CN103929956A - Use of acylsulfonamides for improving plant yield - Google Patents
Use of acylsulfonamides for improving plant yield Download PDFInfo
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- CN103929956A CN103929956A CN201280056571.6A CN201280056571A CN103929956A CN 103929956 A CN103929956 A CN 103929956A CN 201280056571 A CN201280056571 A CN 201280056571A CN 103929956 A CN103929956 A CN 103929956A
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/30—Sulfonamides, the carbon skeleton of the acid part being further substituted by singly-bound nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/37—Sulfonamides, the carbon skeleton of the acid part being further substituted by singly-bound nitrogen atoms, not being part of nitro or nitroso groups having the sulfur atom of at least one of the sulfonamide groups bound to a carbon atom of a six-membered aromatic ring
- C07C311/38—Sulfonamides, the carbon skeleton of the acid part being further substituted by singly-bound nitrogen atoms, not being part of nitro or nitroso groups having the sulfur atom of at least one of the sulfonamide groups bound to a carbon atom of a six-membered aromatic ring having sulfur atoms of sulfonamide groups and amino groups bound to carbon atoms of six-membered rings of the same carbon skeleton
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
- A01N39/04—Aryloxy-acetic acids; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/06—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
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Abstract
Compounds (A) can be used for increasing the yield of useful plants or crop plants with respect to their harvested plant organs, wherein the Compound (A) is selected from compounds of the formula (I) or salts thereof, wherein the symbols are defined as in claim 1, preferably cyprosulfamide [Compound (A1)].
Description
Specification
The present invention relates to the purposes of some compound [compound (A)], it is replied with the place inducing specific growth regulating that described plant, the seed that grows described plant or described plant are grown under its normal habitat for the treatment of crop plants, preferably in the situation that not there is not extreme environmental conditions.
Other terms of the use of term as used in this description " for the method for plant growth regulating " or term " growth regulating process " or word " plant growth regulating " or use word " adjusting " relate to the various plants of some features of improving plant and reply." plant growth regulator " is the activated compound of tool in one or more growth conditions processes of plant.Plant growth regulating distinguishes over herein and is sometimes also defined as plant growth regulating, yet it is intended that insecticidal action or the growth decline that destroys or hinder the growth of plant.For this reason, the compound using in practice of the present invention is used with such amount, and described amount is plant-less toxicity with regard to pending plant, but the growth of stimulating plant or its some part.Therefore, this compounds can also be called as " plant stimulant ", and their effect can be called as " plant growth stimulating ".
Plant growth regulating is to improve the hope method of plant and harvest thereof, to obtain and compare with undressed plant in the practice of agriculture, and the plant growth of improvement and better condition.The molecule of these kinds can suppress or promote cytoactive.Division, elongation and the differentiation of the most common regulating plant cell of plant growth regulator that this means to identify in plant, its mode has multiple-effect the most conventionally in plant.With by known that the comparing of animal, visible trigger event in plant is different.
On molecular level, plant growth regulator can work by following: affect film character, controlling gene expression or affect enzymic activity or bring into play active with at least two kinds of combinations in aforementioned interaction type.
Plant growth regulator is the chemicals of nature origin, for example, for example, for example, also referred to as plant hormone (as non-peptide hormone for example growth hormone, gibberellin (giberrellins), the basic element of cell division, ethene, Brassinosteroids or abscisic acid and salicylic acid (salicilic acid)), fat oligosaccharide kind (the Nod factor), peptide (systemin), derivative of fatty acid class (jasmonate (jasmonates)), and oligosaccharide is (about summary referring to Biochemistry & Molecular Biology of the Plant (2000); Editor Buchanan, Gruissem, Jones, 558-562; With 850-929 page), or they can be that the synthetic compound producing is (as the derivative of naturally occurring auxin: ethrel).Can in many cells and tissue, find the plant growth regulator working with very little concentration, but they seem to concentrate in meristematic tissue and bud.
The mode of action of existing plant growth regulator is normally unknown.Multiple target has been discussed, and in these, most of affected molecules participate in cell divisions and regulate, as respectively by cell-cycle arrest in G1 or G2 phase; Other are for transmitting drought stress answer signal (Biochemistry & Molecular Biology of the Plant (2000); Editor Buchanan, Gruissem, Jones, 558-560 page).Under any circumstance, hormone is controlled the upper mediation can be accredited as extreme complexity and is lowered cascade, and it for example can cause the growth stimulation of organ or the cell type of plant, but also can cause other organs of identical plant or the inhibition in cell type.
As a rule, the direct or indirect involved in plant hormone of kinases is controlled, and in kinases, and protein kinase is key aspect cell cycle control and the control molecule of high degree of specificity.This class kinases is discussed as the target of several plant hormone, as (the Biochemistry & Molecular Biology of the Plant (2000) of the situation about growth hormone and abscisic acid; Editor Buchanan, Gruissem, Jones, 542-565 page and 980-985 page; Morgan (1997), Annu. Rev. Cell. Dev. Biol.,
13, 261-291; The people such as Amon (1993), Cell,
74, 993-1007 page; The people such as Dynlacht (1997), Nature,
389, 149-152 page; Hunt and Nasmyth (1997), Curr. Opin. Cell. Biol.,
9, 765-767 page; Thomas and Hall (1997), Curr. Opin. Cell Biol.,
9, 782-787 page).2-amino-hypoxanthine derivative is described in WO20051117 as preparation and the purposes of plant growth regulator.
Yet, because ecology and economic needs about modern crop treatment compositions constantly increase, for example about toxicity, selectivity, amount of application (application rate), residue, form and favourable manufacture, so have the lasting needs of the new crop treatment compositions of exploitation, described new crop treatment compositions at least has advantages of over known compositions in some fields.Therefore, the object of this invention is to provide further compound, to be applied to plant, to grow the seed of described plant or the place that described plant grows under its normal habitat, for growth regulating, reply, preferably in the situation that not there is not abiotic stress condition.In this; should mention that term " does not exist abiotic stress condition " and is interpreted as in the context of the present invention meaning plant or seed is not exposed to extreme environmental conditions; for example the soil salt of extreme drought, cold-peace heat condition, osmotic stress, waterlogging, rising, rising to the exposure of mineral matter, ozone condition, high light condition, limited nitrogen nutrition element availability or limited phosphorus nutrition element availability, particularly surpass the extreme environmental conditions of the home fluctuation that can occur under normal plants growth conditions.Therefore growth in the situation that not there is not abiotic stress condition is included in growing plant under field condition, and growth conditions, comprises nutrient supply, temperature, water supply and other conditions thus, is considered as for specific crop species average to best.Growth in the situation that not there is not abiotic stress condition is also included in growing plant under greenhouse experiment, and described greenhouse experiment is considered as for crop species average to best.
Usually, good growth can cause the improvement of growth, for example, about following:
-germinate,
-root growth
-branch development,
-rudiment,
-flower development,
The photosynthetic performance of-plant,
-Ye growth, preferably leaf area growth,
-plant/area (plant density of improvement).
Alternately, good growth can cause the improvement about the crop yield of many kinds of parameters, described parameter for example:
-biomass,
-quantitative fruit yield,
-fruit size,
-quantitative grain yield,
-qualitative output is the increase in required constituent content for example, for example the sugar content of sugar beet or the protein content in cereal grains, for the production of the glutelin content of the grain of glue).
Although the improvement of some in above-mentioned growth characteristics can realize together, other very specificity realizations, and other parameters are not had effect or even have ill-effect.
Therefore, be desirable to provide the useful especially plant growth regulation of crop plants, it causes these to process plant, some part of these plants or the good growth of specific crop yield.
The group of compound widely that is selected from acyl sulfonamides group be described in WO-A-97/45016, WO-A-99/16744 and EP-A-365484 and the list of references wherein quoted in; This compound is " compound (A) " hereinafter referred to as.By described publication known " compound (A) ", there is safener character.Safener is for example, together with agricultural chemicals (pesticides) weed killer herbicide, insecticide or fungicide, preferred weed killer herbicide, and one is used from useful plant crop, to reduce the phytotoxic effects of agricultural chemicals to crop plants.Good safener should not reduce the required effect of agricultural chemicals to target biology, for example take weed killer herbicide as agricultural chemicals in the situation that for the effect of ruderal plant.Business security agent from compound (A) is cyclopropyl-sulfonylamide (common name), below also referred to as " compound (A1) ".
By further known this type of acyl sulfonamides safener of WO 2007/062737 also show needle to some abiotic stress for example extreme drought, heat or cold, reduce the particularly effect of the plant injury of maize plant of crop plants.
According to WO 2010/003444, this type of acyl sulfonamides safener has also shown and has improved the particularly root growth of maize plant of crop plants.In addition, regulate crop plants particularly the effect in the shoot growth of maize plant also in list of references, described.
In addition, described by adding acyl sulfonamides safener for strengthening the effect of the effect of some agricultural chemicals.Therefore, WO 2008/131854 has described by adding cyclopropyl-sulfonylamide and has strengthened the effect of defoliant Thidiazuron to vegetable lamb.WO 2008/092615 has described the herbicide effect that strengthens weed killer herbicide azoles quinoline grass ester by adding cyclopropyl-sulfonylamide.
Surprisingly find at present compound (A), particularly compound (A1), can be for increasing useful plant or crop plants the output with regard to the plant organ of its results.
Another object of the present invention is the method for the output with regard to the plant organ of its results for increasing useful plant or crop plants, compound (A) wherein, compound (A1) particularly, amount with effective dose, preferred plant-less toxicity is applied to crop plants, grows the seed of described plant or the place that described plant grows under its normal habitat, preferably in the situation that not there is not extreme environmental conditions.
As term used herein " useful plant " refers to obtain food, animal feed or for the crop plants of the plant of industrial use with acting on, and gardening plant.
In the context of the present invention, term " increase output " preferably means to compare with untreated check plant, the specific yield (specific yield) of the plant organ of results strengthens 2% or surpass 2%, more preferably 5% or surpass 5%, more preferably 8% or surpass 8%, more preferably 10% or surpass 10%, and effect itself can be individually or in addition with any effect combination performance.
In the context of the present invention, term " with regard to the plant organ of its results " limit depend on concrete plant to be considered conventionally results plant organ and under results by its derivative product.This comprises if gather in the crops together several plant organs, the whole biomass of these plant organs, and can indicate subsequently the relatively nonspecific general action of plant growth.Yet, preferably it is limited to seed and produces the seed of gathering in the crops in the situation of plant, for example cereal comprises the seed of maize plant, and oil plants is the seed of oil seed rape or canola for example, and beans is the seed organ of beans, lentil, pea and soybean for example.
Preferably, the plant organ of results also comprises for example seed organ of the results of vegetable lamb of fibre plant, is preferred for the velveteen of the vegetable lamb that derives from kind of skin of procedure of fibre production.
Preferably, the plant organ of results also comprises for example results organ of sugar beet and fodder beet of sugar beet plants.
Term " with regard to the plant organ of its results " also comprises the improvement about the special parameter of the plant organ of results, for example, plant content of starch, the kind glutelin content of benevolence, the protein content of the sugar content of sugar beet, kind benevolence of benevolence.
Preferably, plant organ is when the maturing stage of its growth or approach results in its in ripe period, as be generally used for results.
More preferably object of the present invention be use (as unique agrochemicals compound) separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing purposes or the method for grain yield that is selected from the crop plants of cereal, canola, soybean and cotton crop.
Term " agrochemicals compound " is interpreted as meaning to be selected from any compound of weed killer herbicide, fungicide, insecticide, bactericide, nematocide, miticide, plant growth regulator and safener.
Another preferred object of the present invention be use (as unique agrochemicals compound) separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing purposes or the method for protein content of kind benevolence that is selected from the crop plants of cereal, canola and soybean crops.
Another preferred object of the present invention be use separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing purposes or the method for glutelin content of kind benevolence that is selected from the crop plants of cereal, canola and soybean crops.
Another preferred object of the present invention be use separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing purposes or the method for glutelin content of kind benevolence that is selected from the crop plants of cereal.
Another preferred object of the present invention be use separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing purposes or the method for the beet amount output by weight of sugar beet plants.
Another preferred object of the present invention be use separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing purposes or the method for the biomass yield of the maize plant growing in the situation that not there is not extreme environmental conditions.
Another preferred object of the present invention be use separately or with compound (A), particularly compound (A1) of one or more selected agrochemicals compound combinations, for increasing purposes or the method for the sugar content of sugar beet.
Another preferred object of the present invention be use separately or with compound (A), particularly compound (A1) of one or more selected agrochemicals compound combinations, for increasing purposes or the method for the biomass yield of sugar plant.
Another preferred object of the present invention be use separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing purposes or the method for the biomass yield of the sugar beet plants of growing in the situation that not there is not extreme environmental conditions.
More preferably object of the present invention be use separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing cereal, purposes or the method for the grain yield of preferably wheat, barley, rye, triticale, rice, Chinese sorghum, sugarcane or maize crop.
More preferably object of the present invention be also to use separately or with compound (A), particularly compound (A1) of one or more selected agrochemicals compound combinations, for increasing germination and the purposes of emerging or the method for rice plant.
More preferably object of the present invention be also to use separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing oil crop for example purposes or the method for the grain yield of canola crop.
More preferably object of the present invention be also to use separately or with purposes or the method for compound (A), particularly compound (A1) of one or more selected agrochemicals compound combinations, for increasing the legume crop beans output of soybean crops for example.
More preferably object of the present invention be also to use separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing fiber crop for example purposes or the method for the grain yield of cotton crop.
More preferably object of the present invention be also to use separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing fiber crop for example purposes or the method for the velveteen output of cotton crop.
More preferably object of the present invention be also to use separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing beet crop for example purposes or the method for the Sugarbeet Yield of sugar beet crop.
Another preferred object of the present invention be use separately or with the compound (A) of one or more selected agrochemicals compound combinations, compound (A1) particularly, for increasing purposes or the method for the biomass yield of sugar beet or sugarcane plants.
According to compound of the present invention (A), be interpreted as the compound or its salt of the formula that is selected from (I),
Wherein
X is CH or N;
R
1be-CO-NR
5r
6,-NH-CO-R
7or-NH-CO-NR
8r
9,
If n is 1, (R
2)
nit is radicals R
2if or n surpasses 1, (R
2)
nrepresentative is connected to n radicals R of the different carboatomic ring atoms of foundation ring (basic ring)
2, each R wherein
2halogen, (C independently of one another
1-C
4) haloalkyl, (C
1-C
4) halogenated alkoxy, nitro, (C
1-C
4) alkyl, (C
1-C
4) alkoxyl, (C
1-C
4) alkyl sulphonyl, [(C
1-C
4) alkoxyl] carbonyl or [(C
1-C
4) alkyl] carbonyl,
R
3hydrogen, (C
1-C
4) alkyl, (C
2-C
4) thiazolinyl or (C
2-C
4) alkynyl,
If m is 1, (R
4)
mit is radicals R
4if or m surpasses 1, (R
4)
mrepresentative is connected to m radicals R of the different carboatomic ring atoms of basic ring
4, each R wherein
4halogen, nitro, (C independently of one another
1-C
4) alkyl, (C
1-C
4) haloalkyl, (C
1-C
4) halogenated alkoxy, (C
3-C
6) cycloalkyl, phenyl, (C
1-C
4) alkoxyl, cyano group, (C
1-C
4) alkylthio group, (C
1-C
4) alkyl sulphinyl, (C
1-C
4) alkyl sulphonyl, [(C
1-C
4) alkoxyl] carbonyl or [(C
1-C
4) alkyl] carbonyl;
R
5hydrogen, (C
1-C
6) alkyl, (C
3-C
6) cycloalkyl, (C
2-C
6) thiazolinyl, (C
2-C
6) alkynyl, (C
5-C
6) cycloalkenyl group, phenyl or have be selected from the heteroatomic 3-to 6-of nitrogen, oxygen and sulphur 1-3 unit heterocyclic radical, each of 7 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
6) alkoxyl, (C
1-C
6) halogenated alkoxy, (C
1-C
2) alkyl sulphinyl, (C
1-C
2) alkyl sulphonyl, (C
3-C
6) cycloalkyl, (C
1-C
4) alkoxy carbonyl, [(C
1-C
4) alkyl] carbonyl and phenyl, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
R
6hydrogen, (C
1-C
6) alkyl, (C
3-C
6) cycloalkyl, (C
2-C
6) thiazolinyl or (C
2-C
6) alkynyl, each of 3 kinds of groups finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, hydroxyl, (C
1-C
4) alkyl, (C
1-C
4) alkoxyl and (C
1-C
4) alkylthio group, or
R
5and R
6together with the nitrogen-atoms connecting, represent pyrrolidin-1-yl-or piperidin-1-yl,
R
7hydrogen, (C
1-C
6) alkyl, (C
3-C
6) cycloalkyl, each of 2 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
4) alkoxyl, (C
1-C
6) halogenated alkoxy and (C
1-C
4) alkylthio group, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
R
8hydrogen, (C
1-C
8) alkyl, (C
2-C
6) thiazolinyl, (C
2-C
6) alkynyl or (C
3-C
8) cycloalkyl, each of 4 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
4) alkoxyl, (C
1-C
6) halogenated alkoxy and (C
1-C
4) alkylthio group, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
R
9hydrogen, (C
1-C
8) alkyl, (C
2-C
6) thiazolinyl, (C
2-C
6) alkynyl or (C
3-C
8) cycloalkyl, each of 4 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
4) alkoxyl, (C
1-C
6) halogenated alkoxy and (C
1-C
4) alkylthio group, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
N is 0,1,2,3 or 4, preferably 0,1 or 2, and
M is 0,1,2,3 or 4, preferably 1 or 2.
Preferred compound (A) is the compound or its salt of formula (Ia),
(R wherein
2)
n, R
3, (R
4)
m, R
5, R
6n and m be as about formula (I) definition, and preferably wherein
R
3hydrogen,
If m is 1, (R
4)
mit is radicals R
4if or m surpasses 1, (R
4)
mrepresentative is connected to m radicals R of the different carboatomic ring atoms of foundation ring
4, each R wherein
4halogen, methyl, ethyl, n-pro-pyl, isopropyl, CF independently of one another
3, (C
1-C
4) halogenated alkoxy or (C
1-C
4) alkoxyl,
R
5(C
1-C
6) alkyl or (C
3-C
6) cycloalkyl, each of 2 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
4) alkoxyl, (C
1-C
4) halogenated alkoxy, (C
1-C
2) alkyl sulphinyl, (C
1-C
2) alkyl sulphonyl, (C
3-C
6) cycloalkyl, (C
1-C
4) alkoxy carbonyl and [(C
1-C
2) alkyl] carbonyl, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
R
6hydrogen or (C
1-C
4) alkyl, preferred hydrogen,
M is 0,1 or 2, preferably 1 or 2, and
N is zero.
The compound or its salt of preferred formula (Ia) is such, wherein
R
3hydrogen, and
(R
4)
m2-methoxyl group, and R
5cyclopropyl, or
(R
4)
mthe chloro-2-methoxyl group of 5-, and R
5cyclopropyl, or
(R
4)
m2-methoxyl group, and R
5ethyl, or
(R
4)
mthe chloro-2-methoxyl group of 5-, and R
5isopropyl, or
(R
4)
m2-methoxyl group, and R
5isopropyl, and
R
6hydrogen, and
N is zero.
This compounds is known by WO 99/16744.
The compound or its salt of most preferred formula (Ia) is such compound, wherein
R
3hydrogen,
(R
4)
m2-methoxyl group,
R
5cyclopropyl,
R
6hydrogen, and
N is zero;
(common name " cyclopropyl-sulfonylamide "=compound (A1)).
Preferred compound (A) is the compound or its salt of formula (Ib) in addition,
(R wherein
2)
n, R
3, (R
4)
m, R
7, n and m be as about formula (I) definition, and preferably wherein
R
3hydrogen,
If m is 1, (R
4)
mit is radicals R
4if or m surpasses 1, (R
4)
mrepresentative is connected to m radicals R of the different carboatomic ring atoms of foundation ring
4, each R wherein
4halogen, (C independently of one another
1-C
4) alkyl, CF
3, (C
1-C
4) halogenated alkoxy or (C
1-C
4) alkoxyl,
R
7(C
1-C
6) alkyl or (C
3-C
6) cycloalkyl, each of 2 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
4) alkoxyl, (C
1-C
6) halogenated alkoxy and (C
1-C
4) alkylthio group, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
M is 0,1 or 2, preferably 1 or 2, and
N is zero.
This compounds is known by WO 99/16744.
Preferred compound (A) is the compound or its salt of above formula (Ic) in addition,
(R wherein
2)
n, R
3, (R
4)
m, R
8, R
9, n and m be as about formula (I) definition, and preferably wherein
R
3hydrogen,
If m is 1, (R
4)
mit is radicals R
4if or m surpasses 1, (R
4)
mrepresentative is connected to m radicals R of the different carboatomic ring atoms of foundation ring
4, each R wherein
4halogen, (C independently of one another
1-C
4) alkyl, CF
3, (C
1-C
4) halogenated alkoxy or (C
1-C
4) alkoxyl, preferably halogen, (C
1-C
4) alkyl, CF
3or (C
1-C
4) alkoxyl,
R
8hydrogen, (C
1-C
8) alkyl, (C
2-C
6) thiazolinyl, (C
2-C
6) alkynyl or (C
3-C
8) cycloalkyl,
R
9hydrogen, (C
1-C
8) alkyl, (C
2-C
6) thiazolinyl, (C
2-C
6) alkynyl or (C
3-C
8) cycloalkyl,
M is 0,1 or 2, preferably 1 or 2, and
N is zero.
This compounds is known by EP-A-365484; for example particularly: 1-[4-(N-2-methoxybenzoyl sulfamoyl) phenyl]-3-methyl-urea; 1-[4-(N-2-methoxybenzoyl sulfamoyl) phenyl]-3; 3-dimethyl-urea; 1-[4-(N-4,5-dimethyl benzene formyl sulfamoyl) phenyl]-3-methyl-urea.
By by suitable inorganic or organic acid, for example, as HCl, HBr, H
2sO
4or HNO
3, and oxalic acid or sulfonic acid adds basic group to, for example, on amino or alkyl amino, the compound of formula (I) can form salt.The suitable substituent existing with deprotonation form, for example sulfo group or carboxyl, can with its part can be protonated group, for example amino, form inner salt.Salt can also be by by the suitable substituent hydrogen of sulfo group or carboxyl for example, or-SO
2the acid hydrogen atom of NHCO-group replaces with the upper suitable cation of agricultural and forms.These salt are for example slaine, particularly alkali metal salt or alkali salt, especially sodium salt and sylvite, or ammonium salt, with salt or the quaternary ammonium salt of organic amine.
The upper acceptable salt of the compound of the formula (I) of using according to the present invention and agricultural thereof is below also being called " compound of formula (I) " for short or also referred to as compound (A).
In the description of molecular formula, comprise in additional claims, above-mentioned substituting group has following implication:
Halogen means fluorine, chlorine, bromine or iodine.
Term before group title " halogen (generation) " refers to that this group is by partially or completely halogenation, that is, by F, Cl, Br or I, with any combination, replaced.
Statement " (C
1-C
6) alkyl " mean to there is 1,2,3,4,5 or 6 carbon atom non-annularity saturated hydrocarbon group of not branch or branch of (the C atoms range in bracket is indicated); for example, as methyl, ethyl, propyl group, isopropyl, 1-butyl, 2-butyl, 2-methyl-propyl or tertiary butyl groups.This is equally applicable to for example alkyl in " alkoxyalkyl " of compound group.
Unless otherwise defined, alkyl group and the alkyl group in compound group preferably have 1 to 4 carbon atom.
