CN104029444A - Thermoplastic plastic fiber composite plate and manufacturing method thereof - Google Patents
Thermoplastic plastic fiber composite plate and manufacturing method thereof Download PDFInfo
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- CN104029444A CN104029444A CN201410252991.2A CN201410252991A CN104029444A CN 104029444 A CN104029444 A CN 104029444A CN 201410252991 A CN201410252991 A CN 201410252991A CN 104029444 A CN104029444 A CN 104029444A
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Abstract
The invention provides a thermoplastic plastic fiber composite plate and a manufacturing method of the thermoplastic plastic fiber composite plate. The thermoplastic plastic fiber composite plate comprises the following components in percentage by weight: 40-60% of plastic powder and 40-60% of fiber. By adopting the thermoplastic plastic fiber composite plate and the manufacturing method of the thermoplastic plastic fiber composite plate, various types of plastic fiber composite plates compounded by different plastics and fibers different in density can be manufactured; plastic foam fiber composite plates can also be manufactured, thus meeting different requirements on plastic fiber composite plates in various industries; the thermoplastic plastic fiber composite plate has the advantages of easily available materials and low cost and has important positive significance to the promotion of the development of national economy.
Description
Technical field
The present invention relates to a kind of composite plate and manufacture method thereof, especially a kind of thermoplastic fiber composite plate and manufacture method thereof.
Background technology
Plastic optical fibre composite plate, its tension, bending resistance, shock proof intensity are all also good than pure plastic plate than pure plastic plate excellence, endurance, creep resistance, and its processing characteristics is also very superior.Thereby all trades and professions in the development of the national economy have broad application prospects.
From current manufacturing technology level both domestic and external, by the manufacture method that chopped strand is manufactured thermoplastic fiber composite plate, be mainly that fiber and plastics melting mixing are extruded into plate or are molded into part after evenly, this manufacture method, owing to being subject to the restriction of equipment and process condition, its fibre length used is shorter, general fibre length can only be in 3-6mm scope, and fiber consumption generally can only be in 30%.Thereby make the physical and mechanical property of the plate that makes be subject to certain restriction.Since this century, domestic-developed goes out a kind ofly on adhesive-bonded fabric production line, glass fibre or flaxen fiber to be mixed with polypropylene fiber through being carded to felt, again through the hot-cold low density heat plasticity fiber composite plate of density about 0.4g/cm3 that be pressed into, for automobile inner decoratire lining board.But this method polypropylene fiber price used is higher, state's tax-included price is at 13500-15000 yuan/ton at present, thereby makes product cost higher, and plastic optical fibre kind is single, is difficult to meet the needs to the requirement of product different performance.
Summary of the invention
The object of this invention is to provide a kind of thermoplastic fiber composite plate and manufacture method thereof, can overcome the technical problems such as the cost existing with chopped strand production thermoplastic fiber composite plate is at present high, kind is single, product mechanical property deficiency both at home and abroad.
In order to solve the problems of the technologies described above, technical scheme of the present invention is as follows: thermoplastic fiber composite plate, is characterized in that: according to percentage by weight, be fibrous by the plastic powders of 40-60%, 40-60%.
Improvement to technique scheme: described plastic powders is thermoplastic; Described fiber is the mixture of any one material in glass fibre, flaxen fiber, Chinese alpine rush fiber, carbon fiber, basalt fibre, polyster fibre or any two kinds or two or more materials.
Further improvement to technique scheme: described thermoplastic is polypropylene or polyvinyl chloride or polyethylene or polystyrene or Acrylonitrile-butadiene-styrene Copolymer or foamed polystyrene particle.
The manufacture method of thermoplastic fiber composite plate, method one, its step is as follows:
1) fibre cutting: according to product needed, fiber is cut into the scope of long 50-100mm;
2) fiber opening: fiber is become to single loosen collagen fibre through opener shredding;
3) fiber mixes: two kinds of fibers are mixed by mixer;
4) felt: on adhesive-bonded fabric production line by fiber through combing, moulding, become the fibrofelt of the mass area ratio of process stipulation;
5) acupuncture: make felt reach the packing of regulation by needing machine;
6) dusting: evenly sprinkle by the quantitative plastic powders of Process Planning through duster;
7) acupuncture again: make plastic powders evenly sneak in fibrofelt by needing machine acupuncture on the felt that has spread powder;
8) compound: by operation 6) and operation 7) felt is carried out to 2-4 dustings and composite acupuncture, the mass area ratio and the assurance plastic powders that make felt be combined into process stipulation are sneaked in fibrofelt comprehensively equably;
9) pressing plate: compound good felt becomes the size of process stipulation to send into the high temperature resistant antiseized two-sided conveyer belt of tetrafluoroethene through severing to send in hot-cold press through hot pressing, be cold-pressed into plate.
