CN104194521A - Ceramic-like multicolor paint - Google Patents

Ceramic-like multicolor paint Download PDF

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Publication number
CN104194521A
CN104194521A CN201410437572.6A CN201410437572A CN104194521A CN 104194521 A CN104194521 A CN 104194521A CN 201410437572 A CN201410437572 A CN 201410437572A CN 104194521 A CN104194521 A CN 104194521A
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China
Prior art keywords
parts
enamel
imitating
paint
multicolour
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CN201410437572.6A
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Chinese (zh)
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CN104194521B (en
Inventor
费金华
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Suzhou Shengpula New Material Technology Co Ltd
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Suzhou Shengpula New Material Technology Co Ltd
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Abstract

The invention relates to a ceramic-like multicolor paint which is prepared from the following raw materials in parts by weight: 100 parts of polyvinyl alcohol, 15-25 parts of white cement, 30-40 parts of formaldehyde, 35-45 parts of dichloroethylene, 25-45 parts of urea, 20-40 parts of sodium bicarbonate, 80-90 parts of deionized water, 5-15 parts of hexahydrooxymethyl melamine, 10-20 parts of pigment, 15-35 parts of allyl alcohol, 25-35 parts of glass powder, 10-20 parts of trihydroxy propane triacrylate, 8-10 parts of plasticizer, 10-30 parts of benzoin aether, 20-30 parts of tung oil and 5-25 parts of hydroquinone monomethyl ether. The scrub resistance of the coated film is 2000-3000 times; and after being immersed in water for 30-50 days, the paint does not blister or wrinkle. The surface drying time is 0.5-1.5 hours, and the solid drying time is 18-20 hours; and after being immersed in a saturated calcium hydroxide solution for 10-30 days, the paint does not give out powder or shed. The coated film has bright color, the adhesive force is 100%, and the paint can be widely produced and continuously substituted for the existing materials.