" (C
1-C
6) haloalkyl " mean at statement " (C
1-C
6) alkyl " and under the alkyl mentioned, wherein one or more hydrogen atoms are replaced by the identical or different halogen atom of equal number, for example single haloalkyl, whole haloalkyl, CF
3, CHF
2, CH
2f, CHFCH
3, CF
3cH
2, CF
3cF
2, CHF
2cF
2, CH
2fCHCl, CH
2cl, CCl
3, CHCl
2or CH
2cH
2cl.
" [(C
1-C
4) alkoxyl] (C
1-C
6) alkyl " mean by one or more (C
1-C
4) alkoxyl, preferably by (a C
1-C
4) (the C that replaces of alkoxyl
1-C
6) alkyl.
" (C
1-C
6) alkoxyl " meaning alkoxyl, its carbochain has at statement " (C
1-C
6) alkyl " and under the implication that provides." halogenated alkoxy " is OCF for example
3, OCHF
2, OCH
2f, CF
3cF
2o, OCH
2cF
3or OCH
2cH
2cl.
" (C
2-C
6) thiazolinyl " meaning the acyclic carbochain of branch not or branch, it has a plurality of carbon atoms corresponding to scope described in this, and contains at least one the two key in any position that can be positioned unsaturated group separately." (C
2-C
6) thiazolinyl " correspondingly indicate for example vinyl, pi-allyl, 2-methyl-2-acrylic, 2-cyclobutenyl, pentenyl, 2-methylpent thiazolinyl or hexenyl.
" (C
2-C
6) alkynyl " meaning the acyclic carbochain of branch not or branch, it has a plurality of carbon atoms corresponding to scope described in this, and contains a triple bond in any position that can be positioned unsaturated group separately." (C
2-C
6) alkynyl " correspondingly indicate for example propargyl, 1-methyl-2-propynyl, 2-butynyl or 3-butynyl.
" (C
3-C
6) cycloalkyl " instruction sheet group of naphthene base, for example cyclopropyl, cyclobutyl, cyclopenta or cyclohexyl groups.
" (C
4-C
6) cycloalkenyl group " indication has the undersaturated ring of carbocyclic ring, non-aromatic, part of 4 to 6 carbon atoms; for example 1-cyclobutane base, 2-cyclobutane base, 1-cyclopentenyl, 2-cyclopentenyl, 3-cyclopentenyl or 1-cyclohexenyl group, 2-cyclohexenyl group, 3-cyclohexenyl group, 1; 3-cyclohexadienyl or Isosorbide-5-Nitrae-cyclohexadienyl.
Unless the clearly concrete restriction of definition, the statement in definition " be selected from ... one or more groups " be interpreted as meaning to be selected from each case the one or more identical or different group that limits types of radicals.
According to substituent type and connection, the compound of formula (I) can be used as stereoisomer and exists.The possible stereoisomer being limited by its specific three dimensional form, for example enantiomer, diastereomer, Z and E isomer, comprise by formula (I).When for example there is one or more thiazolinyl, can there is diastereomer (Z and E isomer).When for example there is one or more asymmetric carbon atom, can there is enantiomer and diastereomer.Stereoisomer can obtain from the mixture obtaining preparation by habitual separating method.Chromatography can realize in analytical scale, to find enantiomeric excess or diastereomeric excess, or realizes on preparative-scale, to produce the test sample book for biology test.Can react by use stereoselectivity equally, and come selectivity to prepare stereoisomer with optically active raw material and/or auxiliary agent.Therefore the present invention also relates to it and is comprised by formula (I), but does not show all stereoisomers of its particular stereoisomer form, and composition thereof.
Group definition overview statement above or that list in preferable range, is applied to the end-product of formula (I) and in each case for preparation required corresponding raw material and intermediate product.These group definition can exchange each other, are included in the combination between described preferable range.
As term used herein " useful plant " refers to obtain food, animal feed or for the crop plants of the plant of industrial use with acting on, and gardening plant.
The present invention further provides the method for the treatment of plant, preferably growing plants in the situation that not there is not extreme environmental conditions." there is not the extreme environmental conditions of any kind " and be interpreted as in the context of the present invention meaning plant or seed is not exposed to extreme environmental conditions; for example the soil salt of extreme drought, cold-peace heat condition, osmotic stress, waterlogging, rising, rising to the exposure of mineral matter, ozone condition, high light condition, limited nitrogen nutrition element availability or limited phosphorus nutrition element availability, particularly surpass the extreme environmental conditions of the home fluctuation that can occur under normal plants growth conditions.
Compound (A) particularly compound (A1) can be for example under condition known in the art, by seed treatment or by applying and be applied before emerging or after emerging.
Compound (A) particularly compound (A1) can combine separately or with one or more agrochemical compounds for example under condition known in the art, by seed treatment or by applying and be applied before emerging or after emerging.
Application can be used the technology of spraying before emerging or after emerging, application separately or with the spray solution of compound (A), particularly compound (A1) of one or more agrochemicals compound combinations.This type of spray solution can comprise other habitual components, for example solvent, formulation auxiliary agents, especially water.Further component can comprise active agrochemicals composition described below.
The present invention further provides the purposes of corresponding spray solution output with regard to the plant organ of its results for increasing useful plant or crop plants.Annotation is subsequently applied to purposes of the present invention and the corresponding spray solution of the compound self of formula (I).
When use separately or with the compound (A) of one or more agrochemicals compound combinations, particularly compound (A1) as plant growth regulator for increasing useful plant the output with regard to the plant organ of its results, for example for increasing crop plants (as mentioned above those, preferred cereal is wheat for example, barley, rye, triticale, millet, rice or corn (maize)) grain yield time, amount of application is, for example, in the scope of 0.005g (5 mg)-5000 g active substance/hectare (ha.) soil surfaces, preferably in the scope of 0.01g (10 mg)-2000 g/ha, especially in the scope of 0.05g (50 mg)-1000 g/ha active substances, the active substance of 10-1000 g/ha very particularly, more preferably the active substance of 20-500 g/ha, the active substance of 25-100 g/ha most preferably.
Separately or with the compound (A) of one or more agrochemicals compound combinations, particularly compound (A1) can be applied to plant by following: spray and contain the particularly spray solution of compound (A1) of compound (A), by contain compound (A) particularly the granule of compound (A1) be assigned on the soil of area under cultivation, will contain compound (A) particularly (for example paddy rice) in the solution of compound (A1) or dispersion or granule impouring field water.
Separately or with the compound (A) of one or more agrochemicals compound combinations, particularly compound (A1) can apply and emerge before method (before sowing or with sowing simultaneously, for example plantation before mix or ridge in processing, or after planting) or emerge in early days before method, or the late period application in period after emerging, general until useful plant is in full bloom.
As an alternative, as the application of plant growth regulator, also can be undertaken by processing seed, it comprises for dressing seed and applying the multiple technologies of seed.Herein, amount of application depends on concrete technology and can in preliminary test, measure.Conventionally, the in the situation that of seed treatment, compound (A), particularly compound (A1) is 0.001 gram (1 mg)-10 grams of active substances (a. i.)/kilogram seed as the amount of application of active substance, preferred 0.01g (10 mg)-5 g a. i./kg seed, particularly 0.1g (100 mg)-2 g a. i./kilogram seeds.
If separately or with the compound (A) of one or more agrochemicals compound combinations, particularly compound (A1) solution is for method for treating seeds, wherein seed is immersed in the solution of active substance, the active substance in solution (a. i.) concentration is the 1-15000 ppm based on weight for example, preferred 10-10000 ppm, more preferably 100-5000 ppm.
Plant growth regulator is generally with the effective dose application of the plant-less toxicity of coordinate plant growth." plant-less toxicity " means the amount of such plant growth regulator, and it causes at most damage or the not damaged seldom of output about results product for the crop species of expectation.
When application separately or with the compound (A) of other agrochemicals compound combinations, compound (A1) or (A2) particularly, particularly during compound (A1), it can be applied once or be applied by the gradation application in twice or more times situation, and single application can be by seed treatment, the front or rear processing of emerging.Therefore, can there is applied in any combination, for example by seed treatment subsequently for one or many emerge before and/or the post processing of emerging.
Advantageous applications is to pass through seed treatment.
The further preferably single pre-treatment of emerging.
The further preferably single post processing of emerging.
The pre-treatment of further preferably emerging is 1,2 or 3 post processing of emerging subsequently.
Further preferably seed treatment, is 1,2 or 3 post processing of emerging subsequently.
Further preferably heading and 8 the emerge post processings of leaf in the stage between the phase in early days.
Further preferably late the trophophase until in reproduction period (sprout finish and initial bloom stage between) produce the post processing of emerging of seed bearing plant.
Compound (A), particularly (A1) can be used as independent product or uses with one or more other agrochemicals compound combinations, the preferred agricultural chemicals of described other agrochemicals compounds or plant growth regulator, more preferably plant growth regulator can also be used as the agricultural chemicals of its safener effectively.Especially interestingly compound (A), preferred compound (A1), with the combination of weed killer herbicide, fungicide, insecticide or plant growth regulator, especially preferred be with belong to fungicide kind one or more, the preferably combination of one or both agrochemically active compounds.
The amount of application of the preferred weed killer herbicide of agricultural chemicals (B) is in the scope of the agricultural chemicals for independent (preferably weed killer herbicide) and itself be therefore known.
Present invention further optimization object is the combined use of compound (A), particularly compound (A1) and one or more fungicides, one or more insecticides and/or the combination of one or more plant growth regulator.
More specifically, will with compound (A) or compound (A1), the fungicide of preferred compound (A1) combination is selected from following:
M 9834 [=F-1], essence M 9834 [=F-2], bupirimate [=F-3], chiralaxyl [=F-4], clozylacon [=F-5], dimethirimol [=F-6], the phonetic phenol of second [=F-7], furalaxyl [=F-8], hymexazo [=F-9], metalaxyl [=F-10], metalaxyl-M [=F-11], ofurace [=F-12], Evil frost spirit [=F-13], oxolinic acid [=F-14], benomyl [=F-15], carbendazim [=F-16], the mould prestige of second [=F-17], furidazol [=F-18], fluopicolide [=F-19], Pencycuron [=F-20], probenazole [F-21], thiophanate-methyl [=F-22], zoxamide [F-23], chloro-7-(4-methyl piperidine-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidines [=F-24], difluoro woods [=F-25], biphenyl pyrrole bacterium amine [=F-26], Boscalid [=F-27], carboxin [=F-28], diflumethorim [=F-29], fenfuram [=F-30], fluorine pyrrole bacterium acid amides [=F-31], flutolanil [=F-32], good fortune Lapie [=F-33], mebenil [=F-34], oxycarboxin [=F-35], fluorine azoles bacterium aniline [=F-36], pyrrole metsulfovax [F-37], thifluzamide [=F-38], N-[2-(1,3-dimethylbutyl) phenyl]-5-is fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide [=F-39], pyrazoles naphthalene bacterium amine [=F-40], sedaxane [=F-41], 3-(difluoromethyl)-1-methyl-N-(3', 4', 5'-trifluoro-biphenyl base-2-yl)-1H-pyrazole-4-carboxamide [=F-42], 3-(difluoromethyl)-1-methyl-N-[2-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-1H-pyrazole-4-carboxamide [=F-43], the fluoro-2-of 3-(difluoromethyl)-N-[4-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl]-1-methyl isophthalic acid H-pyrazole-4-carboxamide [F-44], N-[1-(2,4-dichlorophenyl)-1-methoxy propyl-2-yl]-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide [=F-45] and corresponding salt, amisulbrom [=F-46], Fluoxastrobin [=F-47], cyazofamid [=F-48], dimoxystrobin [=F-49], Enestroburin [=F-50], famoxadone [=F-51], Fenamidone [=F-52], fluoxastrobin [=F-53], methyl kresoxim-methyl [=F-54], SSF 126 [=F-55], orysastrobin [=F-56], pyraclostrobin [=F-57], pyribencarb [=F-58],ZEN 90160 [=F-59], oxime bacterium ester [=F-60], (2E)-2-(2-{[6-(3-chloro-2-methyl phenoxy group)-5-FU-4-yl] oxygen base } phenyl)-2-(methoxyimino)-N-methylacetamide [=F-61], (2E)-2-(ethoxy imino)-N-methyl-2-(2-{[({ (1E)-1-[3-(trifluoromethyl)-phenyl] ethylidene } amino) oxygen base] methyl } phenyl) acetamide [=F-62] and corresponding salt, (2E)-2-(methoxyimino)-N-methyl-2-{2-[(E)-(1-[3-(trifluoromethyl)-phenyl] and-ethyoxyl }-imino group) methyl] phenyl } acetamide [=F-63], (2E)-2-{2-[({[(1E) the fluoro-2-phenyl vinyl of-1-(3-{[(E)-1-] oxygen base } phenyl) ethylidene]-amino } oxygen base) methyl] phenyl }-2-(methoxyimino)-N-methyl-acetamide [=F-64], (2E)-2-{2-[({[(2E, 3E)-4-(2,6-dichlorophenyl) fourth-3-alkene-2-subunit] amino } oxygen base) methyl] phenyl }-2-(methoxyimino)-N-methylacetamide, the chloro-N-of 2-(1,1,3-trimethyl-2,3-dihydro-1H-indenes-4-yl) pyridine-3-carboxamide [F-65], 5-methoxyl group-2-methyl-4-(2-{[({ (1E)-1-[3-(trifluoromethyl)-phenyl]-ethylidene }-amino)-oxygen base]-methyl }-phenyl)-2,4-dihydro-3H-1,2,4-triazole-3-ketone [=F-66], 2-{2-[({ cyclopropyl [(4-methoxyphenyl)-imino group] methyl } sulfanyl) methyl] phenyl }-3-methoxy-methyl acrylate [=F-67], N-(3-ethyl-3,5,5-trimethylcyclohexyl)-3-(formoxyl amino)-2-Hydroxylbenzamide [=F-68] and corresponding salt, dinocap [=F-69], fluazinam [=F-70], fentin acetate [=F-71], triphenyl tin chloride [=F-72], triphenyl tin hydroxide [=F-73], Silthiopham [=F-74], amine puts out [=F-75], blasticidin S-S [=F-76], cyprodinil [=F-77], kasugarnycin [=F-78], kasugarnycin hydrochloride hydrate [=F-79], mepanipyrim [=F-80], phonetic mould amine [=F-81], fenpiclonil [=F-82], fludioxonil [=F-83], quinoxyfen [=F-84], chlozolinate [=F-85], iprodione [=F-86], procymidone [=F-87], vinclozolin [=F-88], ammonia propyl-phosphine acid [=F-89], ammonia propyl-phosphine acid potassium [=F-90], Hinosan [=F-91], IBP (IBP) [=F-92], Isoprothiolane [=F-93], pyrazophos [=F-94],Tolelofos-methyl [=F-95], biphenyl [=F-96], iodocarb [=F-97], Propamocarb [F-98], propamocarb [=F-99], fenhexamid [=F-100], azaconazole [=F-101], Bitertanol [=F-102], bromuconazole [=F-103], diclobutrazol [=F-104], Difenoconazole [=F-105], alkene azoles alcohol [=F-106], alkene azoles alcohol-M [=F-107], epoxiconazole [=F-108], etaconazole [=F-109], RH-7592 [=F-110], Fluquinconazole [=F-111], Flusilazole [=F-112], Flutriafol [=F-113], furconazole [=F-114], cis furconazole [=F-115], own azoles alcohol [=F-116], glyoxalin [=F-117], plant bacterium azoles [=F-118], metconazole [=F-119], nitrile bacterium azoles [=F-120], paclobutrazol [=F-121], penconazole [=F-122], propiconazole [=F-123], prothioconazoles [=F-124], simeconazoles [=F-125], volution bacterium amine [=F-126], Tebuconazole [=F-127], triazolone [=F-128], Triadimenol [=F-129], triticonazole [=F-130], uniconazole P [=F-131], voriconazole [=F-132], imazalil [=F-133], Imazalil sulfate [=F-134], Evil imidazoles [=F-135], Fenarimol [=F-136], flurprimidol [=F-137], nuarimol [=F-138], pyrifenox [=F-139], triforine [=F-140], pefurazoate [=F-141], Prochloraz [=F-142], fluorine bacterium azoles [=F-143], alkene frost benzyl azoles [=F-144], cartap [=F-145], dodemorph [=F-146], dodemorfe acetic acid esters [=F-147], butadiene morpholine [=F-148], tridemorph [=F-149], fenpropidin [=F-150], Naftifine [=F-151], pyributicarb [=F-152], Terbinafine [=F-153], 1-(4-chlorphenyl)-2-(1H-1,2,4-triazol-1-yl) suberol [=F-154], 1-(2,2-dimethyl-2,3-dihydro-1H-indenes-1-yl)-1H-imidazoles-5-methyl formate [=F-155], N'-{5-(difluoromethyl)-2-methyl-4-[3-(trimethyl-silicyl) propoxyl group] phenyl }-N-ethyl-N-methyl imido is for formamide [=F-156], N-ethyl-N-methyl-N'-{2-methyl-5-(trifluoromethyl)-4-[3-(trimethyl silyl) propoxyl group] phenyl } imido is for formamide [=F-157],O-{1-[(4-methoxyphenoxy) methyl]-2,2-dimethyl propyl }-1H-imidazoles-1-thiocarboxylic [=F-158], benzene metsulfovax [=F-159], two the third ammonia phosphorus [=F-160], dimethomorph [=F-161], flumorph [=F-162], Propineb [=F-163], Polyoxin [=F-164], Polyoxin (polyoxorim) [=F-165], Validacin (Takeda) [=F-166], ring propionyl bacterium amine [=F-167], two chlorine zarilamids [=F-168], zarilamid [=F-169], Rabcide [=F-170], pyroquilon [=F-171], tricyclazole [=F-172], thiadiazoles element-S-methyl [=F-173], probenazole [=F-174], tiadinil [=F-175], isotianil [=F-176], difoltan [=F-177], captan [=F-178], Bravo [=F-179], mantoquita is for example: Kocide SD [=F-180], copper naphthenate [F-181], copper oxychloride [=F-182], copper sulphate [=F-183], cupric oxide [=F-184], copper 8-hydroxyquinolinate [=F-185], bordeaux mixture [=F-186], dichlofluanid [=F-187], dithianon [=F-188], dodine [=F-189], dodine free alkali [=F-190], fervam [=F-191], folpet [=F-192], fluorine folpet [=F-193], biguanides pungent [=F-194], guazatine acetate [=F-195], iminoctadine [=F-196], biguanides octane benzene sulfonate [=F-197], iminoctadine triacetate [=F-198], mancopper [=F-199], Mancozeb [=F-200], maneb [=F-201], Carbatene [=F-202], Carbatene zinc [=F-203], Propineb [=F-204], sulphur and containing the sulphur preparation [=F-205] of calcium polysulfide, thiram [=F-206], tolyfluanid [=F-207], zineb [=F-208], ziram [=F-209], amibromdol [=F-210], benthiozole [=F-211], bethoxazin [=F-212], capsimycin [=F-213], carvol [=F-214], chinomethionat [=F-215], chloropicrin [=F-216], cufraneb [=F-217], cyflufenamid [=F-218], frost urea cyanogen [=F-219], dazomet [=F-220], debacarb [=F-221], diclomezine [=F-222], antiphen [=F-223], botran [=F-224], difenzoquat [=F-225], difenzoquat Methylsulfate [=F-226], diphenylamines [=F-227], Guardian [=F-228],Ferimzone [=F-229], fluorine biphenyl bacterium [=F-230], flusulfamide [=F-231], fluopicolide [=F-232], fluorine bacterium peace [=F-233], fosatyl-Al [=F-234], hexachloro-benzene [=F-235], 8-hydroxyl-quinoline sulfate [=F-236], iprodione [=F-237], people's metamycin (irumamycin) [=F-238], isotianil [=F-239], methasulfocarb [=F-240], metrafenone [=F-250], methyl-isorhodanate [=F-251], midolthromycin [=F-252], natamycin [=F-253], nickel dimethyldithiocarbamate [=F-254], isopropyl disappear [=F-255], octhilinone [=F-256], AUX is Cabbeen (oxamocarb) [=F-257] not, oxo is put forth energy glad [=F-258], pentachlorophenol [=F-259] and salt, 2-phenylphenol [=F-260] and salt, pipron [=F-261], propyl alcohol rhzomorph-sodium [=F-262], the third oxygen quinoline [=F-263], pyrrolnitrin [=F-264], quinalphos [=F-265], tecloftalam [=F-266], tecnazene [=F-267], azoles bacterium piperazine [=F-268], trichlamide [=F-269], zarilamid [=F-270], 2,3,5,6-tetrachloro-4-(methyl sulphonyl) pyridine [=F-271], N-(the chloro-2-nitrobenzophenone of 4-)-N-ethyl-4-methyl benzenesulfonamide [=F-272], 2-amino-4-methyl-N-phenyl-5-thiazole carboxamides [=F-273], the chloro-N-of 2-(2,3-dihydro-1,1,3-trimethyl-1H-indenes-4-yl)-3-pyridine-2-carboxamide [=F-274], 3-[5-(4-chlorphenyl)-2,3-dimethyl isoxazole-3-yl] pyridine [=F-275], cis-1-(4-chlorphenyl)-2-(1H-1,2,4-triazol-1-yl) suberol [=F-276], 2,4-dihydro-5-methoxyl group-2-methyl-4-[[[[1-[3-(trifluoromethyl) phenyl] ethylidene] amino]-oxygen base] methyl] phenyl]-3H-1,2,3-triazole-3-ketone (185336-79-2) [=F-277], 1-(2,3-dihydro-2,2-dimethyl-1H-indenes-1-yl)-1H-imidazoles-5-methyl formate, 3,4,5-tri-is chloro-2,6-pyridine dimethoxy nitrile, 2-[[[cyclopropyl [(4-methoxyl group-phenyl) imino group] methyl] sulfo-] methyl]-α-(methoxyl group methylene) benzo methyl acetate (benzacetate) [=F-278], the chloro-alpha-propynyl oxygen base-N-[2-[3-of 4-methoxyl group-4-(2-propynyl oxygen base) phenyl] ethyl] benzo-acetamide [=F-279],(2S)-N-[2-[4-[[3-(4-chlorphenyl)-2-propynyl] oxygen base]-3-methoxyphenyl] ethyl]-3-methyl-2-[(methyl sulphonyl) amino] butyramide [=F-280], the chloro-7-of 5-(4-methyl piperidine-1-yl)-6-(2, 4, 6-trifluorophenyl) [1, 2, 4]-triazol [1, 5-a] pyrimidine [=F-281], the chloro-6-(2 of 5-, 4, the fluoro-phenyl of 6-tri-)-N-[(1R)-1, 2, 2-trimethyl propyl group]-[1, 2, 4] triazol [1, 5-a] pyrimidine-7-amine, the chloro-N-[(1R of 5-)-1, 2-dimethyl propyl]-6-(2, 4, 6-trifluorophenyl) [1, 2, 4] triazol [1, 5-a] pyrimidine-7-amine [=F-282], N-[1-(the bromo-3-chloropyridine-2-of 5-yl) ethyl]-2, 4-bis-chloro-nicotinamides [=F-283], N-(the bromo-3-chloropyridine-2-of 5-yl) methyl-2, the chloro-niacinamide of 4-bis-[=F-284], the iodo-3-propyl group of the 2-butoxy-6-chromene ninth of the ten Heavenly Stems-4-ketone [=F-285], N-(3-ethyl-3, 5, 5-trimethylcyclohexyl)-3-formoxyl amino-2-Hydroxylbenzamide, 2-[[[[1-[3 (the fluoro-2-phenylethyl of 1-) oxygen base] phenyl] ethylidene]-amino] oxygen base]-methyl]-α-(methoxyimino)-N-methyl-α E-benzo acetamide [=F-286], the chloro-5-of N-{2-[3-(trifluoromethyl) pyridine-2-yl] ethyl }-2-(trifluoromethyl) benzamide, N-(3', fluoro-xenyl-the 2-of the chloro-5-of 4'-bis-yl)-3-(difluoromethyl)-1-methyl isophthalic acid H-pyrazole-4-carboxamide [=F-287], N-(6-methoxyl group-3-pyridine radicals) cyclopropane carboxamide, 1-[(4-methoxyphenoxy) methyl]-2, 2-dimethyl propyl-1H-imidazoles-1-formic acid [=F-288], O-[1-[(4-methoxyphenoxy) methyl]-2, 2-dimethyl propyl]-1H-imidazoles-1-carbothioic acid [=F-289], 2-(2-{[6-(3-chloro-2-methyl phenoxy group)-5-FU-4-yl] oxygen base } phenyl)-2-(methoxyimino)-N-methylacetamide [=F-290], N-{ (Z)-[(cyclo propyl methoxy)-imino group] [6-(difluoro-methoxy)-2, 3-difluorophenyl]-methyl }-2-benzo acetamide [=F-291].
