CN101613549A - Gold-wire silk fabric inner wall paint - Google Patents
Gold-wire silk fabric inner wall paint Download PDFInfo
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- CN101613549A CN101613549A CN200810126452A CN200810126452A CN101613549A CN 101613549 A CN101613549 A CN 101613549A CN 200810126452 A CN200810126452 A CN 200810126452A CN 200810126452 A CN200810126452 A CN 200810126452A CN 101613549 A CN101613549 A CN 101613549A
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Abstract
Beijing Zhonghua Kecheng Technology Institute is domestic professional scientific research institution, and this product is this institute latest scientific research.A kind of gold-wire silk fabric inner wall paint, it is characterized in that pure-acrylic emulsion 23～32, polycarboxylate type dispersion agent 0.5～1.2, defoamer BA-202 0.4～1.0, frostproofer propylene glycol 1.5～2.5, the potassium hydroxide solution 0.2～0.4 of sanitas LXE 0.1～0.3,40%, film coalescence aid alcohol ester-12 1.5～2.5, acrylic acid series polyocarboxy acid type thickening material 0.5～1.5, nanometer grade silica 1.0～3.0, Nano titanium dioxide 0.8～1.8, Rutile type Titanium Dioxide 10～20, water-ground limestone 8～15, calcined kaolin 8～15, water-based oxygen carbon resin 5～15, deionized water 10～20.This gold-wire silk fabric inner wall paint utilizes the combination of water-based fluorocarbon branch and pure acrylic acid emulsion, and the adding of nanometer grade silica and Nano titanium dioxide, effectively raise the ageing resistance of paint film and have the excellent in water resistance energy, prolonged the work-ing life of paint film greatly.
Description
Technical field
The invention belongs to the architectural decorative coating technical field, relate in particular to a kind of gold-wire silk fabric inner wall paint and preparation method thereof.
Background technology
Gold-wire silk fabric inner wall paint is widely used in the reconstruction, enlarging in city, the reconstruction of the old city town of moving removal homalographic, and the renovation of original a large amount of face brick, mosaic metope.Rainproof coating not only will have good leveling property, the decorative effect excellence, and opacifying power is good, and the characteristics of strong adhesion also need water-fast, alkaline-resisting, abrasion resistance, and are good nontoxic, do not fire characteristics such as construction safety convenience.
Existing rainproof coating is base-material with the modified acroleic acid synthetic resin emulsion mostly, is equipped with multiple high-quality face, filler and auxiliary agent and makes the zero diopter exterior coating.The ageing resistance of this rainproof coating paint film is relatively poor, and after use for some time, be full of cracks and perk appear in the enamelled coating of coating easily, thereby lose rainproof effect.
Summary of the invention
The purpose of this invention is to provide a kind of gold-wire silk fabric inner wall paint lacquer, solved the problem of lacking in existing rainproof water-resistant coating difference and work-ing life with good ageing resistance and excellent water resistance.
The technical solution used in the present invention is as follows:
A kind of gold-wire silk fabric inner wall paint is characterized in that the raw material weight proportioning of this gold-wire silk fabric inner wall paint consists of:
Pure-acrylic emulsion 23～32, polycarboxylate type dispersion agent 0.5～1.2, defoamer BA-202 0.4～1.0, frostproofer propylene glycol 1.5～2.5, sanitas LXE 0.1～0.3,40% potassium hydroxide solution 0.2～0.4, film coalescence aid alcohol ester-12 1.5～2.5, acrylic acid series polyocarboxy acid type thickening material 0.5～1.5, nanometer grade silica 1.0～3.0, Nano titanium dioxide 0.8～1.8, Rutile type Titanium Dioxide 10～20, water-ground limestone 8～15, calcined kaolin 8～15, water-based oxygen carbon resin 5～15, deionized water 10～20.
