CN104193292A - Carbon nano tube enhanced ceramic tile - Google Patents
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- CN104193292A CN104193292A CN201410382687.XA CN201410382687A CN104193292A CN 104193292 A CN104193292 A CN 104193292A CN 201410382687 A CN201410382687 A CN 201410382687A CN 104193292 A CN104193292 A CN 104193292A
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Abstract
The invention discloses a carbon nano tube enhanced ceramic tile. The preparation method comprises the following steps: by taking potassium feldspar, albite, Guangxi white clay, attapulgite, mullite, water, carbon nano tubes, sodium tripolyphosphate and steel fibers as blank raw materials and taking feldspar, kaolin, quartz, fired talc, limestone, chromic oxide, pentoxide boron, aluminium oxide, kieselguhr, fused magnesite, zirconium silicate, titanium oxide, zinc oxide, terbium oxide, samarium oxide, lutecia and metal nanoparticles as glaze raw materials, applying the glaze to the surface of a green body by using a glaze spraying or glaze sprinkling mode, thereby obtaining the carbon nano tube enhanced ceramic tile with good mechanical properties. Moreover, the glaze surface of the ceramic tile is attractive and elegant in appearance.
Description
Technical field
The invention belongs to refractory brick field, the ceramic tile that particularly a kind of carbon nanotube strengthens.
Background technology
Along with the develop rapidly of China's Building Ceramics Industry, China is also more and more vigorous for the demand of building ceramics, the ceramic tile field that especially carbon nanotube strengthens.In this field, people also more and more pay attention to the impact of plastics on new materials for the ceramic tile of carbon nanotube enhancing.And by introducing plastics on new materials, can improve external attractive in appearance, inherent physical and chemical performance and the health environment-friendly of the ceramic tile of carbon nanotube enhancing.
And at Material Field, carbon nanotube has good mechanical property, CNTs tensile strength reaches 50～200GPa, is 100 times of steel, and density but only has 1/6 of steel, at least than the high order of magnitude of conventional graphite fibre; Its Young's modulus can reach 1TPa, suitable with adamantine Young's modulus, is about 5 times of steel.For the carbon nanotube of solid wall with ideal structure, the about 800GPa of its tensile strength.Although the structure of carbon nanotube and the structural similitude of macromolecular material, its structure is much more stable than macromolecular material.Carbon nanotube is the material with high specific strength that can prepare at present.If will be taking Other Engineering material as matrix and carbon nanotube make matrix material, can make matrix material show good intensity, elasticity, fatigue resistance and isotropy, bring great improvement to the performance of matrix material.
Hardness and the diamond of carbon nanotube are suitable, but have good snappiness, can stretch.In industrial conventional enhanced fiber, determine that a key factor of intensity is length-to-diameter ratio, i.e. length and diameter ratio.The length-to-diameter ratio that material engineering Shi Xiwang obtains is at least 20:1, and the length-to-diameter ratio of carbon nanotube is generally more than 1000:1, is desirable high tensile strength fibrous material.In October, 2000, the researchist of Pennsylvania State University of the U.S. claims, the intensity of the strength ratio same volume steel of carbon nanotube is high 100 times, and weight but only has the latter's 1/6 to 1/7.Carbon nanotube thereby quilt claim " super fiber ".
Carbon nanotube and nano material are due to its excellent mechanics, electricity and chemical property having, have broad application prospects, carbon nanotube is applied to the emphasis that ceramic field is also present scientists study, by carbon nanotube is referred in alumina-ceramic, can greatly improve mechanical property and the mechanical property of alumina-ceramic.But still be there is to a lot of challenge to the research in the ceramic tile field of carbon nanotube enhancing in carbon nanotube and Application of micron.
