CN103898752B - A kind of spinning sizing agent being applicable to a high COTTON FABRIC - Google Patents
A kind of spinning sizing agent being applicable to a high COTTON FABRIC Download PDFInfo
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- CN103898752B CN103898752B CN201410147345.XA CN201410147345A CN103898752B CN 103898752 B CN103898752 B CN 103898752B CN 201410147345 A CN201410147345 A CN 201410147345A CN 103898752 B CN103898752 B CN 103898752B
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- Prior art keywords
- parts
- cotton fabric
- applicable
- sizing agent
- high cotton
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- Expired - Fee Related
Links
- 238000004513 sizing Methods 0.000 title claims abstract description 23
- 239000004744 fabric Substances 0.000 title claims abstract description 18
- 229920000742 Cotton Polymers 0.000 title claims abstract description 17
- 238000009987 spinning Methods 0.000 title claims abstract description 15
- 239000002002 slurry Substances 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000003921 oil Substances 0.000 claims abstract description 12
- 239000013530 defoamer Substances 0.000 claims abstract description 10
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 10
- 229920000881 Modified starch Polymers 0.000 claims abstract description 9
- 239000004368 Modified starch Substances 0.000 claims abstract description 9
- 235000019426 modified starch Nutrition 0.000 claims abstract description 9
- 229910004298 SiO 2 Inorganic materials 0.000 claims abstract description 8
- 239000006185 dispersion Substances 0.000 claims abstract description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZCJHFOLNXNSZJG-UHFFFAOYSA-N [Na].NS(O)(=O)=O Chemical compound [Na].NS(O)(=O)=O ZCJHFOLNXNSZJG-UHFFFAOYSA-N 0.000 claims abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- 229920002472 Starch Polymers 0.000 claims description 13
- 239000008107 starch Substances 0.000 claims description 13
- 235000019698 starch Nutrition 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- -1 hydroxypropyl Chemical group 0.000 claims description 8
- 150000003376 silicon Chemical class 0.000 claims description 8
- 235000013312 flour Nutrition 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 108010073771 Soybean Proteins Proteins 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 230000008030 elimination Effects 0.000 claims description 3
- 238000003379 elimination reaction Methods 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 239000013049 sediment Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 235000019710 soybean protein Nutrition 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 7
- 238000009955 starching Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 230000035699 permeability Effects 0.000 abstract description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000005543 nano-size silicon particle Substances 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of spinning sizing agent being applicable to high COTTON FABRIC, its component by mass ratio as follows: nano SiO 2 modified starch 80 parts, 10 parts, albumen slurry, polyacrylate dispersion 8 parts, modified silicon oil defoamer: 2 parts, Argine Monohydrochloride 5 parts; 2 parts, sulfamic acid sodium; Polyacrylate 2 parts.The present invention's slurry of filling a prescription has good film forming and permeability, is specially adapted to the starching of a high COTTON FABRIC, and due in formula not containing polyvinyl alcohol, therefore environmental protection more.
Description
Technical field
The present invention relates to a kind of spinning sizing agent being applicable to a high COTTON FABRIC.
Background technology
Warp sizing is the key link of weaving engineering, and the object of sizing mainly improves the ABRASION RESISTANCE of yarn, reduces filoplume, suitably increases the brute force of yarn, reduces degree of stretching, and to bear the mechanicals efforts that warp thread is subject in weaving process, improves the weavability of yarn.
The slurry of current warp sizing mainly contains the large slurry of starch, polyvinyl alcohol (PVA) and polyacrylic three.Starch is natural polysaecharides high polymer, and Size-Film Forming Properties is good, strong with natural fabric affinity, is easy to destarch; But starch size slashing strength is inadequate, not wear-resisting, and inadequate with polyster fibre affinity.Polyvinyl alcohol pulp serous coat is powerful large, and pliability is good, and slurry fluidity is good, but polyvinyl alcohol is difficult to destarch, and big for environment pollution.Polyacrylic acid size is the general name of the homopolymers of acrylic monomer, copolymer and blend, its viscosity is lower, good fluidity, good adhesiveness is had to synthetic fiber, can be mixed well with starch, PVA slurry, be applicable to the warp sizing of each fibrid, but polyacrylic acid size price is high, raise the production cost of printing and dyeing enterprise.
