CN104115845A - Efficient pesticide composition containing flubendiamide - Google Patents
Efficient pesticide composition containing flubendiamide Download PDFInfo
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- CN104115845A CN104115845A CN201310146170.6A CN201310146170A CN104115845A CN 104115845 A CN104115845 A CN 104115845A CN 201310146170 A CN201310146170 A CN 201310146170A CN 104115845 A CN104115845 A CN 104115845A
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- Prior art keywords
- fluorobenzene
- insect amide
- fluorobenzene insect
- worm
- weight ratio
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- 239000000575 pesticide Substances 0.000 title claims abstract description 26
- 239000005901 Flubendiamide Substances 0.000 title abstract description 4
- ZGNITFSDLCMLGI-UHFFFAOYSA-N flubendiamide Chemical compound CC1=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C1NC(=O)C1=CC=CC(I)=C1C(=O)NC(C)(C)CS(C)(=O)=O ZGNITFSDLCMLGI-UHFFFAOYSA-N 0.000 title abstract description 4
- 241000238631 Hexapoda Species 0.000 claims abstract description 167
- 239000005925 Pymetrozine Substances 0.000 claims abstract description 35
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 claims abstract description 34
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000005885 Buprofezin Substances 0.000 claims abstract description 20
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 claims abstract description 19
- PYLWMHQQBFSUBP-UHFFFAOYSA-N monofluorobenzene Chemical compound FC1=CC=CC=C1 PYLWMHQQBFSUBP-UHFFFAOYSA-N 0.000 claims description 195
- 150000001408 amides Chemical class 0.000 claims description 132
- 125000004494 ethyl ester group Chemical group 0.000 claims description 34
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- FNELVJVBIYMIMC-UHFFFAOYSA-N Ethiprole Chemical compound N1=C(C#N)C(S(=O)CC)=C(N)N1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl FNELVJVBIYMIMC-UHFFFAOYSA-N 0.000 abstract 1
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- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
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- AJKNNUJQFALRIK-UHFFFAOYSA-N 1,2,3-trifluorobenzene Chemical compound FC1=CC=CC(F)=C1F AJKNNUJQFALRIK-UHFFFAOYSA-N 0.000 description 1
- GOYDNIKZWGIXJT-UHFFFAOYSA-N 1,2-difluorobenzene Chemical compound FC1=CC=CC=C1F GOYDNIKZWGIXJT-UHFFFAOYSA-N 0.000 description 1
- VSKSBSORLCDRHS-UHFFFAOYSA-N 1-fluoro-3-iodobenzene Chemical compound FC1=CC=CC(I)=C1 VSKSBSORLCDRHS-UHFFFAOYSA-N 0.000 description 1
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- NAYYNDKKHOIIOD-UHFFFAOYSA-N phthalamide Chemical compound NC(=O)C1=CC=CC=C1C(N)=O NAYYNDKKHOIIOD-UHFFFAOYSA-N 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an efficient pesticide composition containing flubendiamide. An active ingredient A is flubendiamide, and an active ingredient B is one selected from the group consisting of buprofezin, pymetrozine, chlorfenapyr, ethiprole, dicyclanil, spirotetramat and pyriproxyfen, wherein the active ingredient A and the active ingredient B are in the weight ratio of 1:80 to 80:1. The composition provided by the invention has synergism on a plurality of insects harming agricultural production, reduces drug dose of pesticide, mitigates environmental pollution, is safe for human and livestock, has good compatibility and does not cause resistance on the insects.
Description
Technical field
The invention belongs to technical field of pesticide, relate to the application of a kind of highly effective pesticide composition containing fluorobenzene insect amide on crop pests.
Background technology
Fluorobenzene insect amide (flubendiamide): molecular formula: C
23h
22f
7iN
2o
4s, chemical name: 3-iodo-N ＇-(2-mesyl-1, 1-dimethyl ethyl group-N-{4-[1, 2, 2, 2-tetrafluoro-1-(trifluoromethyl) ethyl]-0-tolyl } phthalamide, belong to Novel ortho benzenedicarboxamide insecticides, activate calcium release channel in blue Buddhist nun's alkali recipient cell, cause the property out of control of storing calcium ion to discharge, it is at present few in number compounds that acts on the blue Buddhist nun's alkali of insect cell acceptor, lepidoptera pest is had to spectrum preventive effect, produce without cross resistance with existing insecticide, limited to adult preventive effect, there is no ovicidal action, after in infiltration plant corpus, by xylem, slightly pass to, resistance of rainwater washing against.
Buprofezin, pymetrozine, capillary, second worm nitrile, CGA 183893, spiral shell worm ethyl ester or Nylar all belong to conventional insecticide, are widely used in preventing and treating the insect pest on crops, and control efficiency is better.
