CN104129882A - Novel treatment technology of high-concentration industrial wastewater - Google Patents

Novel treatment technology of high-concentration industrial wastewater Download PDF

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Publication number
CN104129882A
CN104129882A CN201410422408.8A CN201410422408A CN104129882A CN 104129882 A CN104129882 A CN 104129882A CN 201410422408 A CN201410422408 A CN 201410422408A CN 104129882 A CN104129882 A CN 104129882A
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flow guiding
guiding disc
water
diaphragm
main body
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宋岱峰
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CHENGDU MFT MEMBRANE TECHNOLOGY Co Ltd
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CHENGDU MFT MEMBRANE TECHNOLOGY Co Ltd
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Abstract

The invention discloses a novel treatment technology of high-concentration industrial wastewater. A pretreatment unit, a membrane unit with a SUPER membrane element function and an evaporation unit are used in the novel treatment technology. The invention discloses a reverse osmosis membrane device which comprises a round pipe bearing outer shell, a metal seal sheet, a flange plate, a fluid reversing plate, a seal type round pipe bearing inner shell, a water distributor, an inner pull rod, a supporting flow guide plate, a membrane, a liquid inlet pipe and a liquid outlet pipe. According to the novel treatment technology of high-concentration industrial wastewater, a system is high in reliability and integrity, high in automation level, small in occupied area and relatively high in pollutant removal rate, and economic benefits of enterprises are well increased.

Description

High-concentration industrial-water novel treatment technology
Technical field
The present invention relates to a kind of wastewater processing technology, relate to specifically a kind of high-concentration industrial-water novel treatment technology.
Background technology
At present, in Industrial Wastewater Treatment field, the especially waste water of high density, high saliferous, high difficult degradation, does not also have comparatively effective, general technology and method to process it, because the limitation of the singularity of water quality, traditional Physiochemical and biochemical method.
The water quality characteristic of trade effluent
Trade effluent, especially the waste water of high density, high saliferous, high difficult degradation, water-quality constituents complexity, organic content is high, COD (chemical oxygen demand (COD)) generally more than 10000mg/L, even up to several ten thousand to hundreds of thousands of milligrams per liter, containing hazardous and noxious substances, saltiness is also high, has strong acid and strong base, can not directly carry out biochemical treatment.
Trade effluent is commonly used treatment process
For trade effluent, conventional processing mode is divided into two kinds: the first, physico-chemical process+biochemical process; The second, physico-chemical process+biochemical process+advanced treatment.The latter is used in situation that effluent quality has relatively high expectations, but two kinds of methods all need to, before waste water enters biochemical system, first be carried out physico-chemical pretreatment, reduce COD load in water, remove harmful toxic matter, to improve the biochemical effect of waste water.
The problem that conventional physico-chemical process exists
Conventional physico-chemical process comprises at present: the conventional arts such as Fenton, micro-electrolysis, electrocatalysis, microwave catalysis, ozone catalytic, Chlorine Dioxide Oxidation.These technological investments are large, processing cost is high, treatment effect is very limited, impact resistance is poor.Especially in the time that in waste water, COD concentration is higher than 20000mg/l, traditional physico-chemical process need add a large amount of oxygenants, cause processing cost high, and COD clearance is only 10-30%, also can introduce novel substance, causes secondary pollution.
The impact of conventional physico-chemical process existing problems on biochemical section
Tradition physico-chemical process COD clearance is low, not only can cause follow-up biochemical system influent load too high, very huge (common employing multistage anaerobic, the aerobic system series connection) that biochemical system is built, increase investment cost, but also can cause biochemical system fluctuation of service, final outflow water water quality is difficult to reach emission standard.
The limitation that the conventional embrane method of water treatment exists
The conventional embrane method of water treatment requires highly to influent quality, and invests hugely, and the rate of recovery is lower, and the concentrated solution producing is more difficult, and leading portion biochemical system thoroughly can not cause the pollution of the required membrane module of advanced treatment to Pollutant Treatment, affect treatment effect.