Summary of the invention
The object of the invention is for the problems referred to above, develop one carbon nanotube is incorporated into base substrate, nano material is incorporated into the ceramic tile of the carbon nanotube enhancing of glaze,
Base substrate weight part consists of:
10 ~ 45 parts of potassium felspar sands; 10 ~ 20 parts of albites; 15～20 parts of Guangxi white claies; 30～50 parts of attapulgites; 20 ~ 30 parts of mullites; 30～50 parts, water; 1～3 part of carbon nanotube; 1～2 part of tripoly phosphate sodium STPP; 1 ~ 5 part of tempering fiber;
Glaze weight part consists of:
15～25 parts of feldspars, 10 ~ 15 parts of kaolin, 8 ~ 10 parts, quartz, burn 10～20 parts, talcum, 13～22 parts, Wingdale, 0.5～5 part, chromic oxide, five 3～9 parts of oxidation two boron, 8～15 parts, aluminum oxide, 5～12 parts, diatomite, 6～15 parts of electrosmelted magnesite clinkers, 5～14 parts of zirconium silicates, 1 ~ 10 part of titanium oxide, 1 ~ 10 part, zinc oxide, 1 ~ 5 part of terbium sesquioxide, 1 ~ 10 part of Samarium trioxide, 1 ~ 5 part of lutecium oxide, 1 ~ 5 part of metal nanoparticle;
The ceramic tile that described carbon nanotube strengthens is made by the method for being prepared as follows:
(1) after blank raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30-100min, obtains mixing the slurry of homogeneous, by sieving, after mist projection granulating, by waiting static pressure compression moulding, and ageing 1-2 days at room temperature, obtain green compact, at 800 ~ 830 DEG C, green compact are carried out to biscuiting 30-40min subsequently;
(2) after glaze raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30-100min, obtains mixing the glaze of homogeneous;
(3) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green compact surface, then burn till at roller kiln, firing temperature is 1185～1200 DEG C, and firing period is 50 ~ 55min, by following process, obtains the ceramic tile finished product that carbon nanotube strengthens.
As preferably, described metal nanoparticle is gold nano grain, silver nano-grain or copper nano particles.
As preferably, described metal nanoparticle is of a size of 1-30nm.
As preferably, described base substrate weight part consists of: 38 parts of potassium felspar sands; 16 parts of albites; 18 parts of Guangxi white claies; 40 parts of Attapulgite; 27 parts of mullites; 47 parts, water; 2 parts of carbon nanotubes; 1 part of tripoly phosphate sodium STPP; 4 parts of tempering fibers.
As preferably, described glaze weight part consists of: 18 parts of feldspars, 14 parts of kaolin, 9 parts, quartz, burns 15 parts, talcum, 20 parts, Wingdale, 3 parts, chromic oxide, five 6 parts of oxidation two boron, 9 parts, aluminum oxide, 10 parts, diatomite, 8 parts of electrosmelted magnesite clinkers, 7 parts of zirconium silicates, 7 parts of titanium oxide, 8 parts, zinc oxide, 4 parts of terbium sesquioxides, 6 parts of Samarium trioxides, 3 parts of lutecium oxides, 4 parts of metal nanoparticles.
Beneficial effect of the present invention:
(1) the present invention organically combines various blank raw materials and glaze raw material by creationary, and pass through optimal preparation technology, obtain good mechanical property, the ceramic tile that refractory heat-insulating, health environment-friendly, the carbon nanotube that heat conductivility coefficient is little, lightweight, water-intake rate is low, glaze color and luster is obvious and adjustable strengthen.
(2) the present invention is by introducing carbon nanotube as ceramic body material, the not only toughness reinforcing mechanical property of ceramic body, and also reduced the weight of ceramic body;
(3) the present invention, by metal nanoparticle is incorporated into glaze, combines itself and rare earth glaze, has greatly promoted the color of glaze.
(4) the ceramic tile preparation technology that the carbon nanotube that prepared by the present invention strengthens is simple, environmental protection, and be convenient to suitability for industrialized production.
Embodiment
Below in conjunction with specific embodiment, and comparable data describes in further detail the present invention.Should be understood that these embodiment just in order to demonstrate the invention, but not limit the scope of the invention by any way.
Embodiment 1:
The ceramic tile that carbon nanotube strengthens, base substrate weight part consists of:
10 parts of potassium felspar sands; 10 parts of albites; 15 parts of Guangxi white claies; 30 parts of attapulgites; 20 parts of mullites; 30 parts, water; 1 part of carbon nanotube; 1 part of tripoly phosphate sodium STPP; 1 part of tempering fiber;
Glaze weight part consists of:
15 parts of feldspars, 10 parts of kaolin, 8 parts, quartz, burn 10 parts, talcum, 13 parts, Wingdale, 0.5 part, chromic oxide, five 3 parts of oxidation two boron, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts of electrosmelted magnesite clinkers, 5 parts of zirconium silicates, 1 part of titanium oxide, 1 part, zinc oxide, 1 part of terbium sesquioxide, 1 part of Samarium trioxide, 1 part of lutecium oxide, 1 part of gold nano grain; Described size of nanometer gold grain is 10nm;
The ceramic tile that described carbon nanotube strengthens is made by the method for being prepared as follows:
(1) after blank raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the slurry of homogeneous, by sieving, after mist projection granulating, by waiting static pressure compression moulding, and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, green compact are carried out to biscuiting 30min subsequently;
(2) after glaze raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the glaze of homogeneous;
(3) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green compact surface, then burn till at roller kiln, firing temperature is 1185 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that carbon nanotube strengthens.
