CN104145045B - 补充组合物和补充预处理组合物的方法 - Google Patents
补充组合物和补充预处理组合物的方法 Download PDFInfo
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- CN104145045B CN104145045B CN201380010516.8A CN201380010516A CN104145045B CN 104145045 B CN104145045 B CN 104145045B CN 201380010516 A CN201380010516 A CN 201380010516A CN 104145045 B CN104145045 B CN 104145045B
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- 239000002184 metal Substances 0.000 claims abstract description 147
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 80
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- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 52
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 52
- 229910001512 metal fluoride Inorganic materials 0.000 claims abstract description 25
- 229910052747 lanthanoid Inorganic materials 0.000 claims abstract description 11
- 150000002602 lanthanoids Chemical class 0.000 claims abstract description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 8
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- 230000001502 supplementing effect Effects 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 35
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 8
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- 239000011701 zinc Substances 0.000 claims description 8
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- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims description 5
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
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- ZEFWRWWINDLIIV-UHFFFAOYSA-N tetrafluorosilane;dihydrofluoride Chemical compound F.F.F[Si](F)(F)F ZEFWRWWINDLIIV-UHFFFAOYSA-N 0.000 claims description 3
- KKGJAWQIZNKDHY-UHFFFAOYSA-J [O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.OI(=O)=O.OI(=O)=O.O.[Zr+4] Chemical compound [O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.OI(=O)=O.OI(=O)=O.O.[Zr+4] KKGJAWQIZNKDHY-UHFFFAOYSA-J 0.000 claims description 2
- LYTNHSCLZRMKON-UHFFFAOYSA-L oxygen(2-);zirconium(4+);diacetate Chemical compound [O-2].[Zr+4].CC([O-])=O.CC([O-])=O LYTNHSCLZRMKON-UHFFFAOYSA-L 0.000 claims description 2
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- 230000008901 benefit Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 229940005989 chlorate ion Drugs 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-M chlorite Chemical compound [O-]Cl=O QBWCMBCROVPCKQ-UHFFFAOYSA-M 0.000 description 1
- 229940005993 chlorite ion Drugs 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000004673 fluoride salts Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 125000000350 glycoloyl group Chemical group O=C([*])C([H])([H])O[H] 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 239000006115 industrial coating Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NPFOYSMITVOQOS-UHFFFAOYSA-K iron(III) citrate Chemical class [Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NPFOYSMITVOQOS-UHFFFAOYSA-K 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229940005654 nitrite ion Drugs 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- DKEUYXJXQSBKBQ-UHFFFAOYSA-N oxygen(2-);zirconium(4+);dinitrate Chemical compound [O-2].[Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O DKEUYXJXQSBKBQ-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- LLYCMZGLHLKPPU-UHFFFAOYSA-M perbromate Chemical compound [O-]Br(=O)(=O)=O LLYCMZGLHLKPPU-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- BFXAWOHHDUIALU-UHFFFAOYSA-M sodium;hydron;difluoride Chemical compound F.[F-].[Na+] BFXAWOHHDUIALU-UHFFFAOYSA-M 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229960005137 succinic acid Drugs 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229960001367 tartaric acid Drugs 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 description 1
- XJUNLJFOHNHSAR-UHFFFAOYSA-J zirconium(4+);dicarbonate Chemical compound [Zr+4].[O-]C([O-])=O.[O-]C([O-])=O XJUNLJFOHNHSAR-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/86—Regeneration of coating baths
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Cosmetics (AREA)
Abstract
Description
六氟锆酸,45%(获自Honeywell) | 5.6% |
碱式碳酸锆(获自Blue Line Corporation) | 1.3% |
硝酸铜溶液,18%铜(获自Shepherd Chemical) | 1.8% |
去离子水 | 余量 |
六氟锆酸,45%(获自Honeywell) | 17.58% |
碱式碳酸锆(获自Blue Line Corporation) | 5.86% |
甲烷磺酸(获自Sigma-Aldrich Company) | 7.42% |
