WO2003022576A1 - Base sheet specially for digital card-marking and its preparing method - Google Patents

Base sheet specially for digital card-marking and its preparing method Download PDF

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Publication number
WO2003022576A1
WO2003022576A1 PCT/CN2001/001293 CN0101293W WO03022576A1 WO 2003022576 A1 WO2003022576 A1 WO 2003022576A1 CN 0101293 W CN0101293 W CN 0101293W WO 03022576 A1 WO03022576 A1 WO 03022576A1
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WO
WIPO (PCT)
Prior art keywords
substrate
latex
parts
emulsion
acrylate
Prior art date
Application number
PCT/CN2001/001293
Other languages
French (fr)
Chinese (zh)
Inventor
Xiushan Lu
Zengyong Li
Defa Jing
Ming Li
Original Assignee
Tianjin Boyuan New Materials Co., Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Boyuan New Materials Co., Ltd filed Critical Tianjin Boyuan New Materials Co., Ltd
Priority to CN01823529.8A priority Critical patent/CN1289288C/en
Priority to PCT/CN2001/001293 priority patent/WO2003022576A1/en
Publication of WO2003022576A1 publication Critical patent/WO2003022576A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508Supports

Definitions

  • the present invention relates to the field of digital card manufacturing, and in particular, to a special substrate for digital card manufacturing and a method for preparing the substrate.
  • the present invention also relates to a digital printed card made using the substrate. Background of the invention
  • the current printing methods of personalized cards are mainly sublimation and digital color printing.
  • the printing resolution of sublimation is generally only 360dpi, the produced graphics have low definition, the durability of the pattern is not good, and the efficiency is low and the cost is high.
  • the digital color printing card has a resolution of only 300dpi, the color of the card pattern is dark, the printed network lines are clearly visible, and the sharpness index is low. These unsatisfactory printing effects have a lot to do with the material and performance of the substrate.
  • the currently common single-layer structure PVC substrate is not particularly suitable for inkjet printer business cards. Summary of invention
  • the invention provides a new type of special substrate for digital card making.
  • the substrate surface of the substrate is coated with an adhesive layer and an ink absorbing layer, which can realize direct printing, and in particular, a color inkjet printer can be used to directly print colors. Accurate reproduction, high definition and good durability.
  • the preparation of the water-absorbing layer latex, and the coating of each latex layer, the prepared substrate can be directly used for graphic printing.
  • the present invention further provides a digital printed card made by using the above substrate.
  • the card is made by directly printing graphics on the surface of the absorbing layer of the substrate. It can be various standard or non-standard cards, and is especially suitable for short version.
  • the card-making business better meets the needs of users to fully display their individuality.
  • the substrate for digital card manufacturing has a structure including a polymer substrate, an adhesive layer and an ink absorbing layer sequentially coated on the surface of the substrate.
  • the adhesive layer is a transparent layer, which functions as a bonding substrate and an ink absorbing layer.
  • the ink absorbing layer is a translucent layer, which can quickly absorb ink for inkjet printing to ensure the sharpness and durability of graphics.
  • the substrate becomes a translucent or opaque substrate by using a translucent or opaque substrate.
  • graphics can be printed on the translucent substrate in the reverse direction or printed on the opaque substrate in the forward direction.
  • the printing resolution can reach up to Above 1440 dpi, through thermal lamination, digital cards with accurate color reproduction, high definition, good durability and low cost can be cut.
  • the substrate of the present invention can be used to make various standard or non-standard cards, and is especially suitable for short-term card making services with high personalization requirements.
  • the card making cost is not restricted by the size of the production batch.
  • the substrate using the present invention can also be used for offset printing of cards. Detailed description of the invention
  • the structure includes a polymer substrate and an adhesive layer and an ink absorbing layer sequentially coated on the surface of the substrate, that is, the substrate. It includes a polymer substrate, an adhesive layer is coated on the surface of the substrate, and an ink absorbing layer is coated on the surface of the adhesive layer.
  • the polymer base material is selected from the group consisting of polyvinyl chloride (PVC), fluorenyl acrylate-butadiene-styrene copolymer (MBS), polyethylene terephthalate (PET), and polymer Carbonate (PC) translucent substrate, or selected from degradable PVC, polyvinyl chloride and acrylonitrile-butadiene Diene-styrene copolymer blends (PVC / ABS), polyvinyl chloride and calcium carbonate blends (PVC / CaC0 3 ), opaque substrates of PET and ABS.
  • PVC polyvinyl chloride
  • MVS fluorenyl acrylate-butadiene-styrene copolymer
  • PET polyethylene terephthalate
  • PC polymer Carbonate
  • the adhesive layer coated on the surface of the substrate plays the role of adhering the substrate and the ink absorbing layer together.
  • It is a transparent adhesive layer and is made of latex mainly including the following raw material emulsion: polyurethane and acrylic Esters, acrylate-styrene copolymers, ethylene-vinyl acetate copolymers, or mixtures of vinyl acetate-acrylate copolymers.
  • the latex has a viscosity of 15-40 centipoise (CPS).
  • the ink absorbing layer can effectively absorb printing ink, especially color inkjet printing ink, which is helpful for clear and durable printing graphics. It is a translucent layer, which is formed by coating the latex with an absorption layer mainly including the following raw material emulsion. : Polyurethane and acrylate, acrylate and styrene copolymer, ethylene-acetic acid acetate copolymer, or a mixture of vinyl acetate and acrylate copolymer, and polyvinyl acetate (PVA) solution and gelatin solution.
  • the viscosity of this latex can be 80-120CPS.
  • each material layer in the substrate structure is 0. 01-1 mm.
  • a method for preparing a substrate for digital card manufacturing which includes a process for preparing an adhesive layer latex, an ink absorbing layer latex, and a substrate coating process, wherein,
  • the preparation process of the adhesive layer latex includes: mixing and stirring the raw material emulsion, adding the auxiliary agent, and continuing stirring, so that the latex viscosity is 15-40CPS.
  • the raw material Per 100 parts by weight of the raw material, it is preferable to include 94-98 parts of 20-60% polyurethane emulsion and 30-60% acrylate emulsion, 30-60% acrylate-styrene copolymer emulsion, 30-60% ethylene-acetic acid Ethylene copolymer emulsion, or 30-60 ° /.
  • a mixed emulsion consisting of a vinyl acetate-acrylate copolymer emulsion. Because the concentration of the raw material used and the concentration of the raw material emulsion may be different, the ratio of the two emulsions may be different. In general, the ratio of the polyurethane to the other component is about 1: 0. 8-1.
  • the specific dosage ratio can be determined according to the viscosity of the prepared latex.
  • the preparation process of the ink absorbing layer latex includes: mixing the raw material emulsion with the polyvinyl alcohol solution, stirring the mixture, heating the mixture to 40-50 ° C, sequentially adding the gelatin solution and the auxiliary agent, and then adding the ultrafine calcium carbonate and the adsorbent in order. Continue stirring to make the latex fineness of 20 microns, and the latex viscosity is 80-120CPS.
  • the addition ratio of the two is also like the adhesive layer latex, which mainly depends on the viscosity of the latex.
  • the ink absorbing layer raw material also includes 42-48 parts of a 10% polyvinyl alcohol solution, 1-3 parts of a 5-10% gelatin solution, and 2-6 parts of ultra-fine calcium carbonate.
  • the auxiliary agents used in the preparation of the adhesive layer latex include a leveling agent, a defoaming agent, and a thickener, the total amount of which is 2-6 parts by weight; the auxiliary agents used in the preparation of the ink-absorbing layer latex include a dispersant, a leveling agent, and a degreasing agent.
  • the total amount of the foaming agent and the fixing agent is 1-3 parts, and the adsorbent includes silicon dioxide, titanium dioxide, and silicon.
  • a commercially available leveling agent G 1 i de 100 (TEG0), a defoamer Foamax805 (TEG0), a thickener BR100P (Coatex), a dispersant DISPER181 (BYK), and a fixing agent DUR can be used.
  • G 1 i de 100 TAG0
  • TOG0 defoamer Foamax805
  • TOG0 thickener
  • BR100P Coatex
  • BYK dispersant DISPER181
  • fixing agent DUR a commercially available leveling agent G 1 i de 100
  • a defoamer Foamax805 (TEG0)
  • a thickener BR100P Coatex
  • BYK dispersant DISPER181
  • BYK dispersant DISPER181
  • fixing agent DUR fixing agent DUR
  • adsorbent and ultra-fine calcium carbonate are used in the absorbent layer latex, the purpose is to improve the absorption capacity of the absorbent printing ink, and make the surface of the absorbent layer sufficiently fine to ensure the high resolution and high definition of the printed graphics.
  • the adhesion and absorption properties of the coating latex are important conditions.
  • an adhesive layer latex was made.
  • the mixture of the raw material emulsion and the polyvinyl alcohol solution is first stirred at 100-200 rpm for 20-40 minutes, and heated to 40-50 ° C, and then the gelatin solution and the auxiliary agent are sequentially added, and the mixture is kept at the rotation speed for 20-40 minutes.
  • the coating process for preparing the substrate includes: sequentially coating the prepared adhesive layer latex and ink absorbing layer latex on the surface of the substrate, and drying each layer after coating to make each square meter of the adhesive layer and ink absorbing layer Dry glue amounts are 5-10 g and 15-30 g, respectively.
  • the substrate in the form of a roll dip coating, roll coating, extrusion coating, air knife coating, and anilox roll coating can be used.
  • screen coating In the method of roller coating, after coating, it can be dried by hot air, far infrared, microwave drying, etc., and then cut into a substrate of a required size, and sealed and packaged for use.
  • the substrate prepared according to the above method of the present invention can be used for card making, that is, according to another aspect of the present invention, a card made of the above substrate, especially a digital printing card, is further provided.