Description

A kind of enamel-imitating multicolour paint
Technical field
The application belongs to paint field, relates in particular to a kind of enamel-imitating multicolour paint.
Background technology
Coating, in China, tradition name is called paint.So-called coating is to be coated in protected or decorated body surface; and can form with coated article the continuous film of firm attachment, normally, taking resin or oil or emulsion as main, add or do not add pigment, filler; add corresponding additive, with organic solvent or the formulated thick liquid of urea.China's coating circle more authoritative " coating process " book is definition like this: " coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms and adheres to firmly, has some strength, continuous solid film.The film common name film forming like this, claims again paint film or coating." paint finishing can and form the material of complete and tough and tensile protective membrane with the fine bonding of body material in body surface, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, introduces after China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.
Coating refers to the general name that is applied to body surface and can form the material of tough and tensile protective membrane, and building coating is an important class in coating, in China, generally will be used for inner wall of building, exterior wall, and ceiling, ground, the coating of toilet is called building coating.Porcelain-imitated coating claims again ceramic glaze paint, is the building coating that a kind of decorative effect exactly likes enamel facing.Porcelain-imitated coating application surface is extensive.Can carry out mopping and spraying at solid surface such as cement surface, metal covering, plastic cover, timber.Can be used for interior wall, kitchen, toilet, the bathroom joining place of public building interior wall, house, also can be used for the anticorrosion of electrical equipment, machinery and furniture appearance decoration.
So-called enamel-imitating multicolour paint is made up of inconsistent two phase compositions, and wherein a phase dispersion medium is external phase, and another is disperse phase mutually, when application, by disposable spray finishing, just can obtain luxurious, attractive in appearance, colorful pattern.Its main film forming substance of solvent type resin class is solvent type resin, comprise that cold cross-linking curing dual-component polyurethane resin, bi-component acrylic-urethane resin, single-component organic silicon are acrylic resin modified etc., and in addition pigment, solvent, auxiliary agent and formulated porcelain is white, the coating with enamel gloss of pale blue, milk Huang, the multiple color such as pink.Its paint film light, hard, plentiful, exactly likes enamel, have excellent water tolerance, alkali resistance, wear resistance, ageing resistance, and sticking power is extremely strong.And universal along with humanity concept, and the formation of novel harmonious society, the enamel-imitating multicolour paint that designs a kind of water tolerance, scrub resistance and alkali resistance excellence is very important.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of enamel-imitating multicolour paint, solve existing enamel-imitating multicolour paint water tolerance and scrub resistance is poor, dry slowly, the technical problem such as alkali corrosion resistance not.
Technical scheme:
A kind of enamel-imitating multicolour paint, the raw materials by weight portion proportioning of described enamel-imitating multicolour paint is as follows: 100 parts of polyvinyl alcohol; White cement 15-25 part; Formaldehyde 30-40 part; Ethylene Dichloride 35-45 part; Urea 25-45 part; Sodium bicarbonate 20-40 part; Deionized water 80-90 part; Six hydrogen-oxygen methyl melamine 5-15 parts; Pigment 10-20 part; Vinyl carbinol 15-35 part; Glass powder 25-35 part; Glycerin triacrylate 10-20 part; Softening agent 8-10 part; Benzoin ethyl ether 10-30 part; Tung oil 20-30 part; Hydroquinone monomethyl ether 5-25 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described enamel-imitating multicolour paint is as follows: 100 parts of polyvinyl alcohol; 20 parts of white cements; 35 parts, formaldehyde; 40 parts of Ethylene Dichloride; 35 parts, urea; 30 parts of sodium bicarbonates; 85 parts of deionized waters; Six 10 parts of hydrogen-oxygen methyl melamines; 15 parts of pigment; 25 parts of vinyl carbinols; 30 parts, glass powder; 15 parts of Glycerin triacrylates; 9 parts, softening agent; 20 parts of Benzoin ethyl ethers; 25 parts of tung oil; 15 parts of hydroquinone monomethyl ethers.
As a preferred technical solution of the present invention: described pigment adopts medium chrome yellow medium yellow, iron oxide green or iron oxide black.
As a preferred technical solution of the present invention: described softening agent adopts dibutyl phthalate.
Beneficial effect:
A kind of enamel-imitating multicolour paint of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, film scrubbing resistance 2000-3000 time, in water, soak non-foaming after 30-50d, elephant skin not; 2, surface drying 0.5-1.5h, does solid work 18-20h, in saturated aqua calcis, soak 10-30d not dry linting, do not come off; 3, film is bright in luster, and sticking power 100% can the not division of history into periods of widespread production replace current material.
Embodiment
Embodiment 1:
A kind of enamel-imitating multicolour paint, its raw materials by weight portion proportioning is as follows: 100 parts of polyvinyl alcohol; 15 parts of white cements; 30 parts, formaldehyde; 35 parts of Ethylene Dichloride; 25 parts, urea; 20 parts of sodium bicarbonates; 80 parts of deionized waters; Six 5 parts of hydrogen-oxygen methyl melamines; 10 parts of medium chrome yellow medium yellows; 15 parts of vinyl carbinols; 25 parts, glass powder; 10 parts of Glycerin triacrylates; 8 parts of dibutyl phthalates; 10 parts of Benzoin ethyl ethers; 20 parts of tung oil; 5 parts of hydroquinone monomethyl ethers.
Polyvinyl alcohol, formaldehyde, Ethylene Dichloride, urea and sodium bicarbonate are added in deionized water, be heated to 40 DEG C and stir 3h, add six hydrogen-oxygen methyl melamines, vinyl carbinol, glass powder, Glycerin triacrylate, tung oil and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add white cement and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Film scrubbing resistance 2000 times is soaked non-foaming after 30d, elephant skin not in water; Surface drying 1.5h, does solid work 20h, in saturated aqua calcis, soak 10d not dry linting, do not come off.
Embodiment 2:
A kind of enamel-imitating multicolour paint, its raw materials by weight portion proportioning is as follows: 100 parts of polyvinyl alcohol; 25 parts of white cements; 40 parts, formaldehyde; 45 parts of Ethylene Dichloride; 45 parts, urea; 40 parts of sodium bicarbonates; 90 parts of deionized waters; Six 15 parts of hydrogen-oxygen methyl melamines; 20 parts of iron oxide greens; 35 parts of vinyl carbinols; 35 parts, glass powder; 20 parts of Glycerin triacrylates; 10 parts of dibutyl phthalates; 30 parts of Benzoin ethyl ethers; 30 parts of tung oil; 25 parts of hydroquinone monomethyl ethers.
Polyvinyl alcohol, formaldehyde, Ethylene Dichloride, urea and sodium bicarbonate are added in deionized water, be heated to 40 DEG C and stir 3h, add six hydrogen-oxygen methyl melamines, vinyl carbinol, glass powder, Glycerin triacrylate, tung oil and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add white cement and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Film scrubbing resistance 2500 times is soaked non-foaming after 40d, elephant skin not in water; Surface drying 1h, does solid work 19h, in saturated aqua calcis, soak 20d not dry linting, do not come off.
Embodiment 3:
A kind of enamel-imitating multicolour paint, its raw materials by weight portion proportioning is as follows: 100 parts of polyvinyl alcohol; 20 parts of white cements; 35 parts, formaldehyde; 40 parts of Ethylene Dichloride; 35 parts, urea; 30 parts of sodium bicarbonates; 85 parts of deionized waters; Six 10 parts of hydrogen-oxygen methyl melamines; 15 parts of iron oxide blacks; 25 parts of vinyl carbinols; 30 parts, glass powder; 15 parts of Glycerin triacrylates; 9 parts of dibutyl phthalates; 20 parts of Benzoin ethyl ethers; 25 parts of tung oil; 15 parts of hydroquinone monomethyl ethers.
Polyvinyl alcohol, formaldehyde, Ethylene Dichloride, urea and sodium bicarbonate are added in deionized water, be heated to 40 DEG C and stir 3h, add six hydrogen-oxygen methyl melamines, vinyl carbinol, glass powder, Glycerin triacrylate, tung oil and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add white cement and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Film scrubbing resistance 3000 times is soaked non-foaming after 50d, elephant skin not in water; Surface drying 0.5h, does solid work 18h, in saturated aqua calcis, soak 30d not dry linting, do not come off.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, instead of restriction, and therefore any change in implication and the scope suitable with claims of the present invention, all should think to be included in the scope of claims.