To sum up, adopt traditional materialization+biochemical technology to process the waste water of trade effluent, especially high density, high saliferous, high difficult degradation, not only invest hugely, processing cost is high, and treatment effect is very limited.
Summary of the invention
In view of this, the invention provides a kind of high-concentration industrial-water novel treatment technology, system reliability, integrated level are high, and level of automation is high, floor space is little, has higher pollutants removal rate simultaneously, has well improved the economic benefit of enterprise.
For solving above technical problem, technical scheme of the present invention is:
High-concentration industrial-water novel treatment technology, comprises pretreatment unit, SUPER membrane element functional membrane unit and evaporation element.
Described pretreatment unit comprises wastewater equalization pond, water pump and filtering system, this filtering system is ultra-filtration filters system or micro-filtration filtering system or sand filtration filtering system, trade effluent becomes pretreated waste water at the colloid and the suspended particle that are removed after pretreatment unit wherein, and then this pretreated waste water enters SUPER membrane element functional membrane unit again and carries out second step processing.
Described SUPER membrane element functional membrane unit comprises water pump and reverse osmosis membrane apparatus, pretreated waste water is carried out reverse-osmosis treated be pumped to reverse osmosis membrane apparatus under the effect of water pump in, after processing, from reverse osmosis membrane apparatus, discharge concentrated solution and see through liquid, wherein see through liquid and directly discharge or carry out advanced treatment and reclamation, concentrated solution enters evaporation element and carries out the 3rd step processing.
Described evaporation element adopts mechanical steam recompression and multiple-effect evaporation again to process the water in concentrated solution and pollutent, unit carries out mechanically compress to the steam producing for the first time, steam is re-used as heat source after heating up, or using the steam producing for the first time directly as the thermal source of the second stage, steam is re-used as third stage thermal source for the second time, so circulation is repeatedly evaporated separation to concentrated solution, most water in concentrated solution are entered in phlegma, a large amount of salinities and organism are separated out and are become residue, thereby the each pollutant that completes high density separates with the thorough of water, common phlegma directly discharges or carries out advanced treatment and reclamation, and the phlegma that contains volatile solutes will or carry out advanced treatment in process biochemical treatment, and residue burns or landfill.
Reverse osmosis membrane apparatus, comprise pipe bearing shell, two ends up and down at this pipe bearing shell are also respectively arranged with metallic seal sheet and ring flange, position at the two ends up and down of pipe bearing shell inside next-door neighbour's metallic seal sheet and ring flange is also respectively arranged with a reverse dish of fluid, between pipe bearing shell and two reverse dishes of fluid, be also provided with sealed pipe pressure-bearing inner casing, also be provided with in the inside of sealing formula pipe pressure-bearing inner casing and support flow guiding disc and diaphragm, also be provided with water distributor in sealed pipe pressure-bearing inner casing lower end, also be provided with and run through support flow guiding disc in the middle position of water distributor, diaphragm, the draw-in bar of the reverse dish of upper end fluid and metallic seal sheet, both sides at draw-in bar are also respectively arranged with liquid-inlet pipe and drain pipe, at least two flow guiding discs and a diaphragm just can be used in conjunction with, flow guiding disc comprises flow guiding disc main body, centered by this flow guiding disc main body, position is provided with the disk of flow guiding disc mesopore, internal diameter and the draw-in bar of flow guiding disc hollow match, surface in flow guiding disc main body is also provided with boss, in this flow guiding disc main body, be also provided with two water conservancy diversion cracks, on diaphragm, be provided with two directed breaches that match with this water conservancy diversion crack.
