CN104073083A - Water-based elastic fluorocarbon building coating and preparation method thereof - Google Patents
Water-based elastic fluorocarbon building coating and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a water-based elastic fluorocarbon building coating and a preparation method thereof. The water-based elastic fluorocarbon building coating comprises the following components in percentage by weight: 16%-31% of water, 40%-60% of self-made elastic fluorocarbon building emulsions, 2%-6% of high-efficiency film-forming auxiliary agents JS-PPH(302), 5%-10% of superfine rutile TiO2, 1%-5% of superfine talcum powder, 1%-5% of superfine quartz powder, 1%-5% of superfine kaolin, 1%-5% of superfine coarse whiting powder, 0.1%-0.5% of strong dispersing agents, 0.1%-0.5% of multifunctional thickening agents, 0.1%-0.4% of organic silicon defoaming agents JS-2010S and 0.1%-0.4% of strong sterilizing preservative agents 981. The preparation method comprises the following steps: firstly preparing the self-made elastic fluorocarbon building emulsions; and then preparing the water-based elastic fluorocarbon building coating. The water-based elastic fluorocarbon building coating disclosed by the invention is green and environment-friendly and has the advantages of super-long weather resistance, artificial ageing resistance, acid-base resistance, stain resistance, chemical resistance, high adhesive force, good flexibility, scrubbing resistance, breaking elongation, tensile strength, simple preparation process, convenience for operation, high preparation efficiency, low production cost, high market competitiveness, and the like.
Description
Technical field
The invention belongs to technical field of coatings, relate to a kind of building coating, more particularly relate to a kind of aqueous elastic fluorine carbon building coating and preparation method thereof.Coating of the present invention is mainly used in outer wall building coating field.
Background technology
At building field, the brushing of newly-built external walls of building coating and the maintenance of aging blocks room refresh in the brushing process of exterior coating, the normally used fluorine carbon building coating that is mostly at present.Existing this coating is because its snappiness is poor; in the time being subject to the affecting of the unfavorable factors such as extraneous weather, its building surface often can produce crack phenomenon, and along with its crack of time lengthening can further be strengthened gradually; thereby can have a negative impact to buildings, even adverse consequences.Therefore, the scientific research personnel relevant to building field extremely pays close attention to this and payes attention to, one to since thirst for that development is a kind of can improve the snappiness of existing fluorine carbon building coating, novel aqueous elastic fluorine carbon building coating, thus overcome and solves body of wall and covers with paint, lacquer, colour wash, etc. after the phenomenon that easily ftractures of coating.And require this novel not only environmental protection of aqueous elastic fluorine carbon building coating, the more important thing is and will there is the advantages such as weathering resistance, artificial ageing resistance, acid and alkali-resistance, resistance to soiling, chemical-resistant, strong adhesion, the snappiness of overlength is good, scrubbing resistance, elongation at break, tensile strength.
Summary of the invention
The object of the invention is, for overcoming and solving poor defect and the problem of snappiness that existing fluorine carbon building coating exists, provides a kind of aqueous elastic fluorine carbon building coating and preparation method thereof.The not only environmental protection of this coating, the more important thing is and have the advantages such as weathering resistance, artificial ageing resistance, acid and alkali-resistance, resistance to soiling, chemical-resistant, strong adhesion, the snappiness of overlength is good, scrubbing resistance, elongation at break, tensile strength.
For achieving the above object, the technical scheme that the present invention takes is:
A kind of aqueous elastic fluorine carbon building coating, content is by component by mass percentage: water is 16-31%, and self-control elastic fluorocarbon building emulsion is 40-60%, and efficient film coalescence aid JS-PPH (302) is 2-6%, ultra-fine rutile TiO
2for 5-10%, superfine talcum powder is 1-5%, ultrafine quartz powder is 1-5%, ultrafine kaolin is 1-5%, ultrafine heavy calcium powder is 1-5%, and powerful dispersion agent is 0.1～0.5%, and multi-functional thickening material is 0.1-0.5%, silicone antifoam agent JS-2010S is 0.1～0.4%, and strong disinfecting sanitas 981 is 0.1-0.4% composition.
Wherein, described self-control elastic fluorocarbon building emulsion by mass percentage content by component: deionized water is 38%, vinylidene fluoride is 20%, trifluorochloroethylene is 10%, hydroxyethyl methylacrylate is 10%, methyl methacrylate is 8%, N hydroxymethyl acrylamide is 0.8%, ethylene glycol monoallyl ether is 1%, and vinyl propyl ether is 5%, and isopropyl-ethylene base ether is 4.2%, sodium lauryl sulphate is 0.8%, polyoxyethylene nonylphenol ether OP-10 is 1.5%, and Ammonium Persulfate 98.5 is 0.2%, and sodium bisulfite is 0.5% composition.