Embodiment 2:
The ceramic tile that carbon nanotube strengthens, base substrate weight part consists of:
10 parts of potassium felspar sands; 10 parts of albites; 15 parts of Guangxi white claies; 30 parts of attapulgites; 20 parts of mullites; 30 parts, water; 1 part of carbon nanotube; 1 part of tripoly phosphate sodium STPP; 1 part of tempering fiber;
Glaze weight part consists of:
15 parts of feldspars, 10 parts of kaolin, 8 parts, quartz, burn 10 parts, talcum, 13 parts, Wingdale, 0.5 part, chromic oxide, five 3 parts of oxidation two boron, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts of electrosmelted magnesite clinkers, 5 parts of zirconium silicates, 1 part of titanium oxide, 1 part, zinc oxide, 1 part of terbium sesquioxide, 1 part of Samarium trioxide, 1 part of lutecium oxide, 1 part of silver nano-grain; Described silver nano-grain is of a size of 10nm;
The ceramic tile that described carbon nanotube strengthens is made by the method for being prepared as follows:
(1) after blank raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the slurry of homogeneous, by sieving, after mist projection granulating, by waiting static pressure compression moulding, and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, green compact are carried out to biscuiting 30min subsequently;
(2) after glaze raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the glaze of homogeneous;
(3) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green compact surface, then burn till at roller kiln, firing temperature is 1185 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that carbon nanotube strengthens.
Embodiment 3:
The ceramic tile that carbon nanotube strengthens, base substrate weight part consists of:
10 parts of potassium felspar sands; 10 parts of albites; 15 parts of Guangxi white claies; 30 parts of attapulgites; 20 parts of mullites; 30 parts, water; 1 part of carbon nanotube; 1 part of tripoly phosphate sodium STPP; 1 part of tempering fiber;
Glaze weight part consists of:
15 parts of feldspars, 10 parts of kaolin, 8 parts, quartz, burn 10 parts, talcum, 13 parts, Wingdale, 0.5 part, chromic oxide, five 3 parts of oxidation two boron, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts of electrosmelted magnesite clinkers, 5 parts of zirconium silicates, 1 part of titanium oxide, 1 part, zinc oxide, 1 part of terbium sesquioxide, 1 part of Samarium trioxide, 1 part of lutecium oxide, 1 part of copper nano particles; Described copper nano particles is of a size of 10nm;
The ceramic tile that described carbon nanotube strengthens is made by the method for being prepared as follows:
(1) after blank raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the slurry of homogeneous, by sieving, after mist projection granulating, by waiting static pressure compression moulding, and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, green compact are carried out to biscuiting 30min subsequently;
(2) after glaze raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the glaze of homogeneous;
(3) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green compact surface, then burn till at roller kiln, firing temperature is 1185 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that carbon nanotube strengthens.
Embodiment 4:
The ceramic tile that carbon nanotube strengthens, base substrate weight part consists of:
38 parts of potassium felspar sands; 16 parts of albites; 18 parts of Guangxi white claies; 40 parts of Attapulgite; 27 parts of mullites; 47 parts, water; 2 parts of carbon nanotubes; 1 part of tripoly phosphate sodium STPP; 4 parts of tempering fibers;
Glaze weight part consists of:
18 parts of feldspars, 14 parts of kaolin, 9 parts, quartz, burn 15 parts, talcum, 20 parts, Wingdale, 3 parts, chromic oxide, five 6 parts of oxidation two boron, 9 parts, aluminum oxide, 10 parts, diatomite, 8 parts of electrosmelted magnesite clinkers, 7 parts of zirconium silicates, 7 parts of titanium oxide, 8 parts, zinc oxide, 4 parts of terbium sesquioxides, 6 parts of Samarium trioxides, 3 parts of lutecium oxides, 1 part of gold nano grain; Described size of nanometer gold grain is 10nm;
The ceramic tile that described carbon nanotube strengthens is made by the method for being prepared as follows:
(1) after blank raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the slurry of homogeneous, by sieving, after mist projection granulating, by waiting static pressure compression moulding, and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, green compact are carried out to biscuiting 30min subsequently;
(2) after glaze raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the glaze of homogeneous;
(3) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green compact surface, then burn till at roller kiln, firing temperature is 1185 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that carbon nanotube strengthens.