Further, above-mentioned sealed pipe pressure-bearing inner casing is provided with inwall and outer wall, and the space between its inwall and outer wall forms a cavity, and the lower inner wall of this cavity is provided with opening, and this opening is connected with the hole of running through water distributor; The outer wall that described liquid-inlet pipe runs through metallic seal sheet, the reverse dish of fluid and sealed pipe pressure-bearing inner casing is successively connected with the cavity of sealed pipe pressure-bearing inner casing; Described drain pipe runs through successively metallic seal sheet, the reverse dish of fluid and sealed pipe pressure-bearing inner casing and is connected with the internal space of sealed pipe pressure-bearing inner casing; Described draw-in bar comprises the internal layer solid spar that is arranged on shaft core position, is also provided with outer open tube in internal layer solid spar outside, and the internal diameter of this skin open tube is greater than the diameter of internal layer solid spar, between internal layer solid spar and outer open tube, is also provided with stiffening web; On the tube wall of described outer open tube, be also provided with the aperture being communicated with sealed pipe pressure-bearing inner casing internal space; The quantity of described stiffening web is at least two.
Further, the quantity of above-mentioned support flow guiding disc is at least two, and overlaps in the internal space of sealed pipe pressure-bearing inner casing, between every adjacent two support flow guiding discs, is also provided with a diaphragm; Described two water conservancy diversion cracks are symmetricly set in flow guiding disc main body, and two water conservancy diversion crack is in together on the same diameter of flow guiding disc main body, the length of water conservancy diversion crack is identical with the radius of flow guiding disc main body, this water conservancy diversion crack is the inclined ramp at 30-60 ° with the outstanding slant range of axial opposed direction that radially extend top and the bottom, and top and the bottom slideway lays respectively at the upper and lower surface of flow guiding disc main body; On described water conservancy diversion crack, be also vertically installed with at least one support rib, the supported bone of this water conservancy diversion crack is at least divided into two channel parts, the outstanding position of this support rib is pressed on the edge section of the directed breach of diaphragm, by support rib, diaphragm is fixed on to two middle parts between flow guiding disc main body; The outer fix of described water conservancy diversion crack is also provided with locating structure, and this locating structure comprises the draw-in groove and the fixture block that are separately positioned on the upper and lower both sides of flow guiding disc main body; The lobe that the outside of described flow guiding disc mesopore has a circle to arrange along radial direction, lobe is fixed on the inside edge of flow guiding disc main body, between each lobe, be provided with gap, this gap is flow guiding slit, the setting position of the upper and lower surface of this lobe is respectively higher than the upper and lower surface of flow guiding disc main body, better flow guiding disc main body is positioned; The outside adjacent position of described flow guiding disc mesopore is also provided with O type circle pickup groove, the quantity of this O type circle pickup groove is two, be separately positioned on the both sides up and down of flow guiding disc main body, on the outer side of O type circle pickup groove, be also provided with the projection for better fixing O type circle.
Preferred as one, described boss is salient point, and this salient point becomes certain radian to be arranged on the two sides of flow guiding disc main body by sequence.
Preferred as another kind, described boss is raised line, and this raised line becomes certain radian to be arranged on the two sides of flow guiding disc main body by sequence.
In addition, circular or the regular polygon of described diaphragm, also be provided with in the mid-way of this diaphragm the diaphragm mesopore that diameter is identical with flow guiding disc mesopore, this diaphragm by upper and lower two-layer filter and be arranged in the middle of support chip form, the edge contact position of filter and support chip except diaphragm mesopore mutually hot melt become film limit.