Yet in the real process of agricultural production, the problem that pest control the most easily produces is the generation of pest resistance to insecticide.Different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really has the seldom composite of synergistic effect, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor's research, discovery will can produce good synergistic effect after fluorobenzene insect amide and Buprofezin, pymetrozine, capillary, second worm nitrile, CGA 183893, spiral shell worm ethyl ester or pyriproxyfen compound, and not yet open about the relevant report of fluorobenzene insect amide and Buprofezin, pymetrozine, capillary, second worm nitrile, CGA 183893, spiral shell worm ethyl ester or pyriproxyfen compound.
Summary of the invention
The object of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good highly effective pesticide composition containing fluorobenzene insect amide.The highly effective pesticide composition containing fluorobenzene insect amide that the present invention proposes is comprised of active components A and active component B, active components A and active component B weight ratio are 1 ︰ 80～80 ︰ 1, described active components A is selected from fluorobenzene insect amide, active component B is selected from a kind of in Buprofezin, pymetrozine, capillary, second worm nitrile, CGA 183893, spiral shell worm ethyl ester or Nylar, and active components A and the preferred weight ratio of active component B are 1 ︰ 60～60 ︰ 1; More preferably the weight ratio of fluorobenzene insect amide and Buprofezin or capillary is 1 ︰ 25～20 ︰ 1, the weight ratio of fluorobenzene insect amide and pymetrozine is 1 ︰ 30～20 ︰ 1, the weight ratio of fluorobenzene insect amide and second worm nitrile or Nylar is 1 ︰ 25～25 ︰ 1, the weight ratio of fluorobenzene insect amide and CGA 183893 is 1 ︰ 20～25 ︰ 1, and the weight ratio of fluorobenzene insect amide and spiral shell worm ethyl ester is 1 ︰ 25～20 ︰ 1; Most preferably be: the weight ratio of fluorobenzene insect amide and Buprofezin or capillary is 1 ︰ 9～4 ︰ 1, the weight ratio of fluorobenzene insect amide and pymetrozine is 1 ︰ 15～5 ︰ 1, the weight ratio of fluorobenzene insect amide and second worm nitrile or Nylar is 1 ︰ 9～6 ︰ 1, the weight ratio of fluorobenzene insect amide and CGA 183893 is 1 ︰ 1～6 ︰ 1, and the weight ratio of fluorobenzene insect amide and spiral shell worm ethyl ester is 1 ︰ 11～5 ︰ 1.
The purposes of the highly effective pesticide composition containing fluorobenzene insect amide that the present invention proposes for preventing and treating insect on crops, described crops comprise cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop; Described insect comprises that beet armyworm, diamond-back moth, cabbage caterpillar, prodenia litura, leaf miner, tea lesser leafhopper, aphid, aleyrodid, rice fulgorid, rice leaf roller, striped rice borer, paddy stem borer, scale insect, cotton bollworm, cotton boll resemble, arrowhead scales or thrips.
The weight ratio of active components A, active component B is 1 ︰ 80～80 ︰ 1.Conventionally in composition, the weight percentage of active component is gross weight 0.5%～90%, is preferably 5%～80%.According to different preparation types, active component content scope is different.Conventionally, liquid preparation contains 1%～70% active substance by weight, is preferably 5%～50%; Solid pharmaceutical preparation contains 5%～80% active substance by weight, is preferably 10%～80%.
In Pesticidal combination of the present invention, at least contain a kind of surfactant, the dispersion of active component in water while being beneficial to use.Surface-active contents is 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.
Bactericidal composition of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by common processing method known in those skilled in the art, after being about to active substance and mixing with liquid flux or solid carrier, then add surfactant as one or more in dispersant, stabilizing agent, wetting agent, binding agent, defoamer, disintegrant, antifreeze etc.
Pesticidal combination of the present invention, can be processed on demand acceptable formulation on any agricultural chemicals, wherein more preferably formulation is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
When making wetting powder, composition comprises following constituent content: active components A 0.5%～80%, active component B0.5%～80%, dispersant 2%～10%, wetting agent 2%～10%, filler surplus.
When making water dispersible granules, composition comprises following constituent content: active components A 0.5%～80%, active component B0.5%～80%, dispersant 3%～12%, wetting agent 1%～8%, disintegrant 1%～10%, binding agent 0～8%, filler surplus.
When making suspending agent, composition comprises following constituent content: active components A 0.5%～50%, active component B0.5%～50%, dispersant 2%～10%, wetting agent 2%～10%, defoamer 0.01%～2%, thickener 0～2%, antifreeze 0～8%, deionized water add to 100%.
When making suspension emulsion, composition comprises following constituent content: active components A 0.5%～50%, active component B0.5%～50%, dispersant 2%～10%, defoamer 0.01%～2%, solvent 1%～15%, thickener 0～2%, emulsifier 2%～12%, antifreeze 0～8%, deionized water add to 100%.
