CN104045854A - 一种纳米Sb2O3-SiO2复合气凝胶无机阻燃剂及制备方法 - Google Patents
一种纳米Sb2O3-SiO2复合气凝胶无机阻燃剂及制备方法 Download PDFInfo
- Publication number
- CN104045854A CN104045854A CN201410249620.9A CN201410249620A CN104045854A CN 104045854 A CN104045854 A CN 104045854A CN 201410249620 A CN201410249620 A CN 201410249620A CN 104045854 A CN104045854 A CN 104045854A
- Authority
- CN
- China
- Prior art keywords
- preparation
- flame retardant
- composite aerogel
- alcogel
- nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004964 aerogel Substances 0.000 title claims abstract description 65
- 239000002131 composite material Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title abstract description 6
- 239000000377 silicon dioxide Substances 0.000 title abstract description 4
- 239000012796 inorganic flame retardant Substances 0.000 title abstract 4
- 229910052681 coesite Inorganic materials 0.000 title abstract 3
- 229910052906 cristobalite Inorganic materials 0.000 title abstract 3
- 229910052682 stishovite Inorganic materials 0.000 title abstract 3
- 229910052905 tridymite Inorganic materials 0.000 title abstract 3
- 239000003063 flame retardant Substances 0.000 claims abstract description 55
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- -1 silicon alkoxide Chemical class 0.000 claims abstract description 20
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 19
- 239000010703 silicon Substances 0.000 claims abstract description 19
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011240 wet gel Substances 0.000 claims abstract description 16
- 239000002253 acid Substances 0.000 claims abstract description 10
- 150000002500 ions Chemical class 0.000 claims abstract description 10
- 238000000352 supercritical drying Methods 0.000 claims abstract description 8
- 238000002485 combustion reaction Methods 0.000 claims description 41
- 239000003112 inhibitor Substances 0.000 claims description 39
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 36
- 230000001476 alcoholic effect Effects 0.000 claims description 33
- 238000001035 drying Methods 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 28
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 17
- 150000003839 salts Chemical class 0.000 claims description 17
- 239000012530 fluid Substances 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 230000002378 acidificating effect Effects 0.000 claims description 9
- 230000032683 aging Effects 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000013543 active substance Substances 0.000 claims description 7
- 230000008595 infiltration Effects 0.000 claims description 7
- 238000001764 infiltration Methods 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 230000001105 regulatory effect Effects 0.000 claims description 7
- LDMJFDJYOVHUMJ-UHFFFAOYSA-N stibanylidynesilicon Chemical compound [Sb]#[Si] LDMJFDJYOVHUMJ-UHFFFAOYSA-N 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000012546 transfer Methods 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 6
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical group Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 claims description 6
- WBJXZTQXFVDYIZ-UHFFFAOYSA-N [Sb].[N+](=O)(O)[O-] Chemical compound [Sb].[N+](=O)(O)[O-] WBJXZTQXFVDYIZ-UHFFFAOYSA-N 0.000 claims description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical group O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 235000011089 carbon dioxide Nutrition 0.000 claims description 4
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 4
- XXZNHVPIQYYRCG-UHFFFAOYSA-N trihydroxy(propoxy)silane Chemical compound CCCO[Si](O)(O)O XXZNHVPIQYYRCG-UHFFFAOYSA-N 0.000 claims description 4
