CN104140577A - Formula of anti-skid shoe soles and shoe soles and shoes based on formula - Google Patents
Formula of anti-skid shoe soles and shoe soles and shoes based on formula Download PDFInfo
- Publication number
- CN104140577A CN104140577A CN201410388008.XA CN201410388008A CN104140577A CN 104140577 A CN104140577 A CN 104140577A CN 201410388008 A CN201410388008 A CN 201410388008A CN 104140577 A CN104140577 A CN 104140577A
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- Prior art keywords
- parts
- formula
- sole
- shoe soles
- pair
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- Granted
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- 239000000463 material Substances 0.000 claims abstract description 14
- 229920013649 Paracril Polymers 0.000 claims description 16
- 235000004416 zinc carbonate Nutrition 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 12
- 235000021355 Stearic acid Nutrition 0.000 claims description 11
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 10
- 230000000996 additive effect Effects 0.000 claims description 10
- 239000008117 stearic acid Substances 0.000 claims description 10
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 9
- 230000001737 promoting effect Effects 0.000 claims description 9
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical class [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 claims description 8
- 230000003078 antioxidant effect Effects 0.000 claims description 8
- 239000006229 carbon black Substances 0.000 claims description 8
- 235000019241 carbon black Nutrition 0.000 claims description 8
- 235000019504 cigarettes Nutrition 0.000 claims description 8
- 230000005856 abnormality Effects 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 238000004383 yellowing Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 7
- 229920001971 elastomer Polymers 0.000 description 6
- 239000005060 rubber Substances 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 206010023126 Jaundice Diseases 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229940069744 2,2'-dithiobisbenzothiazole Drugs 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
Landscapes
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a formula of a pair of anti-skid shoe soles and a pair of shoe soles and shoes based on the formula. According to the pair of shoe soles and shoes prepared by the formula, the pair of shoe soles is lighter than a conventional pair of shoe soles and strong in air permeability. The prepared pair of shoes is light and comfortable to wear. The pair of shoe soles prepared by the formula can be moulded at one time without being processed. The pair of shoe soles prepared by the formula of shoe sole materials is free from quality abnormalities such as frosting and yellowing. The pair of shoe soles prepared by the formula is excellent in anti-skid performance and can be suitable for being used on ice surfaces and snowfields.
Description
Technical field
The present invention relates to sole and use material field, be specifically related to a kind of anti-slip sole formula and the sole based on this formula and footwear.
Background technology
Shoes are article of usually using in our daily life, and sole is to make the requisite part of shoes.At present, on market, part sole, due to its deficiency of using formula, causes the sole produced overweight.If the sole lighter weight of producing, relevant performance, for example: wear resisting property, compressive property can reduce.And due to the restriction of formula, sole has been used easy jaundice of a specified duration, has told frost; And in part formula, contain heavy metal, lead etc., human body is caused to certain injury.System component is different, and the reason that content is different, causes the non-skid property of sole undesirable.
Summary of the invention
In order to solve the deficiencies in the prior art, a kind of anti-slip sole formula and the sole based on this formula and the footwear of providing of the present invention.
The technical solution that the present invention adopts is:
An anti-slip sole formula, described formula of soles is comprised of following mass parts material:
45-56 parts of 35L type paracrils, 1,052 44-55 parts of type paracrils, 16-20 parts of carbon blacks, 6-10 parts of white cigarettes, 6 parts of DOP, 0.5 part of vulkacit D, 5 parts of zinc carbonates (ZnCO3), 1 part of stearic acid, 1 part of antioxidant SP, 0.9 part of promoting agent PEG, 2 parts of promotor OH3,2 parts of additive DM.
Described a kind of anti-slip sole formula, described formula of soles is comprised of following mass parts material:
50 parts of 35L type paracrils, 50 parts of 1052 type paracrils, 20 parts of carbon blacks, 6 parts of white cigarettes, 6 parts of DOP, 0.5 part of vulkacit D, 5 parts of zinc carbonates (ZnCO3), 1 part of stearic acid, 1 part of antioxidant SP, 0.9 part of promoting agent PEG, 2 parts of promotor OH3,2 parts of additive DM.
An anti-slip sole, comprises half sole and heel, and described half sole and heel are provided with non-skid finish, and described non-skid finish is made by the formula materials described in claim 1 or 2.