Even preferred object of the present invention is following:
the combined use of replying for the place inducing specific growth regulating that plant, the seed that grows described plant and/or described plant are grown under its normal habitat, preferably in the situation that not there is not extreme environmental conditions, thereby and increase the output of this type of treated plant.
Even preferred object of the present invention is compound (A), compound (A1) and be selected from following one or more, the preferred combined use of one or both fungicides particularly, it is replied for the place inducing specific growth regulating that plant, the seed that grows described plant and/or described plant are grown under its normal habitat, preferably in the situation that not there is not extreme environmental conditions, thereby and increase the output of this type of treated plant:
Biphenyl pyrrole bacterium amine [=F-26], fluorine pyrrole bacterium acid amides [=F-31], fluorine azoles bacterium aniline [F-36], pyrazoles naphthalene bacterium amine [F-40], sedaxane [=F41], 3-(difluoromethyl)-1-methyl-N-(3', 4', 5'-trifluoro-biphenyl base-2-yl)-1H-pyrazole-4-carboxamide [=F-42], Fluoxastrobin [F-47], fluoxastrobin [=F-53], pyraclostrobin [F-57], oxime bacterium ester [=F-60], epoxiconazole [=F-108], metconazole [=F-119], propiconazole [=F-123], prothioconazoles [=F-124], Tebuconazole [=F-127].
Even preferred object of the present invention is following:
the combined use of replying for the place inducing specific growth regulating that plant, the seed that grows described plant and/or described plant are grown under its normal habitat, preferably in the situation that not there is not extreme environmental conditions, thereby and increase the output of this type of treated plant.
Even preferred object of the present invention is following:
the combined use of replying for the place inducing specific growth regulating that plant, the seed that grows described plant and/or described plant are grown under its normal habitat, preferably in the situation that not there is not extreme environmental conditions, thereby and increase the output in this type of treated plant.
Even preferred object of the present invention is:
the combined use of replying for the place inducing specific growth regulating that plant, the seed that grows described plant and/or described plant are grown under its normal habitat, preferably in the situation that not there is not extreme environmental conditions, thereby and increase the output of this type of treated plant.。
Comprising following plant yield-increasing composition is still unknown in the art:
。
Therefore, the plant yield-increasing composition above limiting, preferably comprise and be selected from those of following combination as the mixture gametophyte of compound (A1): (i) pyraclostrobin (F-57) and metconazole (F-119), (ii) oxime bacterium ester (F-60) and propiconazole (F-123), (iii) prothioconazoles (F-124) and Tebuconazole (F-127), (iv) fluoxastrobin (F-53) and prothioconazoles (F-124), and (v) oxime bacterium ester (F-60) and prothioconazoles (F-124), (vi) biphenyl pyrrole bacterium amine (F-26) and prothioconazoles (F-124), (vii) biphenyl pyrrole bacterium amine (F-26) and Tebuconazole (F127), (viii) biphenyl pyrrole bacterium amine (F-26) and oxime bacterium ester (F-60), more preferably comprise and be selected from those of following combination as the mixture gametophyte of compound (A1): (i) pyraclostrobin (F-57) and metconazole (F-119), (ii) oxime bacterium ester (F-60) and propiconazole (F-123), (iii) biphenyl pyrrole bacterium amine (F-26) and prothioconazoles (F-124), also be a further object of the present invention.
In addition more specifically, treat to be selected from following with compound (A) insecticide that particularly compound (A1) combines:
Avermectin [=I-1], chlopyrifos [=I-2], clothianidin [=I-3], cyanogen insect amide [=I-4], decis [=I-5], emamectin-benzoate [=I-6], second worm nitrile [=I-7], ethiprole [=I-8], fipronil bisamide [=I-9], flupyradifurone [=I-10], Imidacloprid [=I-11], λ-cyhalothrin [=I-12], lufenuron [=I-13], Rynaxypyr [=I-14], pleocidin [=I-15], ethyl pleocidin (spinoteram) [=I-16], spiral shell worm ethyl ester [=I-17], sulfone worm pyridine [=I-18], Diacloden [=I-19], thiodicarb [=I-20], triflumuron [=I-21], votivo [=I-22].
Even preferred object of the present invention is following combined use of replying for the place inducing specific growth regulating that plant, the seed that grows described plant or described plant are grown under its normal habitat, preferably in the situation that not there is not extreme environmental conditions, thereby and increase the output of this type of treated plant:
。
Even more specifically, the combination partner about insecticide kind is selected from:
Avermectin [=I-1], chlopyrifos [=I-2], clothianidin [=I-3], fipronil [=I-8], flupyradifurone [=I-10], Imidacloprid [=I-11], λ-cyhalothrin [=I-12], lufenuron [=I-13], Rynaxypyr [=I-14], ethyl pleocidin [=I-16], spiral shell worm ethyl ester [=I-17], sulfone worm pyridine [=I-18], Diacloden [I=19], thiodicarb [=I-20], votivo [=I-22]
The combined use of replying for the place inducing specific growth regulating that plant, the seed that grows described plant or described plant are grown under its normal habitat, preferably in the situation that not there is not extreme environmental conditions, thereby and increase the output of this type of treated plant.
Even preferred object of the present invention is following:
the combined use of replying for the place inducing specific growth regulating that plant, the seed that grows described plant or described plant are grown under its normal habitat, preferably in the situation that not there is not extreme environmental conditions, thereby and increase the output of this type of treated plant.
Comprising following plant yield-increasing composition is still unknown in the art:
。
Therefore the composition, above limiting is also a further object of the present invention.
In addition more specifically, treat and compound according to the present invention (A) or compound (A1) combination, preferably treat to be selected from the plant growth regulator of compound (A1) combination:
Chlormequat (CCC) [=PGR-1], ethrel [=PGR-2], mepiquat chloride (mepiquat) [=PGR-3], anti-fall ester [=PGR-4], 2,4-D (=PGR-5), MCPA (=PGR-6) and 2,4-D choline (=PGR-7).
The object of present invention further optimization is following combined use of replying for the place inducing specific growth regulating that plant, the seed that grows described plant or described plant are grown under its normal habitat, preferably in the situation that not there is not extreme environmental conditions, thereby and increase the output of this type of treated plant:
。
Even preferred object of the present invention is
combined use.
Comprising following plant yield-increasing composition is still unknown in the art:
。
Therefore, this type of combination above limiting is also a further object of the present invention.
Even if but should be understood that and ask for protection in the situation that not there is not extreme environment stress conditions, the compound (A) above limiting, preferred compound (A1) and the preferable use of combination that is selected from one or more compounds of agrochemicals compound, but applied in any combination can be also useful under these circumstances: wherein this type of extreme environment stress conditions exists section sometime really, or preferably, be present in interim, wherein really do not exist the period of extreme environment stress conditions by being interrupted one or more periods that the extreme environmental conditions of identical or different kind wherein occurs really.
More specifically, with one or more agrochemicals compounds, preferably be selected from the compound (A) of the agrochemicals compound combination of fungicide, insecticide and plant growth regulator, the purposes of preferred compound (A1) not only shows the unexpected effect that output increases that relates to plant in the situation that not existing extreme environment to coerce, also to more over a long time, preferably several weeks, more preferably a couple of days is exposed to extreme environment stress conditions, preferably the plant of heat and/or drought stress shows and relates to the unexpected effect that output increases.
According to the present invention, find in addition, can by separately or with compound (A), the preferred compound (A1) of other agrochemicals compounds (be particularly above defined as from the preferred compound of fungicide, insecticide and plant growth regulator those) combination, with at least one Fertilizer Combination, be applied in plant or its environment.
Can be according to the present invention together with being generally organic and inorganic nitrogen-containing compound especially above above separately or with other agrochemicals compounds (be defined as from the preferred compound of the fungicide of illustrating in detail, insecticide and plant growth regulator those) compound (A) of combination, the fertilizer that preferred compound (A1) is used, for example urea, urea/formaldehyde condensation products, amino acid, ammonium salt and ammonium nitrate, sylvite (preferably chloride, sulphate, nitrate), the salt of phosphoric acid and/or the salt of phosphorous acid (preferably sylvite and ammonium salt).Under this background, be to be noted that NPK fertilizer, contain the fertilizer of nitrogen, phosphorus and potassium, nitro chalk, comprise in addition calcium or nitric acid-sulfuric acid ammonium (formula (NH
4)
2sO
4nH
4nO
3), the fertilizer of ammonium phosphate and ammonium sulfate.These fertilizer are that those skilled in the art are general known; Also referring to for example Ullmann's Encyclopedia of Industrial Chemistry, the 5th edition, A 10 volumes, 323-431 page, Verlagsgesellschaft, Weinheim, 1987.
Fertilizer can also contain salt (preferably calcium, sulphur, boron, manganese, magnesium, iron, boron, copper, zinc, molybdenum and cobalt) and plant hormone (for example vitamin B1 and indole-3-acetic acid) or its mixture of micronutrient.The fertilizer using according to the present invention can also contain further salt, for example MAP (MAP), diammonium phosphate (DAP), potassium sulfate, potassium chloride, magnesium sulfate.The appropriate amount of secondary nutrient or trace element is based on overall fertilizer, the amount of 0.5-5 % by weight.May composition be further crop production compositions, insecticide or fungicide, growth regulator or its mixture.This will be explained hereinafter in more detail.
Fertilizer can for example be used with the form of powder, granule, granule (prills) or compact (compactates).Yet fertilizer can also be used with the liquid form being dissolved in water-bearing media.In this case, can also use weak ammonia as nitrogenous fertilizer material.The further of fertilizer may component for example be described in Ullmann's Encyclopedia of Industrial Chemistry, and the 5th edition, 1987, the A 10 volumes, 363-401 page, DE-A 41 28 828, in DE-A 19 05 834 and DE-A 196 31 764.In the context of the present invention, can take the form of single fertilizer and/or composite fertilizer, can change general composition of the fertilizer being for example comprised of nitrogen, potassium or phosphorus in broad range.Generally speaking, the potassium content (preferably 3-15 % by weight) of the nitrogen content of 1-30 % by weight (preferably 5-20 % by weight), 1-20 % by weight and the phosphorus content (preferably 3-10 % by weight) of 1-20 % by weight are favourable.Micronutrient levels is conventionally in ppm scope, preferably in the scope of 1-1000 ppm.
In the context of the present invention, fertilizer and separately or with the compound (A) of other agrochemicals compounds (be particularly above defined as from the preferred compound of fungicide, insecticide and plant growth regulator those) combination, preferred compound (A1) simultaneously (synchronizeing) use.Yet, also can first apply fertilizer, and application subsequently separately or with compound (A), the preferred compound (A1) of other agrochemicals compounds (be particularly above defined as from the preferred compound of fungicide, insecticide and plant growth regulator those) combination, or first application separately or with compound (A), the preferred compound (A1) of other agrochemicals compounds (be particularly above defined as from the preferred compound of fungicide, insecticide and plant growth regulator those) combination, and apply subsequently fertilizer.Yet, separately or (be particularly above defined as from fungicide with other agrochemicals compounds, those of the preferred compound of insecticide and plant growth regulator) compound (A) of combination, preferred compound (A1), in the situation of the non-synchronous use of fertilizer, described other agrochemicals compounds are especially above defined as from fungicide, those of the preferred compound of insecticide and plant growth regulator, being applied in functional relationship in the context of the present invention, especially at general 24 hours, preferably 18 hours, more preferably 12 hours, particularly 6 hours, more especially 4 hours, even more especially in the period in 2 hours, realize.In very specific embodiment of the present invention, separately or with compound (A), the preferred compound (A1) of other agrochemicals compounds (be particularly above defined as from the preferred compound of fungicide, insecticide and plant growth regulator those) combination, and fertilizer is being less than 1 hour, is preferably being less than 30 minutes, is being more preferably less than in the time range in 15 minutes and applies.
Can be for following plant for the active component that uses according to the present invention, nonrestrictive enumerating below for example.
As term used herein " useful plant " refers to obtain food, animal feed, fuel or for the crop plants of the plant of industrial use with acting on, also comprise ornamental plants, turf, in public and family field, be used as the conventional tree of ornamental plants, and forest.Forest comprises the tree for the production of timber, cellulose, paper and the product made by the part of setting.
Useful plant comprises for example plant of following type: cereal is wheat, barley, rye, triticale, Du Lunmai (durum wheat), oat, lupulus, rice, corn, millet/Chinese sorghum and maize for example; Beet is sugar beet and fodder beet for example; Fruit is for example apple, pears, plum, peach, apricot, cherry of a kind of fruit, such as apple, pear, etc., drupe and mushy fruit for example, and berry for example strawberry, raspberry, blackberry, blueberry; Beans is beans, lentil, pea and soybean for example; Oil crop are oilseed rape, leaf mustard, opium poppy, olive, sunflower, coconut, castor oil plant, cocoa bean and peanut for example; Melon for example pumpkin/pumpkin, cucumber and muskmelon; Fibre plant is cotton, flax, hemp and jute for example; Citrus fruit is orange, lemon, grapefruit and red tangerine for example; Vegetables are spinach, lettuce, asparagus, wild cabbage species, carrot, onion, tomato, potato and green pepper for example; Lauraceae (Lauraceae) for example avocado, Cinnamomum (
cinnamonum), for example tobacco, nut, coffee, eggplant, sugarcane, tea, capsicum, grape, grape vine, lupulus, banana, rubber plant, ornamental plants are for example spent for camphor tree or other plant, shrub, deciduous tree and coniferous tree, and for the plant on turf and lawn.This is enumerated and is not construed as limiting.
Following plant is considered as the specially suitable target crop to purposes of the present invention or method: oat, rye, triticale, Du Lunmai, cotton, eggplant, turf, a kind of fruit, such as apple, pear, etc., drupe, mushy fruit, corn, wheat, barley, cucumber, tobacco, grape, rice, cereal, pears, capsicum, beans, soybean, oilseed rape, tomato, green pepper, muskmelon, wild cabbage, potato and apple.
The example of the tree that can improve according to the inventive method comprises: abies species (
abiessp.), eucalyptus species (
eucalyptussp.), Picea species (
piceasp.), Pinus species (
pinussp.), Aesculus species (
aesculussp.), plane species (
platanussp.), Tilia species (
tiliasp.), Acer species (
acersp.), Hemlock species (
tsugasp.), Ash species (
fraxinussp), Sorbus species (
sorbussp.), Betula species (
betulasp.), May species (
crataegussp.), Elm species (
ulmussp.), oak species (
quercussp.), beech species (
fagussp.), Salix species (
salixsp.), Populus species (
populussp.).
The preferred tree that can improve according to the inventive method comprises: from the seeds of Aesculus: European horse-chestnut (
a. hippocastanum), bottlebrush buckeye (
a. pariflora), Aesculus pavia (
a. carnea); Seeds from plane: two ball plane trees (
p. aceriflora), a ball plane tree (
p. occidentalis), poly-fruit plane tree (
p. racemosa); Seeds from Picea: European spruce (
p. abies); Seeds from Pinus: pine (
p. radiate), ponderosa pine (
p. ponderosa), pinus contorta (
p. contorta), Scotland pine (
p. sylvestre), wet-land pine tree (
p. elliottii), western kahikatea (
p. montecola), Chinese lace-bark pine (
p. albicaulis), greasiness pine (
p. resinosa), longleaf pine (
p. palustris), torch pine (
p. taeda), Lin Baisong (
p. flexilis), black material pine (
p. jeffregi), pinus banksiana (
p. baksiana), North America Himalayan pine (
p. strobes); The seeds that belong to from eucalyptus: alpine ash (
e. grandis), blue gum (
e. globulus),
e. camadentis, bright fruit eucalyptus (
e. nitens), tasmanian oak (
e. obliqua), almond eucalyptus (
e. regnans), circle fruit eucalyptus (
e. pilularus).
The particularly preferred tree that can improve according to the inventive method comprises: from the seeds of Pinus: pine, ponderosa pine, pinus contorta, Scotland pine, North America Himalayan pine; The seeds that belong to from eucalyptus: alpine ash, blue gum and
e. camadentis.
The particularly preferred tree that can improve according to the inventive method comprises: horse chestnut, plane tree (
platanaceae), lime tree, maple.
The present invention can also be applied to any turfgrass, comprises cold-season turfgrass and warm season turf.The example of cold-season turfgrass be annual bluegrass (Poa L. species (
poaspp.)), for example kentucky blue grass (kentucky blue grass (
poa pratensisl.)), rough bluegrass (rough stalked blue grass (
poa trivialisl.)), Canada blue grass (Canada blue grass (
poa compressal.)), annual annual bluegrass (annual bluegrass (
poa annual.)), highland annual bluegrass (highland annual bluegrass (
poa glaucanthagaudin)), forest land annual bluegrass (forest land annual bluegrass (
poa nemoralisl.)) and bulb annual bluegrass (bulb annual bluegrass (
poa bulbosal.)); Bent grass (Agrostis species (
agrostisspp.)), for example crawl bent grass (agrostis stolonifera (
agrostis palustrishuds.)), thin and delicate bent grass (thin and delicate bent grass (
agrostis tenuissibth.)), velvet bent grass (velvet bent grass (
agrostis caninal.)), south Germany mixes bent grass (Agrostis species comprise thin and delicate bent grass, velvet bent grass and agrostis stolonifera), and redtop (redtop (
agrostis albal.));
Fescue (Festuca species (
festucaspp.)), for example chewing fescue (for example chewing fescue (
festuca rubral. spp. rubra)), the fescue grass of crawling (fescue grass of crawling (
festuca rubral.)), Qiu Shi fescue grass (Qiu Shi fescue grass (
festuca rubra commutatagaud.)), fescue grass (wild fescue grass (
festuca ovinal.)), hard fescue (hard fescue (
festuca longifoliathuill.)), spire fescue grass (spire fescue grass (
festuca capillatalam.)), Festuca Arundinacea (Festuca Arundinacea (
festuca arundinaceaschreb.)) and meadow fescue (and meadow fescue (
festuca elanorl.));
Perennial ryegrass (Lolium species (
loliumspp.)), for example annual ryegrass (Annual Ryegrass (
lolium multiflorumlam.)), English ryegrass (English ryegrass (
lolium perennel.)) and Annual Ryegrass (Annual Ryegrass (
lolium multiflorumlam.));
And wheatgrass (Agropyron species (
agropyronspp.)), for example crested wheat grass (crested wheat grass (
agropyron cristatum(L.) Gaertn.)), light fringe wheatgrass (husky raw wheatgrass (
agropyron desertorum(Fisch.) Schult.)) and west wheatgrass (blue stem wheat straw (
agropyron smithiirydb.)).
Further the example of cold-season turfgrass be beach grass (America happiness sand-grass (
ammophila breviligulatafern.)), awnless brome (awnless brome (
bromus inermisleyss.)), cattail for example timothy grass (timothy grass (
phleum pratensel.)), husky cattail (husky cattail (
phleum subulatuml.)), orchard grass (orchardgrass (
dactylis glomeratal.)), alkali thatch (alkali thatch (
puccinellia distans(L.) Parl.)) and crested dogstail (crested dogstail (
cynosurus cristatusl.)).
The example of warm season turf be Bermuda grass (Bermuda grass (
cynodonspp. L. C. Rich)), Korea lawn grass (Korea lawn grass (
zoysiaspp. Willd.)), saint augustine grass (saint augustine grass (
stenotaphrum secundatumwalt Kuntze)), centipede grass (centipede grass (
eremochloa ophiuroidesmunro Hack.)), carpetweed (class carpetweed (
axonopus affinischase)), paspalum notatum (Bahiagrass (
paspalum notatumflugge)), hidden colored pearl millet (Kikuyugrass (
pennisetum clandestinumhochst. ex Chiov.)), buffalograss (buffalograss (
buchloe dactyloids(Nutt.) Engelm.)), gramagrass (gramagrass (
bouteloua gracilis(H.B.K.) Lag. ex Griffiths)), seashore paspalum (paspalum vaginatum (
paspalum vaginatumswartz)) and tall grama (tall grama (
bouteloua curtipendula(Michx. Torr.)).Cold-season turfgrass is generally preferred for according to purposes of the present invention.Especially preferred is annual bluegrass, bent grass and redtop, fescue and perennial ryegrass.Bent grass is especially preferred.
The particularly preferred scheme providing according to the present invention is the plant of processing plant cultivation kind, its be in each case obtained commercially or in use.Plant cultivation kind is interpreted as meaning such plant, and it has new property (" proterties "), and by conventional breeding, obtain by mutagenesis or by means of recombinant DNA technology.Crop plants can be correspondingly such plant; it can be by following acquisition: conventional breeding and optimization method; or by the combination of biotechnology and gene engineering method or these methods, comprise genetically modified plants and comprise can with the plant variety that can not be protected by plant breeder's right.
Processing method of the present invention therefore also can for example, for the treatment of the biology (GMO) of genetic modification, plant or seed.The plant of genetic modification (or genetically modified plants) be wherein heterologous gene stable integration to the plant in genome.Statement " heterologous gene " means such gene substantially, it provides outward or assembles plant, and when introducing in core, chloroplast or mitochondrial genomes, by expressing destination protein matter or polypeptide or being present in one or more other genes (using for example antisense technology, co-suppression technology or RNAi technology [RNA interference]) in plant by downward or silence, give the plant through transforming agricultural or other character new or that improve.Be positioned heterologous gene in genome also referred to as transgenosis.The transgenosis that ad-hoc location by it in Plant Genome limits is called as conversion or transgenic event.
Processing method of the present invention can be further used for processing the biology (GMO) of genetic modification, and for example wherein heterologous gene, for example, is used viral vectors, instantaneous exotic plant or seed.
Plant and the plant variety preferably according to the present invention, processed comprise all plants with genetic stocks, and described genetic stocks is given particularly advantageous useful proterties (no matter obtaining by breeding and/or biotechnology mode) to these plants.
The plant that can also process according to the present invention and plant variety are those plants that are characterised in that the output feature of enhancing.The output strengthening in described plant can be the plant physiology for example improving, the result of g and D, and for example water service efficiency, water retain the nitrogen use of efficiency, improvement, carbon assimilation, the photosynthesis of improvement, the germination efficiency of increase and the maturation of acceleration strengthening.Output can also be by improving families of plant structure (coerce with non-stress condition under) realize, comprise that early flowering, the control of blooming, seedling vigor, plant size, internode number and distance, root growth, seed size, fruit size, pod size, pod or ear spike number, seed number/pod or the ear fringe for hybrid seed, produced, seed quality, the seed filling of enhancing, the pod of the seed dispersal of minimizing, minimizing ftracture and lodging resistance.Further yield traits comprises that seed forms, and for example the minimizing of carbohydrate content, protein content, oil content and composition, nutritive value, anti-nutrient compounds is, the bin stability of the processability of improvement and Geng Jia.
