CN103980711B - Directional metal wire-filled anti-EMI silica gel liner and preparation method thereof - Google Patents

Directional metal wire-filled anti-EMI silica gel liner and preparation method thereof Download PDF

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Publication number
CN103980711B
CN103980711B CN201410162804.1A CN201410162804A CN103980711B CN 103980711 B CN103980711 B CN 103980711B CN 201410162804 A CN201410162804 A CN 201410162804A CN 103980711 B CN103980711 B CN 103980711B
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silk
tinsel
silica gel
orientation
emi filter
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CN103980711A (en
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龙云耀
贾冬
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Beijing Taipaist Technology Development Co ltd
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Taiyuan City Tai Paisite Electronics Co Ltd
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Abstract

The invention provides a directional metal wire-filled anti-EMI silica gel liner and a preparation method thereof. The directional metal wire-filled anti-EMI silica gel liner comprises colloidal silica, and the metal wire is directly and uniformly distributed in the colloidal silica. The provided anti-EMI silica gel liner has high elasticity as common rubber, and has conductive reliability of metal material.

Description

A kind of anti-EMI filter pad of silica gel of orientation tinsel filling and preparation method thereof
Technical field
The present invention relates to anti-EMI filter technical field, particularly to a kind of anti-EMI filter pad of silica gel of orientation tinsel filling and its Preparation method.
Background technology
Electromagnetic interference (Electromagnetic Interference abbreviation EMI) refer to electromagnetic wave and electronic component act on and The interference phenomenon producing, has Conduction Interference and two kinds of radiation interference.Conduction Interference refers to by conducting medium an electric network On signal coupling (interference) to another electric network.Radiation interference refers to that interference source passes through space and its signal is coupled (interference) To another electric network.With the development of electronics industry, electromagnetic radiation is ubiquitous, not only affects environment, to health Produce harm, and had a strong impact on the normal operation of electronic equipment, naval vessel, vehicle etc., various anti-EMI filter shielding materials are exactly to be The microwave defense material solving electromagnetic interference application and producing.
There is a class anti-EMI filter conductive rubber gasket material, it is the metal adding conduction in silica matrix in shielding material Microgranule, such as argentum powder, silver-plated copper powder, silvered aluminum powder, silvered glass powder, make through molding sulfuration or extrusion molding, for electronics Equipment buckle case buckle at shell gap or cover plate flange.There is provided electrically continuous first, thus preventing electromagnetic-wave leakage, electrification Magnetic seal acts on;Secondly rubber has good water vapor seal effect, can play environment to the circuit of device interior and components and parts Sealing function, in addition can also be used for being grounded the occasion with static discharge.
, as glue Liner Ferrule powder content is between 60~95%, specific insulation is 10 for this traditional conduction-2~10-3 Between Ω cm, have disadvantages that, as big in hardness, low intensity, permanent deformation is big, conductive particle is oxidizable and cost is high etc..
The reason cause these shortcomings be:
A. contain a large amount of metal powders in rubber, the physical property of rubber is had undesirable effect;
B. conductive particle specific surface area is big, oxidizable, electric conductivity in time environment and reduce;
C. contain substantial amounts of argent, relatively costly.
Content of the invention
For solving above-mentioned the deficiencies in the prior art, the present invention provides a kind of anti-EMI filter pad of silica gel of orientation tinsel filling And preparation method thereof, not only there is the high resiliency of General Purpose Rubber, also there is the conductive reliability of metal material.
The technical scheme is that and be achieved in that:A kind of anti-EMI filter pad of silica gel of orientation tinsel filling, including silicon Colloid, described colloidal silica interior orientation is evenly distributed with tinsel.
Wherein it is preferred to, described tinsel is Monel silk or aluminium wire.
Wherein it is preferred to, the string diameter of described Monel silk or aluminium wire is 0.1~0.2mm.
Wherein it is preferred to, described Monel silk or aluminium wire are to be pressed into sine-shaped, sinusoidal Monel silk or aluminium wire.
Wherein it is preferred to, the peak height of described sine-shaped, sinusoidal Monel silk or aluminium wire is 0.05~0.35mm.