Compared with prior art, the present invention has following beneficial effect:
After high-concentration industrial-water novel treatment technical finesse waste liquid of the present invention, the clearance of COD and salt can be up to more than 99%, qualified discharge is really processed in the water outlet of guarantee Sewage treatment systems, and Waste water concentrating liquid measure is few, and water production rate is large, reduce the investment of later stage dope processing, gross investment is low more than 20%; And the processing cost of ton water is only the 20%-30% of traditional physico-chemical process, stablizes, integrated level is high, and level of automation is high, floor space is little;
Reverse osmosis membrane apparatus of the present invention utilizes draw-in bar to substitute the outside link of prior art, reduce the assembly difficulty of internal structure, also reduce the present invention simultaneously the required space size taking has been installed, well save usage space, improve efficiency of assembling, the cost that has reduced buying, has good economic benefit, has better promoted the development of enterprise and industry; The present invention is simple in structure, easy to use, produces and follows the cost of processing lower, can be good at carrying out large-scale production and use;
As preferably, the dish wall thickness of support flow guiding disc of the present invention has been reduced to 0.3~0.5cm by the 0.8cm of prior art, the height of salient point has been reduced to 1~2.5cm by the 3.5cm of prior art, ensureing the quantity that has improved its installation under its normal prerequisite using, the quantity of required equipment while having reduced sewage disposal, has further improved efficiency and the economic benefit of sewage disposal;
As preferably, the present invention is by arranging two water conservancy diversion cracks, whole flow guiding disc is divided into two parts in left and right, make its left and right sides form respectively a semicircular flow channel for liquids, reduce the pressure-losses of soiling solution in flow process, improve the efficiency of sewage purification, also improved result of use simultaneously; The present invention is provided with raised line, raised line can carry out better guide effect to soiling solution, further reduced the pressure-losses of soiling solution in flow process, better utilised the resources of production, reduced production loss, this raised line is larger with the contact area of diaphragm simultaneously, further reduce the stressed of membrane surface, better avoided diaphragm in use destroyed, the work-ing life of having improved diaphragm, and then reduced the frequency of maintenance while use, greatly improve result of use;
As preferably, support flow guiding disc of the present invention utilizes convex line to replace salient point of the prior art, turnover between the helical in the time that current present eddy current spiral motion is milder, and the parthydraulic loss while reducing current turning has further improved again efficiency and economic benefit that afternoon nap is processed.
Brief description of the drawings
Fig. 1 is process flow sheet of the present invention;
Fig. 2 is cross-sectional view of the present invention;
Fig. 3 is the vertical view of draw-in bar of the present invention;
Fig. 4 is a kind of vertical view of flow guiding disc;
Fig. 5 is the B-B sectional view of Fig. 1;
Fig. 6 is the vertical view of another kind of flow guiding disc;
Fig. 7 is the C-C sectional view of Fig. 3;
Fig. 8 is the sectional structure chart of water conservancy diversion crack;
Fig. 9 is the vertical view of diaphragm;
Figure 10 is the sectional structure chart of diaphragm;
Figure 11 is the direct fluid key diagram that supports flow guiding disc and diaphragm.
On figure, Reference numeral is: 1-pipe bearing shell; The reverse dish of 2-fluid; 3-support flow guiding disc; 4-diaphragm; 5-sealed pipe pressure-bearing inner casing; 6-liquid-inlet pipe; 7-drain pipe; 8-water distributor; 9-metallic seal sheet; 10-outer open tube; 11-internal layer solid spar; 12-stiffening web; 31-flow guiding disc main body; 32-salient point; 33-water conservancy diversion crack; 34-locating structure; 35-support rib; 36-O type circle pickup groove; 37-flow guiding disc mesopore; 38-lobe; 39-raised line; 41-diaphragm mesopore; 42-film limit; 43-directed breach; 44-filter; 45-support chip.
Embodiment
Core thinking of the present invention is, a kind of high-concentration industrial-water novel treatment technology is provided, and system reliability, integrated level are high, and level of automation is high, floor space is little, has higher pollutants removal rate simultaneously, has well improved the economic benefit of enterprise.
In order to make those skilled in the art understand better technical scheme of the present invention, below in conjunction with the drawings and specific embodiments, the present invention is described in further detail.
Embodiment 1
As shown in Figure 1, high-concentration industrial-water novel treatment technology, comprises pretreatment unit, SUPER membrane element functional membrane unit and evaporation element.
Described pretreatment unit comprises wastewater equalization pond, water pump and filtering system, this filtering system is ultra-filtration filters system or micro-filtration filtering system or sand filtration filtering system, trade effluent becomes pretreated waste water at the colloid and the suspended particle that are removed after pretreatment unit wherein, and then this pretreated waste water enters SUPER membrane element functional membrane unit again and carries out second step processing.