When making aqueous emulsion, composition comprises following constituent content: active components A 0.5%～50%, active component B0.5%～50%, solvent 1%～30%, emulsifier 1%～15%, antifreeze 0～8%, thickener 0～2%, defoamer 0.01%～2%, deionized water are supplied surplus.
When making microcapsule suspending agent, composition comprises following constituent content: active components A 0.5%～50%, active component B0.5%～50%, macromolecule cyst material 2%～10%, dispersant 1%～10%, organic solvent 1%～10%, defoamer 0.01%～2%, emulsifier 1%～7%, pH adjusting agent 0.01%～5%, deionized water add to 100%.
When making microcapsule suspension-suspending agent, composition comprises following constituent content: active components A 0.5%～50%, active component B0.5%～50%, macromolecule cyst material 2%～10%, dispersant 1%～12%, wetting agent 1%～8%, organic solvent 1%～15%, emulsifier 1%～6%, defoamer 0.01%～2%, thickener 0～2%, pH adjusting agent 0.01%～5%, deionized water add to 100%.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspending agent the key technical indexes of the present invention:
The invention has the advantages that:
(1) after fluorobenzene insect amide and Buprofezin, pymetrozine, capillary, second worm nitrile, CGA 183893, spiral shell worm ethyl ester or pyriproxyfen compound, there is obvious synergy and lasting effect; (2) cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop insect are all had to greater activity; (3) reduce agricultural chemicals dosage, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), to person poultry safety, Environmental compatibility is good; And preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Embodiment 1～18 wetting powder
Fluorobenzene insect amide, active component B, dispersant, wetting agent, filler are mixed in mixed cylinder, after airslide disintegrating mill is pulverized, mix again, can make wetting powder product of the present invention, specifically in Table 1.
Table 1 embodiment 1～18 each component and weight portion
Embodiment 19～36 water dispersible granules
Fluorobenzene insect amide, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, then add other auxiliary agents such as binding agent (can add and can not add), obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, can make water dispersible granules product of the present invention, specifically in Table 2.
Table 2 embodiment 19～36 each component and weight portions
Embodiment 37～54 suspending agents
By dispersant, wetting agent, defoamer, thickener (can add and can not add), antifreeze (can add and can not add), through high speed shear, mix, add fluorobenzene insect amide, active component B, in ball mill, ball milling is 2～3 hours, make diameter of particle all below 5 μ m, surplus is supplied by deionized water, can make suspending agent product of the present invention, specifically in Table 3.
Table 3 embodiment 37～54 each component and weight portions
Embodiment 55～63 suspension emulsions
Dispersant, defoamer, thickener (can add and can not add), antifreeze (can add and can not add) are mixed through high speed shear, add active component B, in ball mill, ball milling is 2～3 hours, make diameter of particle all below 5 μ m, make active component B suspending agent, then by fluorobenzene insect amide, solvent (can add and can not add), emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, surplus is supplied by deionized water, make suspension emulsion product of the present invention, specifically in Table 4,5.
Table 4 embodiment 55～58 each component and weight portions
Table 5 embodiment 59～63 each component and weight portions
Embodiment 64～79 aqueous emulsions
Fluorobenzene insect amide, active component B, solvent, emulsifier are added together, make to be dissolved into even oil phase; Deionized water, antifreeze (can add and can not add), thickener (can add and can not add), defoamer are mixed, become homogeneous water.Under high-speed stirred, water is added to oil phase, surplus is supplied by deionized water; Can make aqueous emulsion product of the present invention, specifically in Table 6.
Table 6 embodiment 64～79 each component and weight portions
Buprofezin, pymetrozine, capillary, second worm nitrile, CGA 183893, spiral shell worm ethyl ester, Nylar in table 1～6 are exchanged, can make novel formulation.
Embodiment 80～82 microemulsions
Fluorobenzene insect amide, active component B are dissolved in the homogenizer that solvent is housed, emulsifier, antifreeze (can add and can not add), defoamer are joined in the homogenizer that above-mentioned solution is housed, surplus gives strong mixing and homogenize after supplying by deionized water, finally obtain the as clear as crystal microemulsion product of the present invention of outward appearance, specifically in Table 7.
Table 7 embodiment 80～82 each component and content
Embodiment 83,84 microcapsule suspending agents mix fluorobenzene insect amide, active component B, macromolecule cyst material, solvent, defoamer, make to be dissolved into even oil phase, under shearing condition, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent, dispersant, surplus is supplied by deionized water, and bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, make the finely disseminated microcapsule suspending agent product of the present composition, specifically in Table 8.
Table 8 embodiment 83,84 each component and weight portions
Embodiment 85,86 microcapsule suspensions-suspending agent are by fluorobenzene insect amide, macromolecule cyst material, solvent, make to be dissolved into even oil phase, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent under shearing condition, make finely disseminated microcapsule suspending agent.Dispersant, wetting agent, defoamer, thickener (can add and can not add) are mixed through high speed shear, add active component B, in ball mill, ball milling is 2～3 hours, make diameter of particle all below 5 μ m, make suspending agent, then suspending agent is joined in the aqueous phase solution of micro-capsule suspension, deionized water is supplied surplus, make the finely disseminated microcapsule suspension-suspending agent of present composition product, specifically in Table 9.
