CN104140577B - A kind of anti-slip sole and slip-proof shoes - Google Patents
A kind of anti-slip sole and slip-proof shoes Download PDFInfo
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- CN104140577B CN104140577B CN201410388008.XA CN201410388008A CN104140577B CN 104140577 B CN104140577 B CN 104140577B CN 201410388008 A CN201410388008 A CN 201410388008A CN 104140577 B CN104140577 B CN 104140577B
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- parts
- sole
- slip
- formula
- nitrile rubber
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- 239000000463 material Substances 0.000 claims abstract description 14
- 229920000459 Nitrile rubber Polymers 0.000 claims description 20
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 16
- 239000011667 zinc carbonate Substances 0.000 claims description 16
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 16
- 235000004416 zinc carbonate Nutrition 0.000 claims description 16
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 13
- 235000021355 Stearic acid Nutrition 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 12
- 239000008117 stearic acid Substances 0.000 claims description 12
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 11
- 230000003213 activating effect Effects 0.000 claims description 11
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- 239000006229 carbon black Substances 0.000 claims description 10
- 235000019504 cigarettes Nutrition 0.000 claims description 10
- 206010023126 Jaundice Diseases 0.000 abstract description 3
- 230000002159 abnormal effect Effects 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- 239000005060 rubber Substances 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229940069744 2,2'-dithiobisbenzothiazole Drugs 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- -1 octadecanoid acid Chemical compound 0.000 description 1
- 150000002885 octadecanoids Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
Landscapes
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of anti-slip sole formula and sole based on this formula and footwear, sole that this formula prepares and footwear, while keeping anti-wear performance, compressive property, contrast conventional soles lighterization, and breathability is strong, and the shoes prepared are dressed lighter, comfortable；The sole prepared by this formula can be with disposal molding, it is not necessary to any processing；The sole that formula of sole material of the present invention prepares is without telling the quality abnormal such as frost, jaundice.And the anti-skid property of soles of this formula system is excellent, can be suitable on the snowfield of ice face using.
Description
Technical field
The present invention relates to sole material field, be specifically related to a kind of anti-slip sole and slip-proof shoes.
Background technology
Shoes are normal commonly used article in our daily life, and sole is to make the requisite part of shoes.At present, market upper part sole uses the deficiency of formula due to it, causes the sole produced overweight.If the sole lighter weight produced, then relevant performance, such as: anti-wear performance, compressive property can reduce.And due to the restriction of formula, sole has used easy jaundice long, has told frost；And containing heavy metal, lead etc. in part formulation, human body is caused certain injury.Formula components is different, and the reason that content is different, the non-skid property causing sole is undesirable.
Summary of the invention
In order to solve the deficiencies in the prior art, the present invention provides a kind of anti-slip sole formula and sole based on this formula and footwear.
The technical solution that the present invention uses is:
A kind of anti-slip sole formula, described formula of soles is made up of following mass parts material:
35L type nitrile rubber 45 56 parts, 1052 type nitrile rubber 44 55 parts, carbon black 16 20 parts, white cigarette 6 10 parts, DOP 6 parts, diphenylguanidine 0.5 part, zinc carbonate (ZnCO3) 5 parts, stearic acid 1 part, antioxidant SP 1 part, activating agent PEG 0.9 part, accelerator OH3 2 parts, additive DM 2 parts.
Described a kind of anti-slip sole formula, described formula of soles is made up of following mass parts material:
35L type nitrile rubber 50 parts, 1052 type nitrile rubber 50 parts, carbon black 20 parts, white cigarette 6 parts, DOP 6 parts, diphenylguanidine 0.5 part, zinc carbonate (ZnCO3) 5 parts, stearic acid 1 part, antioxidant SP 1 part, activating agent PEG 0.9 part, accelerator OH3 2 parts, additive DM 2 parts.
A kind of anti-slip sole, including half sole and heel, described half sole and heel are provided with skid resistant course, and described skid resistant course is made up of the formula materials described in claim 1 or 2.
Described anti-slip sole, described skid resistant course uses post forming on half sole and heel.
May be used without skid resistant course material and be directly prepared into whole sole.