Described ultra-fine rutile TiO
2, superfine talcum powder, ultrafine quartz powder, ultrafine kaolin, the particle diameter of ultrafine heavy calcium powder is 1250 mesh sieves.
For achieving the above object, another technical scheme that the present invention takes is:
The preparation method of a kind of aqueous elastic fluorine carbon building coating of the present invention, comprises the following steps:
The preparation method of step 1, described self-control elastic fluorocarbon building emulsion, concrete steps are:
(1) press formula metering by 1/2 deionized water, 1/2 hydroxyethyl methylacrylate, 1/2 methyl methacrylate, 1/2 N hydroxymethyl acrylamide, 1/2 ethylene glycol monoallyl ether, 1/2 vinyl propyl ether, 1/2 isopropyl-ethylene base ether, 1/2 sodium lauryl sulphate, 1/2 polyoxyethylene nonylphenol ether OP-10 adds in emulsification container, with the rotating speed stirring at low speed 25-30min of 700-900r/min, obtain emulsification emulsion;
(2) emulsion after step (1) emulsification is poured in reactor, under the high-speed stirring condition of 1000-2700r/min, add respectively remaining 1/2 deionized water and whole ammonium persulphate and sodium bisulfites, after passing into nitrogen stir for 4-8 time in reactor, be warming up to 65-75 DEG C, add respectively more remaining 1/2 hydroxyethyl methylacrylate, 1/2 methyl methacrylate, 1/2 N hydroxymethyl acrylamide, 1/2 ethylene glycol monoallyl ether, 1/2 vinyl propyl ether, 1/2 isopropyl-ethylene base ether, 1/2 sodium lauryl sulphate, 1/2 polyoxyethylene nonylphenol ether OP-10 stirs 50-60min, pH ≈ 7-8,
(3) then add again respectively whole vinylidene fluorides and trifluorochloroethylene by formula metering, be raised to 90-110 DEG C in temperature, reactor pressure is to stir under 0.7-1.0MPa, and cooling decompression after insulation reaction 10-152h obtains aqueous elastic fluorine carbon building emulsion.
The preparation of step 2, described aqueous elastic fluorine carbon building coating, concrete steps are:
(1) under the condition stirring at rotating speed with 700-900r/min, by formula metering respectively by water, ultra-fine rutile TiO
2, superfine talcum powder adds in container, stirs 20-25min;
(2) under the condition stirring with 1000-2700r/min rotating speed, by formulating of recipe amount, self-control elastic fluorocarbon building emulsion is added in container, continue to stir 30-35min, then respectively ultrafine quartz powder, ultrafine kaolin, ultrafine heavy calcium powder, efficient film coalescence aid JS-PPH (302) are added in container, to stir 35-40min even again;
(3) add respectively more multi-functional thickening material, powerful dispersion agent, silicone antifoam agent JS-2010S, strong disinfecting sanitas 981, stirs 40-50min, obtains aqueous elastic fluorine carbon building coating.
The advantage that the present invention had compared with prior art and beneficial effect be mainly:
1, not only environmental protection of coating of the present invention, the more important thing is and have the advantages such as weathering resistance, artificial ageing resistance, acid and alkali-resistance, resistance to soiling, chemical-resistant, strong adhesion, the snappiness of overlength is good, scrubbing resistance, elongation at break, tensile strength.
2, coating preparation technology of the present invention is simple, easy to operate, and preparation efficiency is high, and production cost is low, and the market competitiveness is strong.
Embodiment
Further describe technical scheme of the present invention below in conjunction with specific embodiment:
The source of each component: water, elastic fluorocarbon building emulsion (self-control), efficient film coalescence aid JS-PPH (302) (Shanghai Jinshan Chemical Co., Ltd.'s technical grade product), ultra-fine rutile TiO
21250 orders (Langfang Landtek Chemical Co., Ltd. technical grade product), ultrafine quartz powder 1250 orders (sea otter micro mist factory of Henan Province technical grade product), superfine talcum powder 1250 orders (Changxing Qing Shenggai industry company limited technical grade product), ultrafine kaolin (Yangzhou Di Lan industrial chemicals company limited technical grade product), ultrafine heavy calcium powder (Sheng Hua fine chemistry industry technical grade product), multi-functional thickening material (Beijing Gongda Weiye Sci-Tech Research Center's technical grade product), powerful dispersion agent (Beijing Gongda Weiye Sci-Tech Research Center's technical grade product), strong disinfecting sanitas 981 (Shanghai Ji Yi Chemical Co., Ltd. technical grade product), silicone antifoam agent JS-2010S (Shanghai Jinshan Chemical Co., Ltd.'s technical grade product).