  • the card is in an ink absorption layer of the substrate
  • the necessary graphics are printed on it. It can be a standard or non-standard card, such as a business card, bank card, various membership cards, and consumer cards that display personal characteristics and information.
  • the production of the above digital card includes printing the graphic layer on the ink absorbing layer of the opaque substrate in a forward direction, and laminating the surface with a translucent substrate or an adhesive film for lamination; or reverse printing the graphic layer on a translucent substrate.
  • the surface was laminated with an opaque substrate, and the translucent substrate became transparent by thermal lamination.
  • the method for printing the graphic layer includes inkjet printing, screen printing, offset printing, and gravure printing, and is particularly suitable for color inkjet printing, or a combination of inkjet printing and traditional offset printing, for example, a common information display section. Offset printing, inkjet for personalized display Printing, while providing high-quality images, reduces printing costs.
  • the two printed cards are bonded back to back, which becomes a double-sided printed card. If both sides of the opaque substrate used are coated with an adhesive layer and an absorbing layer, a double-sided card is also made according to the above method after printing the graphics and text respectively.
  • the laminating operation in the card making process includes a process of hot pressing at 3-6Mpa, 90-135 ° C for 20-40 minutes, and then cold pressing for 10-20 minutes.
  • the latex of the adhesive layer in the substrate fully exerts its adhesive effect, so that the adhesion between the layers is firm.
  • the entire lamination process can be completed with conventional equipment, or a slight modification of conventional equipment can be used.
  • the card of the present invention may further include, for example, a display card or a description card for fixing to a label, and at this time, the content of the card is reversely printed on the absorption layer of the translucent substrate, and the printing layer is pressed and adhered to the label.
  • the translucent substrate becomes transparent and the card content is clearly displayed.
  • the substrate of the present invention is not only suitable for inkjet printing, but also suitable for a variety of printing methods such as offset printing, screen printing, and missing printing, which makes it possible to produce high-counterfeit personalized cards in high volume, high efficiency, and low cost.
  • the 180 ° peel strength of the finished card made at 90-1 35 ° C and appropriate pressure is> 6N / cm, which meets the international standards for adhesive strength of the card industry.
  • the implementation of the present invention makes it possible for the card making work to go out of the tedious operation procedures such as traditional plate making, offset printing, and silk screen printing, and realizes digital plateless printing card making, which is technically simpler and more convenient for substrates.
  • the invention is not only higher than the traditional card making technology in terms of card production accuracy and color reproduction, but also adopts digital plateless card making technology and has card making cost Low, simple operation, fast production, unlimited printing quantity, can be widely used in the production of various ID cards, IC cards, personalized memorial cards, etc., such as: medical insurance card, family planning card, driving license card, Conference cards, ID cards, various magnetic cards, or wedding commemorative cards, birthday commemorative cards, Christmas cards, VIP cards, etc.
  • the implementation of the present invention is more suitable for the characteristics of global information network production requirements, and will certainly have a very broad application field.
  • FIG. 1 is a schematic perspective view of a substrate of the present invention.
  • Fig. 2 is a schematic diagram of a printed card fragment surface produced using a substrate of the present invention.
  • the substrate for digital card manufacturing includes a substrate 1, an adhesive layer 2, and an ink absorbing layer 3.
  • the substrate 1 may be an opaque or translucent substrate according to different materials.
  • a transparent adhesive layer 2 is coated thereon, and a translucent ink absorbing layer 3 is coated on the surface of the transparent adhesive layer 2.
  • the substrate may be an opaque substrate or a translucent substrate.
  • Figure 2 shows the structure of a printed card made using this substrate.
  • the surface of the ink-absorbing layer 3 of the translucent substrate is printed with a graphic layer in reverse, and it is laminated with an opaque substrate coated with an adhesive layer ( The adhesive layer with the graphic layer facing the opaque substrate) becomes a card, and the translucent substrate becomes transparent after thermal lamination; if an opaque substrate is used, the graphic layer is printed on the surface of the absorption layer 3 in the forward direction, The graphic surface is laminated with a translucent substrate 1 ′ coated with an adhesive layer 1 ′, or directly coated with an adhesive film to form a card. Two cards are bonded with their backs to form a double-sided card. Specific embodiment
  • the prepared adhesive layer latex was applied on a coater in a roll coating manner, coated on an opaque substrate of 0.3 mm of PVC / CaC0 3 , dried by hot air, and the amount of coated dry glue was 5.5 g / m 2 .
  • the ink-absorbing layer emulsion was coated on the adhesive layer with a dry glue amount of 21. 3 g / m 2 .
  • An opaque substrate was obtained.
  • the adhesive layer latex prepared above was roll-coated on a coater on a 0.08 mm PVC translucent substrate, which was dried by hot air, and the dry coating amount was 5.8 g / m 2 .
  • the ink-absorbing layer latex was coated on the adhesive layer and dried, and the dry glue amount was 19.5 g / m 2 .
  • a translucent substrate was obtained.
  • the prepared adhesive layer latex was dip-coated on a coater, and was coated on a transparent PC film of 0.1 mm, dried by hot air, and dried at a temperature of 65 ° C.
  • the amount of dry glue applied was 5.8 g / m 2 .
  • the ink-absorbing layer emulsion was coated on the adhesive layer with a dry glue amount of 24.2 g / m 2 . Made into a translucent substrate.
  • the prepared adhesive layer latex was roller-coated on a coating machine, coated on a PVC / ABS opaque substrate of 0. 3mm, dried at 55 ° C in a hot air, and the dry coating amount was 6. lg / m 2
  • the ink-absorbing layer latex was coated on the adhesive layer with a dry glue amount of 23.9 g / m 2 to obtain an opaque substrate.

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  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to a new base sheet for digital card-making and its preparing method. Substrate of said base sheet is coated with bond layer and ink absorbent layer. Said base sheet can be directly printed, particularly can be directly printed letters and pattern with color reduced accurately, high clarity and good durability by color ink-jet printer. The present base sheet can be used to make various of standard or non-standard card. When printing, letters and pattern are printed on or reversed on transparent sheet, which printing resolution ratio is more than 1440 dpi. Through heat-laminated, digital card can be obtained with color reduction accurately, high clarity, good durability and low cost. The present base sheet is particularly suitable for short-edited card-making with high personality required. Cost of card-making is not restricted with yield.

Description

数码制卡专用基片及其制备方法 发明领域  Special substrate for digital card making and preparation method thereof
本发明涉及数码制卡领域, 尤其涉及一种数码制卡专用基片及该基片 的制备方法, 本发明还涉及使用该基片制作的数码印制卡片。 发明背景  The present invention relates to the field of digital card manufacturing, and in particular, to a special substrate for digital card manufacturing and a method for preparing the substrate. The present invention also relates to a digital printed card made using the substrate. Background of the invention
目前国内外供彩色喷墨打印的基材很多, 主要应用于打印彩色照片、 广告、 幻灯片等, 但进行彩色喷墨打印的制卡专用基材却鲜有报道。 各种 卡片, 包括名片 (卡)、 银行卡、 各种名目的会员消费卡和用于展示企业 或个人特点的卡片的使用日益增多, 这些卡片中除名片多采用纸质, 其它 种类的卡片多为塑料材质 (PVC ), 直接在基材上印刷图文制成卡片, 而胶 印制卡是长期以来的主要制作方法, 该方法需要通过胶片制版后再印刷, 成本高, 工艺繁琐, 一般要求批量作业, 不适合制作个性化卡片和短版制 卡业务, 难以满足个性化卡片的印制要求。 目前的个性化卡片的印制方法 主要是热升华和数字彩印, 热升华的打印分辨率一般只有 360dpi, 制作的 图文清晰度低, 图案的耐久性不好, 而且效率低, 成本高。 数字彩印制卡 的分辨率只有 300dpi, 卡片图案色彩偏灰暗, 印制网线明显可见, 清晰度 指标低。 这些印制效果上的不尽人意之处都与基片的材质和性能有很大关 系, 目前常见的单层结构 PVC材质基片尤其不适用于喷墨打印机制卡。 发明概述  At present, there are many substrates for color inkjet printing at home and abroad, which are mainly used to print color photos, advertisements, slides, etc. However, there are few reports of special substrates for color inkjet printing. The use of various cards, including business cards (cards), bank cards, membership cards of various names, and cards used to show corporate or personal characteristics, is increasing. These cards are mostly paper, except for business cards. It is made of plastic (PVC), and the graphics are printed directly on the substrate to make cards. Offset printing cards have been the main manufacturing method for a long time. This method requires printing through film making. The cost is high, the process is complicated, and batches are generally required. The operation is not suitable for making personalized cards and short-form card making business, and it is difficult to meet the printing requirements of personalized cards. The current printing methods of personalized cards are mainly sublimation and digital color printing. The printing resolution of sublimation is generally only 360dpi, the produced graphics have low definition, the durability of the pattern is not good, and the efficiency is low and the cost is high. The digital color printing card has a resolution of only 300dpi, the color of the card pattern is dark, the printed network lines are clearly visible, and the sharpness index is low. These unsatisfactory printing effects have a lot to do with the material and performance of the substrate. The currently common single-layer structure PVC substrate is not particularly suitable for inkjet printer business cards. Summary of invention
本发明提供了一种新型的数码制卡专用基片, 该基片的基材表面涂布 有粘接层和墨水吸收层, 可实现直接打印, 尤其是可使用彩色喷墨打印机 直接打印出色彩还原准确, 清晰度高, 耐久性好的图文。 水吸收层乳胶的制备, 和各乳胶层的涂布, 制出的基片可以直接用于图文 打印。 The invention provides a new type of special substrate for digital card making. The substrate surface of the substrate is coated with an adhesive layer and an ink absorbing layer, which can realize direct printing, and in particular, a color inkjet printer can be used to directly print colors. Accurate reproduction, high definition and good durability. The preparation of the water-absorbing layer latex, and the coating of each latex layer, the prepared substrate can be directly used for graphic printing.