Described anti-slip sole, described non-skid finish adopts post forming on half sole and heel.
Also can adopt non-skid finish material directly to make whole sole.
A slip-proof shoes, comprises sole and upper of a shoe, and described sole is sole claimed in claim 3.
35L type paracril and 1052 type paracrils are synthetic rubber that a kind of oil-proofness is fabulous, wear resistance is higher, thermotolerance is better, bonding force is strong.Two kinds just containing two kinds of different rubber of the fine content height of propylene.
Carbon black: strengthening agent and the filler of mainly making rubber.
White cigarette belongs to additive, in order to strengthen physical property, is mainly the aspects such as wear-resisting, hardness, pulling force anti tear.
DOP: be a kind of softening agent, can insert between high-polymer molecular chain, weaken intermolecular reactive force, increase distance and activity space between high-polymer molecular chain, increase the plasticity-of superpolymer, reduce the processing temperature of superpolymer.
Vulkacit D: have another name called vulkacit D, have softening agent and contracting to separate the effect of agent in elastomeric material.
Zinc carbonate (ZnCO3): can effectively eliminate pollution and the corrosion of H2S, environmental protection.
Stearic acid is octadecanoic acid, and fusing point is 69.6 ℃, and molecular formula C18H3602, is produced by fat hydrolysis, mainly for the production of stearate.Stearic acid is combined with zinc white and is dissolved rear generation Zinic stearas, because Zinic stearas has lubricious characteristic, can help the demoulding.It is promoting agent that zinc oxide and stearic acid generate Zinic stearas, strengthens the activity of auxiliary agent, plays the effects such as vulcanization leveller, tenderizer, dispersion agent.
Antioxidant SP: for avoiding rubber to be in use subject to the catalysis of ultraviolet ray and ozone attack and thermometal, play in process of production the effect of stablizer, delay the oxidising process of synthesized polymer material, guarantee the stability of goods processing and application.
Promoting agent PEG: as additive, increase oilness and the plasticity of rubber item, reduce the power consumption in the course of processing, extend the work-ing life of rubber item.
Promotor OH3: a kind of promotor, the less material of a kind of consumption of raising speed of reaction.The promotor OH3 that the present invention uses is produced by platform Xiang rubber (Shenzhen) company limited.
Additive DM: chemical name: 2,2'-dithio-bis-benzothiazole, play aborning promotor effect,
The invention has the beneficial effects as follows: the invention provides a kind of formula of soles and the sole based on this formula and footwear, the sole that this formula makes and footwear, when keeping wear resisting property, compressive property, the more lighting of contrast conventional soles, ventilation property is strong, and the shoes that make are dressed lighter, comfortable; The sole being made by this formula can disposal molding, without any processing; The sole that formula of sole material of the present invention makes is without telling the quality abnormals such as frost, jaundice.And this formula system anti-skid property of soles excellent, can be adapted at using on ice face snowfield.
Accompanying drawing explanation
Fig. 1 is attaching type footwear sole construction schematic diagram of the present invention.
Fig. 2 is integrated shoes bottom structure schematic diagram of the present invention.
1-half sole in figure, 2-heel, 3-non-skid finish.
Embodiment
Now in conjunction with embodiment, the present invention is further described.
Formula of soles is as follows:
embodiment 1:
56 parts of 35L type paracrils, 44 parts of 1052 type paracrils, 18 parts of carbon blacks, 8 parts of white cigarettes, 6 parts of DOP, 0.5 part of vulkacit D, 5 parts of zinc carbonates (ZnCO3), 1 part of stearic acid, 1 part of antioxidant SP, 0.9 part of promoting agent PEG, 2 parts of promotor OH3,2 parts of additive DM.
embodiment 2:
50 parts of 35L type paracrils, 50 parts of 1052 type paracrils, 20 parts of carbon blacks, 6 parts of white cigarettes, 6 parts of DOP, 0.5 part of vulkacit D, 5 parts of zinc carbonates (ZnCO3), 1 part of stearic acid, 1 part of antioxidant SP, 0.9 part of promoting agent PEG, 2 parts of promotor OH3,2 parts of additive DM.
embodiment 3:
45 parts of 35L type paracrils, 55 parts of 1052 type paracrils, 16 parts of carbon blacks, 10 parts of white cigarettes, 6 parts of DOP, 0.5 part of vulkacit D, 5 parts of zinc carbonates (ZnCO3), 1 part of stearic acid, 1 part of antioxidant SP, 0.9 part of promoting agent PEG, 2 parts of promotor OH3,2 parts of additive DM.
