CN104149513B - A kind of coating class printed medium and preparation method thereof - Google Patents
A kind of coating class printed medium and preparation method thereof Download PDFInfo
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- CN104149513B CN104149513B CN201410442141.9A CN201410442141A CN104149513B CN 104149513 B CN104149513 B CN 104149513B CN 201410442141 A CN201410442141 A CN 201410442141A CN 104149513 B CN104149513 B CN 104149513B
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Abstract
The invention discloses a kind of coating class printed medium, described coating class printed medium is spread evenly across on base material, it is characterised in that: described coating class printed medium is made up of the cross-linking agent of the water of 100 parts, the silicon dioxide of 8 12 parts, the titanium dioxide of 6 10 parts, the PM 2 acrylic compounds rubber polymer of 50 100 parts, the 676 class rubber polymers of 50 parts, the dispersing aid of 1.4 2.2 parts, the antifoam additives of 0.5 part, the leveling auxiliary agent of 0.3 0.5 parts and 5 parts.The coating class printed medium of the present invention can be greatly improved the ink adherence during ink printing compared to traditional printed medium, improves process color density, increases substantially the scraping and wiping resistance performance of printed matter.
Description
Technical field
The present invention relates to a kind of coating class printed medium and preparation method thereof, it is adaptable to the occasion of letterpress, intaglio printing, lithographic printing, silk screen printing and ink jet printing, and be suitable for producing various colored printing label papers and various colored printing packaging material.
Background technology
Synthetic material is a kind of widely used new material, as a example by PP paper, PP synthetic paper is with the resins such as polyolefin and inorganic filler as primary raw material, is processed by expressing technique, there is the multi-functional material of plastics and paper feature simultaneously, it is a kind of Novel plastic material product, is also a kind of environment-friendly products, have that light specific gravity, intensity is big, anti tear, printing is good, shading, uvioresistant, durable in use, the feature such as economic and environment-friendly.
Based on above advantage, the synthetic material such as PP synthetic paper and PET film is widely used in printed label and printed apcksging material industry.But owing to the self character of PP synthesis stationery and PET film class material determines that its material surface energy is low, printing-ink is difficult to attachment, and after printing, the adherence of ink is poor, color density is low, strong influence practical application effect.
Traditional processing method is that section adds sided corona treatment before printing,-OH and-COOH that corona rear surface produces can build bridge with ink, initial effect is good, but sided corona treatment rear surface tension force can be decayed rapidly, as a example by PET film, after its initial corona processes, effect at most can continue about 7 days；Instability and the feature of easily weakening due to sided corona treatment effect, make the long-term fastness of ink layer after printing the strongest, it is prone to scraping, therefore solves the most traditional printing material of class without coating and generally there is the problem that ink adherence is poor, color density is low, scraping and wiping resistance performance is poor, necessary.
Summary of the invention
Problem to be solved by this invention is to provide a kind of coating class printed medium and preparation method thereof, the feature that when having printing, ink adherence is strong, color density is high, scraping and wiping resistance performance is good.
For solving above-mentioned technical problem, the technical scheme is that a kind of coating class printed medium, described coating class printed medium is spread evenly across on base material, and its innovative point is: described coating class printed medium is made up of water, the silicon dioxide of 8-12 part, the titanium dioxide of 6-10 part, the PM-2 acrylic compounds rubber polymer of 50-100 part, the cross-linking agent of 676 class rubber polymers, the dispersing aid of 1.4-2.2 part, the antifoam additives of 0.5 part, the leveling auxiliary agent of 0.3-0.5 part and 5 parts of 50 parts of 100 parts.
Preferably, described defoamer is modified organic silicon alkanes or Semen Ricini oils modification derivant.
Preferably, described levelling agent is fluorinated levelling agent.
Preferably, described cross-linking agent is the special cross-linking agent of acrylic emulsion.
Preferably, described dispersant is Nano filling dispersant special.
Preferably, the one in PP synthetic paper after described base material is corona or chemical treatment, PET film, PE leaching membrane paper, wood-free paper.
