CN104150714B - Administer sugar refinery sulfur-bearing waste with composite fungus agent and produce the method for compound bacterial fertilizer - Google Patents
Administer sugar refinery sulfur-bearing waste with composite fungus agent and produce the method for compound bacterial fertilizer Download PDFInfo
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- CN104150714B CN104150714B CN201410394853.8A CN201410394853A CN104150714B CN 104150714 B CN104150714 B CN 104150714B CN 201410394853 A CN201410394853 A CN 201410394853A CN 104150714 B CN104150714 B CN 104150714B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
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Abstract
Administer sugar refinery sulfur-bearing waste with composite fungus agent and produce the method for compound bacterial fertilizer, belonging to biological environmental production technology.Composite fungus agent is PSB+DM, and sugar refinery sulfur-bearing waste comprises liquid debris as molasses alcohol waste mash, and solid waste is as filter mud, lime-ash, bagasse etc.Treatment effect to waste: biochemical oxygen demand (BOD) and chemical oxygen demand (COD), reduction rate 60 ~ 70%; Sulfate radical, sulfide, reduction rate 70 ~ 80%.The DM added has multi-efficiency, during the fermentation due to the coordinative role of various bacterium, accelerate the decomposition of organic materials, have stronger degraded and Utilization ability to sulfide, to deodorizing be and suppress the generation of stink to have obvious effect, making the safer health of material fermentation process; Process alcohol waste mash, does not need adjusted to ph.Compared to the prior art, governance efficiency and effect are greatly improved, and effectively reduce construction investment and running cost.
Description
Technical field
The invention belongs to biological environmental production technology, be specifically related to a kind of composite fungus agent and administer sugar refinery sulfur-bearing waste and the method for producing bacterial manure.Said composite fungus agent is PSB+DM, and said sugar refinery sulfur-bearing waste comprises liquid debris as molasses alcohol waste mash, and solid waste is as filter mud, lime-ash, bagasse etc.
Background technology
Molasses alcohol waste mash is the difficult problem of environmental protection of sugar-refining industry for many years always, often produces 1 ton of alcohol, by generation 13 ~ 15 tons of useless mash.When temperature=100 DEG C, PH=3 ~ 5; COD=120000 ~ 160000mg/L; BOD=40000 ~ 60000mg/L; Solid substance=10 ~ 20%; Containing sulfate radical, chlorion, genus high density organic acidity pollutent in useless mash.But also should see, useless mash contains a large amount of organic simultaneously, as sugared part, amino acid, protein, organic acid etc., and the nutrition needed for plant-growth such as nitrogen, phosphorus, potassium, calcium, there is considerable recovery value, can fully utilize.
Photosynthetic bacterium (be called for short PSB) earth occurs the earliest, occurring in nature ubiquity, has the prokaryotic organism of original luminous energy synthetic system, it is the general name of under anaerobic not putting the photosynthetic bacterium of oxygen, the Gram-negative bacteria that a class does not form gemma ability, be a class using light as the energy, the organism of occurring in nature, sulfide, ammonia etc. can be utilized under anaerobism illumination or aerobic dark condition to carry out photosynthetic microorganism as hydrogen donor carbon source of holding concurrently.Photosynthetic bacterium is distributed widely in the places such as natural soil, paddy field, marsh, lake, Jiang Hai, is mainly distributed in the oxygen-starved area that in aquatic environment, light transmissive arrives.The organism of the Partial Species energy enduring high-concentration of photosynthetic bacterium, has the physiological characteristic of removal, decomposing organic matter.Photosynthetic bacterium is again a kind of single cell protein lean type with very high nutritive value, and its amino acid composition is very close to animal proteinum, and vitamin B group rich content in thalline, also containing physiologically active substances such as ubiquinones, therefore can promote vegeto-animal growing.Overwhelming majority photosynthetic bacteria all has nitrogen fixation, the symbiosis in soil of photosynthetic bacteria and actinomycetes, has restraining effect to the thread fungus of causing a disease, and contributes to plant root system development and overcomes continuous cropping obstacle.Photosynthetic bacterial fertilizer can increase farm crop chlorophyll effectively, improves the photosynthesis of plant, various crop is all obtained to the effect of significantly short length, diseases prevention, volume increase.Therefore the soil compaction caused life-time service chemical fertilizer, soil property worsen good improving effect.Therefore agriculturally improve soil with photosynthetic bacterium, improving crop quality and output, is the dominant direction of microorganism fertilizer.
The patent No. researched and developed before applicant is the patented technology of 00113131.1, comprehensive utilization can be realized while improvement alcohol waste mash, produce " photosynthetic bacterial fertilizer " by zymotechnique, accomplish that the environmental benefit in region, economic benefit and social benefit are full of altogether.Technology is constantly progress always, also needs to improve further existing method, to reduce facility floor space, construction investment, energy consumption, running cost and treatment cycle, and can administer sulfur-bearing and to give up solid gurry.
Dietzia maris (Dietziamaris) is called for short DM, it is a kind of complex micro organism fungicide, original name is ocean rhodococcus (Rhodocoeeusmaris), has commercial goods, such as, can buy to Chinese industrial Microbiological Culture Collection administrative center (CICC).