本发明还进一步提供了采用上述基片制作的数码印制卡片, 该卡片通 过在基片的吸收层表面直接打印图文而制成, 可以是各种标准或非标准卡 片, 尤其适用于短版制卡业务, 更好地满足使用者充分展现个性的需求。  The present invention further provides a digital printed card made by using the above substrate. The card is made by directly printing graphics on the surface of the absorbing layer of the substrate. It can be various standard or non-standard cards, and is especially suitable for short version. The card-making business better meets the needs of users to fully display their individuality.
根据本发明提供的数码制卡专用基片, 其构造包括有高分子基材和顺 序涂布于该基材表面的粘接层和墨水吸收层。 其中粘接层为透明层, 起粘 接基材与墨水吸收层的作用, 墨水吸收层是半透明层, 可以快速吸收喷墨 打印的墨水, 以保证图文的清晰度和耐久性。  The substrate for digital card manufacturing provided by the present invention has a structure including a polymer substrate, an adhesive layer and an ink absorbing layer sequentially coated on the surface of the substrate. The adhesive layer is a transparent layer, which functions as a bonding substrate and an ink absorbing layer. The ink absorbing layer is a translucent layer, which can quickly absorb ink for inkjet printing to ensure the sharpness and durability of graphics.
该基片通过使用半透明或不透明基材, 成为半透明或不透明基片, 在 制卡时可将图文反向打印在半透明基片上或正向打印在不透明基片上, 打 印分辨率可高达 1440 dpi 以上, 通过热压层合, 可裁切制出色彩还原准 确、 清晰度高、 耐久性好、 成本低的数码卡片。  The substrate becomes a translucent or opaque substrate by using a translucent or opaque substrate. During card making, graphics can be printed on the translucent substrate in the reverse direction or printed on the opaque substrate in the forward direction. The printing resolution can reach up to Above 1440 dpi, through thermal lamination, digital cards with accurate color reproduction, high definition, good durability and low cost can be cut.
本发明的基片可用于制作各种标准或非标准卡, 尤其适用于个性化要 求高的短版制卡业务, 制卡成本不受制作批量大小的制约。 当需要大批量 制作时, 采用本发明的基片同样可以胶印制卡。 发明详述  The substrate of the present invention can be used to make various standard or non-standard cards, and is especially suitable for short-term card making services with high personalization requirements. The card making cost is not restricted by the size of the production batch. When mass production is required, the substrate using the present invention can also be used for offset printing of cards. Detailed description of the invention
本发明提供的数码制卡基片与目前常用的数码卡基片的区别在于其构 造包括有高分子基材和顺序涂布于该基材表面的粘接层和墨水吸收层, 即 该基片包括有高分子基材, 在基材表面涂布有粘接层, 在粘接层表面涂布 有墨水吸收层。 其中: 所述高分子基材包括选自聚氯乙浠 (PVC )、 曱基丙 烯酸酯 -丁二烯-苯乙烯共聚物 (MBS )、 聚对苯二甲酸乙二醇酯 (PET ) 和 聚碳酸酯(PC ) 的半透明基材, 或选自可降解 PVC、 聚氯乙烯与丙烯腈-丁 二烯-苯乙烯共聚物共混材料 (PVC/ABS )、 聚氯乙烯与碳酸钙混合材料 ( PVC/CaC03 )、 PET 和 ABS 的不透明基材。 这些不同材质的基材均可直接 商购或由生产企业按要求生产, 得到的基片则分别为半透明基片和不透明 基片, 该半透明基片在制卡时经热层压可变成透明。 The difference between the digital card-making substrate provided by the present invention and the digital card substrates currently in use is that the structure includes a polymer substrate and an adhesive layer and an ink absorbing layer sequentially coated on the surface of the substrate, that is, the substrate. It includes a polymer substrate, an adhesive layer is coated on the surface of the substrate, and an ink absorbing layer is coated on the surface of the adhesive layer. Wherein: the polymer base material is selected from the group consisting of polyvinyl chloride (PVC), fluorenyl acrylate-butadiene-styrene copolymer (MBS), polyethylene terephthalate (PET), and polymer Carbonate (PC) translucent substrate, or selected from degradable PVC, polyvinyl chloride and acrylonitrile-butadiene Diene-styrene copolymer blends (PVC / ABS), polyvinyl chloride and calcium carbonate blends (PVC / CaC0 3 ), opaque substrates of PET and ABS. These substrates of different materials can be purchased directly or produced by manufacturers according to requirements. The obtained substrates are translucent substrates and opaque substrates. The translucent substrates can be changed by thermal lamination during card making. Become transparent.
该基片表面涂布的粘接层起到将基材与墨水吸收层粘接在一起的作 用, 为透明粘接层, 是由主要包括下述原料乳液的乳胶涂布而成: 聚氨酯 与丙烯酸酯、 丙烯酸酯-苯乙烯共聚物、 乙烯 -乙酸乙烯共聚物、 或乙酸乙 烯酯-丙烯酸酯共聚物的混合物。 该乳胶的粘度可在 15- 40厘泊 (CPS )。  The adhesive layer coated on the surface of the substrate plays the role of adhering the substrate and the ink absorbing layer together. It is a transparent adhesive layer and is made of latex mainly including the following raw material emulsion: polyurethane and acrylic Esters, acrylate-styrene copolymers, ethylene-vinyl acetate copolymers, or mixtures of vinyl acetate-acrylate copolymers. The latex has a viscosity of 15-40 centipoise (CPS).
所述墨水吸收层可有效吸收打印墨水, 尤其是彩色喷墨打印墨水, 有 助于打印图文的清晰耐久, 为半透明层, 是由主要包括下述原料乳液的吸 收层乳胶涂布而成: 聚氨酯与丙烯酸酯、 丙烯酸酯与苯乙烯共聚物、 乙烯 -乙酸乙晞共聚物、 或乙酸乙烯酯与丙烯酸酯共聚物的混合物, 以及聚乙 浠醇(PVA )溶液和明胶溶液。 该乳胶的粘度可在 80-120CPS。  The ink absorbing layer can effectively absorb printing ink, especially color inkjet printing ink, which is helpful for clear and durable printing graphics. It is a translucent layer, which is formed by coating the latex with an absorption layer mainly including the following raw material emulsion. : Polyurethane and acrylate, acrylate and styrene copolymer, ethylene-acetic acid acetate copolymer, or a mixture of vinyl acetate and acrylate copolymer, and polyvinyl acetate (PVA) solution and gelatin solution. The viscosity of this latex can be 80-120CPS.
通常情况下, 该基片结构中各材料层的厚度均在 0. 01-1毫米。  01-1 毫米。 Under normal circumstances, the thickness of each material layer in the substrate structure is 0. 01-1 mm.
根据本发明的另一方面, 还提供了这种用于数码制卡基片的制备方法, 其包括制备粘接层乳胶和墨水吸收层乳胶和基片涂布的过程, 其中,  According to another aspect of the present invention, there is also provided a method for preparing a substrate for digital card manufacturing, which includes a process for preparing an adhesive layer latex, an ink absorbing layer latex, and a substrate coating process, wherein,
粘接层乳胶的制备过程包括: 将原料乳液混合搅拌均勾后加入助剂, 继续搅拌, 使乳胶粘度在 15-40CPS。  The preparation process of the adhesive layer latex includes: mixing and stirring the raw material emulsion, adding the auxiliary agent, and continuing stirring, so that the latex viscosity is 15-40CPS.
每 100 重量份的原料中, 优选包括 94-98 份由 20-60%聚氨酯乳液与 30- 60%丙烯酸酯乳液、 30-60%丙烯酸酯-苯乙烯共聚物乳液、 30- 60%乙烯- 乙酸乙烯共聚物乳液、 或 30-60°/。乙酸乙烯酯-丙烯酸酯共聚物乳液组成的 混合乳液。 由于使用原料组合及原料乳液的浓度有可能不同, 二种乳液的 配比可以是不同的, 一般情况下聚氨酯与另一种成分的比例大约在 1 : 0. 8-1. 5 左右 (按 100%乳液原料计), 具体用量比可依据制备出乳胶的粘 度来确定。 墨水吸收层乳胶的制备过程包括: 将原料乳液与聚乙烯醇溶液混合搅 拌均勾后加热至 40- 50°C, 顺序加入明胶溶液和助剂, 搅拌后依次加入超 细碳酸钙、 吸附剂, 继续搅拌使乳胶细度 20 微米, 且乳胶粘度在 80- 120CPS。 Per 100 parts by weight of the raw material, it is preferable to include 94-98 parts of 20-60% polyurethane emulsion and 30-60% acrylate emulsion, 30-60% acrylate-styrene copolymer emulsion, 30-60% ethylene-acetic acid Ethylene copolymer emulsion, or 30-60 ° /. A mixed emulsion consisting of a vinyl acetate-acrylate copolymer emulsion. Because the concentration of the raw material used and the concentration of the raw material emulsion may be different, the ratio of the two emulsions may be different. In general, the ratio of the polyurethane to the other component is about 1: 0. 8-1. 5 (about 100 % Emulsion raw materials), the specific dosage ratio can be determined according to the viscosity of the prepared latex. The preparation process of the ink absorbing layer latex includes: mixing the raw material emulsion with the polyvinyl alcohol solution, stirring the mixture, heating the mixture to 40-50 ° C, sequentially adding the gelatin solution and the auxiliary agent, and then adding the ultrafine calcium carbonate and the adsorbent in order. Continue stirring to make the latex fineness of 20 microns, and the latex viscosity is 80-120CPS.