Described SUPER membrane element functional membrane unit comprises water pump and reverse osmosis membrane apparatus, pretreated waste water is carried out reverse-osmosis treated be pumped to reverse osmosis membrane apparatus under the effect of water pump in, after processing, from reverse osmosis membrane apparatus, discharge concentrated solution and see through liquid, wherein see through liquid and directly discharge or carry out advanced treatment and reclamation, concentrated solution enters evaporation element and carries out the 3rd step processing.
Described evaporation element adopts mechanical steam recompression and multiple-effect evaporation again to process the water in concentrated solution and pollutent, unit carries out mechanically compress to the steam producing for the first time, steam is re-used as heat source after heating up, or using the steam producing for the first time directly as the thermal source of the second stage, steam is re-used as third stage thermal source for the second time, so circulation is repeatedly evaporated separation to concentrated solution, most water in concentrated solution are entered in phlegma, a large amount of salinities and organism are separated out and are become residue, thereby the each pollutant that completes high density separates with the thorough of water, common phlegma directly discharges or carries out advanced treatment and reclamation, and the phlegma that contains volatile solutes will or carry out advanced treatment in process biochemical treatment, and residue burns or landfill.
The present invention for COD higher than 10000mg/L, the waste water ton water of salinity more than 1% is invested about 4~60,000 yuan, but because high-concentration waste water accounts for 10%~20% in industrial enterprise's draining proportion, the pollution load of whole waste water processing station reduces greatly simultaneously, the scale at Industrial Wastewater Treatment station is 60~80% left and right of conventional high-concentration waste water treatment station, and therefore whole system output investment ratio and high-concentration waste water conventional treatment process are saved 20% left and right.
Working cost of the present invention is mainly made up of the working cost of SUPER membrane element functional membrane unit and the working cost of evaporation element, the working cost of SUPER membrane element unit is 13 yuan of high-concentration industrial-waters per ton, evaporation element working cost is 19.1 yuan of high-concentration industrial-waters per ton, therefore working cost of the present invention is 32.1 yuan of high-concentration industrial-waters per ton, more saves working cost than 97.8 yuan/ton of the conventional high-concentration industrial-water treatment process such as Fenton process.
The present invention, except application on trade effluent, also can be used on as fields such as petrochemical complex, chemical pharmaceutical, food-drink, also can be used for the processing of feed separation, percolate and sea water desaltination simultaneously.
Embodiment 2
As shown in Fig. 2,3,9, sewage flow guiding filter, comprise at least two flow guiding discs 1 and the diaphragm 10 that are used in conjunction with each other, wherein flow guiding disc 1 setting adjacent with diaphragm 10, and many one than the number of diaphragm 10 of the number of flow guiding disc 1, centered by this flow guiding disc 1, position is provided with the disk of flow guiding disc mesopore 7, surface at flow guiding disc 1 is also provided with boss, on this flow guiding disc 1, be also provided with two water conservancy diversion cracks 3, on diaphragm 10, be provided with two directed breaches 13 that match with this water conservancy diversion crack 3.The lobe 8 that the outside of above-mentioned flow guiding disc mesopore 7 has a circle to arrange along radial direction, lobe 8 is fixed on the inside edge of flow guiding disc 1, between each lobe 8, be provided with gap, this gap is flow guiding slit, the setting position of the upper and lower surface of this lobe 8 is respectively higher than the upper and lower surface of flow guiding disc 1, better flow guiding disc 1 is positioned.The outside adjacent position of described flow guiding disc mesopore 7 is also provided with O type circle pickup groove 6, the quantity of this O type circle pickup groove 6 is two, be separately positioned on the both sides up and down of flow guiding disc 1, on the outer side of O type circle pickup groove 6, be also provided with the projection for better fixing O type circle.Above-mentioned boss is salient point 2, this salient point 2 becomes certain radian to be arranged on the two sides of flow guiding disc 1 by sequence, soiling solution salient point when through salient point can be broken up the solid dielectric of flowing through, can better purify soiling solution, greatly improve the efficiency purifying, and salient point becomes certain radian to be arranged on flow guiding disc by sequence, soiling solution in flow process, can receive salient point setting party to impact, avoid liquid violent reverse in mobile process, well keep the flow velocity of liquid, reduced the loss of pressure in its flow process.In addition, the end of this salient point is circular, can be good at increasing the contact surface of itself and diaphragm, reduces the stressed of membrane surface, horizontal good protection diaphragm, avoid diaphragm applied force excessive and occur damaged.