The concrete raw material weight proportioning of described gold-wire silk fabric inner wall paint consists of:
Pure-acrylic emulsion 28 weight parts, polycarboxylate type dispersion agent 0.5 weight part, defoamer BA-202 0.7 weight part, frostproofer propylene glycol 2 weight parts, sanitas LXE 0.2 weight part, 40% potassium hydroxide solution 0.3 weight part, film coalescence aid alcohol ester-12 2 weight part, acrylic acid series polyocarboxy acid type thickening material 0.9 weight part, nanometer grade silica 1.8 weight parts, Nano titanium dioxide 1.3 weight parts, Rutile type Titanium Dioxide 15 weight parts, water-ground limestone 12 weight parts, calcined kaolin 11 weight parts, water-based oxygen carbon resin 9 weight parts, deionized water 15 weight parts.
Described pure-acrylic emulsion is that the trade mark is the commercially available pure-acrylic emulsion commodity of BC2021.
Described polycarboxylate type dispersion agent can be selected from dispersion agent DA-01, dispersion agent DA-5016 or dispersion agent DA-40.
Described 40% potassium hydroxide solution can replace with 40% sodium hydroxide solution.
Described acrylic acid series polyocarboxy acid type thickening material is thickening material AT-06.
The fineness of described water-ground limestone and calcined kaolin is 600～800 orders.
It is the water-based oxygen carbon resin of F500 that described water-based oxygen carbon resin is selected trade names for use.
The preparation technology of this highly effective rainproof rainproof paint is characterized in that preparation process is as follows:
In deionized water, drop into polycarboxylate type dispersion agent, defoamer BA-202, frostproofer propylene glycol, sanitas LXE, 40% potassium hydroxide solution and film coalescence aid alcohol ester-12, and to mix under 200～300 rev/mins the stirring velocity; Add nano silicon oxide, nano-titanium oxide, Rutile type Titanium Dioxide, water-ground limestone and calcined kaolin then, under 800～1500 rev/mins high-speed stirring condition, mix; Reduce mixing speed to 300 rev/min, add pure-acrylic emulsion and water-based fluororesin and mix, last slowly dropwise addition of acrylic acid is that the polyocarboxy acid type thickening material stirs 10～15 minutes to thorough mixing, and the emulsion that obtains is filtered, standing and reacting under vacuum condition obtains this gold-wire silk fabric inner wall paint.
Employed each raw material of this gold-wire silk fabric inner wall paint is the commercially available prod among the present invention, and pure-acrylic emulsion is a latex paint emulsion.Be applicable to multiple base material, base material is had good sticking power, have characteristics such as good mechanical stability,, high gloss good, good weathering resistance, wear resistance with the compatibility of pigment.Polycarboxylate type dispersion agent can effectively carry out homodisperse with mineral filler and pigment, and the improvement system is to the wettability of color stuffing, shorten milling time, stablize color stuffing dispersion system, prevent color stuffing flocculation, reduction loose colour, tendency such as grow dim.DA is a kind of dispersion agent that is widely used in water-borne coatings, is the polymer aqueous solution of polycarboxylate type, and it has splendid molecular weight and the molecular weight distribution that is rather narrow, and is in the emulsion paint manufacturing processed, fine with the consistency of whole coating system.Select for use the DA dispersion agent can obtain best system lacquer viscosity.After adding the DA dispersion agent, can improve the mud jacking efficient of coating, effectively suppress returning of color stuffing and slightly reach the viscosity knock-on that face is filled out slurry, thereby improve the stability in storage of coating.The dispersion agent that the present invention uses can be dispersion agent DA-01, dispersion agent DA-5016 or the dispersion agent DA-40 in the dispersion agent of commercial goods.