The plant of can be equally processing according to the present invention is hybrid plant, and it has expressed heterotic feature or hybrid vigour, and it causes higher output, vigor, health and conventionally for the resistance of biology and abiotic stress factor.Conventionally by making, selfing male sterile parent line (female parent) and another selfing are male can educate parent line (male parent) hybridization and be prepared this type of plant.Grower is gathered in the crops and be sold to hybrid seed from male sterile plant conventionally.Male sterile plant sometimes (for example, in corn) can produce by emasculation (machinery that is male reproductive organ or male flower is removed), but more generally, male sterile is the result of the hereditary factor in Plant Genome.In this case, and especially when seed be until by hybrid plant, gathered in the crops required product time, guarantee that the male fertility in hybrid plant is recover completely normally useful, described hybrid plant contains is responsible for male sterile hereditary factor.This can be by guaranteeing that male parent has suitable fertilizability recovery gene and realizes, and described fertilizability is recovered gene can recover the male fertility in hybrid plant, and described hybrid plant contains is responsible for male sterile hereditary factor.About male sterile hereditary factor, can be positioned in cytoplasm.The example of cytoplasmic male sterility (CMS) has been described, for example for Brassicas (
brassica) species (WO 1992/005251, WO 1995/009910, WO 1998/27806, WO 2005/002324, WO 2006/021972 and US 6,229,072).Yet, about male sterile hereditary factor, can also be positioned in nuclear gene group.Male sterile plants can also by Plant Biotechnology method for example gene engineering obtain.The useful especially method that obtains male sterile plants is described in WO 89/10396, wherein for example selective expression's ribalgilase, for example barnase (barnase) in the tapetal cell in stamen.Fertilizability subsequently can be by expressing ribonuclease inhibitor in tapetal cell, for example barstar (barstar) and be restored (for example WO 1991/002069).
The plant that can also process according to the present invention or plant variety (by Plant Biotechnology method for example gene engineering obtain) be herbicide-resistant plant, one or more given weed killer herbicides are produced the plant of tolerance.This type of plant can obtain by genetic transformation or the plant that contains the sudden change of giving this type of herbicide tolerance by selection.
Herbicide-resistant plant is glyphosate tolerant plant for example, herbicide glyphosate or its salt is produced the plant of patience.For example, glyphosate tolerant plant can be by with codase: the gene-transformed plant of 5-enol acetone shikimic acid-3-phosphate synthase (EPSPS) obtains.The example of this type of EPSPS gene be bacterium salmonella typhimurium (
salmonella typhimurium) AroA gene (mutant CT7) (people such as Comai, Science (1983), 221,370-371), bacterium agrobacterium species (
agrobacteriumsp.) the CP4 gene (people such as Barry, Curr. Topics Plant Physiol. (1992), 7,139-145), the coding petunia EPSPS (people such as Shah, Science (1986), 233,478-481), tomato EPSPS (people such as Gasser, J. Biol. Chem. (1988), 263,4280-4289) Huo Finger-millet belong to (
eleusine) gene of EPSPS (WO 2001/66704).It can also be the EPSPS of sudden change, described in for example EP-A 0837944, WO 2000/066746, WO 2000/066747 or WO 2002/026995.Glyphosate tolerant plant can also obtain by the encode gene of glyphosate oxidoreductase of expression, as US 5,776,760 and US 5,463,175 in describe.Glyphosate tolerant plant can also obtain by the encode gene of glyphosate acetyl transferase of expression, as for example described in WO 2002/036782, WO 2003/092360, WO 2005/012515 and WO 2007/024782.The plant of the natural existence sudden change that glyphosate tolerant plant can also contain said gene by selection obtains, as described in for example WO 2001/024615 or WO 2003/013226.The plant of expressing the EPSPS gene of conferring glyphosate patience is described in for example U.S. Patent Application No. 11/517,991,10/739,610,12/139,408,12/352,532,11/312,866,11/315,678,12/421,292,11/400,598,11/651,752,11/681,285,11/605,824,12/468,205,11/760,570,11/762,526,11/769,327, in 11/769,255,11/943801 or 12/362,774.Other genes that the comprise conferring glyphosate patience for example plant of decarboxylase gene are for example described in U.S. Patent application 11/588,811,11/185,342,12/364,724,11/185,560 or 12/423,926.
Other herbicide resistant plants are for example to suppressing the weed killer herbicide of glutamine synthase, to produce the plant of patience, and described weed killer herbicide is bialaphos, phosphine oxamate (phosphinothricin) or careless fourth phosphine (glufosinate) for example.This type of plant can be made the enzyme of weed killer herbicide removing toxic substances or be obtained suppressing the saltant type glutamine synthase of resistance by expression, for example, in U.S. Patent Application No. 11/760,602, describe.A kind of this type of efficient solution toxenzyme be for example encode phosphine oxamate transacetylase enzyme (for example from streptomyces (
streptomyces) bar or the pat protein of species).The plant of expressing external source phosphine oxamate transacetylase is for example described in US 5,561,236; US 5,648, and 477; US 5,646, and 024; US 5,273, and 894; US 5,637, and 489; US 5,276, and 268; US 5,739, and 082; US 5,908,810 and US 7,112,665 in.
Further herbicide-resistant plant is also to suppressing the weed killer herbicide of hydroxyphenylpyruvate dioxygenase (HPPD), to produce the plant of tolerance.Hydroxyphenylpyruvate dioxygenase is the enzyme that catalysis ethyl-para-hydroxyphenyl ketone acid (HPP) changes into the reaction of alcapton.To the plant of HPPD inhibitor tolerance, can use the genetic transformation of the naturally occurring resistance HPPD enzyme of coding, for example, from the HPPD enzyme of non-plant biology, for example in WO 2011/076877, WO 2011/076882, WO2011/076892, WO 2011/076885, WO2011/076889, describe, or from monocotyledon for example oat (
avena sativa) or maize (
zea mays) HPPD enzyme, or there is the HPPD enzyme of at least 98% sequence homogeneity with oat or zeistic enzyme, or the HPPD enzyme described in WO/2011/076885, WO2011/076892, WO/2011/076877, WO/2011/076882, WO/2011/076889, or according to WO 1996/038567, WO 1999/024585 and WO 1999/024586 WO 2009/144079, WO 2002/046387, WO/2011/068567, WO/2010/085705 or US 6, the gene of 768,044 encoding mutants or chimeric HPPD enzyme.To the patience of HPPD inhibitor, can also obtain by the encode gene-transformed plant of some enzyme of use, described enzyme can form alcapton, although natural HPPD enzyme is subject to the inhibition of HPPD inhibitor.This type of plant and gene are described in WO 1999/034008 and WO 2002/36787.Plant can also add that the gene-transformed plant of coding HPPD patience enzyme improves by the encode gene of prephenate dehydrogenase of use to the patience of HPPD inhibitor, as described in WO 2004/024928.
Further herbicide resistant plants is acetolactate synthase (ALS) inhibitor have been produced the plant of tolerance.Known ALS inhibitor comprises for example sulfonylureas, imidazolone, triazolo pyrimidine, pyrimidine radicals oxygen base (sulfo-) benzoic ether and/or sulfonyl amino carbonyl triazolinone herbicide.It is known that at ALS enzyme, (also referred to as acetohydroxy acid synthase, the difference sudden change in AHAS) is given to different weed killer herbicides and weed killer herbicide group resistance, as for example Tranel and Wright, Weed Science (2002), 50,700-712 and US 5,605,011, US 5,378, and 824, US 5,141,870 and US 5,013,659 in describe.The generation of resistance to sulfonylureas plant and resistance to imidazolone plant is described in US 5,605,011; US 5,013, and 659; US 5,141, and 870; US 5,767, and 361; US 5,731, and 180; US 5,304, and 732; US 4,761, and 373; US 5,331, and 107; US 5,928, and 937; With US 5,378, in 824; And also in International Publication WO 1996/033270.Further resistance to imidazolone plant is also for example described in WO 2004/040012, WO 2004/106529, WO 2005/020673, WO 2005/093093, WO 2006/007373, WO 2006/015376, WO 2006/024351 and WO 2006/060634.Further resistance to sulfonylureas plant and resistance to imidazolone plant are also described in for example WO 2007/024782 and U.S. Patent Application No. 61/288958.
Can be by following acquisition to the other plant of imidazolone and/or sulfonylureas tolerance: selection or mutational breeding in induced mutation, the cell cultivation under the existence of weed killer herbicide, as for example for soybean at US 5,084, describe in 082, for rice, in WO 1997/41218, describe, for sugar beet at US 5,773,702 and WO 1999/057965 in describe, for lettuce at US 5, in 198,599, describe, or describe in WO 2001/065922 for sunflower.
The plant that can also process according to the present invention or plant variety (by Plant Biotechnology method for example gene engineering obtain) be insect-resistant transgenic plants, some target attack of insect is produced the plant of resistance.This type of plant can obtain by genetic transformation or the plant that contains the sudden change of giving this type of insect-resistant by selection.
In this context, term " insect-resistant transgenic plants " comprises and contains at least one genetically modified any plant, and described transgenosis comprises the following coded sequence of coding:
1) from bacillus thuringiensis (
bacillus thuringiensis) insecticidal crystal protein or its kill insect part, such as by people such as Crickmore, Microbiology and Molecular Biology Reviews (1998), 62, 807-813 compilation, by the people such as Crickmore (2005), in bacillus thuringiensis toxin nomenclature, upgrade (online address: insecticidal crystal protein http://www.lifesci.sussex.ac.uk/Home/Neil_Crickmore/Bt/), or it kills insect part, Cry kinds of protein Cry1Ab for example, Cry1Ac, Cry1F, Cry2Ab, the protein of Cry3Ae or Cry3Bb or its this proteinoid of killing insect part (for example EP 1999141 and WO2007/107302) or being encoded by synthetic gene, as for example U.S. Patent Application No. 12/249, in 016, describe, or
2) insecticidal under the existence of the second crystalline protein except bacillus thuringiensis or its part, insecticidal crystal protein or its part from bacillus thuringiensis, such as the binary toxin being formed by Cy34 and the Cy35 crystalline protein (people such as Moellenbeck, Nat. Biotechnol. (2001), 19,668-72; The people such as Schnepf, Applied Environm. Microb. (2006), 71,1765-1774); Or
3) comprise the hybrid insecticidal protein from the part of two of bacillus thuringiensis different insecticidal crystal proteins, for example above 1) hybrid of the protein hybrid of protein or above 2), the Cry1A.105 protein for example being produced by corn event MON98034 (WO 2007/027777); Or
4) above 1) to 3) any one protein in point, some of them amino acid, 1-10 amino acid particularly, replaced with another amino acid, to obtain the higher insecticidal activity for target insect species, and/or expand the scope of the target caste affecting, and/or due to the variation of inducing in coding DNA in clone or conversion process, the for example Cry3Bb1 protein in corn event MON863 or MON88017, or the Cry3A protein in corn event mir 604; Or
5) from bacillus thuringiensis or Bacillus cercus (
bacillus cereus) desinsection secreted protein or its desinsection part, the Vegetative Insecticidal Proteins of for example listing under following link (VIP), for example, from the protein of VIP3Aa kinds of protein: http://www.lifesci.sussex.ac.uk/Home/Neil_Crickmore/Bt/vip.html, or
6) insecticidal under the existence of the second secreted protein from bacillus thuringiensis or Bacillus cercus, from the secreted protein of bacillus thuringiensis or Bacillus cercus, the binary toxin for example being formed by VIP1A and VIP2A protein (WO 1994/21795); Or
7) comprise the hybrid insecticidal proteins from the part of the different secretory proteins of bacillus thuringiensis or Bacillus cercus, for example 1 above) in the hybrid or above 2 of protein) in the hybrid of protein; Or
8) above 1) to 3) any one protein in point, some of them amino acid, 1-10 amino acid particularly, replaced with another amino acid, to obtain the higher insecticidal activity for target insect species, and/or the scope of the target caste that affects of expansion, and/or for example, due to the variation of inducing in coding DNA in clone or conversion process (simultaneously still encoding insecticidal proteins), the VIP3Aa protein in cotton event COT 102.
Certainly, as used herein, insect-resistant transgenic plants also comprises any plant, the combination that it comprises the gene of the protein of any in the kind 1-8 above of encoding.In one embodiment, zoophobous contains and surpasses a transgenosis, the protein of any in its kind 1-8 above of encoding, with by using identical target insect species desinsection but thering are the different modes of action, for example, from the different proteins of different receptor binding site combinations in insect, the scope of the target caste that expansion affects, or postpone the development of insect to plant resistance to environment stress.
As used herein, " insect-resistant transgenic plants " further comprises and contains at least one genetically modified any plant, described transgenosis produces the sequence of double-stranded RNA after being included in and expressing, described double-stranded RNA suppresses the growth of this insect pest after being taken in by plant insect pest, as for example described in WO 2007/080126, WO 2006/129204, WO 2007/074405, WO 2007/080127 and WO 2007/035650.
The example of anti-nematode plant is in for example U.S. Patent Application No. 11/765,491,11/765,494,10/926,819,10/782,020,12/032,479,10/783,417,10/782,096,11/657,964,12/192,904,11/396,808,12/166,253,12/166,239,12/166,124,12/166,209,11/762,886,12/364,335,11/763,947,12/252,453,12/209,354, describe in 12/491,396 or 12/497,221.
The plant that can also process according to the present invention or plant variety (by Plant Biotechnology method for example gene engineering obtain) abiotic stress factor is tolerated.This type of plant can obtain by genetic transformation or the plant that contains the sudden change of giving this type of stress resistance by selection.Useful especiallyly resistance toly coerce plant and comprise following:
A. contain poly-(ADP-ribose) polymerase (PARP) gene expression and/or the active genetically modified plant that can reduce in plant cell or plant, as described in WO 2000/004173 or EP 04077984.5 or EP 06009836.5;
B. the expression and/or the active stress tolerance that contain the PARG encoding gene that can reduce plant or plant cell strengthen genetically modified plant, as for example described in WO 2004/090140;
C. the stress tolerance that contains the plant function enzyme of coding NADH salvage biosynthetic pathways strengthens genetically modified plant, described enzyme comprises nicotinamidase, nicotinate phosphoribosyltransferase, NAMN adenylyl transferase, NADH synzyme or nicotinamide phosphoribosyl transferase, as described in for example EP 04077624.7 or WO 2006/133827 or PCT/EP07/002433.
The plant that can also process according to the present invention or plant variety (by Plant Biotechnology method for example gene engineering obtain) show change quantity, quality and/or the bin stability of results product, and/or the change character of the special component of results product, for example:
1) genetically modified plants of synthesis modification starch, the change with regard to its Chemical Physics proterties of described modified starch, particularly compare with the synthetic starch in wild-type plant cell or plant, the amylose content of starch or amylose/amylopectin ratios, the degree of branching, average chain length, side chain distribution, viscosity behavior, gel resistance, granularity and/or particle shape, thus this modified starch is more suitable in some application.These genetically modified plants of synthesis modification starch are for example in following middle description:
。
2) do not compare with there is no the wild-type plant of genetic modification, synthetic non-starch carbohydrate polymer or the synthetic genetically modified plants with the non-starch carbohydrate polymer that changes character.Example is to produce the especially plant of inulin and levulan type of polyfructosan, as EP 0663956, WO 1996/001904, WO 1996/021023, in WO 1998/039460 and WO 1999/024593, describe, produce α-1, the plant of 4-glucan, as WO 1995/031553, US 2002/031826, US 6, 284, 479, US 5, 712, 107, WO 1997/047806, WO 1997/047807, in WO 1997/047808 and WO 2000/14249, describe, produce α-1, 6-branched alpha-1, the plant of 4-glucan, as described in WO 2000/73422, with the plant that produces alternan (alternan), as WO 2000/047727, EP 06077301.7, US 5, 908, 975 and EP 0728213 in describe.
3) produce hyaluronic genetically modified plants, as for example described in WO 2006/032538, WO 2007/039314, WO 2007/039315, WO 2007/039316, JP 2006/304779 and WO 2005/012529.
4) genetically modified plants or hybrid plant, for example ' high dissolubility solids content ', ' low irritant ' be (LP) and/or ' long store ' onion (LS) for example to have feature, as what describe in U.S. Patent Application No. 12/020,360 and 61/054,026.
The plant that can also process according to the present invention or plant variety (by Plant Biotechnology method for example gene engineering obtain) be the plant with the fiber characteristics of change, for example vegetable lamb.This type of plant can obtain by the plant of genetic transformation or the sudden change that contains the fiber characteristics of giving this type of change by selection, and comprises:
A) plant vegetable lamb for example, it contains the cellulose synthase gene changing form, as described in WO 1998/000549;
B) plant vegetable lamb for example, it contains rsw2 or the rsw3 homologous nucleic acid changing form, as described in WO 2004/053219;
C) plant vegetable lamb for example, the increase that it contains sucrose phosphosynthase is expressed, as described in WO 2001/017333;
D) plant vegetable lamb for example, the increase with sucrose synthase is expressed, as described in WO 02/45485;
E) plant vegetable lamb for example, wherein 3-dextranase was lowered and was changed for example by fiber selectivity β-1 opportunity of the protoplasmic connection gate on fibrocellular basis, as described in WO 2005/017157;
F) plant vegetable lamb for example, it for example has by N-acetyl-glucosamine transferase gene, comprises nodC, and the expression of chitin synthase gene and have reactive fiber of change, as described in WO 2006/136351.
The plant that can also process according to the present invention or plant variety (by Plant Biotechnology method for example gene engineering obtain) be the plant with the oily overview feature of change, for example oilseed rape or relevant Brassica plants.This type of plant can obtain by the plant of genetic transformation or the sudden change that contains the oily feature of giving this type of change by selection, and comprises:
A) plant oilseed rape plant for example, its generation has the oil of high oleic acid content, as what describe in for example US 5,969,169, US 5,840,946 or US 6,323,392 or US 6,063,947;
B) plant oilseed rape plant for example, its generation has the oil of low linolenic content, as what describe in for example US 6,270,828, US 6,169,190 or US 5,965,755;
C) plant oilseed rape plant for example, its generation has the oil of low-level saturated fatty acid, as what describe in for example US 5,434,283 or U.S. Patent Application No. 12/668303.
The plant that can also process according to the present invention or plant variety (its can by Plant Biotechnology method for example gene engineering obtain) be the plant with the seed shattering feature of change, for example oilseed rape or relevant Brassica plants.This type of plant can obtain by the plant of genetic transformation or the sudden change that contains the seed shattering feature of giving this type of change by selection, and comprise that plant for example has the oilseed rape plant of the seed shattering that postpones or reduce, as U.S. Patent Application No. 61/135, in 230, WO09/068313 and WO10/006732, describe.
The useful especially genetically modified plants that can process according to the present invention are plants of one or more genes of comprising one or more toxin of encoding, it and is obtainable genetically modified plants under following trade (brand) name: YIELD GARD (corn for example, cotton, soybean), KnockOut (for example corn), BiteGard (for example corn), BT-Xtra (for example corn), Bollgard (cotton), Nucotn (cotton), Nucotn 33B (cotton), NatureGard (for example corn), Protecta, Agrisure (corn), Herculex (corn), MaizeGard (corn), MaxGard (corn), TwinLink (cotton), VIPCot (cotton), Widestrike (cotton) and NewLeaf (potato).The example of the herbicide-resistant plant that can mention is obtainable corn variety, cotton variety and soybean varieties under following trade (brand) name: Roundup Ready is (to glyphosate tolerance, for example corn, cotton, soybean), Glytol is (to glyphosate tolerance, cotton), Liberty Link (tolerates phosphine oxamate, for example oilseed rape, cotton, soybean), IMI (to imidazolone tolerance), Optimum Gat (to sulfonylureas and glyphosate tolerance) and SCS (tolerate sulfonylureas, corn for example) and Enlist (to 2,4-D and glyphosate tolerance).The herbicide resistant plants that can mention (plant of breeding under the usual manner for herbicide tolerance) is included in the lower kind of selling of title Clearfield (for example corn).Have improve feature further genetically modified plants kind in trade name, comprise that InVigor (canola), Amflora (potato) Mavera (corn) are lower to sell.The kind that contains different event can be sold under trade name comprises SmartStax.