A kind of slip-proof shoes, including sole and upper of a shoe, described sole is the sole described in claim 3.
35L type nitrile rubber and 1052 type nitrile rubbers are the synthetic rubber that a kind of oil resistivity is fabulous, wearability is higher, thermostability is preferable, bonding force is strong.Two kinds of two kinds of rubber that simply height containing propylene fine content is different.
Carbon black: mainly make reinforcing agent and the filler of rubber.
White cigarette belongs to additive, in order to strengthen physical property, and the aspect such as the most wear-resisting, hardness, pulling force anti tear.
DOP: be a kind of plasticizer, can be inserted between high-polymer molecular chain, weaken intermolecular active force, increase the distance between high-polymer molecular chain and activity space, increase the plasticity of high polymer, reduce the processing temperature of high polymer.
Diphenylguanidine: have another name called diphenylguanidine, has plasticizer and contracting to solve the effect of agent in elastomeric material.
Zinc carbonate (ZnCO3): pollution and the corrosion of H2S, environmental protection can be effectively eliminated.
Stearic acid i.e. octadecanoid acid, fusing point is 69.6 DEG C, and molecular formula C18H3602 is produced by grease hydrolysis, mainly for the production of stearate.Stearic acid generates zinc stearate, because zinc stearate has lubricious characteristic can help the demoulding after being combined dissolve with Zinc Oxide.It is activating agent that zinc oxide and stearic acid generate zinc stearate, strengthens the activity of auxiliary agent, plays the effects such as vulcanizing activator, softening agent, dispersant.
Antioxidant SP: for avoiding rubber in use to be attacked by ultraviolet and ozone and thermometal is catalyzed, play the effect of stabilizer in process of production, delay to synthesize the oxidizing process of macromolecular material, it is ensured that goods processing and the stability of application.
Activating agent PEG: as additive, increase lubricity and the plasticity of rubber, reduce the power consumption in the course of processing, extend the service life of rubber.
Accelerator OH3: a kind of accelerator, improves the less material of a kind of consumption of reaction rate.The accelerator OH3 that the present invention uses is produced by platform Xiang rubber (Shenzhen) company limited.
Additive DM: chemical name: 2,2'-dithio-bis-benzothiazole, plays accelerator effect aborning,
The invention has the beneficial effects as follows: the invention provides a kind of formula of soles and sole based on this formula and footwear, sole that this formula prepares and footwear, keeping while anti-wear performance, compressive property, contrasting conventional soles lighterization, breathability is strong, and the shoes prepared are dressed lighter, comfortable；The sole prepared by this formula can be with disposal molding, it is not necessary to any processing；The sole that formula of sole material of the present invention prepares is without telling the quality abnormal such as frost, jaundice.And this formula system anti-skid property of soles excellent, can be suitable on the snowfield of ice face using.
Accompanying drawing explanation
Fig. 1 is attaching type footwear sole construction schematic diagram of the present invention；
Fig. 2 is integrated shoes bottom structure schematic diagram of the present invention.
1-half sole in figure, 2-heel, 3-skid resistant course.
Detailed description of the invention
In conjunction with detailed description of the invention, the present invention is further described.
Embodiment
1
:
35L type nitrile rubber 56 parts, 1052 type nitrile rubber 44 parts, carbon black 18 parts, white cigarette 8 parts, DOP 6 parts, diphenylguanidine 0.5 part, zinc carbonate (ZnCO3) 5 parts, stearic acid 1 part, antioxidant SP 1 part, activating agent PEG 0.9 part, accelerator OH3 2 parts, additive DM 2 parts.
Embodiment
2
:
35L type nitrile rubber 50 parts, 1052 type nitrile rubber 50 parts, carbon black 20 parts, white cigarette 6 parts, DOP 6 parts, diphenylguanidine 0.5 part, zinc carbonate (ZnCO3) 5 parts, stearic acid 1 part, antioxidant SP 1 part, activating agent PEG 0.9 part, accelerator OH3 2 parts, additive DM 2 parts.