A kind of preparation method of the anti-EMI filter pad of silica gel of orientation tinsel filling, it comprises the following steps:
1) tinsel pre-treatment:Silane coupler or titanate coupling agent is used to process surface after tinsel is deoiled;
2) uniform cloth silk:By tinsel uniform winding on rectangular metal frame, the metal frame twining silk and the metal not twining silk The pressing of frame interval, die cavity external sealant sealing;
3) injecting glue:Liquid glue is arranged bubble in blender, then fills membrane cavity, die cavity is placed in vacuum row's bubble machine and arranges Bubble;
4) sulfidization molding;
5) cut:Cut into the rubber slab of various thickness according to customer demand, cut direction is perpendicular to row silk direction.
Wherein it is preferred to, in described step 2, the silk density after uniform cloth silk is 140 ± 15/cm2.
Beneficial effects of the present invention:
1. the present invention adds tinsel in silica gel, is bonded in tinsel in rubber with chemical method and is difficult to drop out, And do not contain noble metal, tinsel content below 10%, due to tinsel amount less it is ensured that liner has good rubbery Energy.
2. all orientations wiry of the present invention are all vertical with the end face of colloidal silica, conductive reliable.
3. sine-shaped, sinusoidal tinsel, as spring, can make liner have excellent resilience, low compression never becomes Shape.
4. the pad of silica gel of the present invention is suitable for seriously irregular occasion.
5., it is ensured that being not attached between tinsel in arrangement design wiry, therefore moisture content will not be from a silk to another On bar silk, product is made to have good humidity resistance, the shortcomings of overcome conventional particles filled-type rubber easy oxidation corrosion, because This, the moisture resistance having had, it is not connected between tinsel moistureproof to close transmission or " siphon " occurs.
6. can be compatible with many metals and alloy.
7. the pad of silica gel of the present invention can use in large temperature range.
Brief description
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing Have technology description in required use accompanying drawing be briefly described it should be apparent that, drawings in the following description be only this Some embodiments of invention, for those of ordinary skill in the art, on the premise of not paying creative work, acceptable Other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is the metal wire structure schematic diagram of the present invention;
Fig. 2 is the profile of the pad of silica gel of the present invention.
In figure, 1. colloidal silica, 2. tinsel.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation description is it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.It is based on Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of not making creative work Embodiment, broadly falls into the scope of protection of the invention.
A kind of anti-EMI filter pad of silica gel of orientation tinsel filling, including colloidal silica, described colloidal silica interior orientation is uniformly distributed There is tinsel.
A kind of preparation method of the anti-EMI filter pad of silica gel of orientation tinsel filling, it comprises the following steps:
1) tinsel pre-treatment:Silane coupler or titanate coupling agent is used to process surface after tinsel is deoiled;
2) uniform cloth silk:By tinsel uniform winding on rectangular metal frame, the metal frame twining silk and the metal not twining silk The pressing of frame interval, die cavity external sealant sealing;
3) injecting glue:Liquid glue is arranged bubble in blender, then fills membrane cavity, die cavity is placed in vacuum row's bubble machine and arranges Bubble;
4) sulfidization molding;
5) cut:Cut into the rubber slab of various thickness according to customer demand, cut direction is perpendicular to row silk direction.
Wherein, it is to clean wire surface with silane coupler or titanate coupling agent in step 1, to remove tinsel table The dirt in face.
Wherein, in step 2, the silk density after uniform cloth silk is 140 ± 15/cm2.
Wherein, Monel is monel, is the corrosion resistant alloy that a kind of consumption is maximum, purposes is the widest, combination property is splendid.
Embodiment 1
As depicted in figs. 1 and 2, the anti-EMI filter pad of silica gel of a kind of orientation of the present embodiment tinsel filling, including colloidal silica 1, Described colloidal silica interior orientation is evenly distributed with tinsel 2.Tinsel 2 is Monel silk, and string diameter is 0.15mm, is pressed into sinusoidal song Linear.
Wherein, the peak height of sine-shaped, sinusoidal Monel silk is 0.2mm.
The preparation method of the anti-EMI filter pad of silica gel of above-mentioned orientation tinsel filling, comprises the following steps:
1) Monel silk pre-treatment:Monel silk is pressed into sinusoidal, after deoiling, processes surface with silane coupler, Ensure, between tinsel and rubber, there is enough bonding forces;