Defoamer BA-202 is a kind of nominal particle size ACRYLIC EMULSION, it is applicable to multiple formulation for coating material, and have excellent weathering resistance, good anti-stain characteristic and wear resistance with the coating that it made, but and ultraviolet radiation resisting, timber and metallic surface are all had good sticking power.Sanitas LXE is the high-performance anticorrosion and bactericidal agent by Rhom and Hass's Development and Production, it is applicable to emulsion paint, all kinds of water-borne coatings, emulsion polymerization, also can be used for suppressing bacterium and fungi growing at production and memory print printing ink and other moisture organic products.To phenylpropyl alcohol, vinegar third, pure third and other multipolymer fabulous preservative efficacy is arranged, and fabulous compatible conformability is arranged with organic and inorganics composition in these products.Sanitas LXE to phenylpropyl alcohol, vinegar third, pure third and other multipolymer fabulous preservative efficacy is arranged, and fabulous compatible conformability is arranged with organic and inorganics composition in these products.Sanitas LXE used in the present invention can be that the trade name that Rhom and Hass produces is the sanitas of Kathon LXE, also can be the sanitas LXE that Shenzhen Haichuan Company is produced.
40% potassium hydroxide solution is used to regulate the pH value of this highly effective rainproof paint, and the pH value of rainproof paint finished product is adjusted between 7～9.The chemical name of film coalescence aid alcohol ester-12 is 2,2,4-trimethylammonium-1, and the 3-pentanediol mono isobutyrate, it can improve the film forming properties of emulsion paint, reduces the minimum film-forming temperature of emulsion paint, improves the scrub resistance of emulsion paint, improves the emulsion paint color developing.In emulsion paint, use this product, can be lowered into film temperature effectively, improve the paint film scrub resistance, improve the pigment homogeneity, have good color developing, improve paint film adhesion, reduce Alligatoring, peel off.The not hydrolysis in general alkaline medium of this film coalescence aid has good preservation stability.Under the mal-condition lower in temperature, that humidity is bigger, still have film forming properties preferably.Therefore, in emulsion paint, use this product in right amount, can improve the performance of product effectively.Acrylic acid series polyocarboxy acid type thickening material AT-06 can give moderate levelling of coating system and sagging performance, has excellent compatibility with various Emulsion Adhesives, thickening efficiency height, good rheological property.Storage and stability in use through the latex after its thickening are all good, and can satisfy the requirement of the multiple form of construction work course of processing.
Nanometer grade silica has higher surface activity, and it utilizes its surface effects, can effectively improve the hydrophobicity and the contamination resistance of paint film.Nano titanium dioxide can utilize its photocatalytic effect, thereby the anti-uv-ray that improves paint film improves the resistance to deterioration of coating with lacquer.
Beneficial effect of the present invention is, this gold-wire silk fabric inner wall paint utilizes the combination of water-based fluorocarbon branch and pure acrylic acid emulsion, and the adding of nanometer grade silica and Nano titanium dioxide, effectively raise the ageing resistance of paint film and have the excellent in water resistance energy, prolonged the work-ing life of paint film greatly.This highly effective rainproof paint can be used as the rainproof treatment of various building walls widely.
Embodiment
The present invention is further elaborated below in conjunction with embodiment.
Embodiment 1 presses each feed composition that column weight amount proportioning is got this gold-wire silk fabric inner wall paint:
The pure-acrylic emulsion BC-202128kg that the Beijing Orient acrylic is produced, Shenzhen Haichuan Company produces polycarboxylate type dispersion agent 5040 0.5kg, the long wind in Shanghai produces defoamer BA-202 0.7kg, the frostproofer propylene glycol 2kg that Yanshan Petrochemical is made, Shenzhen Haichuan Company produces sanitas LXE 0.2kg, 40% potassium hydroxide solution 0.3kg, Jilin Petrochemical is produced film coalescence aid alcohol ester-12 2kg, Beijing Orient comes gram force to produce acrylic acid series polyocarboxy acid type thickening material AT-06 0.9kg, Haihe River, Jiangsu nanosecond science and technology company produces nanometer grade silica 1.8kg, Nano titanium dioxide 1.3kg, du pont company produces Rutile type Titanium Dioxide 15kg, 600 purpose water-ground limestone 12kg, 600 purpose calcined kaolin 11kg, the Dalian stock company of nation of shaking produces water-based oxygen carbon resin 9kg, deionized water 15kg.