Embodiment 5:
The ceramic tile that carbon nanotube strengthens, base substrate weight part consists of:
38 parts of potassium felspar sands; 16 parts of albites; 18 parts of Guangxi white claies; 40 parts of Attapulgite; 27 parts of mullites; 47 parts, water; 1 part of carbon nanotube; 1 part of tripoly phosphate sodium STPP; 4 parts of tempering fibers;
Glaze weight part consists of:
18 parts of feldspars, 14 parts of kaolin, 9 parts, quartz, burn 15 parts, talcum, 20 parts, Wingdale, 3 parts, chromic oxide, five 6 parts of oxidation two boron, 9 parts, aluminum oxide, 10 parts, diatomite, 8 parts of electrosmelted magnesite clinkers, 7 parts of zirconium silicates, 7 parts of titanium oxide, 8 parts, zinc oxide, 4 parts of terbium sesquioxides, 6 parts of Samarium trioxides, 3 parts of lutecium oxides, 4 parts of gold nano grains; Described size of nanometer gold grain is 30nm;
The ceramic tile that described carbon nanotube strengthens is made by the method for being prepared as follows:
(1) after blank raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the slurry of homogeneous, by sieving, after mist projection granulating, by waiting static pressure compression moulding, and at room temperature ageing 1 day, obtain green compact, at 830 DEG C, green compact are carried out to biscuiting 30min subsequently;
(2) after glaze raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the glaze of homogeneous;
(3) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green compact surface, then burn till at roller kiln, firing temperature is 1200 DEG C, and firing period is 55min, by following process, obtains the ceramic tile finished product that carbon nanotube strengthens.
Comparative example 1:
The ceramic tile that carbon nanotube strengthens, base substrate weight part consists of:
10 parts of potassium felspar sands; 10 parts of albites; 15 parts of Guangxi white claies; 30 parts of attapulgites; 20 parts of mullites; 30 parts, water; 1 part of tripoly phosphate sodium STPP; 1 part of tempering fiber;
Glaze weight part consists of:
15 parts of feldspars, 10 parts of kaolin, 8 parts, quartz, burn 10 parts, talcum, 13 parts, Wingdale, 0.5 part, chromic oxide, five 3 parts of oxidation two boron, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts of electrosmelted magnesite clinkers, 5 parts of zirconium silicates, 1 part of titanium oxide, 1 part, zinc oxide, 1 part of terbium sesquioxide, 1 part of Samarium trioxide, 1 part of lutecium oxide, 1 part of gold nano grain; Described size of nanometer gold grain is 10nm;
The ceramic tile that described carbon nanotube strengthens is made by the method for being prepared as follows:
(1) after blank raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the slurry of homogeneous, by sieving, after mist projection granulating, by waiting static pressure compression moulding, and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, green compact are carried out to biscuiting 30min subsequently;
(2) after glaze raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the glaze of homogeneous;
(3) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green compact surface, then burn till at roller kiln, firing temperature is 1185 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that carbon nanotube strengthens.
Comparative example 2:
The ceramic tile that carbon nanotube strengthens, base substrate weight part consists of:
10 parts of potassium felspar sands; 10 parts of albites; 15 parts of Guangxi white claies; 30 parts of attapulgites; 20 parts of mullites; 30 parts, water; 1 part of carbon nanotube; 1 part of tripoly phosphate sodium STPP; 1 part of tempering fiber;
Glaze weight part consists of:
15 parts of feldspars, 10 parts of kaolin, 8 parts, quartz, burns 10 parts, talcum, 13 parts, Wingdale, 0.5 part, chromic oxide, five 3 parts of oxidation two boron, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts of electrosmelted magnesite clinkers, 5 parts of zirconium silicates, 1 part of titanium oxide, 1 part, zinc oxide, 1 part of terbium sesquioxide, 1 part of Samarium trioxide, 1 part of lutecium oxide;
The ceramic tile that described carbon nanotube strengthens is made by the method for being prepared as follows:
(1) after blank raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the slurry of homogeneous, by sieving, after mist projection granulating, by waiting static pressure compression moulding, and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, green compact are carried out to biscuiting 30min subsequently;
(2) after glaze raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the glaze of homogeneous;
(3) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green compact surface, then burn till at roller kiln, firing temperature is 1185 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that carbon nanotube strengthens.