Table 9 embodiment 85,86 each component and weight portions
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field trial.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, is placed in respectively beaker standby.Adopt and first to soak the method that connects worm after leaf, after the blade of the same size that does not contact any medicament is soaked to 5s in the liquid configuring, take out, naturally dry, put into insect box, then connect for examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat examination borer population used be 50, establishes blank simultaneously, in 72h, checks dead borer population, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50value.If contrast lethality is greater than 10%, be considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value to (x), with method of least squares, draws virulence regression equation, and calculates thus the value of every kind of medicament, according to the abundant equation of Sun Yun, calculates co-toxicity coefficient CTC.Computing formula following (take fluorobenzene insect amide as standard medicament, its toxicity index is 100):
TI * the P of theoretical toxicity index (TTI)=fluorobenzene insect amide of M
fluorobenzene insect amide+tI * P of effective active composition B
effective active compositionb
In formula: the mixture that M is different proportionings
P
effective active compositionb is effective active composition B shared ratio in composition
P
fluorobenzene insect amidefor fluorobenzene insect amide shared ratio in composition
B is selected from a kind of in Buprofezin, pymetrozine, capillary, second worm nitrile, CGA 183893, spiral shell worm ethyl ester, Nylar.
Virulence test part: test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Application Example two:
For trying insect: paddy rice rice leaf roller; Experimental scheme: effective lethal concentration scope of determining the former medicine of fluorobenzene insect amide and Buprofezin and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 10 fluorobenzene insect amide and the buprofezin compound toxicity test analysis of results table to paddy rice rice leaf roller
As shown in Table 10, fluorobenzene insect amide and Buprofezin to paddy rice rice leaf roller proportioning when 1 ︰ 80～80 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80～80 ︰ 1 scopes, when the proportioning of fluorobenzene insect amide and Buprofezin is during at 1 ︰ 25～20 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 220.Through applicant, test and find that the optimum ratio of fluorobenzene insect amide and Buprofezin is 20:1,15:1,10:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:8,1:10,1:15,1:20,1:25, wherein when fluorobenzene insect amide and Buprofezin weight ratio are 1:3, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Application Example three
For trying insect: cabbage aphid; Experimental scheme: effective lethal concentration scope of determining the former medicine of fluorobenzene insect amide and pymetrozine and the two different proportioning mixture through preliminary experiment.
Table 11 fluorobenzene insect amide and the Pyraphione compound toxicity test analysis of results table to cabbage aphid
| Reagent agent | Proportioning | LC 50(ug/mL) | Co-toxicity coefficient (CTC) |
| Fluorobenzene insect amide | — | 0..65 | — |
| Pymetrozine | — | 2..55 | — |
| Fluorobenzene worm Xian An ︰ pymetrozine | 80:1 | 0.37 | 177.32 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 60:1 | 0.35 | 188.03 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 40:1 | 0.33 | 200.64 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 20:1 | 0.30 | 224.69 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 11:1 | 0.30 | 231.11 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 5:1 | 0.30 | 247.62 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 1:1 | 0.41 | 253.66 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 1:4 | 0.61 | 266.39 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 1:9 | 0.80 | 250.00 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 1:15 | 0.90 | 243.27 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 1:20 | 0.96 | 236.98 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 1:30 | 1.05 | 225.77 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 1:40 | 1.19 | 203.59 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 1:60 | 1.30 | 190.63 |
| Fluorobenzene worm Xian An ︰ pymetrozine | 1:80 | 1.38 | 181.68 |
As shown in Table 11, fluorobenzene insect amide and pymetrozine to cabbage aphid proportioning when 1 ︰ 80～80 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80～80 ︰ 1 scopes, when the proportioning of fluorobenzene insect amide and pymetrozine is during at 1 ︰ 30～20 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 220.Through applicant, test and find that the optimum ratio of fluorobenzene insect amide and pymetrozine is 20:1,15:1,10:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:12,1:15,1:20,1:25,1:30, wherein when fluorobenzene insect amide and pymetrozine weight ratio are 1:4, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Application Example four
For trying insect: Laphygma exigua Hubner; Experimental scheme: effective lethal concentration scope of determining the former medicine of fluorobenzene insect amide and capillary and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to Laphygma exigua Hubner of table 12 fluorobenzene insect amide and capillary
| Reagent agent | Proportioning | LC 50(ug/mL) | Co-toxicity coefficient (CTC) |
| Fluorobenzene insect amide | - | O.60 | - |
| Capillary | - | 1.85 | - |
| Fluorobenzene insect amide: capillary | 80∶1 | 0.35 | 172.88 |
| Fluorobenzene insect amide: capillary | 60∶1 | 0.32 | 189.61 |
| Fluorobenzene insect amide: capillary | 40∶1 | 0.30 | 203.37 |