As shown in Figure 6, above-mentioned two water conservancy diversion cracks 3 are symmetricly set on flow guiding disc 1, and two water conservancy diversion crack 3 is in together on the same diameter of flow guiding disc 1, the length of water conservancy diversion crack 3 is identical with the radius of flow guiding disc 1, the inclined ramp at 30-60 ° with the outstanding slant range of axial opposed direction that this water conservancy diversion crack 3 radially extends for top and the bottom, top and the bottom slideway lays respectively at the upper and lower surface of flow guiding disc 1.On described water conservancy diversion crack 3, be also vertically installed with at least one support rib 5, the supported bone 5 of this water conservancy diversion crack 3 is at least divided into two channel parts, this outstanding position of support rib 5 is pressed on the edge section of the directed breach 13 of diaphragm 10, by support rib 5, diaphragm 10 is fixed on to two middle parts between flow guiding disc 1.The present invention is by arranging two water conservancy diversion cracks, whole flow guiding disc is divided into two parts in left and right, makes its left and right sides form respectively a semicircular flow channel for liquids, reduced the pressure-losses of soiling solution in flow process, improve the efficiency of sewage purification, also improved result of use simultaneously.
The outer fix of described water conservancy diversion crack 3 is also provided with locating structure 4, and this locating structure 4 comprises the draw-in groove and the fixture block that are separately positioned on flow guiding disc both sides Shang Xia 1.When mounted the draw-in groove of upper and lower two flow guiding discs is alignd with fixture block and fixture block is inlayed as just carried out to flow guiding disc the location of fast accurate in draw-in groove.
As shown in Figure 7,8, circular or the regular polygon of described diaphragm 10, also be provided with in the mid-way of this diaphragm 10 the diaphragm mesopore 12 that diameter is identical with flow guiding disc mesopore 7, the support chip 15 of this diaphragm by upper and lower two-layer filter 14 and in the middle of being arranged on forms, the edge contact position of filter 14 and support chip 15 except diaphragm mesopore 12 mutually hot melt become film limit 12.The upper and lower two-layer filter of this diaphragm only allows penetrating fluid to enter, and penetrating fluid passes through webbed support chip guiding center position after entering filter, then flows into flow guiding disc centre hole from the flow guiding slit of flow deflector central hole.While setting, diaphragm is fixed between two flow guiding discs, and the space between flow guiding disc is divided into upper and lower two parts, and soiling solution is entering respectively upper and lower two spaces after water conservancy diversion crack, improve the contact area of soiling solution and diaphragm, and then improved the processing efficiency of soiling solution.
Embodiment 3
As shown in Figure 4,5, the difference of the present embodiment and embodiment 1 is, described boss is raised line 9, and this raised line 9 becomes certain radian to be arranged on the two sides of flow guiding disc 1 by sequence.This raised line can carry out better guide effect to soiling solution, has further reduced the pressure-losses of soiling solution in flow process, better utilised the resources of production, reduced production loss; This raised line is larger with the contact area of diaphragm simultaneously, further reduce the stressed of membrane surface, better avoided diaphragm in use destroyed, the work-ing life of having improved diaphragm, and then reduced the frequency of maintenance while use, greatly improve result of use.
Below be only the preferred embodiment of the present invention, it should be pointed out that above-mentioned preferred implementation should not be considered as limitation of the present invention, protection scope of the present invention should be as the criterion with claim limited range.For those skilled in the art, without departing from the spirit and scope of the present invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (10)

1. high-concentration industrial-water novel treatment technology, is characterized in that, comprises pretreatment unit, SUPER membrane element functional membrane unit and evaporation element.