The preparation method of a kind of coating class printed medium, prepares above-mentioned a kind of coating class printed medium, comprises the following steps:
A, first dispersing aid, antifoam additives, leveling auxiliary agent and the cross-linking agent of above-mentioned number are added to the water, with the continuously stirred 30min of the speed of 1000r/min；
B, silicon dioxide and the titanium dioxide of above-mentioned number are joined in above-mentioned solution, with the continuously stirred 60min of the speed of 4000r/min；
C, then it is blended into the PM-2 acrylic compounds rubber polymer of above-mentioned number, 676 class rubber polymers, with the continuously stirred 30min of the speed of 1000r/min；
D, finally by obtain solution left standstill until froth breaking, be i.e. available for the coating class printed medium being coated on base material.
It is an advantage of the current invention that: the coating class printed medium of the present invention has the advantage that 1 compared to traditional printed medium, introduces suitable coating on the printing elements such as PP synthetic paper, PET film, ink adherence ink printing during is greatly improved, improve process color density, increase substantially the scraping and wiping resistance performance of printed matter；2, in traditional Nano filling dispersive process, production process airborne dust is big, and the dispersed with stirring time is long, high energy consumption；Due to the fact that and introduce suitable Nano filling dispersing aid, making filler be more easy to dispersion, so that coating production process airborne dust is little, energy consumption is low；3, suitable rubber polymer system and cross linker system have been selected so that in coating production process, eliminate the bottoming process of tradition coating process, decrease production routine, improve production efficiency, reduce production cost.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further detailed explanation.
Embodiment
1
The coating class printed medium of the present invention is spread evenly across on base material, is made up of the cross-linking agent of the water of 100 parts, the silicon dioxide of 8 parts, the titanium dioxide of 6 parts, the PM-2 acrylic compounds rubber polymer of 100 parts, the 676 class rubber polymers of 50 parts, the dispersing aid of 1.4 parts, the antifoam additives of 0.5 part, the leveling auxiliary agent of 0.3 part and 5 parts.
Above-mentioned defoamer is modified organic silicon alkanes or Semen Ricini oils modification derivant, levelling agent is fluorinated levelling agent, cross-linking agent is the special cross-linking agent of acrylic emulsion, dispersant is Nano filling dispersant special, and base material is the one in the PP synthetic paper after corona or chemical treatment, PET film, PE leaching membrane paper, wood-free paper.
Prepare the preparation method of above-mentioned coating class printed medium, comprise the following steps:
A, first dispersing aid, antifoam additives, leveling auxiliary agent and the cross-linking agent of above-mentioned number are added to the water, with the continuously stirred 30min of the speed of 1000r/min；
B, silicon dioxide and the titanium dioxide of above-mentioned number are joined in above-mentioned solution, with the continuously stirred 60min of the speed of 4000r/min；
C, then it is blended into the PM-2 acrylic compounds rubber polymer of above-mentioned number, 676 class rubber polymers, with the continuously stirred 30min of the speed of 1000r/min；
D, finally by obtain solution left standstill until froth breaking, be i.e. available for the coating class printed medium being coated on base material.
Embodiment
2
The coating class printed medium of the present invention is spread evenly across on base material, is made up of the cross-linking agent of the water of 100 parts, the silicon dioxide of 10 parts, the titanium dioxide of 8 parts, the PM-2 acrylic compounds rubber polymer of 50 parts, the 676 class rubber polymers of 50 parts, the dispersing aid of 1.7 parts, the antifoam additives of 0.5 part, the leveling auxiliary agent of 0.4 part and 5 parts.
Above-mentioned defoamer is modified organic silicon alkanes or Semen Ricini oils modification derivant, levelling agent is fluorinated levelling agent, cross-linking agent is the special cross-linking agent of acrylic emulsion, dispersant is Nano filling dispersant special, and base material is the one in the PP synthetic paper after corona or chemical treatment, PET film, PE leaching membrane paper, wood-free paper.
Prepare the preparation method of above-mentioned coating class printed medium, comprise the following steps:
A, first dispersing aid, antifoam additives, leveling auxiliary agent and the cross-linking agent of above-mentioned number are added to the water, with the continuously stirred 30min of the speed of 1000r/min；
B, silicon dioxide and the titanium dioxide of above-mentioned number are joined in above-mentioned solution, with the continuously stirred 60min of the speed of 4000r/min；
C, then it is blended into the PM-2 acrylic compounds rubber polymer of above-mentioned number, 676 class rubber polymers, with the continuously stirred 30min of the speed of 1000r/min；
D, finally by obtain solution left standstill until froth breaking, be i.e. available for the coating class printed medium being coated on base material.