| Fluorobenzene insect amide: capillary | 20∶1 | 0.27 | 229.66 |
| Fluorobenzene insect amide: capillary | 11∶1 | 0.27 | 235.57 |
| Fluorobenzene insect amide: capillary | 4∶1 | 0.28 | 248.02 |
| Fluorobenzene insect amide: capillary | 1∶1 | 0.35 | 259.74 |
| Fluorobenzene insect amide: capillary | 1∶3 | 0.45 | 272.11 |
| Fluorobenzene insect amide: capillary | 1∶6 | 0.56 | 256.85 |
| Fluorobenzene insect amide: capillary | 1∶9 | 0.62 | 249.42 |
| Fluorobenzene insect amide: capillary | 1∶15 | 0.71 | 233.12 |
| Fluorobenzene insect amide: capillary | 1∶25 | 0.77 | 225.11 |
| Fluorobenzene insect amide: capillary | 1∶40 | 0.88 | 202.57 |
| Fluorobenzene insect amide: capillary | 1∶60 | 0.94 | 192.75 |
| Fluorobenzene insect amide: capillary | 1∶80 | 1.01 | 180.90 |
As shown in Table 12, fluorobenzene insect amide and capillary to Laphygma exigua Hubner proportioning at 1: 80～80: 1 o'clock, co-toxicity coefficient is all greater than 120, illustrate that both were mixed in scope and all show synergistic effect at 1: 80～80: 1, when the proportioning of fluorobenzene insect amide and capillary is during at 1: 25～20: 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 225, wherein when fluorobenzene insect amide and capillary weight ratio are 1: 3, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Application Example five
For trying insect: rice hoppers; Experimental scheme: effective lethal concentration scope of determining fluorobenzene insect amide and the former medicine of second worm nitrile and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to rice hoppers of table 13 fluorobenzene insect amide and second worm nitrile
| Reagent agent | Proportioning | LC 50(ug/mL) | Co-toxicity coefficient (CTC) |
| Fluorobenzene insect amide | - | 0.50 | - |
| Second worm nitrile | - | 0.85 | - |
| Fluorobenzene insect amide: second worm nitrile | 80∶1 | 0.29 | 173.29 |
| Fluorobenzene insect amide: second worm nitrile | 60∶1 | 0.27 | 186.44 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 40:1 | 0.25 | 202.02 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 25:1 | 0.23 | 220.87 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 15:1 | 0.22 | 233.25 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 6:1 | 0.22 | 241.41 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 1:1 | 0.25 | 251.57 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 2:3 | 0.25 | 265.25 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 1:4 | 0.29 | 256.57 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 1:9 | 0.32 | 247.62 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 1:15 | 0.35 | 232.05 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 1:25 | 0.37 | 223.08 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 1:40 | 0.41 | 203.25 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 1:60 | 0.46 | 182.15 |
| Fluorobenzene worm Xian An ︰ second worm nitrile | 1:80 | 0.50 | 168.05 |
As shown in Table 13, fluorobenzene insect amide and second worm nitrile to rice hoppers proportioning when 1 ︰ 80～80 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80～80 ︰ 1 scopes, when the proportioning of fluorobenzene insect amide and second worm nitrile is during at 1 ︰ 25～25 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 220, wherein when fluorobenzene insect amide and second worm nitrile weight ratio are 2:3, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.Application Example six
For trying insect: cotton cotton bollworm; Experimental scheme: effective lethal concentration scope of determining the former medicine of fluorobenzene insect amide and CGA 183893 and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to cotton cotton bollworm of table 14 fluorobenzene insect amide and CGA 183893
| Reagent agent | Proportioning | LC 50(ug/mL) | Co-toxicity coefficient (CTC) |
| Fluorobenzene insect amide | — | 0.65 | — |
| CGA 183893 | — | 0.45 | — |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 80:1 | 0.38 | 170.13 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 60:1 | 0.35 | 184.38 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 40:1 | 0.32 | 200.97 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 25:1 | 0.29 | 220.41 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 19:1 | 0.28 | 227.15 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 11:1 | 0.27 | 232.23 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 6:1 | 0.25 | 244.62 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 2:1 | 0.22 | 257.66 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 1:1 | 0.22 | 242.18 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 1:5 | 0.20 | 237.80 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 1:10 | 0.20 | 232.14 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 1:20 | 0.21 | 218.12 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 1:40 | 0.23 | 197.73 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 1:60 | 0.25 | 181.46 |
| Fluorobenzene worm Xian An ︰ CGA 183893 | 1:80 | 0.27 | 167.81 |
As shown in Table 14, fluorobenzene insect amide and CGA 183893 to cotton cotton bollworm proportioning when 1 ︰ 80～80 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80～80 ︰ 1 scopes, when the proportioning of fluorobenzene insect amide and CGA 183893 is during at 1 ︰ 20～25 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 215, wherein when fluorobenzene insect amide and CGA 183893 weight ratio are 2:1, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Application Example seven
For trying insect: tomato aleyrodid; Experimental scheme: effective lethal concentration scope of determining fluorobenzene insect amide and the former medicine of spiral shell worm ethyl ester and the two different proportioning mixture through preliminary experiment.