Useful especially genetically modified plants that can the processing according to the present invention are such plants, the combination that it comprises transformation event or transformation event, and list in the database of for example multiple country management organization, comprise event 1143-14A (cotton, insect control, not preservation is described in WO2006/128569); Event 1143-51B (not preservation is described in WO2006/128570 for cotton, insect control); Event 1445 (not preservation is described in US2002120964 or WO2002/034946 for cotton, herbicide tolerance); Event 17053 (rice, herbicide tolerance, as PTA-9843 preservation, are described in WO2010/117737); Event 17314 (rice, herbicide tolerance, as PTA-9844 preservation, are described in WO2010/117735); Event 281-24-236 (cotton, insect control-herbicide tolerance, as PTA-6233 preservation, are described in WO2005/103266 or US2005216969); Event 3006-210-23 (cotton, insect control-herbicide tolerance, as PTA-6233 preservation, are described in US2007143876 or WO2005/103266); Event 3272 (corn, qualitative character, as PTA-9972 preservation, are described in WO2006098952 or US2006230473); Event 40416 (corn, insect control-herbicide tolerance, as ATCC PTA-11508 preservation, are described in WO2011/075593); Event 43A47 (corn, insect control-herbicide tolerance, as ATCC PTA-11509 preservation, are described in WO2011/075595); Event 5307 (corn, insect control, as ATCC PTA-9561 preservation, are described in WO2010/077816); Event ASR-368 (bent grass, herbicide tolerance, as ATCC PTA-4816 preservation, are described in US2006162007 or WO2004053062); Event B16 (not preservation is described in US2003126634 for corn, herbicide tolerance); Event BPS-CV127-9 (soybean, herbicide tolerance, as NCIMB No. 41603 preservations, are described in WO2010/080829); Event CE43-67B (cotton, insect control, as DSM ACC2724 preservation, are described in US2009217423 or WO2006/128573); Event CE44-69D (not preservation is described in US20100024077 for cotton, insect control); Event CE44-69D (cotton, insect control,Not preservation is described in WO2006/128571); Event CE46-02A (not preservation is described in WO2006/128572 for cotton, insect control); Event COT102 (not preservation is described in US2006130175 or WO2004039986 for cotton, insect control); Event COT202 (not preservation is described in US2007067868 or WO2005054479 for cotton, insect control); Event COT203 (not preservation is described in WO2005/054480 for cotton, insect control); Event DAS40278 (corn, herbicide tolerance, as ATCC PTA-10244 preservation, are described in WO2011/022469); Event DAS-59122-7 (corn, insect control-herbicide tolerance, as ATCC PTA 11384 preservations, are described in US2006070139); Event DAS-59132 (not preservation is described in WO2009/100188 for corn, insect control-herbicide tolerance); Event DAS68416 (soybean, herbicide tolerance, as ATCC PTA-10442 preservation, are described in WO2011/066384 or WO2011/066360); Event DP-098140-6 (corn, herbicide tolerance, as ATCC PTA-8296 preservation, are described in US2009137395 or WO2008/112019); Event DP-305423-1 (not preservation is described in US2008312082 or WO2008/054747 for soybean, qualitative character); Event DP-32138-1 (corn, crossing system, as ATCC PTA-9158 preservation, are described in US20090210970 or WO2009/103049); Event DP-356043-5 (soybean, herbicide tolerance, as ATCC PTA-8287 preservation, are described in US20100184079 or WO2008/002872); Event EE-1 (not preservation is described in WO2007/091277 for eggplant, insect control); Event FI117 (corn, herbicide tolerance, as ATCC 209031 preservations, are described in US2006059581 or WO1998/044140); Event GA21 (corn, herbicide tolerance, as ATCC 209033 preservations, are described in US2005086719 or WO1998/044140); Event GG25 (corn, herbicide tolerance, as ATCC 209032 preservations, are described in US2005188434 or WO1998/044140); Event GHB119 (cotton,Insect control-herbicide tolerance as ATCC PTA-8398 preservation, is described in WO2008/151780); Event GHB614 (cotton, herbicide tolerance, as ATCC PTA-6878 preservation, are described in US2010050282 or WO2007/017186); Event GJ11 (corn, herbicide tolerance, as ATCC 209030 preservations, are described in US2005188434 or WO1998/044140); Event GM RZ13 (sugar beet, virus resistance, as NCIMB-41601 preservation, are described in WO2010/076212); Event H7-1 (sugar beet, herbicide tolerance, as NCIMB 41158 or NCIMB 41159 preservations, are described in US2004172669 or WO2004/074492); Event JOPLIN1 (not preservation is described in US2008064032 for wheat, tolerance to diseases); Event LL27 (soybean, herbicide tolerance, as NCIMB41658 preservation, are described in WO2006/108674 or US2008320616); Event LL55 (soybean, herbicide tolerance, as NCIMB 41660 preservations, are described in WO2006/108675 or US2008196127); Event LLcotton25 (cotton, herbicide tolerance, as ATCC PTA-3343 preservation, are described in WO2003013224 or US2003097687); Event LLRICE06 (rice, herbicide tolerance, as ATCC-23352 preservation, are described in US6468747 or WO2000/026345); Event LLRICE601 (rice, herbicide tolerance, as ATCC PTA-2600 preservation, are described in US20082289060 or WO2000/026356); Event LY038 (corn, qualitative character, as ATCC PTA-5623 preservation, are described in US2007028322 or WO2005061720); Event mir 162 (corn, insect control, as PTA-8166 preservation, are described in US2009300784 or WO2007/142840); Event mir 604 (not preservation is described in US2008167456 or WO2005103301 for corn, insect control); Event MON15985 (cotton, insect control, as ATCC PTA-2516 preservation, are described in US2004-250317 or WO2002/100163); Event MON810 (not preservation is described in US2002102582 for corn, insect control);Event MON863 (corn, insect control, as ATCC PTA-2605 preservation, are described in WO2004/011601 or US2006095986); Event MON87427 (corn, pollination is controlled, and as ATCC PTA-7899 preservation, describes in WO2011/062904); Event MON87460 (corn, stress tolerance, as ATCC PTA-8910 preservation, are described in WO2009/111263 or US20110138504); Event MON87701 (soybean, insect control, as ATCC PTA-8194 preservation, are described in US2009130071 or WO2009/064652); Event MON87705 (soybean, qualitative character-herbicide tolerance, as ATCC PTA-9241 preservation, are described in US20100080887 or WO2010/037016); Event MON87708 (soybean, herbicide tolerance, as ATCC PTA9670 preservation, are described in WO2011/034704); Event MON87754 (soybean, qualitative character, as ATCC PTA-9385 preservation, are described in WO2010/024976); Event MON87769 (soybean, qualitative character, as ATCC PTA-8911 preservation, are described in US20110067141 or WO2009/102873); Event MON88017 (corn, insect control-herbicide tolerance, as ATCC PTA-5582 preservation, are described in US2008028482 or WO2005/059103); Event MON88913 (cotton, herbicide tolerance, as ATCC PTA-4854 preservation, are described in WO2004/072235 or US2006059590); Event MON 89034 (corn, insect control, as ATCC PTA-7455 preservation, are described in WO2007/140256 or US2008260932); Event MON89788 (soybean, herbicide tolerance, as ATCC PTA-6708 preservation, are described in US2006282915 or WO2006/130436); Event MS11 (oilseed rape, pollination control-herbicide tolerance as ATCC PTA-850 or PTA-2485 preservation, is described in WO2001/031042); Event MS8 (oilseed rape, pollination control-herbicide tolerance as ATCC PTA-730 preservation, is described in WO2001/041558 or US2003188347); Event NK603 (corn, herbicide tolerance, as ATCC PTA-2478 preservation,In US2007-292854, describe); Event PE-7 (not preservation is described in WO2008/114282 for rice, insect control); Event RF3 (oilseed rape, pollination control-herbicide tolerance as ATCC PTA-730 preservation, is described in WO2001/041558 or US2003188347); Event RT73 (not preservation is described in WO2002/036831 or US2008070260 for oilseed rape, herbicide tolerance); Event T227-1 (not preservation is described in WO2002/44407 or US2009265817 for sugar beet, herbicide tolerance); Event T25 (not preservation is described in US2001029014 or WO2001/051654 for corn, herbicide tolerance); Event T304-40 (cotton, insect control-herbicide tolerance, as ATCC PTA-8171 preservation, are described in US2010077501 or WO2008/122406); Event T342-142 (not preservation is described in WO2006/128568 for cotton, insect control); Event TC1507 (not preservation is described in US2005039226 or WO2004/099447 for corn, insect control-herbicide tolerance); Event VIP1034 (corn, insect control-herbicide tolerance as ATCC PTA-3925 preservation, is described in WO2003/052073), event 32316 (corns, insect control-herbicide tolerance as PTA-11507 preservation, is described in WO2011/084632), event 4114 (corns, insect control-herbicide tolerance as PTA-11506 preservation, is described in WO2011/084621).
According to the present invention, to separately or (especially above be defined as from fungicide with other agrochemicals compounds, those of the preferred compound of insecticide and plant growth regulator) compound (A) of the use of combination, preferred compound (A1) can be converted to conventional formulation, solution for example, emulsion, wetting powder, based on water and the suspension based on oily, powder, powder (dusts), paste, soluble powder, soluble granule, for the granule spreading fertilizer over the fields, outstanding newborn concentrating agents, the native compound being flooded by active component, the synthetic being flooded by active component, fertilizer and the microencapsulation in polymeric material.In the context of the present invention, when separately or while using with the form of spray agent according to the present invention with compound (A), the preferred compound (A1) of other agrochemicals compounds (be especially above defined as from the preferred compound of fungicide, insecticide and plant growth regulator those) combination, it is especially preferred.
Therefore the present invention also relates to the spray agent of the output with regard to the plant organ of its results for increasing useful plant or crop plants.
Spray agent is below being described in detail:
Preparation for spray application produces in a known way, for example, by will be separately or with other agrochemicals compounds (be especially above defined as from the preferred compound of fungicide, insecticide and plant growth regulator those) combination, treat that the compound (A), the preferred compound (A1) that according to the present invention, use mix with incremental agent, be liquid flux and/or solid carrier, optional use surfactant, i.e. emulsifier and/or dispersant and/or formation of foam agent.Optionally can also use further conventional additives, for example conventional incremental agent and solvent or thinner, dyestuff, wetting agent, dispersant, emulsifier, defoamer, preservative, secondary thickener, binding agent, gibberellin and water.Preparation is prepared before application or during application in suitable equipment.
The auxiliary agent using can be such material, and it is suitable for giving composition self and/or for example, for example, by its derivative preparation (liquor of spraying) special properties, particular technology character and/or other special biological property.Useful common auxiliary agent comprises: incremental agent, solvent and carrier.
Suitable incremental agent is for example water, polarity and nonpolar organic chemistry liquid, for example, from following kind: aromatic hydrocarbon and non-aromatic hydrocarbon (for example paraffin, alkylbenzene, Fluhyzon, chlorobenzene), alcohol and polyalcohol (its can also be in addition replace, etherificate and/or esterification), amine, acid amides, lactam (for example N-alkyl pyrrolidone) and lactone, sulfone and the sulfoxide (for example dimethyl sulfoxide (DMSO)) of ketone (for example acetone, cyclohexanone), ester (comprising fat and oil) and (gathering) ether, unsubstituted and replacement.
If the incremental agent using is water, for example can also use organic solvent as cosolvent.Useful liquid flux is substantially: aromatic compound, for example dimethylbenzene, toluene or Fluhyzon, chlorination aromatic compound and chlorinated aliphatic hydrocarbon be chlorobenzene, vinyl chloride or carrene for example, aliphatic hydrocarbon is cyclohexane or paraffin for example, for example petroleum fractions, mineral oil and vegetable oil, alcohols for example butanols or ethylene glycol with and ether and ester, ketone is acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK) or cyclohexanone for example, intensive polar solvent is dimethyl sulfoxide (DMSO) and water for example.
Can use for example inorganic pigment of dyestuff, for example iron oxide, titanium oxide and Prussian blue, and organic dyestuff for example alizarin dyes, azo dyes and metal phthalocyanine dyestuff, and the micronutrient salt of iron, manganese, boron, copper, cobalt, molybdenum and zinc for example.
May reside according to the present invention can with preparation in useful wetting agent be all such materials, it promotes the moistening and conventional preparation for active agrochemicals composition.The preferably use alkylnaphthalene sulfonate providing is diisopropyl or diisobutyl naphthalene for example.
May reside according to the present invention can with preparation in useful dispersant and/or emulsifier be conventional all nonionics, anion and the cation dispersing agent that becomes assignment system for active agrochemicals.Preferential available is the mixture of nonionic or anionic dispersing agents or nonionic or anionic dispersing agents.Suitable non-ionic dispersing agent is ethylene oxide/propylene oxide block copolymer, alkyl phenol polyglycol ether and triphenyl vinyl phenol polyglycol ether especially, and phosphorylation or sulfated derivative.Suitable anionic dispersing agents is lignosulphonates, polyacrylic salt and arylsulphonate/formaldehyde condensation products especially.
May reside according to the present invention can with preparation in defoamer be the conventional all foam inhibiting substances that become assignment system for active agrochemicals.Preferential available is silicone defoamer and dolomol.
May reside according to the present invention can with preparation in preservative be can be for this type of purposes for all substances of active agrochemical composition.Example comprises antiphen and phenmethylol hemiformal.
May reside according to the present invention can with preparation in secondary thickener be can be for this type of purposes for all substances of active agrochemical composition.The preferably cellulose derivatives, acrylic acid derivative, xanthans, modified clay and the fine silicon dioxide that provide.
May reside according to the present invention can with preparation in binding agent comprise all conventional adhesive that can be used for dressing seed in product.Preferred example comprises polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and methylcellulose.May reside in gibberellin in the preparation that can use according to the present invention preferably gibberellin A1, A3 (=gibberellic acid), A4 and A7; What provide is particularly preferably to use gibberellic acid.Gibberellin is known (with reference to R. Wegler " Chemie der Pflanzenschutz-und Sch dlingsbek mpfungsmittel " [Chemistry of Crop Protection Compositions and Pesticides], the 2nd volume, Springer Verlag, 1970, the 401-412 pages).
Further additive can be oil, wax and the nutrient (comprising micronutrient) of spices, mineral or plant, optional modification, for example salt of iron, manganese, boron, copper, cobalt, molybdenum and zinc.What exist in addition can be stabilizing agent, for example cold stabilizing agent, antioxidant, light stabilizer or improve chemistry and/or other reagent of physical stability.
Preparation generally contain 0.01-98 % by weight, preferably 0.5-90 % by weight between the compound of formula (I).
In wetting powder, activity component concentration is about 10-90 % by weight for example; Surplus to 100 % by weight is comprised of conventional formulation constituent.Can emulsion concentrate in the situation that, activity component concentration can be for example about 1-90 % by weight, preferred 5-80 % by weight.The active component of the active component that loose dosage formulation contains 1-30 % by weight, preferably common 5-20 % by weight; Can sprayed solution containing the 0.05-80 % by weight of having an appointment, the preferred active component of 2-50 % by weight; In the dispersible granule of water, it is to exist with solid or with liquid form that active component content depends in part on reactive compound, and uses which kind of granulation aid, filler etc.In water, in dispersible granule, the content of active component is for example between 1-95 % by weight, preferred 10-80 % by weight.
When used according to the invention, preparation and type of service that active component can be obtained commercially with it exist, by these auxiliary agents, prepared, in having the mixture of other active components, described other active components are insecticide, attractant, disinfectant, bactericide, miticide, nematocide, fungicide, growth regulator, weed killer herbicide, safener, fertilizer or semiochemical for example.
About the compound of application formula (I), for preferred time of coordinate plant growth, be that the amount of application of ratifying is processed soil, stem and/or leaf.
When according to the present invention separately or while using with other agrochemicals compound combinations, compound (A), preferred compound (A1) generally can be in addition with its commercial formulation, exist with the type of service of being prepared by these preparations, in having the mixture of other active components, described other active components are insecticide, attractant, disinfectant, miticide, nematocide, fungicide, growth regulator, the material that affects plant maturation, safener or weed killer herbicide for example.Especially further suitable mixing gametophyte is different types of active component of appointment in group below for example, and its order does not produce any preferential selection:
Bactericide:
Bronopol, antiphen, trichloromethyl pyridine, Methyl disulfide are for nickel formate, kasugarnycin, octhilinone, furancarboxylic acid, terramycin, probenazole, streptomycin, tecloftalam, copper sulphate and other copper agents.
Insecticide/miticide/nematocide:
I1) acetylcholinesterase (AChE) inhibitor, a) from the material group of carbamates, alanycarb for example, Aldicarb, aldoxycarb, allyxycarb, aminocarb, Evil worm prestige, Benfuracard micro, metalkamate, butacarb, butocarboxim, butanone sulfone prestige, carbaryl, carbofuran, carbosulfan, cloethocarb, dimetilan, ethiofencarb, Bassa, fenothiocarb, fenoxycarb, Carzol, furathiocarb, Mobucin, metham-sodium, methiocarb, Methomyl, meta-tolyl-N-methylcarbamate (MTMC), oxamyl, Aphox, Carbamult, unden, thiofanox, Landrin, XMC, Meobal, triaguron, b) from the group of organophosphorus ester, orthene for example, Jia Ji Bi Evil phosphorus, azinphos-methyl/azinphos ethyl, Rilariol, bromobenzene alkene phosphorus (methyl), butathiofos, cadusafos, trithion, chlorethoxyfos, chlorfenviphos, chlormephos, Resistox, cyanofenphos, cyanophos, chlorfenviphos, demeton-methyl, metilomerkaptofosoksid, dialifos, diazinon, dichlofenthion, dichlorvos/DDVP, Carbicron, Rogor, dimethylvinphos, salithion, disulfoton, EPN, ethion, phonamiphos, etrimfos, famphur, fenamiphos, sumithion, fensulfothion, fenthion, pyrrole fluorine sulphur phosphorus, fonofos, formothion, fosmethilan, fosthiazate, heptenophos, iodfenphos, iprobenfos, isazofos, isofenphos, O-isopropyl salicylate, oxazole phosphorus, malathion, Afos, methacrifos, acephatemet, methidathion, Menite, nuvacron, 2-dichloroethylk dimethyl phosphate, omethoate, oxydemeton_methyl, (methyl/ethyl) parathion, phenthoate dimephenthoate cidial, thimet, Phosalone, phosmet, phosphamidon, phosphorus worm prestige, phoxim, Actellic/Diothyl, Profenofos, Kayaphos, propetamphos, Toyodan, prothoate, pyraclofos, pyridaphethione, the sulphur phosphorus of rattling away, quinalphos, gram line pellet, sulfotep, sulprofos, butyl pyrimidine phosphorus, Swebate, terbufos, Ravap, thiometon, Hostathion, chlorophos, vamidothion.
I2) sodium channel modulators/voltage gated sodium channel retarding agent, a) from the group of pyrethroid, acrinathrin for example, allethrin (dextrorotation cis-trans, dextrorotation-trans), β-cyfloxylate, Biphenthrin, bioallethrin, bioallethrin-S-cyclopenta-isomer, benzyl furan alkene chrysanthemum ester, biopermethrin, bioresmethrin, dichloro alkyne valerate, alpha-cypermethrin, cis resmethrin, cis permethrin, cyhalothrin, cycloprothrin, cyfloxylate, cyhalothrin, cypermethrin (α-, β-, θ-, ζ-), cyphenothrin, eflusilanate, empenthrin (1R isomer), cis fenvalerate, ether chrysanthemum ester, fenfluthrin, fenpropathrin, fenpirithrin, sumicidin, brofluthrinate, flucythrinate, trifluoro chrysanthemum ester, flumethrin, taufluvalinate, halfenprox, gamma-cyhalothrin, Imiprothrin, Kadethrin, λ-cyhalothrin, methoxy benzyl Flumethrin, permethrin (cis, trans), phenothrin (1R-transisomer), prallethrin, the third Flumethrin, protrifenbute, skin resmethrin, pyrethrin, resmethrin, RU 15525, silafluofene, taufluvalinate, tefluthrin, terallethrin, tetramethrin (1R isomer), tralomethrin, transfluthrin, ZXI 8901, pyrethrin (Dalmatian chrysanthemum), b) DDT, c) oxadiazine class, indoxacarb for example, d) semicarbazones, for example metaflumizone (BAS3201).
I3) acetyl choline receptor agonists/antagonist, a) from chloronicotinoyl class group, for example Acetamiprid, AKD 1022, MTI-446, imidaclothiz, Nitenpyram, Nithiazine, thiacloprid, b) nicotine, bensultap, cartap;
I4) from the acetylcholine receptor modulators of multiple killing teichomycin,
I5) the chloride channel antagonist that GABA controls, a) from organochlorine group, for example toxaphene, Niran, 5a,6,9,9a-hexahydro-6,9-methano-2,4, γ-HCH, HCH, heptachlor, lindane, methoxychlor, b) fragrant general class (fiproles), for example acetyl worm nitrile, pyrafluprole, pyriprole, vaniliprole;
I6) chloride channel activator, for example emaricin, ivermectin, thunder cuticulin, milbemycin;
I7) juvenile hormone analogies, for example difenolan, protect young ether, fenoxycarb, hydroprene, kinoprene, methoprene, Nylar, triprene;
I8) ecdysone agonist/chaff interference, for example, encircle worm hydrazides, chlorine worm hydrazides, methoxyfenozide, worm hydrazides;
I9) chitin biosynthesis inhibitor, for example bistrifluron, fluorine cry urea, diflubenzuron, fluazuron, flucycloxuron, flufenoxuron, HEXAFLUMURON, fluorine uride, noviflumuron, penfluron, fluorobenzene urea, Buprofezin, cyromazine;
I10) oxidative phosphorylation inhibitors, a) ATP chaff interference, diafenthiuron for example, b) organo-tin compound, for example azacyclotin, plictran, fenbutatin oxide;
I11) by interrupting the uncoupler of the oxidative phosphorylation of H-proton gradient, a) for example, from pyrroles's group, Ke Fanpai, b) from dinitrophenol dinitrophenolate kind, for example binapacryl, dinobuton, karathane, DNOC, the mite that disappears are many;
I12) site I electron transfer inhibitor, for example METI, especially as an example fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, Tolfenpyrad or hydramethylnon, dicofol;
I13) site II electron transfer inhibitor, for example rotenone;
I14) site III electron transfer inhibitor, for example acequinocyl, fluacrypyrim;
I15) the microorganism chaff interference of insect goldbeater's skin, for example bacillus thuringiensis subsp israelensis (
bacillus thuringiensissubspecies
israelensis), Bacillus sphaericus (
bacillus sphaericus), bacillus thuringiensis (
bacillus thuringiensissubspecies
aizawai), bacillus thuringiensis Ku Er Stark subspecies (
bacillus thuringiensissubspecies
kurstaki), bacillus thuringiensis intend walking first subspecies (
bacillus thuringiensissubspecies
tenebrionis) and BT phytoprotein for example Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34/35Ab1,
I16) lipid synthesis inhibitor, a) from the group of tetronic acid class, for example spiral shell mite ester, Spiromesifen, b) from tetramine acid (tetramic acid) kind, for example spiral shell worm ethyl ester, cis-3-(2,5-3,5-dimethylphenyl)-4-hydroxyl-8-methoxyl group-1-azaspiro [4.5] last of the ten Heavenly stems-3-alkene-2-ketone;
I17) octopaminergic agonist, for example Amitraz;
The inhibitor of the ATP enzyme that I18) magnesium stimulates, for example propargite;
I19) the similar thing of nereistoxin, for example thiocyclam oxalate, dimehypo;
I20) blue Buddhist nun's alkali receptor stimulating agent, a) from benzenedicarboxamide group, b) from the chloro-6-[(1-cyclopropyl of the bromo-4-of the bromo-N-{2-of anthranilamide group: 3-ethyl) carbamyl] phenyl }-1-(3-chloropyridine-2-yl)-1H-pyrazoles-5-formamide (known by WO2005/077934) or 2-[3, the bromo-2-of 5-bis-({ [the bromo-1-of 3-(3-chloropyridine-2-yl)-1H-pyrazoles-5-yl] carbonyl } amino) benzoyl]-1,2-dimethylhydrazine methyl formate (known by WO2007/043677);
I21) biological products, hormone or pheromones, for example nimbin, bacillus species, Beauveria species (
beauveriaspec.), Pherocon CM, Metarhizium species (
metarrhiziumspec.), paecilomyces species (
paecilomycesspec.), thuringiensin, Verticillium species (
verticilliumspec.);
I22) there is the active component of the unknown or nonspecific action mechanism, a) fumigant, for example aluminum phosphate, methyl bromide, vikane, b) anti-feedant, for example ice crystal, chlorine pyridine insect amide, pymetrozine, c) mite growth inhibitor, for example clofentezine, second mite azoles, Hexythiazox, d) sulfanilamide (SN) mite ester, benclothiaz, Citrazon, Bifenazate, fenisobromolate, Buprofezin, chinomethionat, chlordimeform, chlorobenzilate, chloropicrin, diuril benzene, cycloprene, cyflumetofen, CGA 183893, phonetic acyl worm amine, fluorine nitre diphenylamines, fluorine mite thiophene, phonetic worm amine, fluorine mite piperazine, gossyplure (gossyplure), Hydramethylnon Bait, japonilure, Evil worm ketone, oil, piperonyl butoxide, potassium oleate, pyridalyl, sulfluramid, tetradiphon, kill mite thioether, triarathene, synergy piece ether and following known activity compound: 4-{[(6-bromopyridine-3-yl) methyl] (2-fluoro ethyl) amino } furans-2 (5H)-one (known by WO 2007/115644), 4-{[(6-fluorine pyridin-3-yl) methyl] (2,2-, bis-fluoro ethyls) amino } furans-2 (5H)-one (known by WO 2007/115644), chloro-1,3-thiazoles-the 5-of 4-{[(2-yl) methyl] (2-fluoro ethyl) amino } furans-2 (5H)-one (known by WO 2007/115644), 4-{[(6-fluorine pyridin-3-yl) methyl] (2-fluoro ethyl) amino } furans-2 (5H)-one (known by WO 2007/115644), 4-{[(6-fluorine pyridin-3-yl) methyl] (2,2-, bis-fluoro ethyls) amino } furans-2 (5H)-one (known by WO 2007/115644), the chloro-5-fluorine of 4-{[(6-pyridin-3-yl) methyl] (methyl) amino } furans-2 (5H)-one (known by WO 2007/115643), 4-{[(5,6-difluoro pyridine-3-yl) methyl] (2-fluoro ethyl) amino } furans-2 (5H)-one (known by WO 2007/115646), the chloro-5-fluorine of 4-{[(6-pyridin-3-yl) methyl] (cyclopropyl) amino } furans-2 (5H)-one (known by WO 2007/115643), 4-{[(6-fluorine pyridin-3-yl) methyl] (cyclopropyl) amino } furans-2 (5H)-one (known by EP0539588), 4-{[(6-fluorine pyridin-3-yl) methyl] (methyl) amino } furans-2 (5H)-one (known by EP0539588), [1-(6-chloropyridine-3-yl) ethyl] (methyl) oxo bridge-λ 4-sulfane subunit cyanamide (by WO 2007/149134) and diastereomer thereof { [(1R)-1-(6-chloropyridine-3-yl) ethyl] (methyl) oxo bridge-λ 6-sulfane subunit } cyanamide and { [(1S)-1-(6-chloropyridine-3-yl) ethyl] (methyl) oxo bridge-λ 6-sulfane subunit } cyanamide (known by WO 2007/149134 equally) and fluoro-4-methyl-5-[(2 of 1-[2-, 2, 2-trifluoroethyl) sulfinyl] phenyl]-3-(trifluoromethyl)-1H-1, 2,4-triazole-5-amine (known by WO 2006/043635), [(3S, 4aR, 12R, 12aS, 12bS)-3-[(cyclopropyl carbonyl) oxygen base]-6,12-dihydroxy-4, 12b-dimethyl-11-oxo-9-(pyridin-3-yl)-1,3,4, 4a, 5,6, 6a, 12,12a, 12b-decahydro-2H, 11H-benzo [f] pyrans is [4,3-b] chromene-4-yl also] methyl-cyclopropane-formic acid esters (known by WO 2006/129714), 2-cyano group-3-(difluoro-methoxy)-N, N-dimethyl benzene sulfonamide (known by WO2006/056433), 2-cyano group-3-(difluoro-methoxy)-N-methyl benzenesulfonamide (known by WO2006/100288), 2-cyano group-3-(difluoro-methoxy)-N-ethylo benzene sulfonamide (known by WO2005/035486), 4-(difluoro-methoxy)-N-ethyl-N-methyl isophthalic acid, 2-[4-morpholinodithio-3-amine 1,1-dioxide (known by WO2007/057407), N-[1-(2,3-3,5-dimethylphenyl)-2-(3,5-3,5-dimethylphenyl) ethyl]-4,5-dihydro-1,3-thiazoles-2-amine (known by WO2008/104503), 1'-[(2E) and-3-(4-chlorphenyl) third-2-alkene-1-yl]-5-fluorine spiral shell [indoles-3,4'-piperidines]-1 (2H)-yl } (2-chloropyridine-4-yl) ketone (known by WO2003106457), 3-(2,5-3,5-dimethylphenyl)-4-hydroxyl-8-methoxyl group-1,8-diaza spiro [4.5] last of the ten Heavenly stems-3-alkene-2-ketone (known by WO2009049851), 3-(2,5-3,5-dimethylphenyl)-8-methoxyl group-2-oxo-1,8-diaza spiro [4.5] last of the ten Heavenly stems-3-alkene-4-base ethyl carbonate (known by WO2009049851), 4-(fourth-2-alkynes-1-base oxygen base)-6-(3,5-lupetidine-1-yl)-5-FU (known by WO2004099160), (2,2,3,3,4,4,5,5-octafluoro amyl group) (3,3,3-trifluoro propyl) the third two eyeballs (known by WO2005063094), (2,2,3,3,4,4,5,5-octafluoro amyl group) (3,3,4,4,4-, five fluorine butyl) the third two eyeballs (known by WO2005063094), 8-[2-(cyclo propyl methoxy)-4-(trifluoromethyl) phenoxy group]-3-[6-(trifluoromethyl) pyridazine-3-yl]-3-azabicyclo [3.2.1] octane (known by WO2007040280/282), 2-ethyl-7-methoxyl group-3-methyl-6-[(2,2,3,3-tetrafluoro-2,3-dihydro-Isosorbide-5-Nitrae-benzodioxan-6-yl) oxygen base] quinolyl-4 methyl carbonate (known by JP2008110953), 2-ethyl-7-methoxyl group-3-methyl-6-[(2,2,3,3-tetrafluoro-2,3-dihydro-Isosorbide-5-Nitrae-benzodioxan-6-yl) oxygen base] quinolyl-4 acetic acid esters (known by JP2008110953), PF1364 (chemical abstracts 1204776-60-2, known by JP2010018586), 5-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazole-3-yl]-2-(1H-1,2,4-triazol-1-yl) benzonitrile (known by WO2007075459), 5-[5-(2-chloropyridine-4-yl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazole-3-yl]-2-(1H-1,2,4-triazol-1-yl) benzonitrile (known by WO2007075459), 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazole-3-yl]-2-methyl-N-{2-oxo-2-[(2,2,2-trifluoroethyl) amino] ethyl } benzamide (known by WO2005085216).