2) uniform cloth silk:By Monel silk uniform winding on rectangular metal frame, the metal frame twining silk and the metal not twining silk The pressing of frame interval, die cavity external sealant sealing;Interval pressing ensure that the tinsel distance of different layers is certain, and die cavity external is close Sealing sealing ensures that liquid glue will not flow out from the gap between metal frame in follow-up injection process;
3) injecting glue:Liquid glue is arranged bubble in blender, then fills membrane cavity, die cavity is placed in vacuum row's bubble machine and arranges Bubble;
4) sulfidization molding, in the present embodiment, sulfidization molding adopts cold curing.
5) cut:Various thickness and rubber slab in uniform thickness are cut into according to customer demand, cut direction is perpendicular to row Silk direction.
Wherein, in step 2, the silk density after uniform cloth silk is 140 ± 15/cm2.
Embodiment 2
As depicted in figs. 1 and 2, the anti-EMI filter pad of silica gel of a kind of orientation of the present embodiment tinsel filling, including colloidal silica 1, Described colloidal silica interior orientation is evenly distributed with tinsel 2.Tinsel 2 is Monel silk, and string diameter is 0.1mm, is pressed into sine curve Shape.
Wherein, the peak height of sine-shaped, sinusoidal Monel silk is 0.05mm
The preparation method of the anti-EMI filter pad of silica gel of above-mentioned orientation tinsel filling, comprises the following steps:
1) Monel silk pre-treatment:Monel silk is pressed into sinusoidal, after deoiling, processes surface with silane coupler, Ensure, between tinsel and rubber, there is enough bonding forces;
2) uniform cloth silk:By Monel silk uniform winding on rectangular metal frame, the metal frame twining silk and the metal not twining silk The pressing of frame interval, die cavity external sealant sealing;Interval pressing ensure that the tinsel distance of different layers is certain, and die cavity external is close Sealing sealing ensures that liquid glue will not flow out from the gap between metal frame in follow-up injection process;
3) injecting glue:Liquid glue is arranged bubble in blender, then fills membrane cavity, die cavity is placed in vacuum row's bubble machine and arranges Bubble;
4) sulfidization molding, in the present embodiment, sulfidization molding adopts cold curing.
5) cut:Cut into the rubber slab of various thickness according to customer demand, cut direction is perpendicular to row silk direction.
Wherein, in step 2, the silk density after uniform cloth silk is 125/cm2.
Embodiment 3
As depicted in figs. 1 and 2, the anti-EMI filter pad of silica gel of a kind of orientation of the present embodiment tinsel filling, including colloidal silica 1, Described colloidal silica interior orientation is evenly distributed with tinsel 2.Tinsel 2 is Monel silk, and string diameter is 0.2mm, is pressed into sine curve Shape.
Wherein, the peak height of sine-shaped, sinusoidal Monel silk is 0.35mm.
The preparation method of the anti-EMI filter pad of silica gel of above-mentioned orientation tinsel filling, comprises the following steps:
1) Monel silk pre-treatment:Monel silk is pressed into sinusoidal, after deoiling, processes surface with silane coupler, Ensure, between tinsel and rubber, there is enough bonding forces;
2) uniform cloth silk:By Monel silk uniform winding on rectangular metal frame, the metal frame twining silk and the metal not twining silk The pressing of frame interval, die cavity external sealant sealing;Interval pressing ensure that the tinsel distance of different layers is certain, and die cavity external is close Sealing sealing ensures that liquid glue will not flow out from the gap between metal frame in follow-up injection process;
3) injecting glue:Liquid glue is arranged bubble in blender, then fills membrane cavity, die cavity is placed in vacuum row's bubble machine and arranges Bubble;
4) sulfidization molding, in the present embodiment, sulfidization molding adopts high temperature vulcanized curing process.
5) cut:Cut into the rubber slab of various thickness according to customer demand, cut direction is perpendicular to row silk direction.
Wherein, in step 2, the silk density after uniform cloth silk is 155/cm2.
Embodiment 4
As depicted in figs. 1 and 2, the anti-EMI filter pad of silica gel of a kind of orientation of the present embodiment tinsel filling, including colloidal silica 1, Described colloidal silica interior orientation is evenly distributed with tinsel 2.Tinsel 2 is aluminium wire, and string diameter is 0.15mm, is pressed into sine curve Shape.
Wherein, the peak height of sine-shaped, sinusoidal aluminium wire is 0.20mm.
The preparation method of the anti-EMI filter pad of silica gel of above-mentioned orientation tinsel filling, comprises the following steps:
1) aluminium wire pre-treatment:Aluminium wire is pressed into sinusoidal, after deoiling, processes surface it is ensured that gold with silane coupler Belong to, between silk and rubber, there is enough bonding forces;