The composite toxicity test analysis of results table to tomato aleyrodid of table 15 fluorobenzene insect amide and spiral shell worm ethyl ester
| Reagent agent | Proportioning | LC 50(ug/mL) | Co-toxicity coefficient (CTC) |
| Fluorobenzene insect amide | — | 0.70 | — |
| Spiral shell worm ethyl ester | — | 1.85 | — |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 80:1 | 0.40 | 176.35 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 60:1 | 0.38 | 186.10 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 40:1 | 0.35 | 203.07 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 20:1 | 0.32 | 225.40 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 10:1 | 0.31 | 239.29 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 5:1 | 0.32 | 243.96 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 1:1 | 0.40 | 253.62 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 1:2 | 0.45 | 265.15 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 1:6 | 0.59 | 253.20 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 1:11 | 0.67 | 242.03 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 1:16 | 0.72 | 233.44 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 1:25 | 0.78 | 222.22 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 1:40 | 0.87 | 203.63 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 1:60 | 0.98 | 183.07 |
| Fluorobenzene worm Xian An ︰ spiral shell worm ethyl ester | 1:80 | 1.06 | 170.35 |
As shown in Table 15, fluorobenzene insect amide and spiral shell worm ethyl ester to tomato aleyrodid proportioning when 1 ︰ 80～80 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80～80 ︰ 1 scopes, when the proportioning of fluorobenzene insect amide and spiral shell worm ethyl ester is during at 1 ︰ 25～20 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 220, wherein when fluorobenzene insect amide and spiral shell worm ethyl ester weight ratio are 1:2, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.:
Application Example eight
For trying insect: brassicaceous vegetable beet armyworm; Experimental scheme: effective lethal concentration scope of determining the former medicine of fluorobenzene insect amide and Nylar and the two different proportioning mixture through preliminary experiment.Table 16 fluorobenzene insect amide and the pyriproxyfen compound toxicity test analysis of results table to brassicaceous vegetable beet armyworm
| Reagent agent | Proportioning | LC 50(ug/mL) | Co-toxicity coefficient (CTC) |
| Fluorobenzene insect amide | — | 0.45 | — |
| Nylar | — | 0.70 | — |
| Fluorobenzene worm Xian An ︰ Nylar | 80:1 | 0.27 | 167.41 |
| Fluorobenzene worm Xian An ︰ Nylar | 60:1 | 0.25 | 181.07 |
| Fluorobenzene worm Xian An ︰ Nylar | 40:1 | 0.23 | 197.39 |
| Fluorobenzene worm Xian An ︰ Nylar | 25:1 | 0.21 | 217.29 |
| Fluorobenzene worm Xian An ︰ Nylar | 15:1 | 0.20 | 230.18 |
| Fluorobenzene worm Xian An ︰ Nylar | 6:1 | 0.19 | 249.68 |
| Fluorobenzene worm Xian An ︰ Nylar | 1:1 | 0.21 | 261.32 |
| Fluorobenzene worm Xian An ︰ Nylar | 2:3 | 0.21 | 273.32 |
| Fluorobenzene worm Xian An ︰ Nylar | 1:4 | 0.24 | 263.34 |
| Fluorobenzene worm Xian An ︰ Nylar | 1:9 | 0.27 | 246.55 |
| Fluorobenzene worm Xian An ︰ Nylar | 1:15 | 0.29 | 234.22 |
| Fluorobenzene worm Xian An ︰ Nylar | 1:25 | 0.32 | 215.07 |
| Fluorobenzene worm Xian An ︰ Nylar | 1:40 | 0.34 | 204.00 |
| Fluorobenzene worm Xian An ︰ Nylar | 1:60 | 0.38 | 183.34 |
| Fluorobenzene worm Xian An ︰ Nylar | 1:80 | 0.40 | 174.57 |
As shown in Table 16, fluorobenzene insect amide and Nylar to brassicaceous vegetable beet armyworm proportioning when 1 ︰ 80～80 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 80～80 ︰ 1 scopes, when the proportioning of fluorobenzene insect amide and Nylar is during at 1 ︰ 25～25 ︰ 1, synergistic effect is more obviously outstanding, and co-toxicity coefficient is all greater than 215, wherein when fluorobenzene insect amide and Nylar weight ratio are 2:3, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Through test, find: after fluorobenzene insect amide and active component B are composite to the beet armyworm in various crop, diamond-back moth, cabbage caterpillar, prodenia litura, leaf miner, tea lesser leafhopper, aphid, aleyrodid, rice fulgorid, rice leaf roller, striped rice borer, paddy stem borer, scale insect, cotton bollworm, cotton boll resemble, the control of arrowhead scales or thrips has obvious synergistic effect, co-toxicity coefficient is all more than 120.