Safener is preferably selected from:
S1) compound of formula (S1)
Wherein symbol and index are defined as follows separately:
N
a0-5, the natural number of preferred 0-3;
R
a 1halogen, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl, nitro or (C
1-C
4)-haloalkyl;
W
athe divalent heterocyclic group that is unsubstituted or replaces, it is from having the undersaturated or aromatic series five-ring heterocycles of part from 1-3 the heteroatom of N and O, wherein at least one nitrogen-atoms and at the most an oxygen atom be present in ring, preferably from (W
a 1)-(W
a 4) group,
M
a0 or 1;
R
a 2oR
a 3, SR
a 3or NR
a 3r
a 4or saturated or undersaturated 3 to 7 yuan of heterocycles with 3 hetero atoms of at least one nitrogen-atoms and as many as (preferably from O and S), it is connected to the carbonyl in (S1) via nitrogen-atoms, and is unsubstituted or by from (C
1-C
4)-alkyl, (C
1-C
4the group of)-alkoxyl and the optional phenyl replacing replaces, preferred formula OR
a 3, NHR
a 4or N (CH
3)
2formula OR particularly
a 3group;
R
a 3be hydrogen or aliphatic alkyl group unsubstituted or that replace, preferably there is 1-18 carbon atom altogether;
R
a 4hydrogen, (C
1-C
6)-alkyl, (C
1-C
6phenyl)-alkoxyl or replacement or unsubstituted;
R
a 5h, (C
1-C
8)-alkyl, (C
1-C
8)-haloalkyl, (C
1-C
4)-alkoxyl-(C
1-C
8)-alkyl, cyano group or COOR
a 9, R wherein
a 9hydrogen, (C
1-C
8)-alkyl, (C
1-C
8)-haloalkyl, (C
1-C
4)-alkoxyl-(C
1-C
4)-alkyl, (C
1-C
6)-hydroxy alkyl, (C
3-C
12)-cycloalkyl or three-(C
1-C
4)-alkyl silicyl;
R
a 6, R
a 7, R
a 8identical or different, and each hydrogen, (C naturally
1-C
8)-alkyl, (C
1-C
8)-haloalkyl, (C
3-C
12phenyl)-cycloalkyl or replacement or unsubstituted;
Preferably:
A) dichlorophenyl pyrazoline-3-formic acid (S1
a) compound of type, preferred compound is 1-(2 for example, 4-dichlorophenyl)-5-(ethoxy carbonyl)-5-antazoline-3-formic acid, 1-(2,4-dichlorophenyl)-5-(ethoxy carbonyl)--5-antazoline-3-Ethyl formate (S1-1) (" mefenpyrdiethyl ") and related compound, as described in WO-A-91/07874;
B) dichlorophenyl pyrazole carboxylic acid (S1
b) derivative, preferred compound is 1-(2 for example, 4-dichlorophenyl)-5-methylpyrazole-3-Ethyl formate (S1-2), 1-(2,4-dichlorophenyl)-5-isopropyl pyrazoles-3-Ethyl formate (S1-3), 1-(2,4-dichlorophenyl)-5-(1,1-dimethyl ethyl) pyrazoles-3-Ethyl formate (S1-4) and related compound, as described in EP-A-333 131 and EP-A-269 806;
C) 1,5-diphenylpypazole-3-formic acid (S1
c) derivative, preferred compound is 1-(2 for example, 4-dichlorophenyl)-5-Phenylpyrazole-3-Ethyl formate (S1-5), 1-(2-chlorphenyl)-5-Phenylpyrazole-3-methyl formate (S1-6) and related compound, as for example described in EP-A-268554;
D) three iminazole acid type (S1
d) compound, preferred compound is fenchlorazole (ethyl) for example, 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1,2,4-triazole-3-Ethyl formate (S1-7) and related compound, as described in EP-A-174 562 and EP-A-346 620;
E) 5-benzyl-or 5-phenyl-2-isoxazoline-3-formic acid or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid type (S1
e) compound, preferred compound is 5-(2 for example, 4-dichloro-benzenes methyl)-2-isoxazoline-3-Ethyl formate (S1-8) or 5-phenyl-2-isoxazoline-3-Ethyl formate (S1-9) and related compound, as described in WO-A-91/08202, or 5, 5-diphenyl-2-isoxazoline carboxylic acid (S1-10) or 5, 5-diphenyl-2-isoxazoline-3-Ethyl formate (S1-11) (" bis-Ben oxazole acid-ethyl ") or 5, 5-diphenyl-2-isoxazoline-3-formic acid n-pro-pyl ester (S1-12) or 5-(4-fluorophenyl)-5-phenyl-2-isoxazoline-3-Ethyl formate (S1-13), as described in patent application WO-A-95/07897.
S2) quinoline of formula (S2),
Wherein symbol and index are defined as follows separately:
R
b 1halogen, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl, nitro or (C
1-C
4)-haloalkyl;
N
b0-5, the natural number of preferred 0-3;
R
b 2oR
b 3, SR
b 3or NR
b 3r
b 4or saturated or undersaturated 3 to 7 yuan of heterocycles with 3 hetero atoms of at least one nitrogen-atoms and as many as (preferably from O and S), it is connected to the carbonyl in (S2) via nitrogen-atoms, and is unsubstituted or by from (C
1-C
4)-alkyl, (C
1-C
4the group of)-alkoxyl and the optional phenyl replacing replaces, preferred formula OR
b 3, NHR
b 4or N (CH
3)
2formula OR particularly
b 3group;
R
b 3be hydrogen or aliphatic alkyl group unsubstituted or that replace, preferably there is 1-18 carbon atom altogether;
R
b 4hydrogen, (C
1-C
6)-alkyl, (C
1-C
6phenyl)-alkoxyl or replacement or unsubstituted;
T
b(C
1-or C
2)-alkane two base chains, it is unsubstituted or by one or two (C
1-C
4)-alkyl group or [(C
1-C
3)-alkoxyl] carbonyl substituted;
Preferably:
A) 8-quinoline oxy acetic acid type (S2
a) compound, preferably Cloquintocet-mexyl (" cloquintocetmexyl ") is (S2-1), 1,3-dimethyl butyrate-1-base (the chloro-8-quinoline oxy of 5-) acetic acid esters (S2-2), 4-pi-allyl oxygen Ji Dingji (the chloro-8-quinoline oxy of 5-) acetic acid esters (S2-3), 1-pi-allyl oxygen base third-2-base (the chloro-8-quinoline oxy of 5-) acetic acid esters (S2-4), (the chloro-8-quinoline oxy of 5-) ethyl acetate (S2-5), (the chloro-8-quinoline oxy of 5-) methyl acetate (S2-6), (the chloro-8-quinoline oxy of 5-) allyl acetate (S2-7), 2-(the sub-aminooxy group of 2-the third subunit)-1-ethyl (the chloro-8-quinoline oxy of 5-) acetic acid esters (S2-8), 2-oxo third-1-base (the chloro-8-quinoline oxy of 5-) acetic acid esters (S2-9) and related compound, as EP-A-86 750, described in EP-A-94 349 and EP-A-191 736 or EP-A-0 492 366, and also has (the chloro-8-quinoline oxy of 5-) acetic acid (S2-10), its hydrate and salt, for example its lithium, sodium, potassium, calcium, magnesium, aluminium, iron, ammonium, quaternary ammonium, Liu Huo phosphonium salt, as described in WO-A-2002/34048,
B) (the chloro-8-quinoline oxy of 5-) malonic acid type (S2
b) compound, preferred compound is (the chloro-8-quinoline oxy of 5-) diethyl malonate, (the chloro-8--quinoline oxy of 5-) malonic acid diallyl ester, (the chloro-8-quinoline oxy of 5-) malonic acid Methylethyl ester and related compound for example, as described in EP-A-0 582 198.
S3) compound of formula (S3)
Wherein symbol and index are defined as follows separately:
R
c 1(C
1-C
4)-alkyl, (C
1-C
4)-haloalkyl, (C
2-C
4)-thiazolinyl, (C
2-C
4)-haloalkenyl group, (C
3-C
7)-cycloalkyl, preferably dichloromethyl;
R
c 2, R
c 3identical or different, and each hydrogen, (C naturally
1-C
4)-alkyl, (C
2-C
4)-thiazolinyl, (C
2-C
4)-alkynyl, (C
1-C
4)-haloalkyl, (C
2-C
4)-haloalkenyl group, (C
1-C
4)-alkyl carbamoyl-(C
1-C
4)-alkyl, (C
2-C
4)-alkenyl amino formyl-(C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl-(C
1-C
4)-alkyl, dioxolanyl-(C
1-C
4)-alkyl, thiazolyl, furyl, furyl alkyl, thienyl, piperidyl, replacement or unsubstituted phenyl, or R
c 2and R
c 3form together that replace or unsubstituted heterocycle, You Xuan oxazolidine, thiazolidine, piperidines, morpholine, hexahydropyrimidine or benzoxazine ring, preferably: the active component of dichloro acetamide type, it is frequently as safener (soil effect safener) before emerging, " allyl dichloride amine " (N for example, N-diallyl-2, 2-dichloro acetamide) (S3-1), " R-29148 " (3-dichloro-acetyl-2 from Stauffer, 2, 5-trimethyl-1, 3-oxazolidine) (S3-2), " R-28725 " (3-dichloro-acetyl-2 from Stauffer, 2-dimethyl-1, 3-oxazolidine) (S3-3), " benoxacor " (4-dichloro-acetyl-3, 4-dihydro-3-methyl-2H-1, 4-benzoxazine) (S3-4), " PPG-1292 " (N-pi-allyl-N-[(1 from PPG Industries, 3-dioxolanes-2-yl) methyl] dichloro acetamide) (S3-5), " DKA-24 " (N-pi-allyl-N-[(allyl amino carbonyl) methyl from Sagro-Chem] dichloro acetamide) (S3-6), " AD-67 " or " MON 4660 " (3-dichloro-acetyl-1-oxa--3-azaspiro [4 from Nitrokemia or Monsanto, 5] decane) (S3-7), from " TI-35 " (1-dichloro-acetyl azepan) of TRI-Chemical RT (S3-8), from (S3-9) ((RS)-1-dichloro-acetyl-3 of " diclonon " (dicyclo ketone) of BASF or " BAS145138 " or " LAB145138 ", 3, 8a-trimethyl perhydro pyrroles [1, 2-a] pyrimidine-6-ketone), " Xie Cao oxazole " or " MON 13900 " ((RS)-3-dichloro-acetyl-5-(2-furyl)-2, 2-bis-Jia Ji oxazolidine) (S3-10), and (R) isomer (S3-11).
S4) N-acyl sulfonamides and the salt thereof of formula (S4), condition is the compound (A) that they are different from according to the present invention purposes or using method application,
Wherein symbol and index are defined as follows separately:
X
dcH or N;
R
d 1cO-NR
d 5r
d 6or NHCO-R
d 7;
R
d 2halogen, (C
1-C
4)-haloalkyl, (C
1-C
4)-halogenated alkoxy, nitro, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl, (C
1-C
4)-alkyl sulphonyl, (C
1-C
4)-alkoxy carbonyl or (C
1-C
4)-alkyl-carbonyl;
R
d 3hydrogen, (C
1-C
4)-alkyl, (C
2-C
4)-thiazolinyl or (C
2-C
4)-alkynyl;
R
d 4halogen, nitro, (C
1-C
4)-alkyl, (C
1-C
4)-haloalkyl, (C
1-C
4)-halogenated alkoxy, (C
3-C
6)-cycloalkyl, phenyl, (C
1-C
4)-alkoxyl, cyano group, (C
1-C
4)-alkylthio group, (C
1-C
4)-alkyl-sulfinyl, (C
1-C
4)-alkyl sulphonyl, (C
1-C
4)-alkoxy carbonyl or (C
1-C
4)-alkyl-carbonyl;
R
d 5hydrogen, (C
1-C
6)-alkyl, (C
3-C
6)-cycloalkyl, (C
2-C
6)-thiazolinyl, (C
2-C
6)-alkynyl, (C
5-C
6)-cycloalkenyl group, phenyl or contain the v from nitrogen, oxygen and sulphur
dheteroatomic 3-to 6-unit heterocyclic radical, wherein below seven kinds of groups by the v from following
dsubstituting group replaces: halogen, (C
1-C
6)-alkoxyl, (C
1-C
6)-halogenated alkoxy, (C
1-C
2)-alkyl sulphinyl, (C
1-C
2)-alkyl sulphonyl, (C
3-C
6)-cycloalkyl, (C
1-C
4)-alkoxy carbonyl, (C
1-C
4)-alkyl-carbonyl and phenyl, and the in the situation that of cyclic group, also have (C
1-C
4)-alkyl and (C
1-C
4)-haloalkyl;
R
d 6hydrogen, (C
1-C
6)-alkyl, (C
2-C
6)-thiazolinyl or (C
2-C
6)-alkynyl, wherein below three kinds of groups by the v from following
dgroup replaces: halogen, hydroxyl, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl and (C
1-C
4)-alkylthio group, or
R
d 5and R
d 6the nitrogen-atoms having together with it forms pyrrolidinyl or piperidyl group;
R
d 7hydrogen, (C
1-C
4)-alkyl amino, two-(C
1-C
4)-alkyl amino, (C
1-C
6)-alkyl, (C
3-C
6)-cycloalkyl, wherein below 2 kinds of groups by the v from following
dsubstituting group replaces: halogen, (C
1-C
4)-alkoxyl, (C
1-C
6)-halogenated alkoxy and (C
1-C
4)-alkylthio group, and the in the situation that of cyclic group, also have (C
1-C
4)-alkyl and (C
1-C
4)-haloalkyl;
N
d0,1 or 2;
M
d1 or 2;
V
d0,1,2 or 3;
In these, the preferably N-acyl sulfonamides type providing, for example following formula (S4
a) compound, it is for example known by WO-A-97/45016
Wherein
R
d 7(C
1-C
6)-alkyl, (C
3-C
6)-cycloalkyl, wherein below 2 kinds of groups by the v from following
dsubstituting group replaces: halogen, (C
1-C
4)-alkoxyl, (C
1-C
6)-halogenated alkoxy and (C
1-C
4)-alkylthio group, and the in the situation that of cyclic group, also have (C
1-C
4)-alkyl and (C
1-C
4)-haloalkyl;
R
d 4halogen, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl, CF
3;
M
d1 or 2;
V
d0,1,2 or 3;
And also have acylsulfamoylbenzamides, for example following formula (S4
b) compound, it is for example known by WO-A-99/16744,
For example wherein
R
d 5=cyclopropyl and (R
d 4)=5-Cl-2-OMe (S4-2),
R
d 5=ethyl and (R
d 4)=2-OMe (S4-3),
R
d 5=isopropyl and (R
d 4)=5-Cl-2-OMe (S4-4), and
R
d 5=isopropyl and (R
d 4the compound of)=2-OMe (S4-5);
And N-acyl group sulfamoyl phenyl ureas type, formula (S4
c) compound, it is for example known by EP-A-365484,
Wherein
R
d 8and R
d 9hydrogen, (C independently of one another
1-C
8)-alkyl, (C
3-C
8)-cycloalkyl, (C
3-C
6)-thiazolinyl, (C
3-C
6)-alkynyl,
R
d 4halogen, (C
1-C
4)-alkyl, (C
1-C
4)-alkoxyl, CF
3,
M
d1 or 2;
For example
1-[4-(N-2-methoxybenzoyl sulfamoyl) phenyl]-3-MU, 1-[4-(N-2-methoxybenzoyl sulfamoyl) phenyl]-3; 3-dimethyl urea, 1-[4-(N-4,5-dimethyl benzene formyl sulfamoyl) phenyl]-3-MU.
S5) from the active component (S5) of the kind of hydroxy aromatic compound and aromatic-aliphatic carboxylic acid derivates, for example 3,4,5-triacetoxyl group ethyl benzoate, 3,5-dimethoxy-4 '-hydroxybenzoic acid, 3,5-dihydroxy-benzoic acid, 4-hydroxyl salicylic acid, 4-fluorosalicylic acid, 2 hydroxy cinnamic acid 98,2,4-dichloro-cinnamic acid, as described in WO-A-2004/084631, WO-A-2005/015994, WO-A-2005/016001.
S6) from 1; the active component (S6) of the kind of 2-bis-Qing quinoxaline-2-ketone; 1-methyl-3-(2-thienyl)-1 for example; 2-bis-Qing quinoxaline-2-ketone, 1-methyl-3-(2-thienyl)-1; 2-dihydro-quinoxaline-2-thioketones, 1-(2-amino-ethyl)-3-(2-thienyl)-1; 2-bis-Qing quinoxaline-2-keto hydrochloride, 1-(2-methyl sulphonyl amino-ethyl)-3-(2-thienyl)-1; 2-bis-Qing quinoxaline-2-ketone, as described in WO-A-2005/112630.
S7) compound of formula (S7), as described in WO-A-1998/38856,
Wherein symbol and index are defined as follows separately:
R
e 1, R
e 2halogen, (C independently of one another
1-C
4) alkyl, (C
1-C
4) alkoxyl, (C
1-C
4) haloalkyl, (C
1-C
4) alkyl amino, two-(C
1-C
4) alkyl amino, nitro;
A
ecOOR
e 3or COSR
e 4
R
e 3, R
e 4hydrogen, (C independently of one another
1-C
4) alkyl, (C
2-C
6) thiazolinyl, (C
2-C
4) alkynyl, cyano group alkyl, (C
1-C
4) haloalkyl, phenyl, nitrobenzophenone, benzyl, halogeno-benzene methyl, pyridyl alkyl and alkylammonium,
N
e 10 or 1;
N
e 2, n
e 30,1 or 2 independently of one another,
Preferably diphenylmethyl ethoxyacetic acid, diphenylmethyl ethoxyacetic acid ethyl ester, diphenyl methoxy menthyl acetate (CAS number of registration 41858-19-9) are (S7-1).
S8) compound or its salt of formula (S8), as described in WO-A-98/27049,
Wherein
X
fcH or N,
N
fif: X
f=N, n
fthe integer of 0-4, and
If X
f=CH, n
fthe integer of 0-5,
R
f 1halogen, (C
1-C
4)-alkyl, (C
1-C
4)-haloalkyl, (C
1-C
4)-alkoxyl, (C
1-C
4)-halogenated alkoxy, nitro, (C
1-C
4)-alkylthio group, (C
1-C
4)-alkyl sulphonyl, (C
1-C
4)-alkoxy carbonyl, the optional phenyl replacing, the optional phenoxy group replacing,
R
f 2hydrogen or (C
1-C
4)-alkyl,
R
f 3hydrogen, (C
1-C
8)-alkyl, (C
2-C
4)-thiazolinyl, (C
2-C
4)-alkynyl or aryl, wherein every kind of carbon-containing group mentioned above be unsubstituted or by from halogen and alkoxyl one or more, preferably up to three identical or different groups, replace;
Preferred such compound or its salt, wherein
X
fcH,
N
fthe integer of 0-2,
R
f 1halogen, (C
1-C
4)-alkyl, (C
1-C
4)-haloalkyl, (C
1-C
4)-alkoxyl, (C
1-C
4)-halogenated alkoxy,
R
f 2hydrogen or (C
1-C
4)-alkyl,
R
f 3hydrogen, (C
1-C
8)-alkyl, (C
2-C
4)-thiazolinyl, (C
2-C
4)-alkynyl or aryl, wherein each of above-mentioned carbon-containing group be unsubstituted or by from halogen and alkoxyl one or more, preferably up to three identical or different groups, replace.