Earlier deionized water is added in the stirrer, the control stirring velocity is between 200～300 rev/mins, add dispersion agent 5040, defoamer BA-202, frostproofer propylene glycol, sanitas LXE, 40% potassium hydroxide solution and film coalescence aid alcohol ester-12 in order successively, stir and mixed in 10 minutes, add nano silicon oxide, nano-titanium oxide, Rutile type Titanium Dioxide, water-ground limestone and calcined kaolin then, under 800～1500 rev/mins high-speed stirring condition, mix; Reduce mixing speed to 300 rev/min, adding pure-acrylic emulsion and water-based fluororesin mixed 10 minutes, slowly add acrylic acid series polyocarboxy acid type thickening material AT-06 in the mode that drips at last, stir 10～15 minutes to thorough mixing, the emulsion that obtains is filtered, standing and reacting is 24 hours under vacuum condition, obtains this gold-wire silk fabric inner wall paint.
Claims (9)
1. gold-wire silk fabric inner wall paint, the raw material weight proportioning that it is characterized in that this gold-wire silk fabric inner wall paint consists of: pure-acrylic emulsion 23～32, polycarboxylate type dispersion agent 0.5～1.2, defoamer BA-202 0.4～1.0, frostproofer propylene glycol 1.5～2.5, the potassium hydroxide solution 0.2～0.4 of sanitas LXE 0.1～0.3,40%, film coalescence aid alcohol ester-12 1.5～2.5, acrylic acid series polyocarboxy acid type thickening material 0.5～1.5, nanometer grade silica 1.0～3.0, Nano titanium dioxide 0.8～1.8, Rutile type Titanium Dioxide 10～20, water-ground limestone 8～15, calcined kaolin 8～15, water-based oxygen carbon resin 5～15, deionized water 10～20.
2. gold-wire silk fabric inner wall paint according to claim 1 is characterized in that the concrete raw material weight proportioning of described gold-wire silk fabric inner wall paint consists of:
Pure-acrylic emulsion 28 weight parts, polycarboxylate type dispersion agent 0.5 weight part, defoamer BA-202 0.7 weight part, frostproofer propylene glycol 2 weight parts, sanitas LXE 0.2 weight part, 40% potassium hydroxide solution 0.3 weight part, film coalescence aid alcohol ester-12 2 weight part, acrylic acid series polyocarboxy acid type thickening material 0.9 weight part, nanometer grade silica 1.8 weight parts, Nano titanium dioxide 1.3 weight parts, Rutile type Titanium Dioxide 15 weight parts, water-ground limestone 12 weight parts, calcined kaolin 11 weight parts, water-based oxygen carbon resin 9 weight parts, deionized water 15 weight parts.
3. gold-wire silk fabric inner wall paint according to claim 1 is characterized in that described pure-acrylic emulsion is that the trade mark is the commercially available pure-acrylic emulsion commodity of BC2021.
4. gold-wire silk fabric inner wall paint according to claim 1 is characterized in that described polycarboxylate type dispersion agent can be selected from dispersion agent DA-01, dispersion agent DA-5016 or dispersion agent DA-40.
5. gold-wire silk fabric inner wall paint according to claim 1 is characterized in that described 40% potassium hydroxide solution can replace with 40% sodium hydroxide solution.
6. gold-wire silk fabric inner wall paint according to claim 1 is characterized in that described acrylic acid series polyocarboxy acid type thickening material is thickening material AT-06.
7. gold-wire silk fabric inner wall paint according to claim 1 is characterized in that the fineness of described water-ground limestone and calcined kaolin is 600～800 orders.
8. gold-wire silk fabric inner wall paint according to claim 1 is characterized in that it is the water-based oxygen carbon resin of F500 that described water-based oxygen carbon resin is selected trade names for use.