每 100 重量份的原料中, 优选包括 35-45 份由 20- 60%聚氨酯乳液与 For every 100 parts by weight of raw materials, it is preferable to include 35-45 parts of 20-60% polyurethane emulsion and
30-60%丙烯酸酯乳液、 30-60%丙烯酸酯-苯乙烯共聚物乳液、 30-60%乙烯- 乙酸乙烯共聚物乳液、 或 30-60%乙酸乙烯酯-丙烯酸酯共聚物乳液组成的 混合乳液, 二者的添加比例也如粘接层乳胶, 主要取决于乳胶的粘度。 30-60% acrylate emulsion, 30-60% acrylate-styrene copolymer emulsion, 30-60% ethylene-vinyl acetate copolymer emulsion, or 30-60% vinyl acetate-acrylate copolymer emulsion Emulsion, the addition ratio of the two is also like the adhesive layer latex, which mainly depends on the viscosity of the latex.
在该墨水吸收层原料中还包括 42-48份 10%聚乙烯醇溶液、 1-3份 5-10% 明胶溶液、 2-6份超细碳酸钙。  The ink absorbing layer raw material also includes 42-48 parts of a 10% polyvinyl alcohol solution, 1-3 parts of a 5-10% gelatin solution, and 2-6 parts of ultra-fine calcium carbonate.
粘接层乳胶制备中所用助剂包括流平剂、 消泡剂、 增稠剂, 其总量为 2-6 重量份; 墨水吸收层乳胶制备中所用助剂包括分散剂、 流平剂、 消泡 剂、 固色剂, 其总量为 1-3份, 所述吸附剂包括二氧化硅、 二氧化钛、 硅 它们的选择可以参照本领域的公知原则, 即, 这些助剂的种类和添加量可 以依据原料乳液的种类和用量来确定。例如,可使用商购的流平剂 G 1 i de 100 ( TEG0公司), 消泡剂 Foamax805 ( TEG0公司)、 增稠剂 BR100P ( Coatex 公司)、 分散剂 DISPER181 ( BYK公司)、 固色剂 DUR (上海助剂厂)等, 其 它与上述助剂产品性能相同或相似的产品也可适用。  The auxiliary agents used in the preparation of the adhesive layer latex include a leveling agent, a defoaming agent, and a thickener, the total amount of which is 2-6 parts by weight; the auxiliary agents used in the preparation of the ink-absorbing layer latex include a dispersant, a leveling agent, and a degreasing agent. The total amount of the foaming agent and the fixing agent is 1-3 parts, and the adsorbent includes silicon dioxide, titanium dioxide, and silicon. For the selection of these agents, reference may be made to well-known principles in the art, that is, the types and addition amounts of these additives may be Determined according to the type and amount of raw material emulsion. For example, a commercially available leveling agent G 1 i de 100 (TEG0), a defoamer Foamax805 (TEG0), a thickener BR100P (Coatex), a dispersant DISPER181 (BYK), and a fixing agent DUR can be used. (Shanghai Auxiliary Factory), etc., other products with the same or similar performance as the above auxiliary products can also be applied.
吸收层乳胶中使用适当量的吸附剂和超细碳酸钙, 目的在于提高对吸 收打印墨水的吸收能力, 并使吸收层表面达到足够细密, 保证打印图文的 高分辨率和高清晰度。  Appropriate amounts of adsorbent and ultra-fine calcium carbonate are used in the absorbent layer latex, the purpose is to improve the absorption capacity of the absorbent printing ink, and make the surface of the absorbent layer sufficiently fine to ensure the high resolution and high definition of the printed graphics.
为使涂布后的基片确实能够满足打印的要求, 涂布用乳胶的粘接和吸 收性能是^ ί艮重要的条件, 根据本发明优选的方案, 将乳液原料混合后, 先 以 100-200转 /分钟搅拌 20-40分钟,然后顺序加入助剂,保持转速搅拌 1 - 2 小时, 制成粘接层乳胶。原料乳液与聚乙烯醇溶液的混合物料先以 100-200 转 /分钟搅拌 20-40分钟,加热到 40- 50°C搅拌后顺序加入明胶溶液和助剂, 保持转速搅拌 20- 40分钟后依次加入超细碳酸钙、 吸附剂, 以 200- 400转 /分钟搅拌 2-3小时, 制成墨水吸收层乳胶。 In order to make the coated substrate surely meet the requirements of printing, the adhesion and absorption properties of the coating latex are important conditions. According to the preferred solution of the present invention, after mixing the emulsion raw materials, 100- Stir at 200 rpm for 20-40 minutes, then add auxiliaries in sequence and keep stirring at 1-2 In hours, an adhesive layer latex was made. The mixture of the raw material emulsion and the polyvinyl alcohol solution is first stirred at 100-200 rpm for 20-40 minutes, and heated to 40-50 ° C, and then the gelatin solution and the auxiliary agent are sequentially added, and the mixture is kept at the rotation speed for 20-40 minutes. Add ultra-fine calcium carbonate and adsorbent, and stir at 200-400 rpm for 2-3 hours to make an ink-absorbing layer latex.
制备基片的涂布过程包括: 将制备出的粘接层乳胶和墨水吸收层乳胶 顺序涂布在基材表面, 每层涂布后进行干燥, 使粘接层和墨水吸收层的每 平方米干胶量分别为 5-10 克和 15-30 克。 具体地说, 对于卷材形式的基 材, 可采用浸涂、 辊涂、 挤压涂布、 气刀刮涂、 网纹辊涂布, 片材形式的 基材, 可以采用丝网涂布、 辊涂的方法, 涂布后可通过热风、 远红外、 微 波干燥等方式使之干燥, 然后裁切成要求尺寸的基片, 密封包装, 以备使 用。 收层), 在层压过程中经化学变化, 吸收层因粘接层的作用与基材牢固结 合, 在压合中各层之间亦紧密结合, 所以, 制成的卡片具有很好的强度和 韧性, 并具有很好的防水性。 按照本发明上述方法制备的基片可用于制卡, 即根据本发明另一方面内容, 还进一步提供了采用上述基片制作的卡片, 尤其是数码印刷卡片, 该卡片在基片的墨水吸收层上打印有需要的图文。 可以是标准或非标准卡, 例如显示个人特点和信息的名片卡、 银行卡、 各 类会员卡、 消费卡等。  The coating process for preparing the substrate includes: sequentially coating the prepared adhesive layer latex and ink absorbing layer latex on the surface of the substrate, and drying each layer after coating to make each square meter of the adhesive layer and ink absorbing layer Dry glue amounts are 5-10 g and 15-30 g, respectively. Specifically, for the substrate in the form of a roll, dip coating, roll coating, extrusion coating, air knife coating, and anilox roll coating can be used. For the substrate in the form of a sheet, screen coating, In the method of roller coating, after coating, it can be dried by hot air, far infrared, microwave drying, etc., and then cut into a substrate of a required size, and sealed and packaged for use. (Receiving layer), through chemical changes during the lamination process, the absorbent layer is firmly bonded to the substrate due to the role of the adhesive layer, and the layers are also tightly bonded during lamination, so the finished card has good strength And toughness, and has good water resistance. The substrate prepared according to the above method of the present invention can be used for card making, that is, according to another aspect of the present invention, a card made of the above substrate, especially a digital printing card, is further provided. The card is in an ink absorption layer of the substrate The necessary graphics are printed on it. It can be a standard or non-standard card, such as a business card, bank card, various membership cards, and consumer cards that display personal characteristics and information.
上述数码卡的制作包括将图文层正向打印在不透明基片的墨水吸收层 上, 表面覆以半透明基材或带胶膜进行层压; 或将图文层反向打印在半透 明基片的墨水吸收层上, 表面压覆不透明基材进行层压, 半透明基材经热 层压变成透明。 其中, 打印图文层的方法包括喷墨打印、 丝网印刷、 胶印、 凹版印刷, 尤其适用于彩色喷墨打印, 或喷墨打印与传统的胶印等方法结 合使用, 例如, 共同的信息展示部分采用胶印, 个性化展示部分采用喷墨 打印, 在提供高质量图象的同时, 降低印刷成本。 The production of the above digital card includes printing the graphic layer on the ink absorbing layer of the opaque substrate in a forward direction, and laminating the surface with a translucent substrate or an adhesive film for lamination; or reverse printing the graphic layer on a translucent substrate. On the ink absorbing layer of the sheet, the surface was laminated with an opaque substrate, and the translucent substrate became transparent by thermal lamination. The method for printing the graphic layer includes inkjet printing, screen printing, offset printing, and gravure printing, and is particularly suitable for color inkjet printing, or a combination of inkjet printing and traditional offset printing, for example, a common information display section. Offset printing, inkjet for personalized display Printing, while providing high-quality images, reduces printing costs.
两张印制好的卡片背向粘接, 即成为双面印刷卡。 若使用的不透明基 片两面均涂布有粘接层和吸收层, 分别打印图文后按照上述方法亦制成双 面卡。  The two printed cards are bonded back to back, which becomes a double-sided printed card. If both sides of the opaque substrate used are coated with an adhesive layer and an absorbing layer, a double-sided card is also made according to the above method after printing the graphics and text respectively.
该卡片制作过程中的层压操作包括在 3-6Mpa压力, 90- 1 35 °C热压 20- 4 0分钟, 然后冷压 1 0-20分钟的过程。 在所述层压操作过程中, 基片中的 粘接层乳胶充分发挥其粘接作用, 使各层之间粘接牢固。 整个层压过程可 以应用常规装置完成, 或对常规装置稍加改造即可实现。  The laminating operation in the card making process includes a process of hot pressing at 3-6Mpa, 90-135 ° C for 20-40 minutes, and then cold pressing for 10-20 minutes. During the laminating operation, the latex of the adhesive layer in the substrate fully exerts its adhesive effect, so that the adhesion between the layers is firm. The entire lamination process can be completed with conventional equipment, or a slight modification of conventional equipment can be used.