Claims (4)

1. an enamel-imitating multicolour paint, is characterized in that the raw materials by weight portion proportioning of described enamel-imitating multicolour paint is as follows: 100 parts of polyvinyl alcohol; White cement 15-25 part; Formaldehyde 30-40 part; Ethylene Dichloride 35-45 part; Urea 25-45 part; Sodium bicarbonate 20-40 part; Deionized water 80-90 part; Six hydrogen-oxygen methyl melamine 5-15 parts; Pigment 10-20 part; Vinyl carbinol 15-35 part; Glass powder 25-35 part; Glycerin triacrylate 10-20 part; Softening agent 8-10 part; Benzoin ethyl ether 10-30 part; Tung oil 20-30 part; Hydroquinone monomethyl ether 5-25 part.
2. a kind of enamel-imitating multicolour paint according to claim 1, is characterized in that the raw materials by weight portion proportioning of described enamel-imitating multicolour paint is as follows: 100 parts of polyvinyl alcohol; 20 parts of white cements; 35 parts, formaldehyde; 40 parts of Ethylene Dichloride; 35 parts, urea; 30 parts of sodium bicarbonates; 85 parts of deionized waters; Six 10 parts of hydrogen-oxygen methyl melamines; 15 parts of pigment; 25 parts of vinyl carbinols; 30 parts, glass powder; 15 parts of Glycerin triacrylates; 9 parts, softening agent; 20 parts of Benzoin ethyl ethers; 25 parts of tung oil; 15 parts of hydroquinone monomethyl ethers.
3. a kind of enamel-imitating multicolour paint according to claim 1, is characterized in that: described pigment adopts medium chrome yellow medium yellow, iron oxide green or iron oxide black.
4. a kind of enamel-imitating multicolour paint according to claim 1, is characterized in that: described softening agent adopts dibutyl phthalate.
CN201410437572.6A 2014-08-29 2014-08-29 A kind of enamel-imitating multicolour paint Active CN104194521B (en)

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CN104194521B CN104194521B (en) 2016-06-22

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107629553A (en) * 2017-09-07 2018-01-26 广州市优伟家居用品有限公司 A kind of immiscible colored liquid

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1076211A (en) * 1993-04-08 1993-09-15 华东冶金学院 A kind of enamel-imitating multicolour paint and preparation method thereof
CN1112149A (en) * 1993-03-15 1995-11-22 河南省新乡市专利技术开发总公司 Wet-wiping-resistant porcelain-like paint for building
CN103571238A (en) * 2013-11-05 2014-02-12 安徽工贸职业技术学院 Environment-friendly slag dry powder interior wall coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1112149A (en) * 1993-03-15 1995-11-22 河南省新乡市专利技术开发总公司 Wet-wiping-resistant porcelain-like paint for building
CN1076211A (en) * 1993-04-08 1993-09-15 华东冶金学院 A kind of enamel-imitating multicolour paint and preparation method thereof
CN103571238A (en) * 2013-11-05 2014-02-12 安徽工贸职业技术学院 Environment-friendly slag dry powder interior wall coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107629553A (en) * 2017-09-07 2018-01-26 广州市优伟家居用品有限公司 A kind of immiscible colored liquid

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