- MVHZHMKEBJJTCH-UHFFFAOYSA-N CN(C)C.CO[SiH3] Chemical compound CN(C)C.CO[SiH3] MVHZHMKEBJJTCH-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- MGQFVQQCNPBJKC-UHFFFAOYSA-N dibutoxy(diethyl)silane Chemical compound CCCCO[Si](CC)(CC)OCCCC MGQFVQQCNPBJKC-UHFFFAOYSA-N 0.000 claims description 3
- ZWTJVXCCMKLQKS-UHFFFAOYSA-N diethoxy(ethyl)silicon Chemical compound CCO[Si](CC)OCC ZWTJVXCCMKLQKS-UHFFFAOYSA-N 0.000 claims description 3
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 19
- 239000002861 polymer material Substances 0.000 abstract description 3
- 239000000499 gel Substances 0.000 abstract 3
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001462 antimony Chemical class 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 238000012986 modification Methods 0.000 description 13
- 230000004048 modification Effects 0.000 description 13
- 239000000463 material Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 238000000354 decomposition reaction Methods 0.000 description 11
- 239000002245 particle Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000012071 phase Substances 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 229920001617 Vinyon Polymers 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000002114 nanocomposite Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 150000004703 alkoxides Chemical class 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000002508 compound effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229920002903 fire-safe polymer Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000005291 magnetic effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Compounds (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410249620.9A CN104045854B (zh) | 2014-06-09 | 2014-06-09 | 一种纳米Sb2O3-SiO2复合气凝胶无机阻燃剂及制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410249620.9A CN104045854B (zh) | 2014-06-09 | 2014-06-09 | 一种纳米Sb2O3-SiO2复合气凝胶无机阻燃剂及制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104045854A true CN104045854A (zh) | 2014-09-17 |
CN104045854B CN104045854B (zh) | 2016-11-02 |
Family
ID=51499274
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410249620.9A Active CN104045854B (zh) | 2014-06-09 | 2014-06-09 | 一种纳米Sb2O3-SiO2复合气凝胶无机阻燃剂及制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104045854B (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106674965A (zh) * | 2016-12-27 | 2017-05-17 | 上海锦湖日丽塑料有限公司 | 一种高效抑烟阻燃的改性聚芳香酯及其制备方法 |
CN109056341A (zh) * | 2018-08-03 | 2018-12-21 | 安徽农业大学 | 一种阻燃、透气型汽车内饰材料的制备方法 |
CN109081354A (zh) * | 2017-06-14 | 2018-12-25 | 天津城建大学 | 阻燃埃洛石-二氧化硅复合气凝胶材料及其制备方法 |
CN109082016A (zh) * | 2018-07-11 | 2018-12-25 | 桐城市新瑞建筑工程有限公司 | 一种防火甲基板及其制备方法 |
CN109180140A (zh) * | 2018-08-09 | 2019-01-11 | 山东汉诺宝嘉新材料科技有限公司 | 一种纳米气凝胶及其制备方法 |
CN113214781A (zh) * | 2021-03-18 | 2021-08-06 | 广州德海高分子材料科技有限公司 | 一种阻燃型防水防火绝缘密封胶及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02174929A (ja) * | 1988-12-28 | 1990-07-06 | Catalysts & Chem Ind Co Ltd | シリカ酸化アンチモン複合ゾル、その製造方法およびそれよりなる難燃化剤 |
-
2014
- 2014-06-09 CN CN201410249620.9A patent/CN104045854B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02174929A (ja) * | 1988-12-28 | 1990-07-06 | Catalysts & Chem Ind Co Ltd | シリカ酸化アンチモン複合ゾル、その製造方法およびそれよりなる難燃化剤 |
Non-Patent Citations (1)
Title |
---|
张淑云: ""二氧化硅一氧化锑复合溶胶"", 《无机盐工业》, no. 3, 31 March 1992 (1992-03-31), pages 43 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106674965A (zh) * | 2016-12-27 | 2017-05-17 | 上海锦湖日丽塑料有限公司 | 一种高效抑烟阻燃的改性聚芳香酯及其制备方法 |
CN109081354A (zh) * | 2017-06-14 | 2018-12-25 | 天津城建大学 | 阻燃埃洛石-二氧化硅复合气凝胶材料及其制备方法 |