Improvement to method one: the hot pressing temperature in described step 9) is 150-260 ℃, is generally advisable to be greater than 20-30 ℃ of plastics melt temperature; Pressure is 1.5-50kg/cm2; Hot pressing time is 2.5-7 minutes.
Plastic powders in method one is polypropylene, polyvinyl chloride, polyethylene, polystyrene, Acrylonitrile-butadiene-styrene Copolymer.Adopt the plastic powders of these materials and the composite plate that method is made, can make as required the composite panel of plastic material of different densities, different plastics, different fibers.
The manufacture method of thermoplastic fiber composite plate, method two, its step is as follows:
1) fibre cutting: according to product needed, fiber is cut into the scope of long 50-100mm;
2) fiber opening: fiber is become to single loosen collagen fibre through opener shredding;
3) fiber mixes: two kinds of fibers are mixed by mixer;
4) felt: on adhesive-bonded fabric production line by fiber through combing, moulding, become the fibrofelt of the mass area ratio of process stipulation;
5) spread expanded particle: on fibrofelt, spread foamed polystyrene particle;
6) acupuncture: by needing machine, foamed polystyrene particle is sneaked in felt, and make felt reach the packing of regulation;
7) compound: by operation 5) and operation 6) felt is carried out spreading expanded particle and composite acupuncture for 2-4 times, the mass area ratio and the plastic foamed particle of assurance that make felt be combined into process stipulation are sneaked in fibrofelt comprehensively equably;
8) making sheet: compound good felt becomes the size of process stipulation to send in the die cavity of given size through severing, foams, is cooled to plate under the condition of airtight compression.
Improvement to method two: the foamable temperature in described step 8) is 100-110 ℃; Pressure is 1.5-10kg/cm2; Foamed time is 2.5-7 minutes.
Therefore plastic pellet in method two is foamed polystyrene particle, because foamed polystyrene particle particle is thicker, is difficult for entering in felt, needs first combing moulding to spread acupuncture again after particle, and the method can be made foam fibre composite plate.
Beneficial effect:
Use thermoplastic fiber composite plate of the present invention and manufacture method thereof, can produce the various plastic optical fibre composite plates of different densities, different plastics and different fiber composite, also can produce plastic foam fiber composite plate, can meet the different requirements of all trades and professions to plastic optical fibre composite plate, draw materials conveniently, cost is low, can be to promoting the development of national economy have important positive effect.
The specific embodiment
Embodiment mono-:
1) waste polypropylene is worn into 100 object powder through pulverizing;
2) flaxen fiber is cut into 80mm long, through shredding, simultaneously by polyster fibre through shredding;
3) press flaxen fiber 95%, the ratio of polyster fibre 5% mixes in mixer;
4), on adhesive-bonded fabric production line, make the fiber mixing through combing, moulding, acupuncture, become the felt of unit are 420g/m2;
5) through duster, on felt, evenly sprinkle the polypropylene waste material powder of 340g/m2;
6) through needing machine, make plastic powders evenly sneak in felt again;
7) by operation 5) and 6) dusting felt is carried out to two layers of composite acupuncture, make to reach the composite felt of mass area ratio 1500g/m2;
8) felt severing is become to the felt of the specification of process stipulation;
9) felt is sent on the high temperature resistant antiseized two-sided protection conveyer belt of tetrafluoroethene and sent in hot-cold press; at unit pressure 2kg/cm2; at 200 ℃ of temperature; hot-cold pressure each 3 minutes; make plate become thickness 4mm; the low density heat plasticity fiber composite plate of density 0.375g/cm3, this plate, for automobile inner decoratire lining board, meets use standard after testing.
Embodiment bis-:
The glass fibre of length 60mm, percentage by weight 50%, the 80 object polyvinyl chloride powders that add heat stabilizer, light stabilizer, antioxidant, percentage by weight 50%, by the fabrication schedule of embodiment mono-, carry out the composite felt that becomes felt, dusting to be combined into 35,00g,/m2 three times, again in cold-hot press, 210 ℃ of temperature, unit pressure 25kg/cm2,5 minutes time heat, to be cold-pressed into 4mm thick, the high-density plate of density 0.875g/cm3, this plate can be used for building structure plate, electric insulation plate, lorry compartment base plate.
Embodiment tri-:
Each 100 order powder consumptions 45% of 50% of polyethylene virgin material and waste material, the flaxen fiber 90% that 100mm is long and the composite fibre consumption 55% of polyster fibre 10%, by the fabrication schedule of embodiment mono-, carry out the composite felt that twice one-tenth felt, dusting are combined into 2400g/m2, again in hot-cold press, 170 ℃ of temperature, unit pressure 3kg/cm2,4 minutes time heat, to be cold-pressed into 4mm thick, the medium-density plate of density 0.6g/cm3, this plate can be applicable to interior decoration, furniture, office appliance field.