Summary of the invention
The object of the invention is to: the defect overcoming above-mentioned prior art, propose a kind of spinning sizing agent being applicable to a high COTTON FABRIC.
In order to achieve the above object, a kind of spinning sizing agent being applicable to high COTTON FABRIC that the present invention proposes, its component by mass ratio as follows:
Nano SiO 2 modified starch: 80 parts, albumen slurry: 10 parts, polyacrylate dispersion: 8 parts, modified silicon oil defoamer: 2 parts;
Described nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by hydroxypropyl converted starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, hydroxypropyl converted starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 110:6:0.2:0.4;
It is in the sodium hydroxide solution of 0.3% that described albumen slurry adds concentration by soybean protein, elimination sediment after obtains after at the uniform velocity stirring 15 minutes at 40 DEG C;
Described modified silicon oil defoamer by quality proportioning be the polyethers of 1:15 and silicon oil of low hydrogen content modification temperature 1000 DEG C, obtained under modification time 1.5h.
The spinning sizing agent that the present invention is applicable to a high COTTON FABRIC also has following improvement:
1, the present invention is applicable to the spinning sizing agent of a high COTTON FABRIC, also comprises the Argine Monohydrochloride of 5 parts by mass.
2, the present invention is applicable to the spinning sizing agent of a high COTTON FABRIC, also comprises the sulfamic acid sodium of 2 parts by mass.
3, the present invention is applicable to the spinning sizing agent of a high COTTON FABRIC, also comprises the polyacrylate of 2 parts by mass.
The present invention's formula is containing nano SiO 2 modified starch, albumen slurry, polyacrylate dispersion, modified silicon oil defoamer, and proportioning restriction has been carried out to these four kinds of batchings, this kind of slurry has good film forming and permeability, experiment shows the starching being particularly suitable for a high COTTON FABRIC, and owing to not containing polyvinyl alcohol, therefore environmental protection more in formula.
In slurry of the present invention, hydroxypropyl converted starch and nano silicon combine, on the one hand, hydroxypropyl has hydrophily, can weaken the internal hydrogen bond strength of starch granules structure, make it be easy to expand, gelatinization is easy, paste liquid is transparent, good fluidity, retrogradation is weak, and stability is high, make the film forming of slurry better, improve the sizing performance of slurry; Nano silicon contributes to starch dispersion in the slurry on the other hand, also improves the sizing performance of slurry to a certain extent.The albumen slurry added and modified starch promote mutually, and with the use of polyacrylate dispersion, the sizing performance of slurry can be improved further.Plant material for first three, the present invention selects modified silicon oil defoamer as defoamer, can effectively eliminate the foam produced in sizing process, make slurry more fully with clothing in contact, improve starching efficiency, save slurry.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described.
The present embodiment is applicable to the spinning sizing agent of high COTTON FABRIC, its component by mass ratio as follows:
Nano SiO 2 modified starch: 80 parts, albumen slurry: 10 parts, polyacrylate dispersion: 8 parts, modified silicon oil defoamer: 2 parts, Argine Monohydrochloride: 5 parts; Sulfamic acid sodium: 2 parts; Polyacrylate: 2 parts;
Nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by hydroxypropyl converted starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, and hydroxypropyl converted starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 110:6:0.2:0.4;
It is in the sodium hydroxide solution of 0.3% that described albumen slurry adds concentration by soybean protein, elimination sediment after obtains after at the uniform velocity stirring 15 minutes at 40 DEG C;
Described modified silicon oil defoamer by quality proportioning be the polyethers of 1:15 and silicon oil of low hydrogen content modification temperature 1000 DEG C, obtained under modification time 1.5h.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of application claims.