The formula of soles of above-described embodiment 1,2,3 is made to sole, comprise half sole and heel, described half sole and heel are provided with non-skid finish, and described non-skid finish is made by above-mentioned formula materials.Described sole, as shown in Figure 1, described non-skid finish adopts post forming on half sole and heel.As shown in Figure 2, also can adopt non-skid finish material directly to make whole sole, play anti-skidding effect.
Above-mentioned sole is made to a kind of footwear, comprise sole and upper of a shoe, described sole is the sole that above-mentioned materials makes.
By the above-mentioned sole making stretch, the performance test such as wear-resisting, anti-skidding, test result is as follows:
[0031] performance test:
By above-mentioned performance test, can be found out, the sole that this formula makes has good tensile strength, and fastness to rubbing and elongation at break are also higher, and scratch-resistant excellent property can adapt to completely on ice face snowfield and use.
Claims (5)
1. an anti-slip sole formula, is characterized in that, described formula of soles is comprised of following mass parts material:
45-56 parts of 35L type paracrils, 1,052 44-55 parts of type paracrils, 16-20 parts of carbon blacks, 6-10 parts of white cigarettes, 6 parts of DOP, 0.5 part of vulkacit D, 5 parts of zinc carbonates (ZnCO3), 1 part of stearic acid, 1 part of antioxidant SP, 0.9 part of promoting agent PEG, 2 parts of promotor OH3,2 parts of additive DM.
2. a kind of anti-slip sole formula according to claim 1, is characterized in that, described formula of soles is comprised of following mass parts material:
50 parts of 35L type paracrils, 50 parts of 1052 type paracrils, 20 parts of carbon blacks, 6 parts of white cigarettes, 6 parts of DOP, 0.5 part of vulkacit D, 5 parts of zinc carbonates (ZnCO3), 1 part of stearic acid, 1 part of antioxidant SP, 0.9 part of promoting agent PEG, 2 parts of promotor OH3,2 parts of additive DM.
3. an anti-slip sole, comprises half sole (1) and heel (2), and described half sole (1) and heel (2) are provided with non-skid finish (3), it is characterized in that, described non-skid finish (3) is made by the formula materials described in claim 1 or 2.
4. anti-slip sole according to claim 3, is characterized in that, described non-skid finish (3) adopts post forming on half sole (1) and heel (2).
5. a slip-proof shoes, comprises sole and upper of a shoe, it is characterized in that, described sole is sole claimed in claim 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410388008.XA CN104140577B (en) | 2014-08-08 | 2014-08-08 | A kind of anti-slip sole and slip-proof shoes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410388008.XA CN104140577B (en) | 2014-08-08 | 2014-08-08 | A kind of anti-slip sole and slip-proof shoes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104140577A true CN104140577A (en) | 2014-11-12 |
| CN104140577B CN104140577B (en) | 2016-08-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410388008.XA Active CN104140577B (en) | 2014-08-08 | 2014-08-08 | A kind of anti-slip sole and slip-proof shoes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104140577B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105801948A (en) * | 2016-04-26 | 2016-07-27 | 茂泰(福建)鞋材有限公司 | Antiskid rubber composition for ice surface and production method thereof |
| CN111073071A (en) * | 2019-11-28 | 2020-04-28 | 河北畅步防滑鞋科技有限公司 | Anti-slip bottom sheet and production and preparation mechanism thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735495A (en) * | 2009-12-21 | 2010-06-16 | 泰亚鞋业股份有限公司 | Formula of sole of high oil resistant rubber sneakers and manufacturing method of soles |
| CN102731857A (en) * | 2012-06-19 | 2012-10-17 | 苏州伟伦运动休闲用品有限公司 | Abrasion resistance sole and production method thereof |
| CN202738923U (en) * | 2012-07-18 | 2013-02-20 | 福建泉州匹克体育用品有限公司 | Wear-resistant road holding sports shoes |