2) uniform cloth silk:By aluminium wire uniform winding on rectangular metal frame, the metal frame twining silk and the metal frame not twining silk Interval pressing, die cavity external sealant sealing;Interval pressing ensure that the tinsel distance of different layers is certain, and die cavity external seals Glue sealing ensures that liquid glue will not flow out from the gap between metal frame in follow-up injection process;
3) injecting glue:Liquid glue is arranged bubble in blender, then fills membrane cavity, die cavity is placed in vacuum row's bubble machine and arranges Bubble;
4) sulfidization molding, in the present embodiment, sulfidization molding adopts cold curing.
5) cut:Cut into the rubber slab of various thickness according to customer demand, cut direction is perpendicular to row silk direction.
Wherein, in step 2, the silk density after uniform cloth silk is 140 ± 15/cm2.
Embodiment 5
As depicted in figs. 1 and 2, the anti-EMI filter pad of silica gel of a kind of orientation of the present embodiment tinsel filling, including colloidal silica 1, Described colloidal silica interior orientation is evenly distributed with tinsel 2.Tinsel 2 is aluminium wire, and string diameter is 0.1mm, is pressed into sinusoidal.
Wherein, the peak height of sine-shaped, sinusoidal aluminium wire is 0.05mm.
The preparation method of the anti-EMI filter pad of silica gel of above-mentioned orientation tinsel filling, comprises the following steps:
1) aluminium wire pre-treatment:Aluminium wire is pressed into sinusoidal, after deoiling, processes surface it is ensured that gold with silane coupler Belong to, between silk and rubber, there is enough bonding forces;
2) uniform cloth silk:By aluminium wire uniform winding on rectangular metal frame, the metal frame twining silk and the metal frame not twining silk Interval pressing, die cavity external sealant sealing;Interval pressing ensure that the tinsel distance of different layers is certain, and die cavity external seals Glue sealing ensures that liquid glue will not flow out from the gap between metal frame in follow-up injection process;
3) injecting glue:Liquid glue is arranged bubble in blender, then fills membrane cavity, die cavity is placed in vacuum row's bubble machine and arranges Bubble;
4) sulfidization molding, in the present embodiment, sulfidization molding adopts cold curing.
5) cut:Cut into the rubber slab of various thickness according to customer demand, cut direction is perpendicular to row silk direction.
Wherein, in step 2, the silk density after uniform cloth silk is 125/cm2.
Embodiment 6
As depicted in figs. 1 and 2, the anti-EMI filter pad of silica gel of a kind of orientation of the present embodiment tinsel filling, including colloidal silica 1, Described colloidal silica interior orientation is evenly distributed with tinsel 2.Tinsel 2 is aluminium wire, and string diameter is 0.2mm, is pressed into sinusoidal.
Wherein, the peak height of sine-shaped, sinusoidal aluminium wire is 0.35mm.
The preparation method of the anti-EMI filter pad of silica gel of above-mentioned orientation tinsel filling, comprises the following steps:
1) aluminium wire pre-treatment:Aluminium wire is pressed into sinusoidal, after deoiling, processes surface it is ensured that gold with silane coupler Belong to, between silk and rubber, there is enough bonding forces;
2) uniform cloth silk:By aluminium wire uniform winding on rectangular metal frame, the metal frame twining silk and the metal frame not twining silk Interval pressing, die cavity external sealant sealing;Interval pressing ensure that the tinsel distance of different layers is certain, and die cavity external seals Glue sealing ensures that liquid glue will not flow out from the gap between metal frame in follow-up injection process;
3) injecting glue:Liquid glue is arranged bubble in blender, then fills membrane cavity, die cavity is placed in vacuum row's bubble machine and arranges Bubble;
4) sulfidization molding, in the present embodiment, sulfidization molding adopts high temperature vulcanized curing process.
5) cut:Cut into the rubber slab of various thickness according to customer demand, cut direction is perpendicular to row silk direction.
Wherein, in step 2, the silk density after uniform cloth silk is 155/cm2
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6
Tensile strength >=1.8MPa 2.0 2.2 1.9 2.1 2.3 2.0
Percentage elongation >=200% 220 240 210 230 250 220
Hardness A35 ± 5 35 32 38 36 34 39
Tearing strength >=8Kg/cm 11 12 10 12 13 10
Silk 140 ± 15/cm of density2 140 125 155 140 125 155
Shield effectiveness (14KHZ~1GHZ) >=60dB 70 65 80 60 70 80
As can be seen from the above table, the pad of silica gel of present invention preparation not only remains the original performance of silica gel, and its stretching is strong Degree, tear strength are higher, and resistivity is 10-2~10-3Between Ω cm, good anti-EMI filter effect can be played.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention Within god and principle, any modification, equivalent substitution and improvement made etc., should be included within the scope of the present invention.