Effect experiment part: test medicine is researched and developed, provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 10% fluorobenzene insect amide suspending agent (autogamy), 25% Buprofezin wetting powder (commercial), 50% pymetrozine water dispersing granule (commercial), 10% capillary suspending agent (autogamy), 10% second worm nitrile suspending agent (autogamy), 10% CGA 183893 wetting powder (autogamy), 240g/l spiral shell worm ethyl ester suspending agent (autogamy), 10.8% Nylar missible oil (autogamy).
Application Example nine fluorobenzene insect amides and active component B and the composite control brassicaceous vegetable beet armyworm test of pesticide effectiveness thereof
This test arrangement is at Xian District, Shanxi Province suburban area, and before medicine, investigation brassicaceous vegetable beet armyworm insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 10 days, 20 days.Result of the test is as follows:
Table 17 fluorobenzene insect amide and active component B and the composite control brassicaceous vegetable beet armyworm test of pesticide effectiveness thereof
As can be seen from Table 17, after fluorobenzene insect amide and active component B are composite, can effectively prevent and treat brassicaceous vegetable beet armyworm, through inventor's evidence fluorobenzene insect amide and active component B, also can effectively prevent and treat brassicaceous vegetable diamond-back moth, cabbage caterpillar, prodenia litura, aphid after composite, control efficiency is all higher than 96%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten fluorobenzene insect amides and active component B and the composite control paddy rice rice leaf roller test of pesticide effectiveness thereof
This test arrangement is in Hanzhong City suburb, Shaanxi Province, and before medicine, investigation paddy rice rice leaf roller insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 18 fluorobenzene insect amide and active component B and the composite control paddy rice rice leaf roller test of pesticide effectiveness thereof
As can be seen from Table 18, after fluorobenzene insect amide and active component B are composite, can effectively prevent and treat paddy rice rice leaf roller, through inventor's evidence fluorobenzene insect amide and active component B, also can effectively prevent and treat rice hoppers, striped rice borer, paddy stem borer after composite, control efficiency is all higher than 96%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten phenyl-monofluoride insect amides and active component B and the composite control tea tree tea lesser leafhopper test of pesticide effectiveness thereof
This test arrangement is in suburb, Ya'an, Sichuan Province, and before medicine, investigation tea tree tea lesser leafhopper insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 15 days, 30 days.Result of the test is as follows:
Table 19 fluorobenzene insect amide and active component B and the composite control tea tree tea lesser leafhopper test of pesticide effectiveness thereof
As can be seen from Table 19, fluorobenzene insect amide and active component B and composite control tea tree tea lesser leafhopper thereof, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten difluorobenzene insect amides and active component B and the composite control cucumber aleyrodid test of pesticide effectiveness thereof
This test arrangement is at Xian District, Shanxi Province suburban area, and before medicine, investigation cucumber powder mite evil index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 20 fluorobenzene insect amide and active component B and the composite control cucumber aleyrodid test of pesticide effectiveness thereof
As can be seen from Table 20, fluorobenzene insect amide and active component B and composite control cucumber aleyrodid thereof, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten trifluoro-benzene insect amides and active component B and the composite control mandarin tree leaf miner test of pesticide effectiveness thereof
This test arrangement is in Hanzhong City suburb, Shaanxi Province, and before medicine, investigation mandarin tree leaf miner insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 21 fluorobenzene insect amide and active component B and the composite control mandarin tree leaf miner test of pesticide effectiveness thereof
As can be seen from Table 21, after fluorobenzene insect amide and active component B are composite, can effectively prevent and treat mandarin tree leaf miner, through inventor's evidence fluorobenzene insect amide and active component B, also can effectively prevent and treat mandarin tree aphid, scale insect, arrowhead scales after composite, control efficiency is all higher than 95%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten phenyl tetrafluoride insect amides and active component B and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
This test arrangement is at Xianyang, Shanxi province suburban area, and before medicine, investigation cotton cotton bollworm insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculate preventive effect for after dispenser 3 days, 10 days, 20 days.Result of the test is as follows:
Table 22 fluorobenzene insect amide and active component B and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