Embodiment tetra-:
The long polyacrylonitrile-based carbon fibre 45% of 50mm, 120 order ABS powder 55%, by the fabrication schedule of embodiment mono-, carry out the composite felt that becomes felt, dusting to be combined into 40,00g,/m2 three times, again in hot-cold press, 260 ℃ of temperature, unit pressure 30kg/cm2,6 minutes time heat, to be cold-pressed into 4mm thick, the high-density plate of density 1g/cm3, this plate can be used for the fields such as aviation, sports goods, military project.
Embodiment five:
The long glass fibre of 60mm on adhesive-bonded fabric production line through being carded to the felt of 400g/m2, through duster, evenly sprinkle the foamed polystyrene particle of 400g/m2, cover again the Chopped Strand Mat of 100g/ ㎡ in the above, through acupuncture, become felt, then be cut into the specification of 2150 * 1150mm, send in the die cavity of 2150 * 1150 * 5mm, airtight in the situation that, at 110 ℃ of temperature, foamable is 6 minutes, the polystyrene foam fiber composite plate that is 0.18g/cm3 through cooling acquisition density.This plate, for the automobile top-cap inner decoratire lining board of commercial car, meets the requirements after testing.
In the present invention, thermoplastic can be the general-purpose plastics such as polypropylene, polyvinyl chloride, polyethylene, polystyrene, Acrylonitrile-butadiene-styrene Copolymer (ABS), also can be other extraordinary thermoplastic, these plastics can be that new plastic can be also waste plastics.These described plastics all should add the auxiliary agents such as heat stabilizer, antioxidant, light stabilizer, coupling agent according to the processing formula of each plastics, through granulation, wear into 70-120 object powder and use.
Fiber in thermoplastic fiber composite plate can be glass fibre, flaxen fiber, Chinese alpine rush fiber, carbon fiber, basalt fibre, polyster fibre, and fibre length is 50-100mm scope, and wherein polyster fibre adopts standard fibers.
The cooperation of the kind of plastic powders and the kind of fiber is selected, can require to select according to the physical and mechanical property of plate, such as: require that physical and mechanical property is good, the thermoplastic fiber composite plate of good weatherability can adopt Acrylonitrile-butadiene-styrene Copolymer (ABS) or special plastic and carbon fiber or the compound making sheet of basalt fibre, selected PP or PE or PVC and glass fibre or flaxen fiber making sheet that general performance requires.
Claims (8)
1. thermoplastic fiber composite plate, is characterized in that: according to percentage by weight, be fibrous by the plastic powders of 40-60%, 40-60%.
2. thermoplastic fiber composite plate according to claim 1, is characterized in that: described plastic powders is thermoplastic; Described fiber is the mixture of any one material in glass fibre, flaxen fiber, Chinese alpine rush fiber, carbon fiber, basalt fibre, polyster fibre or any two kinds or two or more materials.
3. manufacture thermoplastic fiber composite plate according to claim 1 and 2, is characterized in that: described thermoplastic is polypropylene or polyvinyl chloride or polyethylene or polystyrene or Acrylonitrile-butadiene-styrene Copolymer.
4. manufacture thermoplastic fiber composite plate according to claim 1 and 2, is characterized in that: described thermoplastic is foamed polystyrene particle.
5. the manufacture method of thermoplastic fiber composite plate, its step is as follows:
1) fibre cutting: according to product needed, fiber is cut into the scope of long 50-100mm;
2) fiber opening: fiber is become to single loosen collagen fibre through opener shredding;
3) fiber mixes: two kinds of fibers are mixed by mixer;
4) felt: on adhesive-bonded fabric production line by fiber through combing, moulding, become the fibrofelt of the mass area ratio of process stipulation;
5) acupuncture: make felt reach the packing of regulation by needing machine;
6) dusting: evenly sprinkle by the quantitative plastic powders of Process Planning through duster;
7) acupuncture again: make plastic powders evenly sneak in fibrofelt by needing machine acupuncture on the felt that has spread powder;
8) compound: by operation 6) and operation 7) felt is carried out to 2-4 dustings and composite acupuncture, the mass area ratio and the assurance plastic powders that make felt be combined into process stipulation are sneaked in fibrofelt comprehensively equably;
9) pressing plate: compound good felt becomes the size of process stipulation to send into the high temperature resistant antiseized two-sided conveyer belt of tetrafluoroethene through severing to send in hot-cold press through hot pressing, be cold-pressed into plate.
6. the manufacture method of thermoplastic fiber composite plate according to claim 5, is characterized in that: the hot pressing temperature in described step 9) is 150-260 ℃; Pressure is 1.5-50kg/cm2; Hot pressing time is 2.5-7 minutes.