本发明的卡片还可以包括例如用来粘固在标示物上的展示卡或说明 卡, 此时卡片内容被反向打印在半透明基片的吸收层上, 打印层面向标示 物压覆粘固, 半透明基片变成透明, 清楚显示卡片内容。  The card of the present invention may further include, for example, a display card or a description card for fixing to a label, and at this time, the content of the card is reversely printed on the absorption layer of the translucent substrate, and the printing layer is pressed and adhered to the label. The translucent substrate becomes transparent and the card content is clearly displayed.
本发明的基片不仅适用于喷墨打印, 还适合于胶印、 丝网印、 漏印等 多种印刷方式, 使大批量、 高效率、 低成本制作高防伪个性化卡片成为可 能。 经测试, 在 90-1 35 °C和适当压力下制得成品卡的 180° 剥离强度> 6N/cm, 符合制卡行业关于粘接强度的国际标准。  The substrate of the present invention is not only suitable for inkjet printing, but also suitable for a variety of printing methods such as offset printing, screen printing, and missing printing, which makes it possible to produce high-counterfeit personalized cards in high volume, high efficiency, and low cost. After testing, the 180 ° peel strength of the finished card made at 90-1 35 ° C and appropriate pressure is> 6N / cm, which meets the international standards for adhesive strength of the card industry.
从以上所述可得出, 本发明的实施使制卡工作走出传统的制版、 胶印、 丝印等繁瑣的作业程序成为可能, 实现了数字化无版印刷制卡, 技术上更 加简便, 而且在基片生产和制卡全过程中无有害液体和气体排出, 有利于 环保; 并且本发明不仅在卡片的制作精度和色彩还原方面高于传统制卡技 术, 采用数字化无版制卡技术同时具有制卡成本低, 操作简单, 制作快捷, 印刷数量不受限制, 可广泛用于各种证件卡、 IC卡、 个性化的有像纪念卡 等的制作, 例如: 医疗保险卡、 计划生育卡、 驾照卡、 会议卡、 身份证、 各类磁卡, 或婚纱纪念卡、 生日纪念卡、 圣诞卡、 贵宾卡等。 在数字时代 的今天, 本发明的实施更适用于全球信息网络制作要求的特点, 必将具有 很广阔的应用领域。 附图说明 From the above, it can be concluded that the implementation of the present invention makes it possible for the card making work to go out of the tedious operation procedures such as traditional plate making, offset printing, and silk screen printing, and realizes digital plateless printing card making, which is technically simpler and more convenient for substrates. There is no harmful liquid and gas discharged during the whole process of production and card making, which is beneficial to environmental protection; and the invention is not only higher than the traditional card making technology in terms of card production accuracy and color reproduction, but also adopts digital plateless card making technology and has card making cost Low, simple operation, fast production, unlimited printing quantity, can be widely used in the production of various ID cards, IC cards, personalized memorial cards, etc., such as: medical insurance card, family planning card, driving license card, Conference cards, ID cards, various magnetic cards, or wedding commemorative cards, birthday commemorative cards, Christmas cards, VIP cards, etc. In the digital age today, the implementation of the present invention is more suitable for the characteristics of global information network production requirements, and will certainly have a very broad application field. BRIEF DESCRIPTION OF THE DRAWINGS
图 1是本发明基片的立体示意图。  FIG. 1 is a schematic perspective view of a substrate of the present invention.
图 2是利用本发明基片制作的印刷卡片断面示意图。  Fig. 2 is a schematic diagram of a printed card fragment surface produced using a substrate of the present invention.
如图 1所示, 本发明提供的数码制卡专用基片包括了基材 1、 粘接层 2 和墨水吸收层 3 , 基材 1根据使用材质的不同可以是不透明或半透明基材, 其上涂布有透明粘接层 2 , 在该透明粘接层 2 表面则涂布有半透明墨水吸 收层 3 , 根据基材的不同, 该基片可以是不透明基片或半透明基片。  As shown in FIG. 1, the substrate for digital card manufacturing provided by the present invention includes a substrate 1, an adhesive layer 2, and an ink absorbing layer 3. The substrate 1 may be an opaque or translucent substrate according to different materials. A transparent adhesive layer 2 is coated thereon, and a translucent ink absorbing layer 3 is coated on the surface of the transparent adhesive layer 2. Depending on the substrate, the substrate may be an opaque substrate or a translucent substrate.
图 2 所示为应用该基片制作的印刷卡片的结构, 半透明基片的墨水吸 收层 3 的表面反向印有图文层, 与涂有粘接层 ' 的不透明基材 被层 压 (使图文层面向不透明基材的粘接层)成为卡片, 半透明基片经热层压 后变成透明; 若使用不透明基片时, 图文层被正向打印在吸收层 3的表面, 该图文表面压覆的是涂有粘接层 1' 的半透明基材 1 ' , 或直接覆以带胶 膜成为卡片。 两张卡片背向粘接, 即可成为双面卡片。 具体实施例  Figure 2 shows the structure of a printed card made using this substrate. The surface of the ink-absorbing layer 3 of the translucent substrate is printed with a graphic layer in reverse, and it is laminated with an opaque substrate coated with an adhesive layer ( The adhesive layer with the graphic layer facing the opaque substrate) becomes a card, and the translucent substrate becomes transparent after thermal lamination; if an opaque substrate is used, the graphic layer is printed on the surface of the absorption layer 3 in the forward direction, The graphic surface is laminated with a translucent substrate 1 ′ coated with an adhesive layer 1 ′, or directly coated with an adhesive film to form a card. Two cards are bonded with their backs to form a double-sided card. Specific embodiment
以下结合实施例详细说明本发明的实现, 目的在于帮助阅读者理解本 发明的设计思想, 不对本发明的实施范围构成限定。 实施例 1  The following describes the implementation of the present invention in detail with reference to the embodiments. The purpose is to help readers understand the design idea of the present invention and does not limit the implementation scope of the present invention. Example 1
制备粘接层乳胶:  Preparation of adhesive layer latex:
取 48份 50%丙烯酸酯乳液(北京东方化工厂 BC-2021 ), 48份 40%聚氨 酯乳液(BAYER公司 90UD ), 1 16份蒸馏水加入搅拌缸中, 以 150转 /分钟 搅拌 30分钟, 顺序加入 0. 5份流平剂 (TEG0公司 G l idol OO ), 0. 5份消泡 剂 (TEG0公司 Foamax805 ), 3份增稠剂 (Coa tex公司 BR100P ), 保持 150 转 /分钟, 搅拌 1小时出料, 乳胶粘度 21CPS。 制备墨水吸收层乳胶: Take 48 parts of 50% acrylate emulsion (Beijing Dongfang Chemical Factory BC-2021), 48 parts of 40% polyurethane emulsion (BAYER 90UD), 1 16 parts of distilled water into the mixing tank, stir at 150 rpm for 30 minutes, and add in order 0.5 parts of leveling agent (Glidol OO of TEG0 company), 0.5 parts of defoaming agent (Foamax805 of TEG0 company), 3 parts of thickener (Coa tex company BR100P), maintaining 150 rpm, stirring for 1 hour Discharge, latex viscosity 21CPS. Preparation of ink-absorbing layer latex:
取 20份 50°/。丙浠酸酯乳液(北京东方化工厂 BC- 2021 ), 20份 40%聚氨 酯乳液 ( BAYER公司 90UD ), 45份 10%PVA溶液 ( 17-88型), 68. 5份蒸馏 水加入搅拌缸中, 150转 /分钟的转速搅拌 30分钟。 将该乳液加热到 45 °C, 顺序加入 2份 10%明胶溶液(感光级), 0. 5份分散剂 ( BY 公司 DISPER181 )、 0. 5份流平剂(TEG0公司 Gl idel OO ), 0. 5份消泡剂( TEG0公司 Foamax805 ), 0. 5份固色剂 (上海助剂厂 DUR ), 150转 /分钟, 搅拌 30分钟, 依次加入 4份超细 CaC03(平定县轻质 CaC03厂)、 4份 Si02 (天津化工研究院 TB- 104 ), 2份 Ti02 (美联无机化工公司 TIONA RCL-373 ), 1份硅藻土 (天津市大港 一中化工厂), 300转 /分钟搅拌 2. 5 小时。 用刮板细度计测量乳胶细度为 18微米, 旋转粘度剂测其粘度为 110CPS。 出料包装备用。 Take 20 servings of 50 ° /. Propionate emulsion (Beijing Dongfang Chemical Factory BC-2021), 20 parts of 40% polyurethane emulsion (BAYER 90UD), 45 parts of 10% PVA solution (17-88 type), 68.5 parts of distilled water was added to the mixing tank, Stir at 150 rpm for 30 minutes. The emulsion was heated to 45 ° C, and 2 parts of a 10% gelatin solution (photosensitive grade), 0.5 parts of a dispersant (BY company DISPER181), and 0.5 parts of a leveling agent (TEG0 Gl idel OO) were sequentially added, 0 5 parts of a defoamer (TEG0 Corporation Foamax805), 0. 5 parts of fixing agent (Shanghai additives plant DUR), 150 r / min, stirred for 30 minutes, were added 4 parts of ultrafine CaC0 3 (Pingding light CaC0 3 plants), 4 parts of Si0 2 (Tianjin Institute of Chemical Technology TB-104), 2 parts of Ti0 2 (Midland Inorganic Chemical Company TIONA RCL-373), 1 part of diatomaceous earth (Tianjin Dagang No.1 Chemical Plant), 300 RPM for 2.5 hours. The fineness of the latex was 18 micrometers measured with a scraper fineness meter, and the viscosity was 110 CPS as measured with a rotational viscosity agent. Discharge packaging for future use.