S9) from the active component (S9) of the classification of 3-(5-tetrazole radical carbonyl)-2-quinolone, for example 1,2-dihydro-4-hydroxyl-1-ethyl-3-(5-tetrazole radical carbonyl)-2-quinolone (CAS number of registration: 219479-18-2), 1,2-dihydro-4-hydroxyl-1-methyl-3-(5-tetrazole radical carbonyl)-2-quinolone (CAS number of registration: 95855-00-8), as described in WO-A-1999/000020.
S10) formula (S10
a) or (S10
b) compound, as described in WO-A-2007/023719 and WO-A-2007/023764,
Wherein
R
g 1halogen, (C
1-C
4)-alkyl, methoxyl group, nitro, cyano group, CF
3, OCF
3
Y
g, Z
go or S independently of one another,
N
gthe integer of 0-4,
R
g 2(C
1-C
16)-alkyl, (C
2-C
6)-thiazolinyl, (C
3-C
6)-cycloalkyl, aryl; Benzyl, halogeno-benzene methyl,
R
g 3hydrogen or (C
1-C
6)-alkyl.
S11) active component of oxyimino group type of compounds (S11), it is considered to the composition of dressing seed, " oxabetrinil " ((Z)-1 for example, 3-dioxolanes-2-base-methoxyl group-imino group-(phenyl) acetonitrile) (S11-1), it is considered to the seed dressing safener for millet for the damage due to isopropyl methoxalamine, " fluxofenim " (1-(4-chlorphenyl)-2, 2, the fluoro-1-ethyl ketone of 2-tri-O-(1, 3-dioxolanes-2-ylmethyl) oxime) (S11-2), it is considered to the seed dressing safener for millet for the damage due to isopropyl methoxalamine, with " cyometrinil " or " CGA-43089 " ((Z)-cyano group methoxyl group-imino group (phenyl) acetonitrile) (S11-3), it is considered to the seed dressing safener for millet for the damage due to isopropyl methoxalamine.
S12) from the active component (S12) of the classification of different sulfo-chromanone, for example, from [(3-oxo-1H-2-benzothiopyran derivative-4 (3H)-subunit) methoxyl group] methyl acetate (CAS number of registration: 205121-04-6) (S12-1) and related compound of WO-A-1998/13361.
S13) from one or more compounds of group (S13): " naphthalene acid anhydride " (1, 8-naphthalene dicarboxylic acids acid anhydride) (S13-1), it is considered to the seed dressing safener for corn for the damage due to thiocarbamate herbicide, " fenclorim " (4, the chloro-2-phenyl pyrimidine of 6-bis-) (S13-2), it is considered to sow in rice the safener about the third careless amine, (the chloro-4-Trifluoromethyl-1 of 2-of " separating careless amine ", 3-thiazole-5-formic acid benzyl esters) (S13-3), it is considered to the seed dressing safener for millet for the damage due to alachlor and isopropyl methoxalamine, " CL 304415 " (CAS number of registration 31541-57-8) (4-carboxyl-3 from American Cyanamid, 4-dihydro-2H-1-chromene-4-acetic acid) (S13-4), it is considered to the safener for corn for the damage due to imidazolone, " MG 191 " (CAS number of registration 96420-72-3) (2-dichloromethyl-2-methyl isophthalic acid from Nitrokemia, 3-dioxolanes) (S13-5), it is considered to the safener for corn, from " MG-838 " (CAS number of registration 133993-74-5) (2-1-oxa--4-azaspiro [4.5] decane-4-bis-bamic acid acrylic esters) of Nitrokemia (S13-6), " disulfoton " (O, O-diethyl S-2-ethylenebis dithiocarbamate diethyldithioposphoric acid ester) (S13-7), " dietholate " (O, O-diethyl O-phenyl thiophosphate) (S13-8), " mephenate " (4-Chlorophenylmethyl carbamate) (S13-9).
S14) except the herbicide action for noxious plant, also have the crop plants active component of the safener effect of rice for example, for example " dimepiperate " or " MY-93 " (
s-1-methyl isophthalic acid-phenyl ethyl piperidine-1-thiocarboxylic), it is considered to the safener for rice for the damage due to weed killer herbicide molinate, " daimuron " or " SK 23 " (1-(1-methyl isophthalic acid-phenylethyl)-3-p-tolyl urea), it is considered to the safener for rice for the damage due to weed killer herbicide imazosulfuron, " cumyluron "=" JC-940 " (3-(2-Chlorophenylmethyl)-1-(1-methyl isophthalic acid-phenylethyl) urea, referring to JP-A-60087254), it is considered to the safener for rice for the damage due to some weed killer herbicides, " methoxyphenone " or " NK 049 " (3, 3'-dimethyl-4-methoxy benzophenone), it is considered to the safener for rice for the damage due to some weed killer herbicides, " CSB " (the bromo-4-of 1-(chloromethyl sulfonyl) benzene) (CAS number of registration 54091-06-4) from Kumiai, it is considered to be in rice the safener for the damage due to some weed killer herbicides.
S15) compound of formula (S15) or its dynamic isomer, as described in WO-A-2008/131861 and WO-A-2008/131860,
Wherein
R
h 1(C
1-C
6) halogenated alkyl group, and
R
h 2hydrogen or halogen, and
R
h 3, R
h 4hydrogen, (C independently of one another
1-C
16) alkyl, (C
2-C
16) thiazolinyl or (C
2-C
16) alkynyl, wherein below 3 kinds of groups each is unsubstituted or replaced by following one or more groups naturally: halogen, hydroxyl, cyano group, (C
1-C
4) alkoxyl, (C
1-C
4) halogenated alkoxy, (C
1-C
4) alkylthio group, (C
1-C
4) alkyl amino, two [(C
1-C
4) alkyl] amino, [(C
1-C
4) alkoxyl] carbonyl, [(C
1-C
4) halogenated alkoxy] carbonyl, the unsubstituted or (C that replaces
3-C
6) cycloalkyl, unsubstituted or the phenyl and heterocyclic radical or the (C unsubstituted or that replace that replace
3-C
6) cycloalkyl, (C
4-C
6) cycloalkenyl group, in a side of ring, be fused to (the C of the saturated or undersaturated carbocyclic ring of 4-to 6-unit
3-C
6) cycloalkyl the or be fused to (C of the saturated or undersaturated carbocyclic ring of 4-to 6-unit in a side of ring
4-C
6) cycloalkenyl group, wherein below 4 kinds of groups each is unsubstituted or replaced by following one or more groups naturally: halogen, hydroxyl, cyano group, (C
1-C
4) alkyl, (C
1-C
4) haloalkyl, (C
1-C
4) alkoxyl, (C
1-C
4) halogenated alkoxy, (C
1-C
4) alkylthio group, (C
1-C
4) alkyl amino, two [(C
1-C
4) alkyl] amino, [(C
1-C
4) alkoxyl] carbonyl, [(C
1-C
4) halogenated alkoxy] carbonyl, the unsubstituted or (C that replaces
3-C
6) cycloalkyl, unsubstituted or the phenyl and the heterocyclic radical unsubstituted or that replace that replace,
Or
R
h 3(C
1-C
4)-alkoxyl, (C
2-C
4) alkene oxygen base, (C
2-C
6) alkynyloxy group or (C
2-C
4) halogenated alkoxy, and
R
h 4hydrogen or (C
1-C
4)-alkyl, or
R
h 3and R
h 4nitrogen-atoms together with Direct Bonding is four to eight yuan of heterocycles, except nitrogen-atoms, it can also contain further ring hetero atom, preferably up to two from the further ring hetero atom of N, O and S, and it is unsubstituted or is replaced by following one or more groups: halogen, cyano group, nitro, (C
1-C
4) alkyl, (C
1-C
4) haloalkyl, (C
1-C
4) alkoxyl, (C
1-C
4) halogenated alkoxy and (C
1-C
4) alkylthio group.
S16) mainly as weed killer herbicide, also crop plants there is the active component of safener effect, for example (2, 4-dichlorophenoxy) acetic acid (2, 4-D), (4-chlorophenoxy) acetic acid, (R, S)-2-(the chloro-oxy-o-cresyl of 4-) propionic acid (mecoprop), 4-(2, 4-dichlorophenoxy) butyric acid (2, 4-DB), (the chloro-oxy-o-cresyl of 4-) acetic acid (MCPA), 4-(the chloro-oxy-o-cresyl of 4-) butyric acid, 4-(4-chlorophenoxy) butyric acid, 3, the chloro-O-Anisic Acid of 6-bis-(dicamba), 1-(ethoxy carbonyl) ethyl 3, the chloro-O-Anisic Acid ester of 6-bis-(lactidichlor-ethyl).
Affect the material of plant maturation:
When using in mixture preparation or groove mixture (tankmix) according to the present invention, being used for according to the available combination gametophyte of the compound of formula (I) is for example based on suppressing following known activity composition: for example, 1-Aminocyclopropane-1-carboxylate synthase, 1-amino-cyclopropane-1-carboxylic oxidase and ethylene receptor, for example ETR1, ETR2, ERS1, ERS2 or EIN4, as for example Biotechn. Adv. 2006,24,357-367; Bot. Bull. Acad. Sin. 199,40,1-7 or Plant Growth Reg. 1993,13, describe in 41-46 and the document wherein quoted.
Affect plant ripe and can comprise with the example of the known substance of the compounds of this invention combination following active component (compound by according to International Standards Organization (International Organization for Standardization) " common name " or chemical name or code name name (ISO)), and comprise all the time all types of service, for example acid, salt, ester and isomer, for example stereoisomer and optical isomer.For example, mention following a kind of type of service and multiple type of service in some cases:
Rhizobiotoxin, 2-amino ethoxy vinyl glycine (AVG), methoxy-ethylene base glycine (MVG), vinyl glycine, amino oxygen guanidine-acetic acid, Sinefungin, adenosylhomocysteine, 2-ketone-4-methyl thiobutyrate, 2-(methoxyl group)-2-oxoethyl (isopropyl subunit) aminooxoacetic acid ester, 2-(own oxygen base)-2-oxoethyl (isopropyl subunit) aminooxoacetic acid ester, 2-(isopropyl oxygen base)-2-oxoethyl (ring caproic subunit) aminooxoacetic acid ester, putrescine, spermidine, spermine, 1,8-diaminourea-4-amino-ethyl octane, L-canaline, daminozide, amino cyclopropyl-1-the methyl formate of 1-, N-methyl isophthalic acid-amino cyclopropyl-1-formic acid, amino cyclopropyl-1-the formamide of 1-, amino cyclopropyl-1-the formic acid derivates of 1-replacing, as DE3335514, EP30287, described in DE2906507 or US5123951, the amino cyclopropyl-1-hydroxamic acid of 1-, 1-methyl cyclopropene, 3-methyl cyclopropene, 1-ethyl cyclopropylene, 1-n-pro-pyl cyclopropylene, 1-cyclopropanyl methyl alcohol, carvol, eugenol, ring third-1-alkene-1-guanidine-acetic acid sodium, ring third-2-alkene-1-guanidine-acetic acid sodium, 3-(ring third-2-alkene-1-yl) sodium propionate, 3-(ring third-1-alkene-1-yl) sodium propionate, jasmonic, methyl jasmonate, jasmonic ethyl ester.
Affect the material of plant health and germination:
Available combination gametophyte for the compounds of this invention at mixture preparation or groove mixture is the known activity composition that affects plant health or germination.Affect plant health and germination and can comprise with the example of the known substance of the compounds of this invention combination following active component (compound by according to " common name " of International Standards Organization (ISO) or chemical name or code name name), and comprise all the time all types of service, for example acid, salt, ester and isomer, for example stereoisomer and optical isomer.For example, mention following a kind of type of service and multiple type of service in some cases: methyl amimoacetic acid, phenylalanine, tryptophan, N'-methyl isophthalic acid-phenyl-1-N, N-diethylamino Methanesulfomide, as apiose-galacturonic acid glycan of describing in WO2010017956, 4-oxo-4-[(2-phenylethyl) amino] butyric acid, 4-{[2-(1H-indol-3-yl) ethyl] amino }-4-ketobutyric acid, 4-[(3-picoline-2-yl) amino]-4-ketobutyric acid, allantoin, 5-ALA, (2S, 3R) described in WO2010122956-2-(3,4-dihydroxy phenyl)-3,4-dihydro-2H-chromene-3, relevant catechin in 5,7-trihydroxylic alcohol and structure, 2-hydroxyl-4-(methyl sulfanyl) butyric acid, (3E, 3 α R, 8 β S)-3-described in EP2248421 ({ [(2R)-4-methyl-5-oxo-DHF-2-yl] oxygen base } methylene)-3,3 α, 4,8 beta-tetrahydros-2H-indeno [1,2-b] furans-2-ketone and relevant lactone, abscisic acid, (2Z, 4E)-5-[6-acetenyl-1-hydroxyl-2,6-dimethyl-4-oxo hexamethylene-2-alkene-1-yl]-3-methylpent-2,4-dienoic acid, methyl-(2Z, 4E)-5-[6-acetenyl-1-hydroxyl-2,6-dimethyl-4-oxo hexamethylene-2-alkene-1-yl]-3-methylpent-2,4-diene acid esters.
Weed killer herbicide or plant growth regulator:
Available combination gametophyte for the purposes of the present invention at the compound of mixture preparation or groove mixture Chinese style (I) is for example based on suppressing following known activity composition: acetolactate synthase, acetyl-CoA carboxylase, cellulose synthase, enol acetone shikimic acid-3-phosphate synthase, glutamine synthelase, p _ Hydroxyphenyl pyruvic acid dioxygenase, phytoene dehydrogenase, Photosystem I, Photosystem I I, proporphyrinogen oxidase, gibberellin biosynthesis, as for example Weed Research 26 (1986) 441-445 or " The Pesticide Manual ", the 15th edition, The British Crop Protection Council and the Royal Soc. of Chemistry, 2009 and the document wherein quoted in describe.
Can comprise following active component (compound by according to " common name " of International Standards Organization (ISO) or chemical name or code name name) with the known weed killer herbicide of the compounds of this invention combination or the example of plant growth regulator, and comprise all the time all types of service, for example acid, salt, ester and isomer, for example stereoisomer and optical isomer.For example, mention following a kind of type of service and multiple type of service in some cases:
Possible mixing gametophyte from weed killer herbicide group is:
Acetochlor, acifluorfen, acifluorfen sodium, aclonifen, alachlor, allidochlor, alloxydimsodium, alloxydimsodium sodium, ametryn, amicarbazone, first alachlor, amidosulfuron, encircle the third pyrimidine acid, encircle the third pyrimidine acid potassium, encircle the third pyrimidine acid methyl esters, chlorine Fampridine, Amrol, Amcide Ammate, anilofos, the spirit of sulphur grass, atrazine, azoles pyridine alkynes grass, azimsulfuron, beflubutamid, benazolin, ethyl benazolin, benfluralin, benfuresate, bensulfuron-methyl, methyl bensulfuron-methyl, bensulide, bentazone, benzo dicyclo ketone, benzofenap, dicyclo pyrones (bicyclopyrone), bifenox, bialaphos, bialaphos sodium, two careless ether, two careless ether sodium, bromacil, bromobutide, bromofenoxim, Brominal, Brominal potassium, enanthic acid Brominal, sad Brominal, butyric acid Brominal, hydroxyl humulone, butachlor, butafenacil, butamifos, butenachlor, butralin, butroxydim, butylate, cafenstrole, carbetamide, azoles humulone, carfentrazoneethyl, chloramben, bromax, Fenac, Fenac sodium, Bidisin, chlorflurenol, methyl chlorflurenol, Pynamin, chlorimuronethyl, ethyl chloride Sulfometuron Methyl, chlorine phthalimide, chlortoluron, chlorine dimethyl phthalate, chlorine sulphur is grand, indolone grass, ethylindole ketone grass, cinmethylin, cinosulfuron, clethodim, alkynes oxalic acid, clodinafop-propargyl, clomazone, clomeprop, clopyralid, cloransulammethyl, methyl cloransulammethyl, cumyluron, cyanamide, cyanazine, cycloate, AC322140, cycloxydim, cyhalofop-butyl, cyhalofop-butyl-butyl, cyprazine, 2,4-D, 2,4-D-butoxy (butoxyl),-butyl,-Dimethyl Ammonium,-diolamin,-ethyl,-2-ethylhexyl,-isobutyl group,-iso-octyl,-isopropyl ammonium,-potassium,-tri-isopropyl alcohol ammoniums and-triethanolamine, 2,4-DB, 2,4-DB-butyl,-Dimethyl Ammonium,-iso-octyl,-potassium and-sodium, daimuron (daimuron, dymron), dalapon, dazomet, Decanol, desmedipham, detosyl-pyrazolate (DTP), dicamba, dichlobenil, drip propionic acid, drip propionic acid-P, diclofop-methyl, diclofop-methyl-methyl, diclofop-methyl-P-methyl, diclosulam, difenzoquat, diflufenican, diflufenzopyr, diflufenzopyr sodium, oxazole is grand, dimepiperate, dimethachlor, dimethametryn, dimethenamid, dimethenamid-P, ether Huang is grand, dinitramine, dinoterb, diphenamide, diquat, dibromo diquat, dithiopyr, diuron, DNOC, endothal, EPTC, esprocarb, ethalfluralin, ethametsulfuron, methyl amine tribenuron-methyl, ethiozin, ethofumesate, ethoxyfenethyl, ethoxyfen-ethyl, ethoxysulfuron, ethobenzanid, F-5331 is the fluoro-5-[4-of the chloro-4-of N-[2-(3-fluoropropyl)-4,5-dihydro-5-oxo-1H-TETRAZOLE-1-yl]-phenyl]-ethane sulphonamide, F-7967 is the fluoro-2-of the chloro-5-of 3-[7-(trifluoromethyl)-1H-benzimidazole-4-yl]-1-methyl-6-(trifluoromethyl) pyrimidine-2,4 (1H, 3H)-diketone (dion), oxazole diclofop-methyl, oxazole diclofop-methyl-P, Yi Ji oxazole diclofop-methyl, oxazole diclofop-methyl-P-ethyl, fenoxasulfone, fentrazamide, wheat straw volt, flampropisopropyl-M, flampropmethyl-M, flazasulfuron, florasulam, fluazifop, fluazifop-P, fluazifop-butyl, fluazifop-P-butyl, flucarbazonesodium, flucarbazonesodium sodium, flucetosulfuron, fluchloraline, flufenacet (thifluzamide, thiazole oxamide), flufenpyrethyl, ethyl flufenpyrethyl, Flumetsulam, Flumiclorac pentyl, amyl group Flumiclorac pentyl, flumioxazin, fluometuron, fluoroglycofen-ethyl, fluoroglycofen-ethyl, tetrafluoro propionic acid, flupyrsulfuron-methyl-sodium, flupyrsulfuron-methyl-sodium-methyl-sodium, flurenol, butyl flurenol, fluridone, fluorochloridone, fluroxypyr, methyl fluroxypyr, flurtamone, fluorine thiophene grass ester, fluthiacet-methyl, flufenacet, fomesafen, fomesafen sodium, foramsulfuron, ioxynil, grass fourth phosphine, grass ammonium phosphine, grass fourth phosphine-P, grass fourth phosphine-P-ammonium, grass fourth phosphine-P-sodium, glyphosate, glyphosate-isopropyl ammonium,-ammonium,-bis-ammoniums,-Dimethyl Ammonium,-potassium,-sodium and-trimethyl sulfosalt, H-9201 is O-(2,4-dimethyl-6-nitrobenzophenone)-O-ethyl-isopropylthio phosphate, halosulfuronmethyl, methyl chloride pyrazosulfuron, fluazifop-butyl, fluazifop-butyl-P, fluazifop-butyl-ethoxyethyl group, fluazifop-butyl-P-ethoxyethyl group, haloxyfop-P-methyl, haloxyfop-P-methyl-P, hexazinone, HW-02 is 1-(dimethoxyphosphoryl)-ethyl-(2,4-dichlorophenoxy) acetic acid esters, miaow oxalic acid, methyl miaow oxalic acid, imazamox, imazamox ammonium, imazapic, imazapic-ammonium, imazapyr, imazapyr-isopropyl ammonium, imazaquin, imazaquin-ammonium, imazethapyr, imazethapyr-ammonium, imazosulfuron, indanofan, triazine indenes grass amine, iodine sulphur is grand, iodine sulphur is grand-methyl-sodium, ioxynil, ioxynil-sodium, ioxynil-potassium, ioxynil-caprylate, Chinese mugwort minute carbazones, isoproturon, Yi Evil is grand, Yi Evil acyl grass amine, isoxazole humulone, karbutilate, KUH-043 is 3-({ [5-(difluoromethyl)-1-methyl-3-(trifluoromethyl)-1H-pyrazoles-4-yl] methyl } sulfonyl)-5,5-dimethyl-4,5-dihydro-1,2-oxazole, ketospiradox, lactofen, lenacil, lorox, MCPA (salt and ester), MCPB (salt and ester), MCPB-methyl,-ethyl is with – sodium, mecoprop, mecoprop-sodium, with-butoxy, mecoprop-P, mecoprop-P-butoxy,-Dimethyl Ammonium,-2-ethylhexyl is with – potassium, mefenacet, mefluidide, mesosulfuronmethyl, methyl mesosulfuronmethyl, mesotrione, metham-sodium, oxazole acyl grass amine, metamitron, metazachlor, metazosulfuron, methabenzthiazuron, Sulfonylurea, thiophene grass ether, methyl-isorhodanate, metobromuron, isopropyl methoxalamine, S-isopropyl methoxalamine, metosulam, metoxuron, piperazine humulone, metsulfuron-methyl, methyl metsulfuron-methyl, molinate, afesin, monosulfmeturon, monosulfmeturon ester, MT-128 is the chloro-N-[(2E of 6-)-3-chlorine third-2-alkene-1-yl]-5-methyl-N-phenyl pyridazine-3-amine, MT-5950 is the chloro-4-of N-[3-(1-Methylethyl)-phenyl]-2-methylpent acid amides, NGGC-011, napropamide, NC-310 is 4-(2,4-dichloro-benzoyl base)-1-methyl-5-benzyloxy pyrazoles, neburea, nicosulfuron, n-nonanoic acid, norflurazon, oleic acid (fatty acid), orbencarb, phonetic aniline sulphur is grand, oryzalin, Que Bing oxazole grass, Evil humulone, oxasulfuron, go barnyard grass peace, Oxyfluorfen, paraquat, PP-148, pebulate, n-nonanoic acid (Nonans ure), pendimethalin, penoxsuam, pentachlorophenol, Huan Wu Evil humulone, pethoxamid, oil, phenmedipham, ethyl phenmedipham, picloram, fluorine pyrrole acyl grass amine, azoles quinoline grass ester, piperophos, the third careless amine, primisulfuronmethyl, fluoromethane Sulfometuron Methyl, prodiamine, trefanocide, clefoxidim, prometryn, prometryn, propachlor, Stam F-34, Evil oxalic acid, propazine, propham, propisochlor, propoxyl group carbazones, propoxyl group carbazones-sodium, propyrisulfuron, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyrrole grass ether, ethyl pyrrole grass ether, sulphonyl grass pyrazoles, pyrazolate (pyrazolate, pyrazolate), pyrazosulfuron, ethyl pyrazosulfuron, pyrazoxyfen, ester grass ether, iso-propyl-ester nitrofen, propyl-ester nitorfen, pyribenzoxim, pyributicarb, the careless alcohol of rattling away, pyridate, pyriftalid, KIH 6127, methyl KIH 6127, flumetsulam, pyrithiobac-sodium, pyrithiobac-sodium-sodium, pyroxasulfone, pyroxsulam, dichloro quinolinic acid, quinmerac, quinoclamine, quizalofop-ethyl, quizalofop-ethyl-ethyl, quizalofop-ethyl-P, quizalofop-ethyl-P-ethyl, quizalofopPtefuryl, rimsulfuron, benzene flumetsulam, sethoxydim, Tupersan, Simanex, symetryne, sulphur humulone, sulfentrazone, sulfometuronmethyl, methyl sulfometuronmethyl, sulphosate, Tupersan, SW-065, SYN-523, SYP-249 is 1-ethyoxyl-3-methyl isophthalic acid-oxo fourth-3-chloro-4-of alkene-2-base-5-[2-(trifluoromethyl) phenoxy group]-2-nitrobenzoyl acid esters, SYP-300 is the fluoro-3-oxo-4-of 1-[7-(third-2-alkynes-1-yl)-3,4-dihydro-2H-1,4-benzoxazole-6-yl]-3-propyl group-2-thiocarbamoyl imidazole quinoline-4,5-diketone, TCA (trichloroacetic acid), TCA-sodium, tebuthiuron, special chaff ester ketone, ring sulphur ketone, tepraloxydim, terbacil, terbucarb, Te Dingtong, Garagard, terbutryn, P DimethenamidP, thiophene grass is fixed, thiophene ketone sulphur is grand, methyl thiazolium ketone sulphur is grand, thifensulfuronmethyl, methylthiophene sulphur is grand, benthiocarb, benzene pyrazoles humulone, tralkoxydim, fluorine ketone sulphur grass amine, triallate, triasulfuron, triaziflam, tribenuron-methyl, methyl tribenuron-methyl, Triclopyr, trietazine, trifloxysulfuron, trifloxysulfuron-sodium, trefanocide, triflusulfuronmethyl, methyl triflusulfuronmethyl, tritosulfuron, ureasulfuric acid, vernolate, ZJ-0862 i.e. the chloro-N-{2-[(4 of 3,4-bis-, 6-dimethoxypyridin-2-yl) oxygen base] benzyl } aniline and following compound:
。
The gametophyte that may mix from plant growth regulator group is for example:
Abscisic acid, thiadiazoles element, thiadiazoles element-S-methyl, 5-ALA, ancymidol, 6-benzyl aminopurine, brassin lactones, catechin, adjust tartaric acid, cyclanilide, 3-(ring third-1-thiazolinyl) propionic acid, 3-(ring third-1-thiazolinyl) propionic acid, sodium salt, daminozide, dazomet, Decanol, dikegulac, dikegulac-sodium, endothal, flumetralim, flurenol, butyl flurenol, flurprimidol, CPPU, gibberellic acid, inabenfide, indole-3-acetic acid (IAA), 4-indol-3-yl butyric acid, Isoprothiolane, jasmonic, methyl jasmonate, kinetin, maleic acid hydrazide, mepiquate chloride (mepiquat chloride), 1-methyl cyclopropene, 2-(1-naphthyl) acetamide, 1-naphthyl acetic acid, 2-naphthoxyacetic acid, nitrophenolate-mixture, 4-oxo-4[(2-phenylethyl) amino] butyric acid, paclobutrazol, N-phenyl phthalamidic acid, probenazole, adjust naphthenic acid, adjust naphthenic acid-calcium, jasmone, propham, salicylic acid, witchweed lactone, tecnazene, Thidiazuron, triacontanol, anti-fall ester, tsitodef, uniconazole P, uniconazole P-P.