Claims (5)

1., it is characterised in that including colloidal silica, described colloidal silica is default for a kind of anti-EMI filter pad of silica gel of orientation tinsel filling To being evenly distributed with tinsel, described tinsel is Monel silk or aluminium wire;Described Monel silk or aluminium wire are to be pressed into sinusoidal song Linear Monel silk or aluminium wire.
2. a kind of anti-EMI filter pad of silica gel of orientation tinsel filling according to claim 1 is it is characterised in that described The string diameter of Monel silk or aluminium wire is 0.1~0.2mm.
3. according to claim 2 a kind of orientation tinsel filling anti-EMI filter pad of silica gel it is characterised in that described just The peak height of the Monel silk of chord curve shape or aluminium wire is 0.05~0.35mm.
4. the preparation method of the anti-EMI filter pad of silica gel of orientation tinsel filling described in a kind of any one of claims 1 to 3, its It is characterised by, comprise the following steps:
1) tinsel pre-treatment:Silane coupler or titanate coupling agent is used to process surface after tinsel is deoiled;
2) uniform cloth silk:By tinsel uniform winding on rectangular metal frame, between the metal frame twining silk and the metal frame not twining silk Every pressing, die cavity external sealant sealing;
3) injecting glue:Liquid glue is arranged bubble in blender, then fills membrane cavity, die cavity is placed in row's bubble in vacuum row's bubble machine;
4) sulfidization molding;
5) cut:Cut into the rubber slab of various thickness according to customer demand, cut direction is perpendicular to row silk direction.
5. the preparation method of the anti-EMI filter pad of silica gel of a kind of orientation tinsel filling according to claim 4, its feature exists In:In described step 2, the silk density after uniform cloth silk is 140 ± 15/cm2.
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CN106976188A (en) * 2016-01-18 2017-07-25 深圳市海德讯科技有限公司 Thermal transfer conducting resinl pads forming method in a kind of high-accuracy mould
CN110894359B (en) * 2019-12-05 2022-02-18 中国电子科技集团公司第三十三研究所 Sponge type directional conductive rubber and preparation method thereof
CN112908528B (en) * 2020-12-10 2023-02-10 睿惢思工业科技(苏州)有限公司 Conductive foam and manufacturing process thereof

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JP3518267B2 (en) * 1997-08-07 2004-04-12 住友電装株式会社 EMI suppression cable
CN103571215A (en) * 2012-07-18 2014-02-12 天瑞企业股份有限公司 High thermal conductivity and EMI sheltering high polymer composite material
CN103602072A (en) * 2013-11-29 2014-02-26 国家电网公司 Conductive silicone rubber with electromagnetic shielding performance and manufacturing method

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Address before: 030400 No. 1, No. 9 North Lane, Liu Village Commercial Street, Xugou Town, Qingxu County, Taiyuan City, Shanxi Province

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