Summary of the invention
The object of the invention is to make further improvements existing method.
One, administer sugar refinery liquid sulfur-bearing waste with composite fungus agent and produce the method for compound bacterial fertilizer, it is characterized in that as follows:
A. by alcohol waste mash temperature adjustment to 18 ~ 45 DEG C, the best is 25 ~ 32 DEG C;
B. aerobic aeration is carried out, the acidification hydrolization process of air-flow mix and blend;
C. enter and to inoculate in advance and the bio-oxidation pond cultivated does fermentative processing, in pond, the weight ratio of PSB and DM is 1:0.3 ~ 0.6, and the gross weight of both PSB and DM is 3 ~ 5% of handled liquid weight, and fermentation time is 40 ~ 48 hours;
D. liquid compound bacterial fertilizer is obtained after fermentation ends.
Said acidification hydrolization is treated to prior art, such as can adopt with the following method: add urea, phosphamidon and potassium primary phosphate simultaneously, the gross weight of three be the thousandth of handled amount of liquid as 5/1000ths, urea by weight: phosphamidon: dipotassium hydrogen phosphate is 1:0.5 ~ 2:0.5 ~ 0.2.
Two, administer sugar refinery liquid sulfur-containing solid waste with composite fungus agent and produce the method for compound bacterial fertilizer, it is characterized in that as follows:
A. by solid waste temperature adjustment to 18 ~ 45 DEG C, the best is 25 ~ 32 DEG C; PH value is adjusted to 3 ~ 10, and the best is 7;
B. mechanical turning is carried out, the acidification hydrolization process that mixing oxygenation is stirred;
C. enter and to inoculate in advance and the bio-oxidation pond cultivated does fermentative processing, in pond, the weight ratio of PSB and DM is 1:0.3 ~ 0.6, and the gross weight of both PSB and DM is 1.5 ~ 2.5% of handled solid weight, and fermentation time is 72 ~ 120 hours;
D. solid compound bacterial fertilizer is obtained after fermenting-ripening.
Said acidification hydrolization is treated to prior art, such as can adopt with the following method: add urea, phosphamidon and potassium primary phosphate simultaneously, the gross weight of three be the thousandth of handled amount of liquid as 5/1000ths, urea by weight: phosphamidon: dipotassium hydrogen phosphate is 1:0.5 ~ 2:0.5 ~ 0.2.
The inventive method products obtained therefrom can reach following technical requirements:
One, Liquid Fertilizer
Two, solid fertilizer
Technical indicator
Three, no matter be Liquid Fertilizer or solid fertilizer, heavy metal limit requires to be (mg/kg):
Recommend consumption for every mu of the inventive method products obtained therefrom:
(1) Liquid Fertilizer is for sugarcane, every mu of consumption 4 ~ 6 tons; Vegetative period does not need spraying fertilizer again.
(2) solid fertilizer is for sugarcane, and every mu of consumption 80 ~ 120 kilograms makees base fertilizer, imposes 40 kilograms of inorganic composite mixed fertilizers vegetative period.
The inventive method is to the treatment effect of waste:
(1) biochemical oxygen demand (BOD) and chemical oxygen demand (COD), reduction rate 60 ~ 70%;
(2) sulfate radical, sulfide, reduction rate 70 ~ 80%.
The inventive method and prior art contrast as follows.
1, waste dreggy alcohol of sugar refinery is processed: use single psb Fermentation by Photosynthetic Bacteria, fermentation time is 120 ~ 144 hours; Use psb+DM compound bacteria-fermented, fermentation time reduction is 40 ~ 48 hours;
2, process sugar refinery solid waste: use single psb Fermentation by Photosynthetic Bacteria, fermentation time is for being 360 ~ 480 hours; Use psb+DM compound bacteria-fermented, fermentation time is for shortening to 72 ~ 120 hours.
3, for Sugarcane Fertilization, gained bacterial manure of the present invention and existing psb photosynthetic bacterium bacterial manure agrochemical index contrast and are:
Seedling rate: improve 17 ~ 19%;
Tillering capacity: improve 15 ~ 17%;
Mu productive tiller: improve 22 ~ 23%;
Per mu yield: improve 18 ~ 20%;
Containing sugar: improve 0.15%.
Beneficial effect of the present invention: the DM added has multi-efficiency, during the fermentation due to the coordinative role of various bacterium, accelerate the decomposition of organic materials, stronger degraded and Utilization ability is had to sulfide, there is obvious effect to the generation of deodorizing and suppression stink, make the safer health of material fermentation process; Process alcohol waste mash, does not need adjusted to ph.Compared to the prior art, governance efficiency and effect are greatly improved in the present invention, effectively reduce construction investment and running cost.
Embodiment
See following instance.
1, serial experiment situation
2, one of industrialization case of comparative examples
(1) administer object: the molasses alcohol waste mash of sugar enterprise, use the psb Fermentation by Photosynthetic Bacteria that prior art is single, by biotechnology harmless treatment, make it be converted into liquid bio fertilizer and be back to sugarcane district.Exploiting entity: sugar refinery, Yunnan, treatment scale 1000m
3/ d; Treatment unit cubic capacity: 8000m
3; Build up in December, 2000 and throw factory.