2. high-concentration industrial-water novel treatment technology according to claim 1, it is characterized in that, described pretreatment unit comprises wastewater equalization pond, water pump and filtering system, this filtering system is ultra-filtration filters system or micro-filtration filtering system or sand filtration filtering system, trade effluent becomes pretreated waste water at the colloid and the suspended particle that are removed after pretreatment unit wherein, and then this pretreated waste water enters SUPER membrane element functional membrane unit again and carries out second step processing.
3. high-concentration industrial-water novel treatment technology according to claim 2, it is characterized in that, described SUPER membrane element functional membrane unit comprises water pump and reverse osmosis membrane apparatus, pretreated waste water is carried out reverse-osmosis treated be pumped to reverse osmosis membrane apparatus under the effect of water pump in, after processing, from reverse osmosis membrane apparatus, discharge concentrated solution and see through liquid, wherein see through liquid and directly discharge or carry out advanced treatment and reclamation, concentrated solution enters evaporation element and carries out the 3rd step processing.
4. high-concentration industrial-water novel treatment technology according to claim 3, it is characterized in that, described evaporation element adopts mechanical steam recompression and multiple-effect evaporation again to process the water in concentrated solution and pollutent, unit carries out mechanically compress to the steam producing for the first time, steam is re-used as heat source after heating up, or using the steam producing for the first time directly as the thermal source of the second stage, steam is re-used as third stage thermal source for the second time, so circulation is repeatedly evaporated separation to concentrated solution, most water in concentrated solution are entered in phlegma, a large amount of salinities and organism are separated out and are become residue, thereby the each pollutant that completes high density separates with the thorough of water, common phlegma directly discharges or carries out advanced treatment and reclamation, and the phlegma that contains volatile solutes will or carry out advanced treatment in process biochemical treatment, and residue burns or landfill.
5. the reverse osmosis membrane apparatus described in claim 3~4 any one, it is characterized in that, comprise pipe bearing shell (1), also be respectively arranged with metallic seal sheet (9) and ring flange at the two ends up and down of this pipe bearing shell (1), the up and down two ends next-door neighbour metallic seal sheets (9) inner at pipe bearing shell (1) are also respectively arranged with a reverse dish of fluid (2) with the position of ring flange, between pipe bearing shell (1) and two reverse dishes of fluid (2), be also provided with sealed pipe pressure-bearing inner casing (5), also be provided with in the inside of sealing formula pipe pressure-bearing inner casing (5) and support flow guiding disc (3) and diaphragm (4), also be provided with water distributor (8) in sealed pipe pressure-bearing inner casing (5) lower end, also be provided with in the middle position of water distributor (8) to run through and support flow guiding disc (3), diaphragm (4), the draw-in bar of the reverse dish of upper end fluid (2) and metallic seal sheet (9), also be respectively arranged with liquid-inlet pipe (6) and drain pipe (7) in the both sides of draw-in bar, at least two flow guiding discs (1) just can be used in conjunction with a diaphragm (10), flow guiding disc (3) comprises flow guiding disc main body (31), centered by this flow guiding disc main body (31), position is provided with the disk of flow guiding disc mesopore (37), internal diameter and the draw-in bar of flow guiding disc hollow (37) match, surface in flow guiding disc main body (31) is also provided with boss, in this flow guiding disc main body (31), be also provided with two water conservancy diversion cracks (33), on diaphragm (4), be provided with two directed breaches (43) that match with this water conservancy diversion crack (33).
