CN103911881A - Printing paste applicable to ramie cotton fabrics - Google Patents
Printing paste applicable to ramie cotton fabrics Download PDFInfo
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- CN103911881A CN103911881A CN201410153986.6A CN201410153986A CN103911881A CN 103911881 A CN103911881 A CN 103911881A CN 201410153986 A CN201410153986 A CN 201410153986A CN 103911881 A CN103911881 A CN 103911881A
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Abstract
The invention relates to a printing paste applicable to ramie cotton fabrics. The printing paste comprises the following components in parts by weight: 20 parts of nanosilicon dioxide modified starch, 18 parts of carboxymethylcellulose, 4 parts of albumen size, 1 part of polyving akohol and 100 parts of deionized water. The printing paste takes the nanosilicon dioxide modified starch and carboxymethylcellulose as main components and the albumen size and the polyving akohol as auxiliary materials, so that all properties of the printing paste meet the printing and dyeing requirements, the conventional sodium alga acid can be replaced and the production costs of printing and dyeing industries can be reduced. The paste is especially suitable for printing and dyeing ramie cotton fabrics.
Description
Technical field
The present invention relates to a kind of printing gum that is applicable to ramie cotton fabric.
Background technology
In printing with reactive dye, thickener is generally used as thickener and regulates the rheological property of mill base.Sodium alginate because it does not react with REACTIVE DYES, tinctorial yield is high, chromatogram is complete, easily from fabric wash away, the advantage such as fabrics feel soft, be the first-selection of printing paste with active dye always.But its price is more expensive, stamp cost is relatively high, and therefore finding the thickener that a kind of # with low cost can print meticulous colored type has become the task of top priority.
Starch is a kind of renewable resource, and its deposit is abundant, easily obtains, but has active hydroxyl on its molecule, easily reacts with dyestuff, therefore in the application of printing paste with active dye, is restricted.
Summary of the invention
The object of the invention is to: overcome the defect of above-mentioned prior art, propose a kind of printing gum that is applicable to ramie cotton fabric.
In order to achieve the above object, the present invention propose a kind of printing gum that is applicable to ramie cotton fabric, its component by mass ratio as follows:
20 parts of nano SiO 2 modified starch, carboxymethyl cellulose 18,4 parts, albumen slurry, polyvinyl alcohol 1,100 parts of deionized waters;
Described nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by carboxymethyl starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, and carboxymethyl starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 110:6:0.2:0.4;
Described carboxymethyl starch is that cornstarch is poured into after absolute alcohol, stirring fully disperses cornstarch and drops in order NaOH, monoxone, and finally drop into etherificate after remaining NaOH, final drying makes, and described cornstarch, NaOH, chloroacetic mass ratio are 100:5:8;
It is in 0.1% sodium hydroxide solution that described albumen slurry adds concentration by soybean protein, at the uniform velocity stirs after 20 minutes at 45 DEG C and obtains after elimination sediment;
Described carboxymethyl cellulose is that the maize straw of pulverizing and absolute alcohol, NaOH are carried out to quaternization, and then under nitrogen protection, adds monoxone and epoxychloropropane to react; Then add NaOH to continue slaking, finally utilizing salt acid for adjusting pH is 8, after being dried, makes.
The printing gum that the present invention is applicable to ramie cotton fabric also has following improvement:
1, the present invention is applicable to the printing gum of ramie cotton fabric, also comprises the Sodium Benzoate of 3 parts by mass.
2, the present invention is applicable to the printing gum of ramie cotton fabric, also comprises the sodium thiosulfate of 3 parts by mass.
3, the present invention is applicable to the printing gum of ramie cotton fabric, also comprises the hydrochloric acid of 2 parts by mass.
Thickener of the present invention is mainly taking nano SiO 2 modified starch, carboxymethyl cellulose as main, and albumen slurry and polyvinyl alcohol are auxiliary, and various aspects of performance can meet printing and dyeing demand, and alternative traditional sodium alginate has reduced the production cost of printing and dyeing enterprise.Thickener of the present invention is adjusted above-mentioned four kinds of batchings, makes it be particularly useful for the printing and dyeing of ramie cotton fabric.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described.
