106A (en) * | 2013-09-26 | 2013-12-25 | 天津灯塔涂料工业发展有限公司 | Alcohol acid ripple finish and preparation method thereof |
CN103627307A (en) * | 2013-11-22 | 2014-03-12 | 广州贝客音涂料有限公司 | Coating capable of achieving orange grain/ripple effect and preparation method of coating |
Non-Patent Citations (1)
Title |
---|
夏宇正等: "《涂料最新生产技术与配方》", 31 October 2009, article "一种丙烯酸氨基醇酸树脂橘纹漆", pages: 90 * |
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