Embodiment
3
The coating class printed medium of the present invention is spread evenly across on base material, is made up of the cross-linking agent of the water of 100 parts, the silicon dioxide of 12 parts, the titanium dioxide of 8 parts, the PM-2 acrylic compounds rubber polymer of 70 parts, the 676 class rubber polymers of 50 parts, the dispersing aid of 1.7 parts, the antifoam additives of 0.5 part, the leveling auxiliary agent of 0.4 part and 5 parts.
Above-mentioned defoamer is modified organic silicon alkanes or Semen Ricini oils modification derivant, levelling agent is fluorinated levelling agent, cross-linking agent is the special cross-linking agent of acrylic emulsion, dispersant is Nano filling dispersant special, and base material is the one in the PP synthetic paper after corona or chemical treatment, PET film, PE leaching membrane paper, wood-free paper.
Prepare the preparation method of above-mentioned coating class printed medium, comprise the following steps:
A, first dispersing aid, antifoam additives, leveling auxiliary agent and the cross-linking agent of above-mentioned number are added to the water, with the continuously stirred 30min of the speed of 1000r/min；
B, silicon dioxide and the titanium dioxide of above-mentioned number are joined in above-mentioned solution, with the continuously stirred 60min of the speed of 4000r/min；
C, then it is blended into the PM-2 acrylic compounds rubber polymer of above-mentioned number, 676 class rubber polymers, with the continuously stirred 30min of the speed of 1000r/min；
D, finally by obtain solution left standstill until froth breaking, be i.e. available for the coating class printed medium being coated on base material.
Embodiment
4
The coating class printed medium of the present invention is spread evenly across on base material, is made up of the cross-linking agent of the water of 100 parts, the silicon dioxide of 12 parts, the titanium dioxide of 10 parts, the PM-2 acrylic compounds rubber polymer of 90 parts, the 676 class rubber polymers of 50 parts, the dispersing aid of 2.2 parts, the antifoam additives of 0.5 part, the leveling auxiliary agent of 0.5 part and 5 parts.
Above-mentioned defoamer is modified organic silicon alkanes or Semen Ricini oils modification derivant, levelling agent is fluorinated levelling agent, cross-linking agent is the special cross-linking agent of acrylic emulsion, dispersant is Nano filling dispersant special, and base material is the one in the PP synthetic paper after corona or chemical treatment, PET film, PE leaching membrane paper, wood-free paper.
Prepare the preparation method of above-mentioned coating class printed medium, comprise the following steps:
A, first dispersing aid, antifoam additives, leveling auxiliary agent and the cross-linking agent of above-mentioned number are added to the water, with the continuously stirred 30min of the speed of 1000r/min；
B, silicon dioxide and the titanium dioxide of above-mentioned number are joined in above-mentioned solution, with the continuously stirred 60min of the speed of 4000r/min；
C, then it is blended into the PM-2 acrylic compounds rubber polymer of above-mentioned number, 676 class rubber polymers, with the continuously stirred 30min of the speed of 1000r/min；
D, finally by obtain solution left standstill until froth breaking, be i.e. available for the coating class printed medium being coated on base material.
Above an embodiment of the invention is described in detail, but content has been only the preferred embodiment of the invention, it is impossible to be considered the practical range for limiting the invention.All impartial changes made according to the invention application range and improvement etc., within all belonging to the patent covering scope of the invention.
Claims (6)
1. the preparation method of a coating class printed medium, it is characterised in that: described coating class is printed
Medium by 100 parts water, the silicon dioxide of 8-12 part, the titanium dioxide of 6-10 part,
The PM-2 acrylic compounds rubber polymer of 50-100 part, the 676 class rubber polymers of 50 parts,
The dispersing aid of 1.4-2.2 part, the antifoam additives of 0.5 part, the leveling auxiliary agent of 0.3-0.5 part
Cross-linking agent composition with 5 parts；
Comprise the following steps:
A, first dispersing aid, antifoam additives, leveling auxiliary agent and the cross-linking agent of above-mentioned number are joined
In water, with the continuously stirred 30min of the speed of 1000r/min；
B, silicon dioxide and the titanium dioxide of above-mentioned number are joined in above-mentioned solution, with
The continuously stirred 60min of speed of 4000r/min；
C, then it is blended into the PM-2 acrylic compounds rubber polymer of above-mentioned number, 676 class rubber polymers, with
The continuously stirred 30min of speed of 1000r/min；
D, finally by obtain solution left standstill until froth breaking, be i.e. available for being coated on base material
Coating class printed medium.