The present embodiment is applicable to the printing gum of ramie cotton fabric, its component by mass ratio as follows:
20 parts of nano SiO 2 modified starch, carboxymethyl cellulose 18,4 parts, albumen slurry, polyvinyl alcohol 1,3 parts of Sodium Benzoates, 3 parts, sodium thiosulfate, 2 parts of hydrochloric acid, 100 parts of deionized waters;
Described nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by carboxymethyl starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, and carboxymethyl starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 110:6:0.2:0.4;
Carboxymethyl starch is that cornstarch is poured into after absolute alcohol, stirring fully disperses cornstarch and drops in order NaOH, monoxone, and finally drop into etherificate after remaining NaOH, final drying makes, and described cornstarch, NaOH, chloroacetic mass ratio are 100:5:8;
It is in 0.1% sodium hydroxide solution that albumen slurry adds concentration by soybean protein, at the uniform velocity stirs after 20 minutes at 45 DEG C and obtains after elimination sediment;
Carboxymethyl cellulose is that the maize straw of pulverizing and absolute alcohol, NaOH are carried out to quaternization, and then under nitrogen protection, adds monoxone and epoxychloropropane to react; Then add NaOH to continue slaking, finally utilizing salt acid for adjusting pH is 8, after being dried, makes.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of requirement of the present invention.
Claims (4)
1. be applicable to a printing gum for ramie cotton fabric, its component by mass ratio as follows:
20 parts of nano SiO 2 modified starch, carboxymethyl cellulose 18,4 parts, albumen slurry, polyvinyl alcohol 1,100 parts of deionized waters;
Described nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by carboxymethyl starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, and carboxymethyl starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 110:6:0.2:0.4;
Described carboxymethyl starch is that cornstarch is poured into after absolute alcohol, stirring fully disperses cornstarch and drops in order NaOH, monoxone, and finally drop into etherificate after remaining NaOH, final drying makes, and described cornstarch, NaOH, chloroacetic mass ratio are 100:5:8;
It is in 0.1% sodium hydroxide solution that described albumen slurry adds concentration by soybean protein, at the uniform velocity stirs after 20 minutes at 45 DEG C and obtains after elimination sediment;
Described carboxymethyl cellulose is that the maize straw of pulverizing and absolute alcohol, NaOH are carried out to quaternization, and then under nitrogen protection, adds monoxone and epoxychloropropane to react; Then add NaOH to continue slaking, finally utilizing salt acid for adjusting pH is 8, after being dried, makes.
2. the printing gum that is applicable to ramie cotton fabric according to claim 1, is characterized in that: the Sodium Benzoate that also comprises 3 parts by mass.
3. the printing gum that is applicable to ramie cotton fabric according to claim 2, is characterized in that: the sodium thiosulfate that also comprises 3 parts by mass.
4. the printing gum that is applicable to ramie cotton fabric according to claim 3, is characterized in that: the hydrochloric acid that also comprises 2 parts by mass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410153986.6A CN103911881A (en) | 2014-04-17 | 2014-04-17 | Printing paste applicable to ramie cotton fabrics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410153986.6A CN103911881A (en) | 2014-04-17 | 2014-04-17 | Printing paste applicable to ramie cotton fabrics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103911881A true CN103911881A (en) | 2014-07-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410153986.6A Pending CN103911881A (en) | 2014-04-17 | 2014-04-17 | Printing paste applicable to ramie cotton fabrics |
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| CN (1) | CN103911881A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107869055A (en) * | 2017-10-31 | 2018-04-03 | 常州市尚泽纺织品有限公司 | A kind of preparation method of the wear-resisting spinning sizing agent of high viscosity |
| CN107956154A (en) * | 2017-12-20 | 2018-04-24 | 苏州润弘贸易有限公司 | Ramie cotton fabric printing gum |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6139590A (en) * | 1999-03-15 | 2000-10-31 | Burlington Chemical Co., Inc. | Post-dye screen color printing |
| CN101768877A (en) * | 2009-01-05 | 2010-07-07 | 金军 | Sodium alginate composite printing paste and application thereof |
| CN102011327A (en) * | 2010-12-10 | 2011-04-13 | 毕贤程 | Printing and dyeing process of cotton fabrics |
-
2014
- 2014-04-17 CN CN201410153986.6A patent/CN103911881A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6139590A (en) * | 1999-03-15 | 2000-10-31 | Burlington Chemical Co., Inc. | Post-dye screen color printing |
| CN101768877A (en) * | 2009-01-05 | 2010-07-07 | 金军 | Sodium alginate composite printing paste and application thereof |
| CN102011327A (en) * | 2010-12-10 | 2011-04-13 | 毕贤程 | Printing and dyeing process of cotton fabrics |
Non-Patent Citations (1)
| Title |
|---|
| 马晨红: "新型印花糊料的研究及应用", 《河南科学》, vol. 18, no. 3, 30 September 2000 (2000-09-30), pages 267 - 269 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107869055A (en) * | 2017-10-31 | 2018-04-03 | 常州市尚泽纺织品有限公司 | A kind of preparation method of the wear-resisting spinning sizing agent of high viscosity |
| CN107956154A (en) * | 2017-12-20 | 2018-04-24 | 苏州润弘贸易有限公司 | Ramie cotton fabric printing gum |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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Application publication date: 20140709 |