Comparative example 3: the ceramic tile that a kind of carbon nanotube strengthens, base substrate weight part consists of:
10 parts of potassium felspar sands; 10 parts of albites; 15 parts of Guangxi white claies; 30 parts of attapulgites; 20 parts of mullites; 30 parts, water; 1 part of tripoly phosphate sodium STPP; 1 part of tempering fiber;
Glaze weight part consists of:
15 parts of feldspars, 10 parts of kaolin, 8 parts, quartz, burns 10 parts, talcum, 13 parts, Wingdale, 0.5 part, chromic oxide, five 3 parts of oxidation two boron, 8 parts, aluminum oxide, 5 parts, diatomite, 6 parts of electrosmelted magnesite clinkers, 5 parts of zirconium silicates, 1 part of titanium oxide, 1 part, zinc oxide, 1 part of terbium sesquioxide, 1 part of Samarium trioxide, 1 part of lutecium oxide;
The ceramic tile that described carbon nanotube strengthens is made by the method for being prepared as follows:
(1) after blank raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the slurry of homogeneous, by sieving, after mist projection granulating, by waiting static pressure compression moulding, and at room temperature ageing 1 day, obtain green compact, at 800 DEG C, green compact are carried out to biscuiting 30min subsequently;
(2) after glaze raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30min, obtains mixing the glaze of homogeneous;
(3) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green compact surface, then burn till at roller kiln, firing temperature is 1185 DEG C, and firing period is 50min, by following process, obtains the ceramic tile finished product that carbon nanotube strengthens.
By comparative example 1-3 and embodiment 1 are compared, in the time being added with carbon nanotube as blank raw material, the mechanical property of base substrate and mechanical property increase rate have reached 20%, and this ceramic tile strengthening for carbon nanotube is a very large progress; And by metal nanoparticle is incorporated in glaze, because the metal nanoparticle of different size has distinct colors, therefore, the color of glaze will be contributed to regulate, and there is the glaze of metalluster, by the aesthetic measure of ceramic tile that greatly improves carbon nanotube and strengthen.
Claims (5)
1. the ceramic tile that carbon nanotube strengthens, is characterized in that:
Base substrate weight part consists of:
10 ~ 45 parts of potassium felspar sands; 10 ~ 20 parts of albites; 15～20 parts of Guangxi white claies; 30～50 parts of attapulgites; 20 ~ 30 parts of mullites; 30～50 parts, water; 1～3 part of carbon nanotube; 1～2 part of tripoly phosphate sodium STPP; 1 ~ 5 part of tempering fiber;
Glaze weight part consists of:
15～25 parts of feldspars, 10 ~ 15 parts of kaolin, 8 ~ 10 parts, quartz, burn 10～20 parts, talcum, 13～22 parts, Wingdale, 0.5～5 part, chromic oxide, five 3～9 parts of oxidation two boron, 8～15 parts, aluminum oxide, 5～12 parts, diatomite, 6～15 parts of electrosmelted magnesite clinkers, 5～14 parts of zirconium silicates, 1 ~ 10 part of titanium oxide, 1 ~ 10 part, zinc oxide, 1 ~ 5 part of terbium sesquioxide, 1 ~ 10 part of Samarium trioxide, 1 ~ 5 part of lutecium oxide, 1 ~ 5 part of metal nanoparticle;
The ceramic tile that described carbon nanotube strengthens is made by the method for being prepared as follows:
(1) after blank raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, abrading-ball is aluminum oxide abrading-ball, by ball milling 30-100min, obtains mixing the slurry of homogeneous, by sieving, after mist projection granulating, by waiting static pressure compression moulding, and ageing 1-2 days at room temperature, obtain green compact, at 800 ~ 830 DEG C, green compact are carried out to biscuiting 30-40min subsequently;
(2) after glaze raw material is mixed in proportion, carry out ball milling, ball-milling medium is ethanol and water mixture, and abrading-ball is aluminum oxide abrading-ball, by ball milling 30-100min, obtains mixing the glaze of homogeneous;
(3) adopt the mode of glaze spraying or pouring glaze that glaze is imposed on green compact surface, then burn till at roller kiln, firing temperature is 1185～1200 DEG C, and firing period is 50 ~ 55min, by following process, obtains the ceramic tile finished product that carbon nanotube strengthens.