硝酸铜溶液,18%铜(获自Shepherd Chemical) | 7.6% |
去离子水 | 余量 |
Claims (19)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/402,951 US20120145039A1 (en) | 2009-10-08 | 2012-02-23 | Replenishing compositions and methods of replenishing pretreatment compositions |
US13/402,951 | 2012-02-23 | ||
PCT/US2013/027225 WO2013126632A1 (en) | 2012-02-23 | 2013-02-22 | Replenishing compositions and methods of replenishing pretreatment compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104145045A CN104145045A (zh) | 2014-11-12 |
CN104145045B true CN104145045B (zh) | 2018-03-02 |
Family
ID=47833416
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201380010516.8A Active CN104145045B (zh) | 2012-02-23 | 2013-02-22 | 补充组合物和补充预处理组合物的方法 |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP2817435B1 (zh) |
KR (1) | KR101664637B1 (zh) |
CN (1) | CN104145045B (zh) |
CA (1) | CA2864754C (zh) |
ES (1) | ES2564283T3 (zh) |
HK (1) | HK1198660A1 (zh) |
HU (1) | HUE027975T2 (zh) |
IN (1) | IN2014DN07065A (zh) |
MX (1) | MX2014010231A (zh) |
PL (1) | PL2817435T3 (zh) |
RU (1) | RU2014138258A (zh) |
WO (1) | WO2013126632A1 (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103695883A (zh) * | 2014-01-13 | 2014-04-02 | 马连众 | 一种环保型冷轧钢板硅化剂及其制备方法 |
GB201407690D0 (en) * | 2014-05-01 | 2014-06-18 | Henkel Ag & Co Kgaa | Non chromate coloured conversion coating for aluminum |
HUE036114T2 (hu) * | 2014-12-12 | 2018-06-28 | Henkel Ag & Co Kgaa | Optimalizált eljárási rendszer fluorid-tartalmú fürdõkön alapuló korrózióvédelmi fém-elõkezeléshez |
JP6837332B2 (ja) | 2016-12-28 | 2021-03-03 | 日本パーカライジング株式会社 | 化成処理剤、化成皮膜の製造方法、化成皮膜付き金属材料、及び塗装金属材料 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101705482A (zh) * | 2009-11-19 | 2010-05-12 | 广州电器科学研究院 | 一种烷基磺酸化学镀锡液及基于该化学镀锡液的镀锡工艺 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4370177A (en) * | 1980-07-03 | 1983-01-25 | Amchem Products, Inc. | Coating solution for metal surfaces |
EP0739428B1 (en) * | 1993-11-29 | 1999-10-13 | Henkel Corporation | Composition and process for treating metal |
US5614650A (en) * | 1995-03-07 | 1997-03-25 | Sandler; Stanley R. | Zirconium compounds of sulfonic acids |
ATE412073T1 (de) | 2002-12-24 | 2008-11-15 | Chemetall Gmbh | Verfahren zur vorbehandlung vor der beschichtung |
US8673091B2 (en) | 2007-08-03 | 2014-03-18 | Ppg Industries Ohio, Inc | Pretreatment compositions and methods for coating a metal substrate |
AU2009225715B2 (en) * | 2008-03-17 | 2013-09-26 | Henkel Ag & Co. Kgaa | Metal treatment coating compositions, methods of treating metals therewith and coated metals prepared using the same |
US8951362B2 (en) * | 2009-10-08 | 2015-02-10 | Ppg Industries Ohio, Inc. | Replenishing compositions and methods of replenishing pretreatment compositions |
-
2013
- 2013-02-22 KR KR1020147023548A patent/KR101664637B1/ko active IP Right Grant
- 2013-02-22 CA CA2864754A patent/CA2864754C/en active Active
- 2013-02-22 MX MX2014010231A patent/MX2014010231A/es active IP Right Grant
- 2013-02-22 ES ES13708018.0T patent/ES2564283T3/es active Active
- 2013-02-22 WO PCT/US2013/027225 patent/WO2013126632A1/en active Application Filing
- 2013-02-22 CN CN201380010516.8A patent/CN104145045B/zh active Active
- 2013-02-22 EP EP13708018.0A patent/EP2817435B1/en active Active
- 2013-02-22 RU RU2014138258A patent/RU2014138258A/ru not_active Application Discontinuation
- 2013-02-22 PL PL13708018T patent/PL2817435T3/pl unknown
- 2013-02-22 IN IN7065DEN2014 patent/IN2014DN07065A/en unknown
- 2013-02-22 HU HUE13708018A patent/HUE027975T2/en unknown
-
2014
- 2014-12-02 HK HK14112118.6A patent/HK1198660A1/zh unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101705482A (zh) * | 2009-11-19 | 2010-05-12 | 广州电器科学研究院 | 一种烷基磺酸化学镀锡液及基于该化学镀锡液的镀锡工艺 |
Also Published As
Publication number | Publication date |
---|---|
CA2864754C (en) | 2016-08-16 |
MX2014010231A (es) | 2014-11-12 |
HK1198660A1 (zh) | 2015-05-22 |
HUE027975T2 (en) | 2016-11-28 |
KR20140119762A (ko) | 2014-10-10 |
IN2014DN07065A (zh) | 2015-04-10 |
EP2817435B1 (en) | 2016-02-17 |
CN104145045A (zh) | 2014-11-12 |
ES2564283T3 (es) | 2016-03-21 |
PL2817435T3 (pl) | 2016-08-31 |
CA2864754A1 (en) | 2013-08-29 |
KR101664637B1 (ko) | 2016-10-10 |
EP2817435A1 (en) | 2014-12-31 |
RU2014138258A (ru) | 2016-04-10 |
WO2013126632A1 (en) | 2013-08-29 |
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