Claims (4)
1. be applicable to a spinning sizing agent for high COTTON FABRIC, its component by mass ratio as follows:
Nano SiO 2 modified starch: 80 parts, albumen slurry: 10 parts, polyacrylate dispersion: 8 parts, modified silicon oil defoamer: 2 parts;
Described nano SiO 2 modified starch adds in deionized water after being mixed with silica flour by hydroxypropyl converted starch, and add NaOH and methyl alcohol, after being hydrolyzed, dry purification obtains, wherein, hydroxypropyl converted starch: silica flour: NaOH: the quality proportioning of methyl alcohol is: 110:6:0.2:0.4;
It is in the sodium hydroxide solution of 0.3% that described albumen slurry adds concentration by soybean protein, elimination sediment after obtains after at the uniform velocity stirring 15 minutes at 40 DEG C;
Described modified silicon oil defoamer by quality proportioning be the polyethers of 1:15 and silicon oil of low hydrogen content modification temperature 100 DEG C, obtained under modification time 1.5h.
2. the spinning sizing agent being applicable to a high COTTON FABRIC according to claim 1, is characterized in that: the Argine Monohydrochloride also comprising 5 parts by mass.
3. the spinning sizing agent being applicable to a high COTTON FABRIC according to claim 2, is characterized in that: the sulfamic acid sodium also comprising 2 parts by mass.
4. the spinning sizing agent being applicable to a high COTTON FABRIC according to claim 3, is characterized in that: the polyacrylate also comprising 2 parts by mass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410147345.XA CN103898752B (en) | 2014-04-14 | 2014-04-14 | A kind of spinning sizing agent being applicable to a high COTTON FABRIC |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410147345.XA CN103898752B (en) | 2014-04-14 | 2014-04-14 | A kind of spinning sizing agent being applicable to a high COTTON FABRIC |
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| Publication Number | Publication Date |
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| CN103898752A CN103898752A (en) | 2014-07-02 |
| CN103898752B true CN103898752B (en) | 2016-04-06 |
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| CN201410147345.XA Expired - Fee Related CN103898752B (en) | 2014-04-14 | 2014-04-14 | A kind of spinning sizing agent being applicable to a high COTTON FABRIC |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106400492A (en) * | 2016-08-31 | 2017-02-15 | 西达（无锡）生物科技有限公司 | Starch weaving slurry for replacing PVA |
| CN106637966A (en) * | 2016-11-17 | 2017-05-10 | 无锡明盛纺织机械有限公司 | Starch textile sizing agent for replacing PVA (polyvinyl alcohol) |
| CN106381704A (en) * | 2016-11-17 | 2017-02-08 | 无锡明盛纺织机械有限公司 | Starch textile pulp replacing PVA (Polyvinyl Alcohol) |
| CN106521952A (en) * | 2016-11-18 | 2017-03-22 | 无锡明盛纺织机械有限公司 | Starch textile size |
| CN107893331A (en) * | 2017-11-29 | 2018-04-10 | 苏州润弘贸易有限公司 | A kind of spinning sizing agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1382864A (en) * | 2002-06-12 | 2002-12-04 | 弘生集团有限公司 | Size composition for textile |
| CN102382471A (en) * | 2010-08-31 | 2012-03-21 | 山东万得福实业集团有限公司 | Prescription of biodegradable soybean protein thermoplastic material |
| CN103087332A (en) * | 2013-01-21 | 2013-05-08 | 东华大学 | Preparation method of proteins and protein-based sizes for warp sizing |
| CN103643515A (en) * | 2013-12-30 | 2014-03-19 | 张海峰 | Textile size and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0247371A (en) * | 1988-08-08 | 1990-02-16 | Kiyoueishiya Yushi Kagaku Kogyo Kk | Silicone-based softening agent composition for textile |
| JP3618484B2 (en) * | 1996-08-28 | 2005-02-09 | 日澱化學株式会社 | Polyvinyl acetate emulsion and non-accumulating fiber glue |
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2014
- 2014-04-14 CN CN201410147345.XA patent/CN103898752B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1382864A (en) * | 2002-06-12 | 2002-12-04 | 弘生集团有限公司 | Size composition for textile |
| CN102382471A (en) * | 2010-08-31 | 2012-03-21 | 山东万得福实业集团有限公司 | Prescription of biodegradable soybean protein thermoplastic material |
| CN103087332A (en) * | 2013-01-21 | 2013-05-08 | 东华大学 | Preparation method of proteins and protein-based sizes for warp sizing |
| CN103643515A (en) * | 2013-12-30 | 2014-03-19 | 张海峰 | Textile size and preparation method thereof |
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| CN103898752A (en) | 2014-07-02 |
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