One, the mass percent content of embodiment 1-5 recipe ingredients is as shown in the table:
Two, the preparation method of embodiment 1-5, step is as follows:
The preparation method of step 1, described self-control elastic fluorocarbon building emulsion, concrete steps are:
(1) be 38% by formulation deionised water, vinylidene fluoride is 20%, and trifluorochloroethylene is 10%, hydroxyethyl methylacrylate is 10%, methyl methacrylate is 8%, and N hydroxymethyl acrylamide is 0.8%, and ethylene glycol monoallyl ether is 1%, vinyl propyl ether is 5%, isopropyl-ethylene base ether is 4.2%, and sodium lauryl sulphate is 0.8%, and polyoxyethylene nonylphenol ether OP-10 is 1.5%, Ammonium Persulfate 98.5 is 0.2%, and sodium bisulfite is 0.5%.First by 1/2 deionized water wherein, 1/2 hydroxyethyl methylacrylate, 1/2 methyl methacrylate, 1/2 N hydroxymethyl acrylamide, 1/2 ethylene glycol monoallyl ether, 1/2 vinyl propyl ether, 1/2 isopropyl-ethylene base ether, 1/2 sodium lauryl sulphate, 1/2 polyoxyethylene nonylphenol ether OP-10 adds in emulsification container, with the rotating speed stirring at low speed 25-30min of 700-900r/min, obtain emulsification emulsion;
(2) emulsion after step (1) emulsification is poured in reactor, under the high-speed stirring condition of 1000-2700r/min, add respectively remaining 1/2 deionized water and whole ammonium persulphate and sodium bisulfites, after passing into nitrogen stir for 4-8 time in reactor, be warming up to 65-75 DEG C, add respectively more remaining 1/2 hydroxyethyl methylacrylate, 1/2 methyl methacrylate, 1/2 N hydroxymethyl acrylamide, 1/2 ethylene glycol monoallyl ether, 1/2 vinyl propyl ether, 1/2 isopropyl-ethylene base ether, 1/2 sodium lauryl sulphate, 1/2 polyoxyethylene nonylphenol ether OP-10 stirs 50-60min, pH ≈ 7-8,
(3) then add again respectively whole vinylidene fluorides and trifluorochloroethylene by formula metering, be raised to 90-110 DEG C in temperature, reactor pressure is to stir under 0.7-1.0MPa, and cooling decompression after insulation reaction 10-152h obtains aqueous elastic fluorine carbon building emulsion.
The preparation of step 2, described aqueous elastic fluorine carbon building coating, concrete steps are:
(1) under the condition stirring at rotating speed with 700-900r/min, by formula metering respectively by water, ultra-fine rutile TiO
2, superfine talcum powder adds in container, stirs 20-25min;
(2) under the condition stirring with 1000-2700r/min rotating speed, by formulating of recipe amount, self-control elastic fluorocarbon building emulsion is added in container, continue to stir 30-35min, then respectively ultrafine quartz powder, ultrafine kaolin, ultrafine heavy calcium powder, efficient film coalescence aid JS-PPH (302) are added in container, to stir 35-40min even again;
(3) add respectively more multi-functional thickening material, powerful dispersion agent, silicone antifoam agent JS-2010S, strong disinfecting sanitas 981, stirs 40-50min, obtains aqueous elastic fluorine carbon building coating.
Three, embodiment 1-5 products obtained therefrom performance test results are as shown in the table:
Claims (4)
1. an aqueous elastic fluorine carbon building coating, is characterized in that, content is by component by mass percentage: water is 16-31%, and self-control elastic fluorocarbon building emulsion is 40-60%, and efficient film coalescence aid JS-PPH (302) is 2-6%, ultra-fine rutile TiO
2for 5-10%, superfine talcum powder is 1-5%, ultrafine quartz powder is 1-5%, ultrafine kaolin is 1-5%, ultrafine heavy calcium powder is 1-5%, and powerful dispersion agent is 0.1～0.5%, and multi-functional thickening material is 0.1-0.5%, silicone antifoam agent JS-2010S is 0.1～0.4%, and strong disinfecting sanitas 981 is 0.1-0.4% composition.
2. a kind of aqueous elastic fluorine carbon building coating according to claim 1, it is characterized in that, described self-control elastic fluorocarbon building emulsion by mass percentage content by component: deionized water is 38%, vinylidene fluoride is 20%, trifluorochloroethylene is 10%, hydroxyethyl methylacrylate is 10%, methyl methacrylate is 8%, N hydroxymethyl acrylamide is 0.8%, ethylene glycol monoallyl ether is 1%, vinyl propyl ether is 5%, isopropyl-ethylene base ether is 4.2%, sodium lauryl sulphate is 0.8%, polyoxyethylene nonylphenol ether OP-10 is 1.5%, Ammonium Persulfate 98.5 is 0.2%, sodium bisulfite is 0.5% composition.