As can be seen from Table 22, after fluorobenzene insect amide and active component B are composite, can effectively prevent and treat cotton cotton bollworm, also can effectively prevent and treat cotton boll after composite resemble through inventor's evidence fluorobenzene insect amide and active component B, control efficiency is all higher than 95%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Chrysanthemum Control of Aphids is viewed and admired in Application Example ten phenyl-pentafluoride insect amides and active component B and composite control thereof
This test arrangement is in nursery, Xi'an City, Shanxi Province, and before medicine, chrysanthemum aphid insect pest index is viewed and admired in investigation, in the dispenser of insect pest initial stage of origination, within after dispenser 3 days, 15 days, 30 days, investigates insect pest indexes and calculates preventive effect.Result of the test is as follows:
Chrysanthemum Control of Aphids is viewed and admired in table 23 fluorobenzene insect amide and active component B and composite control thereof
As can be seen from Table 23, chrysanthemum aphid is viewed and admired in fluorobenzene insect amide and active component B and composite control thereof, through inventor's evidence fluorobenzene insect amide and active component B, also can effectively prevent and treat and view and admire chrysanthemum thrips after composite, and control efficiency is all higher than 96%, the preventive effect that is better than single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
After through different local throughout the country tests, draw, after fluorobenzene insect amide and Buprofezin, pymetrozine, capillary, second worm nitrile, CGA 183893, spiral shell worm ethyl ester, pyriproxyfen compound to the beet armyworm in various crop, diamond-back moth, cabbage caterpillar, prodenia litura, leaf miner, tea lesser leafhopper, aphid, aleyrodid, rice fulgorid, rice leaf roller, striped rice borer, paddy stem borer, scale insect, cotton bollworm, cotton boll resemble, the preventive effect of the common insect such as arrowhead scales or thrips is all more than 95%, be better than single dose preventive effect, synergistic effect is obvious.
Claims (6)
1. the highly effective pesticide composition containing fluorobenzene insect amide, effective active composition is active components A and active component B, it is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 80～80 ︰ 1, described active components A is selected from fluorobenzene insect amide, and active component B is selected from a kind of in Buprofezin, pymetrozine, capillary, second worm nitrile, CGA 183893, spiral shell worm ethyl ester or Nylar.
2. the highly effective pesticide composition containing fluorobenzene insect amide according to claim 1, is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 60～60 ︰ 1.
3. the highly effective pesticide composition containing fluorobenzene insect amide according to claim 2, is characterized in that:
The weight ratio of fluorobenzene insect amide and Buprofezin or capillary is 1 ︰ 25～20 ︰ 1;
The weight ratio of fluorobenzene insect amide and pymetrozine is 1 ︰ 30～20 ︰ 1;
The weight ratio of fluorobenzene insect amide and second worm nitrile or Nylar is 1 ︰ 25～25 ︰ 1;
The weight ratio of fluorobenzene insect amide and CGA 183893 is 1 ︰ 20～25 ︰ 1;
The weight ratio of fluorobenzene insect amide and spiral shell worm ethyl ester is 1 ︰ 25～20 ︰ 1.
4. according to the highly effective pesticide composition containing fluorobenzene insect amide described in any one in claims 1 to 3, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-suspending agent.
5. the highly effective pesticide composition containing fluorobenzene insect amide according to claim 4 is used for the purposes of preventing and treating insect on crops.
6. purposes according to claim 5, is characterized in that: described insect is that beet armyworm, diamond-back moth, cabbage caterpillar, prodenia litura, leaf miner, tea lesser leafhopper, aphid, aleyrodid, rice fulgorid, rice leaf roller, striped rice borer, paddy stem borer, scale insect, cotton bollworm, cotton boll resemble, arrowhead scales or thrips.
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| CN104488913A (en) * | 2014-12-23 | 2015-04-08 | 安徽众邦生物工程有限公司 | Buprofezin-containing insecticidal composition |
| CN106259343A (en) * | 2015-05-25 | 2017-01-04 | 浙江省化工研究院有限公司 | A kind of pyriproxyfen-containing and the Pesticidal combination of chlorine fluorine cyanogen insect amide |
| CN106472512A (en) * | 2016-10-11 | 2017-03-08 | 佛山市盈辉作物科学有限公司 | A kind of containing chlorine fluorine cyanogen insect amide and the Pesticidal combination of Nylar |
| CN111789118A (en) * | 2020-05-27 | 2020-10-20 | 浙江中山化工集团股份有限公司 | Insecticide composition containing flubendiamide and chlorfenapyr and preparation method thereof |
| CN113197208A (en) * | 2021-05-11 | 2021-08-03 | 安徽丰乐农化有限责任公司 | Insecticidal composition containing flubendiamide and acetoprole and application thereof |
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| CN113197208A (en) * | 2021-05-11 | 2021-08-03 | 安徽丰乐农化有限责任公司 | Insecticidal composition containing flubendiamide and acetoprole and application thereof |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Patentee after: SHAANXI MEIBANG PHARMACEUTICAL GROUP Co.,Ltd. Address before: 715500 Shaanxi Pucheng Weinan County agricultural base industrial park Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
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