6. high-concentration industrial-water novel treatment technology according to claim 5, it is characterized in that, described sealed pipe pressure-bearing inner casing (5) is provided with inwall and outer wall, space between its inwall and outer wall forms a cavity, the lower inner wall of this cavity is provided with opening, and this opening is connected with the hole of running through water distributor (8); The outer wall that described liquid-inlet pipe (6) runs through metallic seal sheet (9), the reverse dish of fluid (2) and sealed pipe pressure-bearing inner casing (5) is successively connected with the cavity of sealed pipe pressure-bearing inner casing (5); Described drain pipe (7) runs through successively metallic seal sheet (9), the reverse dish of fluid (2) and sealed pipe pressure-bearing inner casing (5) and is connected with the internal space of sealed pipe pressure-bearing inner casing (5); Described draw-in bar comprises the internal layer solid spar (11) that is arranged on shaft core position, also be provided with outer open tube (10) in internal layer solid spar (11) outside, the internal diameter of this skin open tube (10) is greater than the diameter of internal layer solid spar (11), between internal layer solid spar (11) and outer open tube (10), is also provided with stiffening web (12); On the tube wall of described outer open tube (10), be also provided with the aperture being communicated with sealed pipe pressure-bearing inner casing (5) internal space; The quantity of described stiffening web (12) is at least two.
7. high-concentration industrial-water novel treatment technology according to claim 6, it is characterized in that, the quantity of described support flow guiding disc (3) is at least two, and overlap in the internal space of sealed pipe pressure-bearing inner casing (5), between every adjacent two support flow guiding discs (3), be also provided with a diaphragm (4); Described two water conservancy diversion cracks (33) are symmetricly set in flow guiding disc main body (31), and two water conservancy diversion crack (33) is in together on the same diameter of flow guiding disc main body (31), the length of water conservancy diversion crack (33) is identical with the radius of flow guiding disc main body (31), the inclined ramp at 30-60 ° with the outstanding slant range of axial opposed direction that this water conservancy diversion crack (33) radially extends for top and the bottom, top and the bottom slideway lays respectively at the upper and lower surface of flow guiding disc main body (31); On described water conservancy diversion crack (33), be also vertically installed with at least one support rib (35), this supported bone of water conservancy diversion crack (33) (35) is at least divided into two channel parts, the outstanding position of this support rib (35) is pressed on the edge section of the directed breach (43) of diaphragm (4), by support rib (35), diaphragm (4) is fixed on to the middle part between two flow guiding disc main bodys (31); The outer fix of described water conservancy diversion crack (33) is also provided with locating structure (34), and this locating structure (34) comprises the draw-in groove and the fixture block that are separately positioned on the upper and lower both sides of flow guiding disc main body (31); The lobe (38) that the outside of described flow guiding disc mesopore (37) has a circle to arrange along radial direction, lobe (38) is fixed on the inside edge of flow guiding disc main body (31), between each lobe (38), be provided with gap, this gap is flow guiding slit, the setting position of the upper and lower surface of this lobe (38) is respectively higher than the upper and lower surface of flow guiding disc main body (31), better flow guiding disc main body (31) is positioned; The outside adjacent position of described flow guiding disc mesopore (37) is also provided with O type circle pickup groove (36), the quantity of this O type circle pickup groove (36) is two, be separately positioned on the both sides up and down of flow guiding disc main body (31), on the outer side of O type circle pickup groove (36), be also provided with the projection for better fixing O type circle.
8. high-concentration industrial-water novel treatment technology according to claim 7, it is characterized in that, described boss is salient point (32), and this salient point (32) becomes certain radian to be arranged on the two sides of flow guiding disc main body (31) by sequence.
9. high-concentration industrial-water novel treatment technology according to claim 7, it is characterized in that, described boss is raised line (39), and this raised line (39) becomes certain radian to be arranged on the two sides of flow guiding disc main body (31) by sequence.
10. according to the high-concentration industrial-water novel treatment technology described in claim 5~9 any one, it is characterized in that, circular or the regular polygon of described diaphragm (4), also be provided with the diaphragm mesopore (42) that diameter is identical with flow guiding disc mesopore (37) in the mid-way of this diaphragm (4), the support chip (45) of this diaphragm by upper and lower two-layer filter (44) and in the middle of being arranged on form, the edge contact position of filter (44) and support chip (45) except diaphragm mesopore (42) mutually hot melt become film limit (42).
CN201410422408.8A 2014-08-25 2014-08-25 Novel treatment technology of high-concentration industrial wastewater Pending CN104129882A (en)

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