生产基片:  Production substrate:
制备的粘接层乳胶在涂布机上以辊涂的方式, 涂布在 0. 3mm 的 PVC/ CaC03不透明基材上,热风烘干,涂布干胶量为 5. 5g/m2。 以同样方式在粘接 层上涂布墨水吸收层乳胶, 干胶量为 21. 3 g/m2。 得到不透明基片。 5g / m 2。 The prepared adhesive layer latex was applied on a coater in a roll coating manner, coated on an opaque substrate of 0.3 mm of PVC / CaC0 3 , dried by hot air, and the amount of coated dry glue was 5.5 g / m 2 . In the same manner, the ink-absorbing layer emulsion was coated on the adhesive layer with a dry glue amount of 21. 3 g / m 2 . An opaque substrate was obtained.
制卡:  Card:
用裁切机将上述涂好的基片裁切成 A4尺寸,用 EPSON STYLUS PHOTO EX 3 喷墨打印机在其吸收层表面正向打印图文,打印分辨率 1440dpi ,基片可快 速吸干墨水, 图文效果较好。图文表面覆带胶膜层压,层压条件:压力 4 Mpa 温度 115 °C,热压时间 20 分钟, 常温冷压时间 20分钟。 图文无变化, 膜 的 180°剥离强度为 10. 5N/cm。 实施例 2  Use a cutting machine to cut the coated substrate into A4 size, and use the EPSON STYLUS PHOTO EX 3 inkjet printer to print graphics on the surface of the absorption layer with a print resolution of 1440dpi. The substrate can quickly absorb ink. Graphic effects are better. The graphic surface is covered with adhesive film lamination. Laminating conditions: pressure 4 Mpa temperature 115 ° C, hot pressing time 20 minutes, normal temperature cold pressing time 20 minutes. There was no change in the text, and the 180 ° peel strength of the film was 10. 5 N / cm. Example 2
制备粘接层乳胶:  Preparation of adhesive layer latex:
取 48份 47%丙烯酸酯-苯乙烯共聚物乳液(北京东方化工厂 PC-( ), 48 份 40%聚氨酯乳液(BAYER公司 90UD), 109 份蒸馏水加入搅拌缸中, 150 转 /分钟搅拌 30分钟, 顺序加入 0.5份流平剂 (TEG0公司 GlidolOO), 0.5 份消泡剂 (TEG0公司 Foamax805 ), 3份增稠剂 (Coatex公司 BR100P), 保 持 150转 /分钟, 搅拌 1小时出料, 乳胶粘度 21CPS。 Take 48 parts of 47% acrylate-styrene copolymer emulsion (Beijing Dongfang Chemical Factory PC- (), 48 40% polyurethane emulsion (90UD from BAYER), 109 parts of distilled water were added to the mixing tank, and stirred at 150 rpm for 30 minutes, and 0.5 parts of a leveling agent (TEG0 GlidolOO) and 0.5 parts of an antifoaming agent (TEA0 Foamax805) were added in this order. , 3 parts thickener (Coatex BR100P), kept at 150 rpm, stirred for 1 hour and discharged, the latex viscosity was 21CPS.
制备墨水吸收层乳胶:  Preparation of ink-absorbing layer latex:
取 20份 47%丙烯酯酸和苯乙烯共聚乳液(北京东方化工厂 PC-04), 20 份 40%聚氨酯乳液(BAYER公司 90UD), 49份 10%PVA溶液( 17-88型), 47.5 份蒸馏水加入搅拌缸中 150转 /分钟, 搅拌 30分钟。 将乳液加热到 45。C, 顺序 2份 10%明胶溶液(感光级), 0.5份分散剂 (BYK公司 DISPER181)、 0.5份流平剂(TEG0公司 Glidel00)、0.5份消泡剂(TEG0公司 Foamax805 ), 0.5份固色剂 (上海助剂厂 DUR), 150转 /分钟搅拌 30分钟, 依次加入 3 份超细 CaC03(平定县轻质 CaC03厂)、 3.5份 Si02(天津化工研究院 TB- 104 ), 0.5 份硅藻土 (天津市大港一中化工厂), 300转 /分钟搅拌 2.5 小时。 用 刮板细度计测量乳胶细度为 16微米, 旋转粘度剂测其粘度为 105CPS。 出 料包装。 Take 20 parts of 47% acrylic acid and styrene copolymer emulsion (Beijing Dongfang Chemical Factory PC-04), 20 parts of 40% polyurethane emulsion (BAYER 90UD), 49 parts of 10% PVA solution (17-88 type), 47.5 parts Distilled water was added to the mixing tank at 150 rpm and stirred for 30 minutes. Heat the emulsion to 45. C, 2 parts of 10% gelatin solution (photosensitive grade), 0.5 parts of dispersant (BYK DISPER181), 0.5 parts of leveling agent (TEG0 company Glidel00), 0.5 parts of antifoaming agent (TEG0 company Foamax805), 0.5 parts of color fixing Agent (Shanghai Auxiliary Plant DUR), stirring at 150 rpm for 30 minutes, adding 3 parts of ultra-fine CaC0 3 (Pingding Light CaC0 Factory 3 ), 3.5 parts of Si0 2 (Tianjin Institute of Chemical Technology TB-104), 0.5 Portion of diatomaceous earth (Tianjin No.1 Sinochem Plant), stirred at 300 rpm for 2.5 hours. The fineness of the latex was measured with a scraper fineness meter to be 16 micrometers, and the viscosity was measured to be 105 CPS with a rotational viscosity agent. Out packaging.
生产基片:  Production substrate:
将以上制备的粘接层乳胶在涂布机上以辊涂的方式, 涂布在 0.08mm的 PVC 半透明基材上,热风供干,涂布干胶量为 5.8g/m2。 以同样方式在粘接 层上涂布墨水吸收层乳胶, 干燥, 干胶量为 19.5 g/m2。 得到半透明基片。 The adhesive layer latex prepared above was roll-coated on a coater on a 0.08 mm PVC translucent substrate, which was dried by hot air, and the dry coating amount was 5.8 g / m 2 . In the same manner, the ink-absorbing layer latex was coated on the adhesive layer and dried, and the dry glue amount was 19.5 g / m 2 . A translucent substrate was obtained.
制卡:  Card:
用裁切机将涂好的基片裁切成 A4尺寸, 用 CANON BJC 6500喷墨打印 机将图文反向打印在上述半透明基片上,打印分辨率 1440dpi,基片可快速 吸干墨水, 图文效果较好。 该打印有图文的基片覆在 0.3隱厚表面涂布了 粘接层的 PVC/ CaC03不透明材上,打印面面向基材粘接层面层压, 层压条 件: 压力 4 Mpa温度 115'C,热压时间, 20分钟, 冷压时间 20分钟。 图文 清晰无变化, 膜的 180。剥离强度为 9.4N/cm。 实施例 3 Use a cutting machine to cut the coated substrate into A4 size. Use a CANON BJC 6500 inkjet printer to print the text on the translucent substrate in reverse. The printing resolution is 1440dpi. The substrate can quickly absorb ink. The effect is better. The printed substrate is coated on an opaque PVC / CaC0 3 material with an adhesive layer coated on a 0.3-thick surface. The printed side faces the substrate and the adhesive layer is laminated. Laminating conditions: pressure 4 Mpa temperature 115 ' C, hot pressing time, 20 minutes, cold pressing time 20 minutes. Graphic Clear without change, 180 of film. The peeling strength was 9.4 N / cm. Example 3
制备粘接层乳胶:  Preparation of adhesive layer latex:
取 40份 50%丙烯酸酯乳液(北京东方化工厂 BC-2021 ), 56份 40%聚氨 酯乳液(BAYER公司 90UD), 112 份蒸馏水加入搅拌缸中, 150 转 /分钟搅 拌 30分钟, 顺序加入 0.5份流平剂 (TEG0公司 Glidol00)、 0.5份消泡剂 (TEG0公司 Foamax805 ), 2份增稠剂 (BAYER公司 LW44 ), 保持 150转 /分 钟, 搅拌 1小时出料, 乳胶粘度 28CPS(40°C)。  Take 40 parts of 50% acrylate emulsion (Beijing Dongfang Chemical Factory BC-2021), 56 parts of 40% polyurethane emulsion (BAYER 90UD), 112 parts of distilled water into the mixing tank, 150 rpm for 30 minutes, add 0.5 parts in order Leveling agent (Glidol00 of TEG0 company), 0.5 part of defoamer (Foamax805 of TEG0 company), 2 parts of thickener (LY44 of BAYER company), keep 150 rpm, stir for 1 hour and discharge, latex viscosity 28CPS (40 ° C ).