CN109082016A (zh) * | 2018-07-11 | 2018-12-25 | 桐城市新瑞建筑工程有限公司 | 一种防火甲基板及其制备方法 |
CN109056341A (zh) * | 2018-08-03 | 2018-12-21 | 安徽农业大学 | 一种阻燃、透气型汽车内饰材料的制备方法 |
CN109056341B (zh) * | 2018-08-03 | 2021-07-23 | 安徽农业大学 | 一种阻燃、透气型汽车内饰材料的制备方法 |
CN109180140A (zh) * | 2018-08-09 | 2019-01-11 | 山东汉诺宝嘉新材料科技有限公司 | 一种纳米气凝胶及其制备方法 |
CN109180140B (zh) * | 2018-08-09 | 2021-06-04 | 山东汉诺宝嘉新材料科技有限公司 | 一种纳米气凝胶及其制备方法 |
CN113214781A (zh) * | 2021-03-18 | 2021-08-06 | 广州德海高分子材料科技有限公司 | 一种阻燃型防水防火绝缘密封胶及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN104045854B (zh) | 2016-11-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104045854A (zh) | 一种纳米Sb2O3-SiO2复合气凝胶无机阻燃剂及制备方法 | |
US10682619B2 (en) | Nano-silica dispersion having amphiphilic properties and a double-particle structure and its production method | |
CN108059917B (zh) | 一种纳米改性聚硅氮烷抗静电材料及其制备方法 | |
CN103242684B (zh) | 二氧化硅包覆碳纳米管及其制备方法 | |
CN102344699B (zh) | 纳米二氧化硅修饰蒙脱土粒子制备及应用于原位法生成改性水性聚氨酯树脂的方法 | |
CN103725199B (zh) | 一种加成型氟硅橡胶纳米防冻粘涂料及其制备方法 | |
CN101544838B (zh) | 一种超疏水纳米SiO2/高聚物复合膜及其制备方法 | |
DE102016224274A1 (de) | Siliziumdioxid-aerogel, wärmedämmstoff, und verfahren zur herstellung von siliziumdioxid-aerogel | |
CN102249593A (zh) | 一种有机硅粉末防水剂的制备方法 | |
CN102219469A (zh) | 一种纳米复合绝热材料及其制备方法 | |
CN104774603A (zh) | 一种基于纳米颗粒与Gemini表面活性剂的稳定泡沫体系及其制备方法 | |
CN105820276A (zh) | 一种超高电导率石墨烯改性聚甲基丙烯酸甲酯复合材料的制备方法 | |
CN113421695B (zh) | 一种水性碳纳米管分散液、导电浆料及其制备方法 | |
CN105712670B (zh) | 一种智能纳米保温防火材料及其生产方法 | |
CN112897532A (zh) | 一种二氧化硅气凝胶粉体及其制备方法和应用 | |
CN110760102A (zh) | 剪切增稠液/细菌纤维素-二氧化硅复合材料及其制备方法 | |
JP6102393B2 (ja) | 中空シリカナノ粒子の製造方法 | |
TWI384021B (zh) | 奈米無機氧化物的相轉移方法 | |
CN104987780A (zh) | 一种新型建筑改性墙涂料及其制备方法 | |
Liu et al. | Facile fabrication of compressive aerogels with novel core/shell fibrous skeleton for oil sorption and thermal evaporation | |
CN105925192A (zh) | 一种保温隔热石油沥青防水涂料及其制备方法 | |
CN111574978A (zh) | 一种冻胶堵剂、制备方法及其应用 | |
CN101306834A (zh) | 高隔热性纳米复合材料及其隔热制品的制备方法 | |
CN116410617A (zh) | 一种表面改性玻璃微珠复合填料及其制备方法与应用 | |
CN103087448A (zh) | PVDF/PVA/纳米SiO2复合膜 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP03 | Change of name, title or address |
Address after: Xinhai Industrial Park 251096 Shandong city of Binzhou province Wudi county (north of Beijing Road East, Qi Yue Lu) Patentee after: Wudi moist New Material Co., Ltd. Address before: Xinhai Industrial Park 251096 Shandong city of Binzhou province Wudi county (CMC office building room 106) Patentee before: Wudi Sinorance Chemical Co., Ltd. |
|
CP03 | Change of name, title or address | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20180420 Address after: 100044 Friendship Hotel, room 62414, 1 Zhongguancun South Street, Haidian District, Beijing. Patentee after: Beijing Jinhui friends Management Consultants Limited Address before: Xinhai Industrial Park 251096 Shandong city of Binzhou province Wudi county (north of Beijing Road East, Qi Yue Lu) Patentee before: Wudi moist New Material Co., Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190701 Address after: 272000 No. 104, No. 1 Jixiangbei Street, Shizhong District, Jining City, Shandong Province Patentee after: Qin Ruxin Address before: Room 62414, Friendship Hotel, No. 1 South Street, Zhongguancun, Haidian District, Beijing Patentee before: Beijing Jinhui friends Management Consultants Limited |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201123 Address after: 214000 No. 115 West Jie Jie Road, Yicheng street, Yixing, Wuxi, Jiangsu Patentee after: WUXI CHENYUAN TECHNOLOGY Co.,Ltd. Address before: 272000 No. 104, Jixiang North Street, Shizhong District, Jining, Shandong, 104 Patentee before: Qin Ruxin |