The present invention illustrates by following biology embodiment, but is not limited to this.
Biology embodiment
A) test condition
A1) test condition in greenhouse test
Used the tank test with 8 cm diameter tanks, under the normal excellent growing conditions for plant, in greenhouse, tested.Each tank comprises 6-8 strain plant.Result is the mean value of twice repetition.
Application by seed treatment, emerge before or the post processing of emerging complete.Before or after emerging, application is undertaken by spraying, and uses 100-300 l/ water/hectare.Crop plants species and when application crop plants vegetative stage be reported in result table.In combination, the dose rate of the herbicidal activity composition of application is also mentioned in result table separately respectively.
Evaluate by visual grading (0-100% grade, as after application several days that point out in result table, more treated with respect to undressed inspection tank) and complete.Result (as the mean value on all plant/tanks with as at 2 mean values that repeat) is shown in below in result table.
A2) test condition in field trial
(tank test, 10 square metres of tanks repeat for 2-4 time) are carried out in test under natural field condition.
Application by seed treatment, emerge before or the post processing of emerging complete, by directly (independent once application), or sequential processing example is if seed treatment is subsequently for spraying application before emerging and/or after emerging.Before emerging or after emerging, applying by spray application uses 100-300 l/ water/hectare to carry out.When application, the vegetative stage of crop species is reported in result table.In sequential application, the dose rate of the herbicidal activity composition of application is also described in result table separately respectively.
Evaluate by visual grading (0-100% grade) or counted.Test is gathered in the crops after crop reaches full maturity.After results, measure benevolence/seed/beet gross weight of every tank.Result is as the mean value report repeating at 2-4.Time between application and evaluation or counting/results describes equally in result table.
A3) seed treatment condition
Active component is applied to undressed dry seed together with carrier.After making the short time period of seed drying, they can use standard facility sowing at any time in tank or field.
B) abbreviation in result table
Ai=active component (based on 100% active component)
CPA=cyclopropyl-sulfonylamide (compound of the present invention (A1))
Dosage [g/ai]=with a gram dose rate for active component/hectare
EPC=epoxiconazole (F-108 of the present invention)
Fb=be (sequential application) subsequently
Mg ai/ seed=milligram active component/seed (/ benevolence)
G ai/kg seed=gram active component/kg seed
Before emerging=application (spraying) (before emerging) after seed plantation
After emerging=application (spraying) after crop plants is emerged
PTC=prothioconazoles (F-124 of the present invention)
ST=as seed treatment application (before plantation)
TBC=Tebuconazole (F-127 of the present invention)
TFS=oxime bacterium ester (F-60 of the present invention)
UTC=undressed contrast
The grain yield (ripe benevolence) of the results of output [t/ha]=represent with metric ton (1000 kg)/hectare.
C) result in field trial
Table 1: the grain yield effect to corn (maize) after using the seed treatment of cyclopropyl-sulfonylamide
1)application: the seed treatment before plantation
2)output: at latter 110 days of plantation (short season kind), grain yield during results.
Table 2: the germination of rice plant and emerging after the seed treatment with cyclopropyl-sulfonylamide
1)application: seed treatment (prior to seeding)
2)evaluate: emerge latter 12 days.
Table 3: to application before the emerging of cyclopropyl-sulfonylamide for the grain yield Zuo Yong – of winter wheat
1)application: the autumn before emerging
2)output: in application latter 247 days, grain yield during results.
Table 4: to application after the emerging of the grain yield effect-cyclopropyl-sulfonylamide of spring wheat
1)application: start to occur ear fringe (GS49)
2)output: in application latter 48 days, grain yield during results.
Table 5: to application after the emerging of the grain yield effect-cyclopropyl-sulfonylamide of corn
1)application: 6-8 leaf
2)output: in application latter 130 days, grain yield during results.
Table 6: to application after the emerging of output effect-cyclopropyl-sulfonylamide of cotton
1)application: before blooming (GS 55)
2)output: in application latter 90 days, cotton velveteen output during results.
Table 7: to application after the emerging of output effect (the glutelin content)-cyclopropyl-sulfonylamide of spring wheat
1)application: ear fringe occurs
2)output: in application latter 35 days, the glutelin content (absolute) in results grain
3)output: in application latter 35 days, the relative glutelin content in results grain.
Table 8: to application after the emerging of grain yield effect-cyclopropyl-sulfonylamide of soybean
1)application: before blooming (GS 60)
2)output: in application latter 45 days, grain yield during results.
Table 9: the sequential application to the grain yield effect-cyclopropyl-sulfonylamide of canola
1)application: the 1. seed treatment fb before plantation
2. after emerging when 4 – 6 leaf fb
3. after emerging when stem extends fb
4. after emerging when starting to bloom
2)output: in application latter 63 days, grain yield during results.
Table 10: the post processing of emerging to the grain yield Zuo Yong – of canola with cyclopropyl-sulfonylamide
1)application: vegetative stage (GS 52)-before blooming
2)output: in processing latter 63 days, grain yield during results.
Table 11: the sequential application to the grain yield effect-cyclopropyl-sulfonylamide of corn
1)application: the 1. seed treatment fb before plantation
2. after emerging when 2 – 4 leaf fb
3. after emerging when 6 – 8 leaf fb
4. after emerging before blooming
2)output: after emerging 98 days, grain yield during results.
Table 12: the sequential application to the output effect-cyclopropyl-sulfonylamide of corn
1)application: the 1. seed treatment fb before plantation
2. after emerging when 2 – 4 leaf fb
3. after emerging when 6 – 8 leaf fb
4. after emerging before blooming time
2)output: after emerging 98 days, biomass yield during results
3)output: after emerging 98 days, plant density during results.
Table 13: the sequential application to the output effect-cyclopropyl-sulfonylamide of beet
1)application: the 1. seed treatment fb before plantation
2. after emerging when 2 – 4 leaf fb
3. after emerging when 6 – 8 leaf fb
4. after emerging when 10 – 12 leaf
2)output: emerge and process latter 44 days at last, candy output during results
3)output: emerge and process latter 44 days at last, Sugarbeet Yield (storing root/main body) by weight during results.
Table 14: the seed treatment to the grain yield Zuo Yong – of winter wheat with cyclopropyl-sulfonylamide
1)application: the seed treatment before plantation
2)output: in plantation latter 290 days, grain yield during results.
Table 15: the sequential application to grain yield effect-cyclopropyl-sulfonylamide of rice
1)application: the 1. seed treatment fb before plantation
2. after emerging when 4 – 6 leaf fb
3. after emerging when stem extends fb
4. after emerging when starting to bloom
2)output: apply latter 75 days at last, grain yield during results.
Table 16: the post processing of emerging to grain yield Zuo Yong cyclopropyl-sulfonylamide (CPA)+epoxiconazole (EPC) for – of spring wheat
1)application: the Hou – boot leaf sheath of emerging spring is opened
2)output: in application latter 55 days, grain yield during results.
Table 17: the post processing of emerging to grain yield Zuo Yong cyclopropyl-sulfonylamide (CPA)+prothioconazoles (PTC)+Tebuconazole (TBC) for – of spring wheat
1)application: the Hou – boot leaf sheath of emerging spring is opened
2)output: in application latter 55 days, grain yield during results.
Table 18: the post processing of emerging to the grain yield Zuo Yong of corn cyclopropyl-sulfonylamide (CPA)+(prothioconazoles (PTC)+oxime bacterium ester (TFS)) for –
1)application: the Hou – of emerging starts to bloom
2)output: in application latter 122 days, grain yield during results.
Table 19: the post processing of emerging to grain yield Zuo Yong cyclopropyl-sulfonylamide (CPA)+Tebuconazole (TBC) for – of oilseed rape in spring (canola)
1)application: the Hou – of emerging starts to bloom
2)output: in application latter 92 days, grain yield during results.
Table 20: the post processing of emerging to grain yield Zuo Yong cyclopropyl-sulfonylamide (CSA)+(2,4-D+MCPA) for – of spring wheat
1)application: the Hou – of emerging starts to bloom
2)output: in application latter 55 days, grain yield during results.
Claims (20)
1. the purposes of compound (A) output with regard to the plant organ of its results for increasing useful plant or crop plants, described plant grows in its normal habitat, and wherein said compound (A) is selected from the compound or its salt of formula (I)
Wherein
X is CH or N;
R
1be-CO-NR
5r
6,-NH-CO-R
7or-NH-CO-NR
8r
9,
If n is 1, (R
2)
nr
2group, if or n surpass 1, (R
2)
nrepresentative is connected to n R of the different carboatomic ring atoms of foundation ring
2group, wherein each R
2halogen, (C independently of one another
1-C
4) haloalkyl, (C
1-C
4) halogenated alkoxy, nitro, (C
1-C
4) alkyl, (C
1-C
4) alkoxyl, (C
1-C
4) alkyl sulphonyl, [(C
1-C
4) alkoxyl] carbonyl or [(C
1-C
4) alkyl] carbonyl,
R
3hydrogen, (C
1-C
4) alkyl, (C
2-C
4) thiazolinyl or (C
2-C
4) alkynyl,
If m is 1, (R
4)
mr
4group, if or m surpass 1, (R
4)
mrepresentative is connected to m R of the different carboatomic ring atoms of foundation ring
4group, wherein each R
4halogen, nitro, (C independently of one another
1-C
4) alkyl, (C
1-C
4) haloalkyl, (C
1-C
4) halogenated alkoxy, (C
3-C
6) cycloalkyl, phenyl, (C
1-C
4) alkoxyl, cyano group, (C
1-C
4) alkylthio group, (C
1-C
4) alkyl sulphinyl, (C
1-C
4) alkyl sulphonyl, [(C
1-C
4) alkoxyl] carbonyl or [(C
1-C
4) alkyl] carbonyl;
R
5hydrogen, (C
1-C
6) alkyl, (C
3-C
6) cycloalkyl, (C
2-C
6) thiazolinyl, (C
2-C
6) alkynyl, (C
5-C
6) cycloalkenyl group, phenyl or have be selected from the heteroatomic 3-to 6-of nitrogen, oxygen and sulphur 1-3 unit heterocyclic radical, each of 7 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
6) alkoxyl, (C
1-C
6) halogenated alkoxy, (C
1-C
2) alkyl sulphinyl, (C
1-C
2) alkyl sulphonyl, (C
3-C
6) cycloalkyl, (C
1-C
4) alkoxy carbonyl, [(C
1-C
4) alkyl] carbonyl and phenyl, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
R
6hydrogen, (C
1-C
6) alkyl, (C
3-C
6) cycloalkyl, (C
2-C
6) thiazolinyl or (C
2-C
6) alkynyl, each of 3 kinds of groups finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, hydroxyl, (C
1-C
4) alkyl, (C
1-C
4) alkoxyl and (C
1-C
4) alkylthio group, or
R
5and R
6together with the nitrogen-atoms connecting, represent pyrrolidin-1-yl-or piperidin-1-yl,
R
7hydrogen, (C
1-C
6) alkyl, (C
3-C
6) cycloalkyl, each of 2 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
4) alkoxyl, (C
1-C
6) halogenated alkoxy and (C
1-C
4) alkylthio group, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
R
8hydrogen, (C
1-C
8) alkyl, (C
2-C
6) thiazolinyl, (C
2-C
6) alkynyl or (C
3-C
8) cycloalkyl, each of 4 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
4) alkoxyl, (C
1-C
6) halogenated alkoxy and (C
1-C
4) alkylthio group, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
R
9hydrogen, (C
1-C
8) alkyl, (C
2-C
6) thiazolinyl, (C
2-C
6) alkynyl or (C
3-C
8) cycloalkyl, each of 4 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
4) alkoxyl, (C
1-C
6) halogenated alkoxy and (C
1-C
4) alkylthio group, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
N is 0,1,2,3 or 4, preferably 0,1 or 2, and
M is 0,1,2,3 or 4, preferably 1 or 2.
2. purposes as claimed in claim 1, is characterized in that compound (A) is selected from the compound or its salt of formula (Ia),
(R wherein
2)
n, R
3, (R
4)
m, R
5, R
6, n and m definition as described in about formula (I), and preferably wherein
R
3hydrogen,
If m is 1, (R
4)
mr
4group, if or m surpass 1, (R
4)
mrepresentative is connected to m R of the different carboatomic ring atoms of foundation ring
4group, wherein each R
4halogen, methyl, ethyl, n-pro-pyl, isopropyl, CF independently of one another
3, (C
1-C
4) halogenated alkoxy or (C
1-C
4) alkoxyl,
R
5(C
1-C
6) alkyl or (C
3-C
6) cycloalkyl, each of 2 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
4) alkoxyl, (C
1-C
4) halogenated alkoxy, (C
1-C
2) alkyl sulphinyl, (C
1-C
2) alkyl sulphonyl, (C
3-C
6) cycloalkyl, (C
1-C
4) alkoxy carbonyl and [(C
1-C
2) alkyl] carbonyl, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
R
6hydrogen or (C
1-C
4) alkyl, preferred hydrogen,
M is 0,1 or 2, preferably 1 or 2, and
N is zero.
3. purposes as claimed in claim 1, is characterized in that compound (A) is selected from the compound or its salt of formula (Ib),
(R wherein
2)
n, R
3, (R
4)
m, R
7, n and m definition as described in about formula (I), and preferably wherein
R
3hydrogen,
If m is 1, (R
4)
mr
4group, if or m surpass 1, (R
4)
mrepresentative is connected to m R of the different carboatomic ring atoms of foundation ring
4group, wherein each R
4halogen, (C independently of one another
1-C
4) alkyl, CF
3, (C
1-C
4) halogenated alkoxy or (C
1-C
4) alkoxyl,
R
7(C
1-C
6) alkyl or (C
3-C
6) cycloalkyl, each of 2 kinds of groups wherein finally mentioning is unsubstituted or replaces by being selected from 1,2 or 3 following group: halogen, (C
1-C
4) alkoxyl, (C
1-C
6) halogenated alkoxy and (C
1-C
4) alkylthio group, and the in the situation that of the group of ring-type basis, also have (C
1-C
4) alkyl and (C
1-C
4) haloalkyl,
M is 0,1 or 2, preferably 1 or 2, and
N is zero.
4. purposes as claimed in claim 1, is characterized in that compound (A) is selected from the compound or its salt of formula (Ic),
(R wherein
2)
n, R
3, (R
4)
m, R
8, R
9, n and m definition as described in about formula (I), and preferably wherein
R
3hydrogen,
If m is 1, (R
4)
mr
4group, if or m surpass 1, (R
4)
mrepresentative is connected to m R of the different carboatomic ring atoms of foundation ring
4group, wherein each R
4halogen, (C independently of one another
1-C
4) alkyl, CF
3, (C
1-C
4) halogenated alkoxy or (C
1-C
4) alkoxyl, preferably halogen, (C
1-C
4) alkyl, CF
3or (C
1-C
4) alkoxyl,
R
8hydrogen, (C
1-C
8) alkyl, (C
2-C
6) thiazolinyl, (C
2-C
6) alkynyl or (C
3-C
8) cycloalkyl,
R
9hydrogen, (C
1-C
8) alkyl, (C
2-C
6) thiazolinyl, (C
2-C
6) alkynyl or (C
3-C
8) cycloalkyl,
M is 0,1 or 2, preferably 1 or 2, and
N is zero.
5. purposes as claimed in claim 1 or 2, is characterized in that compound (A) is cyclopropyl-sulfonylamide.
6. the purposes as described in any one in claim 1-5, is characterized in that increasing the grain yield of crop plants, and described crop plants is selected from cereal, canola, soybean and cotton crop.
7. the purposes as described in any one in claim 1-5, is characterized in that increasing the glutelin content of the kind benevolence of crop plants, and described crop plants is selected from cereal, canola and soybean crops.
8. the purposes as described in any one in claim 1-5, is characterized in that increasing the glutelin content of the kind benevolence of crop plants, and described crop plants is selected from cereal.
9. the purposes as described in any one in claim 1-5, is characterized in that increasing the protein content of the kind benevolence of crop plants, and described crop plants is selected from cereal, canola and soybean crops.
10. the purposes as described in any one in claim 1-5, is characterized in that increasing the output of the beet amount by weight of sugar beet plants.
11. purposes as described in any one in claim 1-5, is characterized in that increasing the sugar content of sugar plant.
12. purposes as described in any one in claim 1-5, is characterized in that increasing the germination of cereal and emerging.
13. purposes as described in any one in claim 1-5, is characterized in that being increased in the biomass yield of the maize plant growing in the situation that does not have extreme environmental conditions.
14. purposes as described in any one in claim 1-5, is characterized in that increasing the biomass yield of sugar plant.
15. for increasing useful plant or crop plants the method for the output with regard to the plant organ of its results, described plant grows in its normal habitat, and wherein as the compound limiting in any one in claim 1-5 (A) with effective dose, preferably the amount of plant-less toxicity be applied to as described in crop plants, grow as described in plant seed or as described in the plant place of growing under its normal habitat.
16. according to the method for claim 15, and wherein compound (A) is applied with one or more compound combinations that are selected from fungicide, insecticide and plant growth regulator.
17. according to the method for claim 16, and wherein compound (A) and following applied in any combination: (i) fluoxastrobin and prothioconazoles, (ii) pyraclostrobin and metconazole, (iii) oxime bacterium ester and propiconazole, (iv) oxime bacterium ester and prothioconazoles, (v) prothioconazoles and Tebuconazole, (vi) biphenyl pyrrole bacterium amine and prothioconazoles, (vii) biphenyl pyrrole bacterium amine and Tebuconazole or (viii) biphenyl pyrrole bacterium amine and oxime bacterium ester.
18. according to the method for any one in claim 16 or 17, and wherein compound (A) is as defined in claim 5.
19. plant yield-increasing compositions, its inclusion compound (A) and further comprise the combination of two kinds of fungicides, described combination is selected from:
(i) pyraclostrobin and metconazole, (ii) oxime bacterium ester and propiconazole, (iii) prothioconazoles and Tebuconazole, (iv) fluoxastrobin and prothioconazoles, (v) oxime bacterium ester and prothioconazoles, (vi) biphenyl pyrrole bacterium amine and prothioconazoles, (vii) biphenyl pyrrole bacterium amine and Tebuconazole and (viii) biphenyl pyrrole bacterium amine and oxime bacterium ester.
20. according to the plant yield-increasing composition of claim 19, and wherein compound (A) is as defined in claim 5.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11181702 | 2011-09-16 | ||
| EP11181702.9 | 2011-09-16 | ||
| PCT/EP2012/068096 WO2013037955A1 (en) | 2011-09-16 | 2012-09-14 | Use of acylsulfonamides for improving plant yield |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103929956A true CN103929956A (en) | 2014-07-16 |
| CN103929956B CN103929956B (en) | 2017-02-22 |
Family
ID=46875792
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280056571.6A Expired - Fee Related CN103929956B (en) | 2011-09-16 | 2012-09-14 | Use of acylsulfonamides for improving plant yield |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US10301257B2 (en) |
| EP (1) | EP2755472B1 (en) |
| JP (1) | JP6138797B2 (en) |
| CN (1) | CN103929956B (en) |
| AR (1) | AR087874A1 (en) |
| AU (1) | AU2012307321B2 (en) |
| BR (1) | BR112014006217B1 (en) |
| CA (1) | CA2848620C (en) |
| EA (1) | EA029208B1 (en) |
| MX (1) | MX357299B (en) |
| UA (1) | UA115971C2 (en) |
| WO (1) | WO2013037955A1 (en) |
| ZA (1) | ZA201401482B (en) |
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Also Published As
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| JP6138797B2 (en) | 2017-05-31 |
| CA2848620C (en) | 2020-03-10 |
| AU2012307321A1 (en) | 2014-03-20 |
| BR112014006217A2 (en) | 2017-04-11 |
| US20150291518A1 (en) | 2015-10-15 |
| BR112014006217B1 (en) | 2019-01-15 |
| MX2014002670A (en) | 2014-04-14 |
| AR087874A1 (en) | 2014-04-23 |
| EP2755472A1 (en) | 2014-07-23 |
| US20190233369A1 (en) | 2019-08-01 |
| EA201490616A1 (en) | 2014-08-29 |
| ZA201401482B (en) | 2015-07-29 |
| UA115971C2 (en) | 2018-01-25 |
| CA2848620A1 (en) | 2013-03-21 |
| AU2012307321B2 (en) | 2016-07-14 |
| EP2755472B1 (en) | 2016-08-31 |
| WO2013037955A1 (en) | 2013-03-21 |
| CN103929956B (en) | 2017-02-22 |
| MX357299B (en) | 2018-07-04 |
| JP2014530182A (en) | 2014-11-17 |
| US10301257B2 (en) | 2019-05-28 |
| EA029208B1 (en) | 2018-02-28 |
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