3. a kind of aqueous elastic fluorine carbon building coating according to claim 1, is characterized in that described ultra-fine rutile TiO
2, superfine talcum powder, ultrafine quartz powder, the particle diameter of ultrafine kaolin and ultrafine heavy calcium powder is 1250 mesh sieves.
4. a preparation method for aqueous elastic fluorine carbon building coating according to claim 1, is characterized in that, comprises the following steps:
The preparation method of step 1, described self-control elastic fluorocarbon building emulsion, concrete steps are:
(1) press formula metering by 1/2 deionized water, 1/2 hydroxyethyl methylacrylate, 1/2 methyl methacrylate, 1/2 N hydroxymethyl acrylamide, 1/2 ethylene glycol monoallyl ether, 1/2 vinyl propyl ether, 1/2 isopropyl-ethylene base ether, 1/2 sodium lauryl sulphate, 1/2 polyoxyethylene nonylphenol ether OP-10 adds in emulsification container, with the rotating speed stirring at low speed 25-30min of 700-900r/min, obtain emulsion;
(2) emulsion after step (1) emulsification is poured in reactor, under the high-speed stirring condition of 1000-2700r/min, add respectively remaining 1/2 deionized water and whole ammonium persulphate and sodium bisulfites, after passing into nitrogen stir for 4-8 time in reactor, be warming up to 65-75 DEG C, add respectively more remaining 1/2 hydroxyethyl methylacrylate, 1/2 methyl methacrylate, 1/2 N hydroxymethyl acrylamide, 1/2 ethylene glycol monoallyl ether, 1/2 vinyl propyl ether, 1/2 isopropyl-ethylene base ether, 1/2 sodium lauryl sulphate, 1/2 polyoxyethylene nonylphenol ether OP-10 stirs 50-60min, pH ≈ 7-8,
(3) then add again respectively whole vinylidene fluorides and trifluorochloroethylene by formula metering, be raised to 90-110 DEG C in temperature, reactor pressure is to stir under 0.7-1.0MPa, and cooling decompression after insulation reaction 10-152h obtains aqueous elastic fluorine carbon building emulsion;
The preparation of step 2, described aqueous elastic fluorine carbon building coating, concrete steps are:
1) under the condition stirring at rotating speed with 700-900r/min, by formula metering respectively by water, ultra-fine rutile TiO
2, superfine talcum powder adds in container, stirs 20-25min;
2) under the condition stirring with 1000-2700r/min rotating speed, by formulating of recipe amount, self-control elastic fluorocarbon building emulsion is added in container, continue to stir 30-35min, then respectively ultrafine quartz powder, ultrafine kaolin, ultrafine heavy calcium powder, efficient film coalescence aid JS-PPH (302) are added in container, to stir 35-40min even again;
3) add respectively more multi-functional thickening material, powerful dispersion agent, silicone antifoam agent JS-2010S, strong disinfecting sanitas 981, stirs 40-50min, obtains aqueous elastic fluorine carbon building coating.
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| CN106497252A (en) * | 2016-09-23 | 2017-03-15 | 安徽吉思特智能装备有限公司 | Heat-insulated radial pattern coating of the modified fluorine carbon of a kind of atlapulgite and preparation method thereof |
| CN106519825A (en) * | 2016-09-23 | 2017-03-22 | 安徽吉思特智能装备有限公司 | Fly ash microsphere-based fluorocarbon thermal insulation radiation coating and preparation method thereof |
| CN106519824A (en) * | 2016-09-23 | 2017-03-22 | 安徽吉思特智能装备有限公司 | Alcoholic hydroxyl group-resisting fluoro-carbon heat-radiation-isolating coating material and preparation method thereof |
| CN106497258A (en) * | 2016-09-27 | 2017-03-15 | 安徽吉思特智能装备有限公司 | Heat-insulated radial pattern coating of the fluorine carbon of a kind of low-surface-energy and preparation method thereof |
| CN106497257A (en) * | 2016-09-27 | 2017-03-15 | 安徽吉思特智能装备有限公司 | Heat-insulated radial pattern coating of the enhanced fluorine carbon of a kind of Titanium Dioxide and preparation method thereof |
| CN106752605A (en) * | 2016-11-17 | 2017-05-31 | 上海衡峰氟碳材料有限公司 | A kind of novel aqueous fluorocarbon coating |
| CN107418341A (en) * | 2017-09-26 | 2017-12-01 | 安徽喜宝高分子材料有限公司 | A kind of resistant fluorine carbon wall finiss and preparation method thereof |
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