2. the preparation method of coating class printed medium as claimed in claim 1, it is characterised in that:
Described defoamer is modified organic silicon alkanes or Semen Ricini oils modification derivant.
3. the preparation method of coating class printed medium as claimed in claim 1, it is characterised in that:
Described levelling agent is fluorinated levelling agent.
4. the preparation method of coating class printed medium as claimed in claim 1, it is characterised in that:
Described cross-linking agent is the special cross-linking agent of acrylic emulsion.
5. the preparation method of coating class printed medium as claimed in claim 1, it is characterised in that:
Described dispersant is Nano filling dispersant special.
6. the preparation method of coating class printed medium as claimed in claim 1, it is characterised in that:
Described base material be the PP synthetic paper after corona or chemical treatment, PET film, PE leaching membrane paper,
One in wood-free paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410442141.9A CN104149513B (en) | 2014-09-02 | 2014-09-02 | A kind of coating class printed medium and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410442141.9A CN104149513B (en) | 2014-09-02 | 2014-09-02 | A kind of coating class printed medium and preparation method thereof |
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| CN104149513A CN104149513A (en) | 2014-11-19 |
| CN104149513B true CN104149513B (en) | 2016-07-13 |
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| CN201410442141.9A Expired - Fee Related CN104149513B (en) | 2014-09-02 | 2014-09-02 | A kind of coating class printed medium and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108752615A (en) * | 2018-06-11 | 2018-11-06 | 江苏万宝瑞达高新技术有限公司 | A kind of BOPP thermosensitive film production methods suitable for the printing of UV ink |
| CN114574117A (en) * | 2022-02-25 | 2022-06-03 | 深圳昌茂粘胶新材料有限公司 | Weather-proof medium-resistant high-temperature-resistant label tape and manufacturing method thereof |
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| CN102092209A (en) * | 2010-10-29 | 2011-06-15 | 哈尔滨工业大学 | Ink-jet recording material and preparation method thereof as well as method for preparing ink absorption layer coating liquid |
| CN102501676A (en) * | 2011-10-14 | 2012-06-20 | 江苏格美高科技发展有限公司 | Matte waterproof polypropylene photo paper applicable for aqueous ink |
| CN102922893A (en) * | 2012-10-30 | 2013-02-13 | 江苏格美高科技发展有限公司 | Medical laser color printing and imaging PET (Polyester) film and preparation method thereof |
| CN103897529A (en) * | 2012-12-27 | 2014-07-02 | 青岛佳艺影像新材料技术有限公司 | Manufacturing method of coating liquid for dual-layer front-spray light box sheets |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002019032A2 (en) * | 2000-08-30 | 2002-03-07 | Alcoa Inc. | Pretreated sheet product for lithographic plates |
| WO2003022576A1 (en) * | 2001-08-30 | 2003-03-20 | Tianjin Boyuan New Materials Co., Ltd | Base sheet specially for digital card-marking and its preparing method |
| WO2011100029A1 (en) * | 2010-02-12 | 2011-08-18 | Exxonmobil Oil Corporation | Coated polymeric film |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102092209A (en) * | 2010-10-29 | 2011-06-15 | 哈尔滨工业大学 | Ink-jet recording material and preparation method thereof as well as method for preparing ink absorption layer coating liquid |
| CN102501676A (en) * | 2011-10-14 | 2012-06-20 | 江苏格美高科技发展有限公司 | Matte waterproof polypropylene photo paper applicable for aqueous ink |
| CN102922893A (en) * | 2012-10-30 | 2013-02-13 | 江苏格美高科技发展有限公司 | Medical laser color printing and imaging PET (Polyester) film and preparation method thereof |
| CN103897529A (en) * | 2012-12-27 | 2014-07-02 | 青岛佳艺影像新材料技术有限公司 | Manufacturing method of coating liquid for dual-layer front-spray light box sheets |
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