7. the manufacture method of thermoplastic fiber composite plate, its step is as follows:
1) fibre cutting: according to product needed, fiber is cut into the scope of long 50-100mm;
2) fiber opening: fiber is become to single loosen collagen fibre through opener shredding;
3) fiber mixes: two kinds of fibers are mixed by mixer;
4) felt: on adhesive-bonded fabric production line by fiber through combing, moulding, become the fibrofelt of the mass area ratio of process stipulation;
5) spread expanded particle: on fibrofelt, spread foamed polystyrene particle;
6) acupuncture: by needing machine, foamed polystyrene particle is sneaked in felt, and make felt reach the packing of regulation;
7) compound: by operation 5) and operation 6) felt is carried out spreading expanded particle and composite acupuncture for 2-4 times, the mass area ratio and the plastic foamed particle of assurance that make felt be combined into process stipulation are sneaked in fibrofelt comprehensively equably;
8) making sheet: compound good felt becomes the size of process stipulation to send in the die cavity of given size through severing, foams, is cooled to plate under the condition of airtight compression.
8. the manufacture method of thermoplastic fiber composite plate according to claim 7, is characterized in that: the foamable temperature in described step 8) is 100-110 ℃; Pressure is 1.5-10kg/cm2; Foamed time is 2.5-7 minutes.
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Cited By (5)
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CN104928847A (en) * | 2015-06-27 | 2015-09-23 | 奇瑞汽车股份有限公司 | Thermoplastic carbon fiber composite material |
CN106883534A (en) * | 2017-04-07 | 2017-06-23 | 冷纯廷 | The enhanced PVC board of fibre modification and its production technology |
CN108068424A (en) * | 2017-12-28 | 2018-05-25 | 浙江华江科技股份有限公司 | A kind of preparation method of ultralight high-strength GMT composite boards |
CN109109427A (en) * | 2018-08-04 | 2019-01-01 | 苏州弗瑞斯特汽车新材料有限公司 | A kind of manufacturing process of non-woven fabrics |
CN112848367A (en) * | 2020-12-31 | 2021-05-28 | 浙江华江科技股份有限公司 | Preparation method of novel vehicle ultra-light high-strength GMT composite board |
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CN101418495A (en) * | 2008-12-10 | 2009-04-29 | 黄云清 | The preparation method of leached fibre felt by electrostatic dry |
CN101439604A (en) * | 2008-12-10 | 2009-05-27 | 黄云清 | Method for manufacturing light GMT sheet material |
CN101654873A (en) * | 2009-09-11 | 2010-02-24 | 黄云清 | Method for manufacturing novel lining plate |
KR20130136164A (en) * | 2012-06-04 | 2013-12-12 | 한화엘앤씨 주식회사 | Method for manufacturing thermoplastic composite using continuous fiber reinforced thermoplastic prepreg sheet and thermoplastic compositemanufactured by that method |
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Patent Citations (5)
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CN101410245A (en) * | 2006-03-28 | 2009-04-15 | 法国费保利内 | Pprocess for producing a stampable reinforced composite semi-finished product |
CN101418495A (en) * | 2008-12-10 | 2009-04-29 | 黄云清 | The preparation method of leached fibre felt by electrostatic dry |
CN101439604A (en) * | 2008-12-10 | 2009-05-27 | 黄云清 | Method for manufacturing light GMT sheet material |
CN101654873A (en) * | 2009-09-11 | 2010-02-24 | 黄云清 | Method for manufacturing novel lining plate |
KR20130136164A (en) * | 2012-06-04 | 2013-12-12 | 한화엘앤씨 주식회사 | Method for manufacturing thermoplastic composite using continuous fiber reinforced thermoplastic prepreg sheet and thermoplastic compositemanufactured by that method |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104928847A (en) * | 2015-06-27 | 2015-09-23 | 奇瑞汽车股份有限公司 | Thermoplastic carbon fiber composite material |
CN106883534A (en) * | 2017-04-07 | 2017-06-23 | 冷纯廷 | The enhanced PVC board of fibre modification and its production technology |
CN108068424A (en) * | 2017-12-28 | 2018-05-25 | 浙江华江科技股份有限公司 | A kind of preparation method of ultralight high-strength GMT composite boards |
CN109109427A (en) * | 2018-08-04 | 2019-01-01 | 苏州弗瑞斯特汽车新材料有限公司 | A kind of manufacturing process of non-woven fabrics |
CN112848367A (en) * | 2020-12-31 | 2021-05-28 | 浙江华江科技股份有限公司 | Preparation method of novel vehicle ultra-light high-strength GMT composite board |
CN112848367B (en) * | 2020-12-31 | 2022-05-03 | 浙江华江科技股份有限公司 | Preparation method of ultra-light high-strength GMT composite board for vehicle |
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Application publication date: 20140910 |