Embodiment
3
:
35L type nitrile rubber 45 parts, 1052 type nitrile rubber 55 parts, carbon black 16 parts, white cigarette 10 parts, DOP 6 parts, diphenylguanidine 0.5 part, zinc carbonate (ZnCO3) 5 parts, stearic acid 1 part, antioxidant SP 1 part, activating agent PEG 0.9 part, accelerator OH3 2 parts, additive DM 2 parts.
A kind of sole, including half sole and heel, described half sole and heel are provided with skid resistant course, and described skid resistant course is made up of above-mentioned formula materials.
Described sole, described skid resistant course uses post forming on half sole and heel.
May be used without skid resistant course material and be directly prepared into whole sole.
A kind of footwear, including sole and upper of a shoe, described sole is the sole that above-mentioned material prepares.
Performance test:
By above-mentioned performance test it can be seen that the sole that this formula prepares has good hot strength, abrasion resistance is the highest with elongation at break, scratch-resistant function admirable, can adapt to completely use on the snowfield of ice face.
Claims (6)
1. an anti-slip sole, it is characterised in that described formula of soles is made up of following mass parts material:
35L type nitrile rubber 45 56 parts, 1052 type nitrile rubber 44 55 parts, carbon black 16 20 parts, white cigarette 6 10 parts, DOP 6 parts, diphenylguanidine 0.5 part, zinc carbonate 5 parts, stearic acid 1 part, antioxidant SP 1 part, activating agent PEG
0.9 part, age resistor OH3 2 parts, additive DM 2 parts.
A kind of anti-slip sole the most according to claim 1, it is characterised in that described formula of soles is made up of following mass parts material:
35L type nitrile rubber 50 parts, 1052 type nitrile rubber 50 parts, carbon black 20 parts, white cigarette 6 parts, DOP 6 parts, diphenylguanidine 0.5 part, zinc carbonate 5 parts, stearic acid 1 part, antioxidant SP 1 part, activating agent PEG 0.9 part, age resistor OH3 2 parts, additive DM 2 parts.
3. an anti-slip sole, including half sole (1) and heel (2), described half sole (1) and heel (2) are provided with skid resistant course (3), it is characterized in that, described skid resistant course (3) is by 35L type nitrile rubber 45 56 parts, 1052 type nitrile rubber 44 55 parts, carbon black 16 20 parts, white cigarette 6 10 parts, DOP 6 parts, diphenylguanidine 0.5 part, zinc carbonate 5 parts, stearic acid 1 part, antioxidant SP 1 part, activating agent PEG
0.9 part, age resistor OH3 2 parts, additive DM 2 parts make.
4.According to claim 3Anti-slip sole, it is characterized in that, described skid resistant course (3) is made up of 35L type nitrile rubber 50 parts, 1052 type nitrile rubber 50 parts, carbon black 20 parts, white cigarette 6 parts, DOP 6 parts, diphenylguanidine 0.5 part, zinc carbonate 5 parts, stearic acid 1 part, antioxidant SP 1 part, activating agent PEG 0.9 part, age resistor OH3 2 parts, additive DM 2 parts.
Anti-slip sole the most according to claim 3, it is characterised in that described skid resistant course (3) uses post forming on half sole (1) and heel (2).