9. the preparation technology of the described gold-wire silk fabric inner wall paint of claim 1, it is characterized in that preparation process is as follows: in deionized water, drop into polycarboxylate type dispersion agent, defoamer BA-202, frostproofer propylene glycol, sanitas LXE, 40% potassium hydroxide solution and film coalescence aid alcohol ester-12, and to mix under 200～300 rev/mins the stirring velocity; Add nano silicon oxide, nano-titanium oxide, Rutile type Titanium Dioxide, water-ground limestone and calcined kaolin then, under 800～1500 rev/mins high-speed stirring condition, mix; Reduce mixing speed to 300 rev/min, add pure-acrylic emulsion and water-based fluororesin and mix, last slowly dropwise addition of acrylic acid is that the polyocarboxy acid type thickening material stirs 10～15 minutes to thorough mixing, and the emulsion that obtains is filtered, standing and reacting under vacuum condition obtains this gold-wire silk fabric inner wall paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810126452A CN101613549A (en) | 2008-06-27 | 2008-06-27 | Gold-wire silk fabric inner wall paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810126452A CN101613549A (en) | 2008-06-27 | 2008-06-27 | Gold-wire silk fabric inner wall paint |
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| CN101613549A true CN101613549A (en) | 2009-12-30 |
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| CN200810126452A Pending CN101613549A (en) | 2008-06-27 | 2008-06-27 | Gold-wire silk fabric inner wall paint |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101245198B (en) * | 2008-03-13 | 2011-03-23 | 常州市美伦钛业有限公司 | Coated titanium dioxide manufacture method |
| CN102964960A (en) * | 2012-11-15 | 2013-03-13 | 中山蓝海洋水性涂料有限公司 | Water-based fluorocarbon coating used for external wall and preparation method thereof |
| CN103087632A (en) * | 2013-01-15 | 2013-05-08 | 三明市永耀涂料有限公司 | Water-based paint |
| CN103087633A (en) * | 2013-01-15 | 2013-05-08 | 三明市永耀涂料有限公司 | Automatic control production method of water-based paint |
| CN104109434A (en) * | 2014-06-21 | 2014-10-22 | 芜湖朗润新材料有限公司 | Inorganic anti-stripping paint |
| CN109439105A (en) * | 2017-08-30 | 2019-03-08 | 罗雪洁 | A kind of anti-aging water paint for internal walls of environmental protection |
-
2008
- 2008-06-27 CN CN200810126452A patent/CN101613549A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101245198B (en) * | 2008-03-13 | 2011-03-23 | 常州市美伦钛业有限公司 | Coated titanium dioxide manufacture method |
| CN102964960A (en) * | 2012-11-15 | 2013-03-13 | 中山蓝海洋水性涂料有限公司 | Water-based fluorocarbon coating used for external wall and preparation method thereof |
| CN102964960B (en) * | 2012-11-15 | 2014-12-31 | 中山蓝海洋水性涂料有限公司 | Water-based fluorocarbon coating used for external wall and preparation method thereof |
| CN103087632A (en) * | 2013-01-15 | 2013-05-08 | 三明市永耀涂料有限公司 | Water-based paint |
| CN103087633A (en) * | 2013-01-15 | 2013-05-08 | 三明市永耀涂料有限公司 | Automatic control production method of water-based paint |
| CN103087633B (en) * | 2013-01-15 | 2015-01-21 | 三明市永耀涂料有限公司 | Automatic control production method of water-based paint |
| CN103087632B (en) * | 2013-01-15 | 2015-01-21 | 三明市永耀涂料有限公司 | Water-based paint |
| CN104109434A (en) * | 2014-06-21 | 2014-10-22 | 芜湖朗润新材料有限公司 | Inorganic anti-stripping paint |
| CN109439105A (en) * | 2017-08-30 | 2019-03-08 | 罗雪洁 | A kind of anti-aging water paint for internal walls of environmental protection |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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Open date: 20091230 |