2. the ceramic tile that carbon nanotube as claimed in claim 1 strengthens, is characterized in that described metal nanoparticle is gold nano grain, silver nano-grain or copper nano particles.
3. the ceramic tile that carbon nanotube as claimed in claim 1 or 2 strengthens, is characterized in that described metal nanoparticle is of a size of 1-30nm.
4. the ceramic tile that carbon nanotube as claimed in claim 3 strengthens, is characterized in that described base substrate weight part consists of: 38 parts of potassium felspar sands; 16 parts of albites; 18 parts of Guangxi white claies; 40 parts of Attapulgite; 27 parts of mullites; 47 parts, water; 2 parts of carbon nanotubes; 1 part of tripoly phosphate sodium STPP; 4 parts of tempering fibers.
5. the ceramic tile that carbon nanotube as claimed in claim 4 strengthens, is characterized in that described glaze weight part consists of: 18 parts of feldspars, 14 parts of kaolin, 9 parts, quartz, burns 15 parts, talcum, 20 parts, Wingdale, 3 parts, chromic oxide, five 6 parts of oxidation two boron, 9 parts, aluminum oxide, 10 parts, diatomite, 8 parts of electrosmelted magnesite clinkers, 7 parts of zirconium silicates, 7 parts of titanium oxide, 8 parts, zinc oxide, 4 parts of terbium sesquioxides, 6 parts of Samarium trioxides, 3 parts of lutecium oxides, 4 parts of metal nanoparticles.
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| CN101486591A (en) * | 2008-01-17 | 2009-07-22 | 金在浩 | Water soluble photo-curable antistatic composition and conductive hard tile flooring material coated with the same |
| CN102505822A (en) * | 2011-10-11 | 2012-06-20 | 信益陶瓷(中国)有限公司 | Ceramic tile with gold-plated surface and manufacturing method thereof |
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| CN101486591A (en) * | 2008-01-17 | 2009-07-22 | 金在浩 | Water soluble photo-curable antistatic composition and conductive hard tile flooring material coated with the same |
| CN101462882A (en) * | 2009-01-21 | 2009-06-24 | 武汉理工大学 | Ultrafast sintering method for preparing carbon nano-tube reinforced ceramic |
| CN102505822A (en) * | 2011-10-11 | 2012-06-20 | 信益陶瓷(中国)有限公司 | Ceramic tile with gold-plated surface and manufacturing method thereof |
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| CN104690018A (en) * | 2015-02-16 | 2015-06-10 | 福建省晋江万利瓷业有限公司 | Recovery system for ceramic production equipment cleaning materials |
| CN104690018B (en) * | 2015-02-16 | 2017-03-29 | 福建省晋江万利瓷业有限公司 | Ceramic production device cleans the recovery system of material |
| CN104844155A (en) * | 2015-06-01 | 2015-08-19 | 苏州拓科仪器设备有限公司 | Glass tile prepared from laterite |
| CN108640645A (en) * | 2018-05-10 | 2018-10-12 | 安徽省亚欧陶瓷有限责任公司 | A kind of preparation method of micropore complex phase decorative porcelain |
| CN108794022A (en) * | 2018-07-03 | 2018-11-13 | 贵州大学 | A kind of technique using ardealite and flyash relieving haperacidity coproduction refractory brick |
| CN112939462A (en) * | 2021-04-01 | 2021-06-11 | 亚细亚建筑材料股份有限公司 | Matt glaze |
| CN113024227A (en) * | 2021-04-07 | 2021-06-25 | 麻建华 | High-temperature and low-temperature resistant anti-skid ceramic tile and preparation method thereof |
| CN116947457A (en) * | 2023-07-10 | 2023-10-27 | 佛山市柏雅乐建材有限公司 | Preparation process and application of hard alloy reinforced ceramic tile |
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