(2) administer object: the molasses alcohol waste mash of sugar enterprise, use the inventive method, by biotechnology harmless treatment, make it be converted into liquid bio fertilizer and be back to sugarcane district.Exploiting entity: sugar refinery, Yunnan, treatment scale 1000m
3/ d; Treatment unit cubic capacity: 3000m
3; Be constructed and put into operation in December, 2006, technique is unexposed.
3, industrialization case of comparative examples two
(1) object is administered: sugar enterprise's solid waste: filter mud, lime-ash, bagasse.Use the psb Fermentation by Photosynthetic Bacteria that prior art is single, by biotechnology fermentation process, make it be converted into solid bacterial manure and be back to sugarcane district.Exploiting entity: sugar refinery, Yunnan, treatment scale 16000t/a; Treatment unit floor space: 13000m
2; Build up in December, 2006 and throw factory.
(2) object is administered: sugar enterprise's solid waste: filter mud, lime-ash, bagasse.Use the technology of the present invention, by biotechnology fermentation process, make it be converted into solid bacterial manure and be back to sugarcane district.Exploiting entity: sugar refinery, Yunnan, treatment scale 16000t/a; Treatment unit floor space: 8000m
2; Be constructed and put into operation in December, 2007, technique is unexposed.
(3) solid dielectric, material object: sugar enterprise's solid waste, filter mud, lime-ash, bagasse.Use the technology of the present invention, by biotechnology fermentation process, make it be converted into solid biologic fertilizer and be back to sugarcane district.Exploiting entity: sugar refinery, Yunnan, treatment scale 16000t/a; Treatment unit floor space: 6000m
2; Be constructed and put into operation in December, 2012, technique is unexposed.
Claims (4)
1. administer sugar refinery liquid sulfur-bearing waste with composite fungus agent and produce a method for compound bacterial fertilizer, it is characterized in that as follows:
A. by alcohol waste mash temperature adjustment to 18 ~ 45 DEG C;
B. aerobic aeration is carried out, the acidification hydrolization process of air-flow mix and blend;
C. enter and to inoculate in advance and the bio-oxidation pond cultivated does fermentative processing, in pond, the weight ratio of photosynthetic bacterium and Dietzia maris is 1:0.3 ~ 0.6, in pond, photosynthetic bacterium and the gross weight both Dietzia maris are 3 ~ 5% of handled liquid weight, and fermentation time is 40 ~ 48 hours;
D. liquid compound bacterial fertilizer is obtained after precipitation.
2. composite fungus agent as claimed in claim 1 is administered sugar refinery liquid sulfur-bearing waste and is produced the method for compound bacterial fertilizer, it is characterized in that alcohol waste mash temperature adjustment to 25 ~ 32 DEG C.
3. administer sugar refinery sulfur-containing solid waste with composite fungus agent and produce a method for compound bacterial fertilizer, it is characterized in that as follows:
A. by solid waste temperature adjustment to 18 ~ 45 DEG C, pH value is adjusted to 3 ~ 10;
B. mechanical turning is carried out, the acidification hydrolization process that mixing oxygenation is stirred;
C. enter and to inoculate in advance and the bio-oxidation pond cultivated does fermentative processing, in pond, the weight ratio of photosynthetic bacterium and Dietzia maris is 1:0.3 ~ 0.6, in pond, photosynthetic bacterium PSB and the gross weight both Dietzia maris DM are 1.5 ~ 2.5% of handled sulfur-containing solid waste weight, and fermentation time is 72 ~ 120 hours;
D. solid compound bacterial fertilizer is obtained after fermenting-ripening.
4. composite fungus agent as claimed in claim 3 is administered sugar refinery sulfur-containing solid waste and is produced the method for compound bacterial fertilizer, it is characterized in that pH value is adjusted to 7 by solid waste temperature adjustment to 25 ~ 32 DEG C.
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CN105601350A (en) * | 2015-12-31 | 2016-05-25 | 南宁太美生物科技有限公司 | Method for preparing organic nutrient solution by processing and biologically fermenting organic wastes |
CN108060101B (en) * | 2018-01-09 | 2021-08-10 | 广州市第二中学 | Ocean Dietzia W02-3a and application thereof in denitrification |
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CN1315296A (en) * | 2000-03-29 | 2001-10-03 | 昆明元特生物环保有限责任公司 | Process for treating waste liquid of molasses alcohol |
CN100383233C (en) * | 2000-08-24 | 2008-04-23 | 蓝昆元 | Method for producing photosynthetic bacterial thallus by using molasses alcohol mash liquor |
CN1161456C (en) * | 2001-05-17 | 2004-08-11 | 蓝昆元 | Bacterium for degradating residual agricultural chemical and its preparing process |
CN1286775C (en) * | 2003-01-30 | 2006-11-29 | 张维民 | Method for producing biologically fermented active organic fertilizer by using organic wasters and its device |
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