制备墨水吸收层乳胶:  Preparation of ink-absorbing layer latex:
取 20份 47%丙烯酸酯-苯乙烯共聚物乳液(北京东方化工厂 PC-04 ), 20 份 40%聚氨酯乳液(BAYER公司 90UD), 49份 10%PVA溶液( 17- 88型), 47.5 份蒸馏水加入搅拌缸中, 150转 /分钟搅拌 30分钟。 将乳液加热到 45°C, 顺序加入 2份 10%明胶溶液(感光级), 0.5份分散剂(BYK公司 DISPER181 ), 0.5份流平剂(TEG0公司 Glidel00)、0.5份消泡剂(TEG0公司 Foamax805 ), 0.5份固色剂 (上海助剂厂 DUR), 150转 /分钟搅拌 30分钟, 依次加入 3 份超细 CaC03(平定县 ^质 CaC03厂)、 3.5份 Si02(天津化工研究院 TB- 104 ), 0.5 份硅藻土 (天津市大港一中化工厂), 300转 /分钟搅拌 2.5 小时。 用 刮板细度计测量乳胶细度为 17 微米, 旋转粘度剂测其粘度为 105CPS(40 °C)。 出料包装。 Take 20 parts of 47% acrylate-styrene copolymer emulsion (Beijing Dongfang Chemical Factory PC-04), 20 parts of 40% polyurethane emulsion (BAYER Company 90UD), 49 parts of 10% PVA solution (17-88 type), 47.5 parts Distilled water was added to the mixing tank and stirred at 150 rpm for 30 minutes. Heat the emulsion to 45 ° C, add 2 parts of 10% gelatin solution (photosensitive grade), 0.5 part of dispersant (BYK DISPER181), 0.5 part of leveling agent (TEG0 Glidel00), 0.5 part of antifoaming agent (TEG0) Foamax805), 0.5 parts of fixing agent (Shanghai Auxiliary Factory DUR), 150 rpm stirring for 30 minutes, 3 parts of ultra-fine CaC0 3 (Pingding ^ quality CaC0 3 plant), 3.5 parts of Si0 2 (Tianjin Chemical Research TB-104), 0.5 parts of diatomaceous earth (Dagang No.1 Sinochem Plant in Tianjin), and stirred at 300 rpm for 2.5 hours. The fineness of the latex was 17 micrometers measured with a scraper fineness meter, and the viscosity was 105 CPS (40 ° C) measured by a rotational viscosity agent. Out packaging.
生产基片:  Production substrate:
制备的粘接层乳胶在涂布机上以浸涂的方式, 涂布在 0. lmm的 PC透明 膜上,热风烘干,烘干温度 65°C涂布干胶量为 5.8g/m2。 以同样方式在粘接 层上涂布墨水吸收层乳胶, 干胶量为 24.2 g/m2。 制成半透明基片。 The prepared adhesive layer latex was dip-coated on a coater, and was coated on a transparent PC film of 0.1 mm, dried by hot air, and dried at a temperature of 65 ° C. The amount of dry glue applied was 5.8 g / m 2 . In the same manner, the ink-absorbing layer emulsion was coated on the adhesive layer with a dry glue amount of 24.2 g / m 2 . Made into a translucent substrate.
制卡: 用裁切机将涂好的基片裁切成 A4尺寸, 分别用 CANON BJC 6500喷墨 打印机将囹文反向在打印在基片上,打印分辨率 1440dpi,基片可快速吸干 墨水, 图文效果较好。 基片覆在 0.28隱厚的 PVC/ CaC03基材上,该不透明 基材与打印图文的接触面涂布有同样的粘接层, 层压条件: 压力 4 Mpa 温 度 115°C,热压时间, 20 分钟, 常温冷压时间 20 分钟。 图文清晰无变化, 膜的 180°剥离强度为 8.9N/cm。 实施例 4 Card: Use a cutting machine to cut the coated substrate into A4 size, and use a CANON BJC 6500 inkjet printer to print the script on the substrate in reverse. The printing resolution is 1440dpi. The substrate can quickly absorb ink. The effect is better. The substrate is coated on a 0.28 hidden thick PVC / CaC0 3 substrate. The contact surface of the opaque substrate and the printed graphics is coated with the same adhesive layer. Lamination conditions: pressure 4 Mpa temperature 115 ° C, hot pressing Time, 20 minutes, cold pressing time at room temperature 20 minutes. The picture is clear and unchanged, and the 180 ° peel strength of the film is 8.9 N / cm. Example 4
制备粘接层乳胶:  Preparation of adhesive layer latex:
取 42份 50%丙烯酸酯乳液(北京东方化工厂 BC-2021 ), 54份 40%聚氨 酯乳液(BAYER公司 90UD), 113份蒸馏水加入搅拌缸中, 150转 /分钟搅 拌 30分钟, 顺序加入 0.5份流平剂 (TEG0公司 Glidol00)、 0.5份消泡剂 (TEG0公司 Foamax805 ), 2份增稠剂 (BAYER公司 LW44 ), 保持 150转 /分 钟, 搅拌 1小时出料, 乳胶粘度 30CPS(40°C)。  Take 42 parts of 50% acrylate emulsion (Beijing Dongfang Chemical Factory BC-2021), 54 parts of 40% polyurethane emulsion (BAYER 90UD), 113 parts of distilled water into the mixing tank, 150 rpm for 30 minutes, and add 0.5 parts in order Leveling agent (Glidol00 of TEG0 company), 0.5 part of defoamer (Foamax805 of TEG0 company), 2 parts of thickener (LY44 of BAYER company), keep 150 rpm, stir for 1 hour and discharge, latex viscosity 30CPS (40 ° C ).
制备墨水吸收层乳胶:  Preparation of ink-absorbing layer latex:
取 20份 50%丙烯酸酯乳液(北京东方化工厂 BC- 2021 ), 20份 40%聚氨 酯乳液 ( BAYER公司 90UD ), 45份 10%PVA溶液 ( 17-88型), 68, 5份蒸馏 水加入搅拌缸中, 150转 /分钟搅拌 30分钟。 将乳液加热到 45°C, 顺序加 入 2份 10%明胶溶液(感光级), 0.5份分散剂 (BYK公司 DISPER181)、 0.5 份流平剂 (TEG0公司 GlidelOO), 0.5份消泡剂 (TEG0公司 Foamax805 ), 0.5份固色剂 (上海助剂厂 DUR), 150转 /分钟, 搅拌 30分钟, 依次加入 4份超细 CaC03(平定县轻质 &(:03厂)、 4份 Si02(天津化工研究院 TB- 104 ), 2份 Ti02 (美联无机化工公司 TIONA RCL- 373 )、 1 份硅藻土 (天津市大港 一中化工厂), 300转 /分钟搅拌 2.5 小时。 用刮板细度计测量乳胶细度为 18微米, 旋转粘度剂测其粘度为 110CPS。 出料包装。 生产基片: Take 20 parts of 50% acrylate emulsion (Beijing Dongfang Chemical Factory BC-2021), 20 parts of 40% polyurethane emulsion (BAYER 90UD), 45 parts of 10% PVA solution (17-88 type), 68, 5 parts of distilled water and stir. Stir in a cylinder at 150 rpm for 30 minutes. Heat the emulsion to 45 ° C, add 2 parts of 10% gelatin solution (photosensitive grade), 0.5 part of dispersant (BYK DISPER181), 0.5 part of leveling agent (TEG0 GlidelOO), 0.5 part of antifoaming agent (TEG0) Foamax805), 0.5 parts of fixing agent (Shanghai Auxiliary Factory DUR), 150 rpm, stirring for 30 minutes, 4 parts of ultra-fine CaC0 3 (Pingding County Lightweight & (: 0 3 plant), 4 parts of Si0 2 (Tianjin Institute of Chemical TB- 104), 2 parts of Ti0 2 (AP inorganic chemical company TIONA RCL- 373), 1 part of diatomaceous earth (Tianjin port in a chemical plant), 300 rev / min stirring for 2.5 hours. with The fineness of the latex is 18 micrometers measured by a scraper fineness meter, and the viscosity is 110 CPS measured by a rotational viscosity agent. Production substrate:
制备的粘接层乳胶在涂布机上以辊涂的方式,涂布在 0. 3mm的 PVC/ ABS 不透明基材上, 55 °C热风烘干,涂布干胶量为 6. lg/m2; 以同样方式在粘接 层上涂布墨水吸收层乳胶, 干胶量为 23. 9 g/m2, 得到不透明基片。 Lg / m 2 The prepared adhesive layer latex was roller-coated on a coating machine, coated on a PVC / ABS opaque substrate of 0. 3mm, dried at 55 ° C in a hot air, and the dry coating amount was 6. lg / m 2 In the same manner, the ink-absorbing layer latex was coated on the adhesive layer with a dry glue amount of 23.9 g / m 2 to obtain an opaque substrate.
制卡:  Card:
用裁切机将涂好的基片裁切成 A4尺寸,分别用 EPSON STYLUS PHOTO EX3 喷墨打印机打印图文,打印分辨率 1440dpi,基片可快速吸干墨水, 图文效 果较好。表面履 0. 08隱厚 PVC带胶膜层压, 层压条件: 压力 4 Mpa温度 115 °C ,热压时间 20分钟, 冷压时间 20分钟。 图文无变化, 膜的 180°剥离强 度为 9. 8N/cm。 得到单面印刷卡片。  Use a cutting machine to cut the coated substrate into A4 size, and use EPSON STYLUS PHOTO EX3 inkjet printer to print the graphics. The print resolution is 1440dpi. The substrate can quickly dry the ink, and the graphics are better. Surface tread 0.08 hidden thick PVC film with lamination, laminating conditions: pressure 4 Mpa temperature 115 ° C, hot pressing time 20 minutes, cold pressing time 20 minutes. There is no change in the text, and the 180 ° peel strength of the film is 9.8 N / cm. Get single-sided printed cards.

Claims

权利要求书 Claim
1、 一种数码制卡专用基片, 该基片包括有高分子基材, 在基材表面涂 布有粘接层, 在粘接层表面涂布有墨水吸收层。 1. A special substrate for digital card manufacturing, the substrate includes a polymer substrate, an adhesive layer is coated on the surface of the substrate, and an ink absorbing layer is coated on the surface of the adhesive layer.