| CN103483643A (en) * | 2013-10-11 | 2014-01-01 | 昆山纯柏精密五金有限公司 | Rubber composition for firefighting shoes |
-
2014
- 2014-08-08 CN CN201410388008.XA patent/CN104140577B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735495A (en) * | 2009-12-21 | 2010-06-16 | 泰亚鞋业股份有限公司 | Formula of sole of high oil resistant rubber sneakers and manufacturing method of soles |
| CN102731857A (en) * | 2012-06-19 | 2012-10-17 | 苏州伟伦运动休闲用品有限公司 | Abrasion resistance sole and production method thereof |
| CN202738923U (en) * | 2012-07-18 | 2013-02-20 | 福建泉州匹克体育用品有限公司 | Wear-resistant road holding sports shoes |
| CN103483643A (en) * | 2013-10-11 | 2014-01-01 | 昆山纯柏精密五金有限公司 | Rubber composition for firefighting shoes |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105801948A (en) * | 2016-04-26 | 2016-07-27 | 茂泰(福建)鞋材有限公司 | Antiskid rubber composition for ice surface and production method thereof |
| CN111073071A (en) * | 2019-11-28 | 2020-04-28 | 河北畅步防滑鞋科技有限公司 | Anti-slip bottom sheet and production and preparation mechanism thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104140577B (en) | 2016-08-24 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160602 Address after: 325000 Longwan Road, Haibin District, Wenzhou, Zhejiang, Haining Applicant after: WENZHOU YIHE SHOE MATERIAL CO., LTD. Address before: The beach of Longwan District of Wenzhou City, Zhejiang province 325000 Ningcheng Industrial Zone Applicant before: Wenzhou Haibin Xiulong Shoe Materials Co., Ltd. |
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Denomination of invention: Anti-skid shoe soles and anti-skid shoes Effective date of registration: 20180130 Granted publication date: 20160824 Pledgee: Bank of Ningbo, Limited by Share Ltd, Wenzhou branch Pledgor: WENZHOU YIHE SHOE MATERIAL CO., LTD. Registration number: 2018990000027 |
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Date of cancellation: 20180425 Granted publication date: 20160824 Pledgee: Bank of Ningbo, Limited by Share Ltd, Wenzhou branch Pledgor: WENZHOU YIHE SHOE MATERIAL CO., LTD. Registration number: 2018990000027 |
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Denomination of invention: Anti-skid shoe soles and anti-skid shoes Effective date of registration: 20180427 Granted publication date: 20160824 Pledgee: Bank of Communications Ltd Wenzhou City West Branch Pledgor: WENZHOU YIHE SHOE MATERIAL CO., LTD. Registration number: 2018990000320 |
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Date of cancellation: 20190507 Granted publication date: 20160824 Pledgee: Bank of Communications Ltd Wenzhou City West Branch Pledgor: WENZHOU YIHE SHOE MATERIAL CO., LTD. Registration number: 2018990000320 |
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Denomination of invention: Anti-skid shoe soles and anti-skid shoes Effective date of registration: 20190517 Granted publication date: 20160824 Pledgee: Bank of Communications Ltd Wenzhou City West Branch Pledgor: WENZHOU YIHE SHOE MATERIAL CO., LTD. Registration number: 2019990000443 |
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Date of cancellation: 20211019 Granted publication date: 20160824 Pledgee: Bank of Communications Ltd. Wenzhou City West Branch Pledgor: WENZHOU YIHE SHOE MATERIAL Co.,Ltd. Registration number: 2019990000443 |
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Denomination of invention: Anti slip sole and anti slip shoe Effective date of registration: 20211020 Granted publication date: 20160824 Pledgee: Zhejiang Tailong Commercial Bank Co.,Ltd. Wenzhou Lucheng Tengqiao small and micro franchise sub branch Pledgor: WENZHOU YIHE SHOE MATERIAL Co.,Ltd. Registration number: Y2021330001970 |
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Date of cancellation: 20220428 Granted publication date: 20160824 Pledgee: Zhejiang Tailong Commercial Bank Co.,Ltd. Wenzhou Lucheng Tengqiao small and micro franchise sub branch Pledgor: WENZHOU YIHE SHOE MATERIAL Co.,Ltd. Registration number: Y2021330001970 |
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