6. a slip-proof shoes, including sole and upper of a shoe, it is characterised in that described sole is the sole described in claim 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410388008.XA CN104140577B (en) | 2014-08-08 | 2014-08-08 | A kind of anti-slip sole and slip-proof shoes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410388008.XA CN104140577B (en) | 2014-08-08 | 2014-08-08 | A kind of anti-slip sole and slip-proof shoes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104140577A CN104140577A (en) | 2014-11-12 |
| CN104140577B true CN104140577B (en) | 2016-08-24 |
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ID=51849924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410388008.XA Active CN104140577B (en) | 2014-08-08 | 2014-08-08 | A kind of anti-slip sole and slip-proof shoes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104140577B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105801948B (en) * | 2016-04-26 | 2017-11-24 | 茂泰(福建)鞋材有限公司 | A kind of ice face anti-slip rubber composition and its production method |
| CN111073071B (en) * | 2019-11-28 | 2022-05-03 | 河北畅步防滑鞋科技有限公司 | Anti-slip bottom sheet and production and preparation mechanism thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735495A (en) * | 2009-12-21 | 2010-06-16 | 泰亚鞋业股份有限公司 | Formula of sole of high oil resistant rubber sneakers and manufacturing method of soles |
| CN102731857A (en) * | 2012-06-19 | 2012-10-17 | 苏州伟伦运动休闲用品有限公司 | Abrasion resistance sole and production method thereof |
| CN202738923U (en) * | 2012-07-18 | 2013-02-20 | 福建泉州匹克体育用品有限公司 | Wear-resistant road holding sports shoes |
| CN103483643A (en) * | 2013-10-11 | 2014-01-01 | 昆山纯柏精密五金有限公司 | Rubber composition for firefighting shoes |
-
2014
- 2014-08-08 CN CN201410388008.XA patent/CN104140577B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735495A (en) * | 2009-12-21 | 2010-06-16 | 泰亚鞋业股份有限公司 | Formula of sole of high oil resistant rubber sneakers and manufacturing method of soles |
| CN102731857A (en) * | 2012-06-19 | 2012-10-17 | 苏州伟伦运动休闲用品有限公司 | Abrasion resistance sole and production method thereof |
| CN202738923U (en) * | 2012-07-18 | 2013-02-20 | 福建泉州匹克体育用品有限公司 | Wear-resistant road holding sports shoes |
| CN103483643A (en) * | 2013-10-11 | 2014-01-01 | 昆山纯柏精密五金有限公司 | Rubber composition for firefighting shoes |
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| Publication number | Publication date |
|---|---|
| CN104140577A (en) | 2014-11-12 |
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Effective date of registration: 20160602 Address after: 325000 Longwan Road, Haibin District, Wenzhou, Zhejiang, Haining Applicant after: WENZHOU YIHE SHOE MATERIAL CO., LTD. Address before: The beach of Longwan District of Wenzhou City, Zhejiang province 325000 Ningcheng Industrial Zone Applicant before: Wenzhou Haibin Xiulong Shoe Materials Co., Ltd. |
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Denomination of invention: Anti-skid shoe soles and anti-skid shoes Effective date of registration: 20180130 Granted publication date: 20160824 Pledgee: Bank of Ningbo, Limited by Share Ltd, Wenzhou branch Pledgor: WENZHOU YIHE SHOE MATERIAL CO., LTD. Registration number: 2018990000027 |
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Date of cancellation: 20180425 Granted publication date: 20160824 Pledgee: Bank of Ningbo, Limited by Share Ltd, Wenzhou branch Pledgor: WENZHOU YIHE SHOE MATERIAL CO., LTD. Registration number: 2018990000027 |
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Denomination of invention: Anti-skid shoe soles and anti-skid shoes Effective date of registration: 20180427 Granted publication date: 20160824 Pledgee: Bank of Communications Ltd Wenzhou City West Branch Pledgor: WENZHOU YIHE SHOE MATERIAL CO., LTD. Registration number: 2018990000320 |
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Date of cancellation: 20190507 Granted publication date: 20160824 Pledgee: Bank of Communications Ltd Wenzhou City West Branch Pledgor: WENZHOU YIHE SHOE MATERIAL CO., LTD. Registration number: 2018990000320 |
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Denomination of invention: Anti-skid shoe soles and anti-skid shoes Effective date of registration: 20190517 Granted publication date: 20160824 Pledgee: Bank of Communications Ltd Wenzhou City West Branch Pledgor: WENZHOU YIHE SHOE MATERIAL CO., LTD. Registration number: 2019990000443 |
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Denomination of invention: Anti slip sole and anti slip shoe Effective date of registration: 20211020 Granted publication date: 20160824 Pledgee: Zhejiang Tailong Commercial Bank Co.,Ltd. Wenzhou Lucheng Tengqiao small and micro franchise sub branch Pledgor: WENZHOU YIHE SHOE MATERIAL Co.,Ltd. Registration number: Y2021330001970 |
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Date of cancellation: 20220428 Granted publication date: 20160824 Pledgee: Zhejiang Tailong Commercial Bank Co.,Ltd. Wenzhou Lucheng Tengqiao small and micro franchise sub branch Pledgor: WENZHOU YIHE SHOE MATERIAL Co.,Ltd. Registration number: Y2021330001970 |
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