2、 权利要求 1所述的数码制卡专用基片, 其中: 所述高分子基材包括 选自聚氯乙烯、 曱基丙烯酸酯 -丁二烯-苯乙烯共聚物、 聚对苯二曱酸乙二 醇酯和聚碳酸酯的半透明基材, 或选自可降解聚氯乙烯、 聚氯乙烯 /丙烯 腈-丁二烯 -苯乙烯共聚物共混材料、 聚氯乙烯 /碳酸钙混合材料、 聚对苯 二曱酸乙二醇酯和丙烯腈-丁二烯 -苯乙烯共聚物的不透明基材。  2. The substrate for digital card manufacturing according to claim 1, wherein: the polymer base material is selected from the group consisting of polyvinyl chloride, fluorenyl acrylate-butadiene-styrene copolymer, and polyterephthalic acid Translucent substrate of glycol ester and polycarbonate, or selected from degradable polyvinyl chloride, polyvinyl chloride / acrylonitrile-butadiene-styrene copolymer blend material, polyvinyl chloride / calcium carbonate blend material , Opaque substrate of polyethylene terephthalate and acrylonitrile-butadiene-styrene copolymer.
3、 权利要求 1所述的数码制卡专用基片, 其中: 所述粘接层是由主要 包括下述原料乳液的粘接层乳胶涂布而成: 聚氨酯与丙烯酸酯、 丙烯酸酯 -苯乙浠共聚物、 乙烯 -乙酸乙烯共聚物、 或乙酸乙烯酯 -丙烯酸酯共聚物 的混合物, 且该粘接层为透明粘接层。  3. The special substrate for digital card manufacturing according to claim 1, wherein: the adhesive layer is latex coated with an adhesive layer mainly comprising the following raw material emulsions: polyurethane and acrylate, acrylate-styrene A fluorene copolymer, an ethylene-vinyl acetate copolymer, or a mixture of a vinyl acetate-acrylate copolymer, and the adhesive layer is a transparent adhesive layer.
4、 权利要求 1所述的数码制卡专用基片, 其中: 所述墨水吸收层是由 主要包括下述原料乳液的吸收层乳胶涂布而成: 聚氨酯与丙烯酸酯、 丙烯 酸酯与苯乙烯共聚物、 乙烯 -乙酸乙烯共聚物、 或乙酸乙烯酯与丙烯酸酯 共聚物的混合物, 以及聚乙烯醇溶液和明胶溶液, 为可吸收打印墨水的半 透明吸收层。  4. The substrate for digital card manufacturing according to claim 1, wherein: the ink absorbing layer is coated with latex mainly comprising the following raw material emulsion: polyurethane and acrylate, acrylate and styrene copolymerized Polymers, ethylene-vinyl acetate copolymers, or mixtures of vinyl acetate and acrylate copolymers, as well as polyvinyl alcohol solutions and gelatin solutions, are translucent absorbent layers that can absorb printing ink.
5、 权利要求 2所述的数码专用基片, 该基片是不透明基片, 该不透明 基片的两面均顺序涂布有粘接层和墨水吸收层。  5. The digital special substrate according to claim 2, wherein the substrate is an opaque substrate, and both sides of the opaque substrate are sequentially coated with an adhesive layer and an ink absorbing layer.
6、 权利要求 1-5所述数码制卡专用基片的制备方法, 其包括在基材表 面顺序涂布粘接层乳胶和墨水吸收层乳胶的过程, 其中,  6. The method for preparing a substrate for digital card manufacturing according to claims 1-5, comprising a process of sequentially coating an adhesive layer latex and an ink absorbing layer latex on the surface of the substrate, wherein,
粘接层乳胶为将原料乳液混合搅拌均勾后, 加入助剂继续搅拌而成, 使乳胶粘度在 15-40厘泊;  The adhesive layer latex is made by mixing and stirring the raw material emulsion and adding the auxiliary agent to continue stirring, so that the latex viscosity is 15-40 centipoise;
墨水吸收层乳胶为原料乳液与聚乙烯醇溶液的混合物料中加入明胶溶 液和助剂及超细碳酸钙和吸附剂搅拌制备而成, 且该乳胶的细度 20 微 米, 粘度在 80-120厘泊; Ink absorbing layer latex is used as a raw material, and a mixture of polyvinyl alcohol solution and gelatin is added Liquid and additives and ultra-fine calcium carbonate and adsorbent are prepared by stirring, and the fineness of the latex is 20 microns, the viscosity is 80-120 centipoise;
涂布后基片上粘接层和墨水吸收层的每平方米干胶量分别为 5-10克和 15- 30克。  The dry glue amount per square meter of the adhesive layer and the ink absorbing layer on the substrate after coating was 5-10 g and 15-30 g, respectively.
7、 权利要求 6所述的制备方法, 其中, 在制备粘接层乳胶时, 每 100 重量份的原料中, 包括 94-98 份由 20- 60%聚氨酯乳液与 30- 60%丙烯酸酯 乳液、 30- 60%丙烯酸酯-苯乙烯共聚物乳液、 30-60%乙烯-乙酸乙浠共聚物 乳液、 或 30-60%乙酸乙烯酯-丙烯酸酯共聚物乳液组成的混合乳液。  7. The preparation method according to claim 6, wherein, in preparing the adhesive layer latex, each 100 parts by weight of the raw material comprises 94-98 parts of 20-60% polyurethane emulsion and 30-60% acrylate emulsion, A mixed emulsion composed of 30-60% acrylate-styrene copolymer emulsion, 30-60% ethylene-acetic acid acetate copolymer emulsion, or 30-60% vinyl acetate-acrylate copolymer emulsion.
8、 权利要求 6所述的制备方法, 其中, 在制备墨水吸收层乳胶时, 每 100重量份的原料中, 包括 35-45份由 20-60%聚氨酯乳液与 30-60%丙烯酸 酯乳液、 30- 60%丙烯酸酯-苯乙烯共聚物乳液、 30- 60°/。乙烯-乙酸乙烯共聚 物乳液、 或 30- 60%乙酸乙烯酯 -丙烯酸酯共聚物乳液组成的混合乳液, 原 料中还包括 42-48份 10%聚乙烯醇溶液、 1-3份 5- 10°/»明胶溶液、 2- 6份超 细碳酸钙。  8. The preparation method according to claim 6, wherein, in preparing the ink-absorbing layer latex, each 100 parts by weight of the raw material includes 35-45 parts of a 20-60% polyurethane emulsion and a 30-60% acrylate emulsion, 30-60% acrylate-styrene copolymer emulsion, 30-60 ° /. Ethylene-vinyl acetate copolymer emulsion, or mixed emulsion composed of 30-60% vinyl acetate-acrylate copolymer emulsion, the raw materials also include 42-48 parts of a 10% polyvinyl alcohol solution, 1-3 parts of 5- 10 ° / »Gelatin solution, 2 to 6 parts of ultrafine calcium carbonate.
9、 权利要求 6、 7、 8所述的制备方法, 其中, 粘接层乳胶制备中所用 助剂包括流平剂、 消泡剂、 增稠剂, 其总量为 2-6 重量份; 墨水吸收层乳 胶制备中所用助剂包括分散剂、 流平剂、 消泡剂、 固色剂, 其总量为 1-3 份, 所述吸附剂包括二氧化硅、 二氧化钛、 硅藻土。  9. The preparation method according to claim 6, 7, and 8, wherein the auxiliary agent used in the preparation of the adhesive layer latex includes a leveling agent, an antifoaming agent, and a thickener, and the total amount thereof is 2-6 parts by weight; ink The auxiliary used in the preparation of the absorbent layer latex includes a dispersant, a leveling agent, an antifoaming agent, and a fixing agent, and the total amount thereof is 1-3 parts, and the adsorbent includes silica, titanium dioxide, and diatomaceous earth.
10、 一种数码印刷卡片, 该卡片采用权利要求 1 - 5 所述基片, 在基片 的墨水吸收层上打印有图文层。  10. A digital printed card using the substrate according to claim 1 to 5, and a graphic layer is printed on the ink absorbing layer of the substrate.
11、 权利要求 10所述的数码印刷卡, 所述图文层被正向打印在不透明 基片的墨水吸收层上, 表面层压覆有半透明基材或带胶膜。  11. The digital printing card according to claim 10, wherein the graphic layer is printed on the ink absorbing layer of the opaque substrate in a forward direction, and the surface is laminated with a translucent substrate or an adhesive film.
12、 权利要求 10所述的数码印刷卡, 所述图文层被反向打印在半透明 基片的墨水吸收层上, 该图文层表面压覆有涂布了粘接剂的不透明基材。  12. The digital printing card according to claim 10, wherein the graphic layer is reverse printed on the ink-absorbing layer of a translucent substrate, and the surface of the graphic layer is laminated with an opaque substrate coated with an adhesive. .
PCT/CN2001/001293 2001-08-30 2001-08-30 Base sheet specially for digital card-marking and its preparing method WO2003022576A1 (en)

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CN104149513A (en) * 2014-09-02 2014-11-19 江苏格美高科技发展有限公司 Coating class printing media and manufacturing method thereof
CN106117587A (en) * 2016-08-19 2016-11-16 上海谷奇数码科技有限公司 Erect image multi-functional Weak solvent printed material, the preparation method of printed material and card
CN106117586A (en) * 2016-08-19 2016-11-16 上海谷奇数码科技有限公司 Mirror image multi-functional Weak solvent printed material, the preparation method of printed material and card

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CN109135607A (en) * 2018-08-23 2019-01-04 天津博苑高新材料有限公司 A kind of lamination fabrication Film laminated substrate and the manufacturing process of durability
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Cited By (5)

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CN102774162A (en) * 2011-05-11 2012-11-14 上海纳尔数码喷印材料股份有限公司 PE braided base cloth digital printing material and manufacturing technology thereof
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CN104149513A (en) * 2014-09-02 2014-11-19 江苏格美高科技发展有限公司 Coating class printing media and manufacturing method thereof
CN106117587A (en) * 2016-08-19 2016-11-16 上海谷奇数码科技有限公司 Erect image multi-functional Weak solvent printed material, the preparation method of printed material and card
CN106117586A (en) * 2016-08-19 2016-11-16 上海谷奇数码科技有限公司 Mirror image multi-functional Weak solvent printed material, the preparation method of printed material and card

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