CN103882722B - The discoloration method of blue or green floss - Google Patents
The discoloration method of blue or green floss Download PDFInfo
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- CN103882722B CN103882722B CN201410084892.8A CN201410084892A CN103882722B CN 103882722 B CN103882722 B CN 103882722B CN 201410084892 A CN201410084892 A CN 201410084892A CN 103882722 B CN103882722 B CN 103882722B
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Abstract
The invention discloses the discoloration method of a kind of blue or green floss, comprise the following steps: 1. enzyme is washed;2. pretreatment;3. oxygen bleaching;4. drift is reduced.Use that the blue or green floss whiteness after discoloration method of the present invention is high, weightlessness less, strength loss little, good hand touch, it is easy to spinning, and bleaching time is short, water-saving, power saving, low cost.
Description
Technical field
The present invention relates to lint decolouring technology field, the discoloration method of a kind of blue or green floss.
Background technology
Blue or green floss is the cashmere that a kind of whiteness is only second to white woolenless cloth, blue or green floss itself is cashmere fiber, its length, fineness are the same with white floss, only because with natural ecru, cannot be used for the bright-coloured color shallow, middle of comparison to dye (the most gloomy after dyeing), price fewer than white floss per ton more than 10 about ten thousand, therefore, many producers will green grass or young crops floss decolour after use, to reach to save the purpose of white floss consumption reduction cost when white floss.
The most on the market, the blue or green cold decolouring technology of floss of many uses, its shortcoming is that bleaching time is long, and nearly 48 hours, production efficiency was low, and after decolouring, the damage of cashmere scale is big, wastes time and energy.Also have and use heat decoloring technology, average bleaching time was at 7~9 hours, and many employing heat decoloring technology there is the problem that ferrous salt consumption is big, and washing time is many, some washing time up to 5~7 times, water wasting, time-consuming, rinse sordid ferrous ion over oxidation cashmere fiber when oxygen bleaching, not only waste hydrogen peroxide, and cause cashmere damage big, weightless high, whiteness is low, efficiency is low.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, propose the discoloration method of a kind of blue or green floss, the cycle is short, and efficiency is high, low cost, and whiteness is good, weightless less, strength loss is little, good hand touch, it is easy to spinning.
In order to realize foregoing invention purpose, the present invention provides techniques below scheme: the discoloration method of a kind of blue or green floss, comprises the following steps: for the most following concentration is all relatively blue or green floss weight,
1., enzyme washes: green grass or young crops floss being put under room temperature flock dyeing cylinder and adds soft water, bath raio is 1:10~15, stirring, is sequentially added into 1~the nonionic lotion of 3% and the mercerising protease immersion treatment of 0.1%~0.2%, and regulation pH value is 8~9;It is warming up to 40 DEG C~55 DEG C, is incubated 15~25 minutes, emptying, washing;
2., pretreatment: blue or green floss after step 1. being washed adds soft water, stirring, and adjusting pH value is 4~5, is sequentially added into the sodium hydrosulfite of 1~5%, adds 0.5~1% chelating agent, 1~2.5%FeSO4;It is warming up to 55~57 DEG C, is incubated 40~60 minutes, emptying, wash 1~2 time;
3., oxygen bleaching: the blue or green floss after 2. step washes adds soft water, stirring, is sequentially added into 10~20% hydrogen peroxide bleaching stabilizer, 3~6% cashmere protective agent and 24~36% hydrogen peroxide dipping washing, and adjusting pH value is 8~9;It is warming up to 55~57 DEG C, is incubated 40~60 minutes, emptying, wash 1~2 time;
4., reduction drift: the blue or green floss after 3. step washes adds soft water, stirring, be sequentially added into 1~3% formic acid, 1~3% sodium hydrosulfite, 0.2~0.5% chelating agent process, be warming up to 40~50 DEG C, be incubated 20~25 minutes;Wash 1~2 time.
Further, temperature-rise period is intensification 1 per minute~3 DEG C.
Further, one or more during described chelating agent is organic phospho acid or its salt and tetrasodium ethylenediamine tetraacetate.
Further, described organic phospho acid and salt thereof are 1-hydroxy ethylidene-1,1-diphosphonic acid or its sodium salt, ATMP or its sodium salt, ethylene diamine tetra methylene phosphonic acid sodium, diethylene triamine pentamethylene phosphonic or its sodium salt, 2-phosphonobutane-1,2,4-tricarboxylic acids four sodium, hexapotassium potassium salt, one or more in double hexamethylene triamine five methylenephosphonic acid sodium.
Further, described chelating agent is made up of than component following weight:
Organic phospho acid sodium 2 tetrasodium ethylenediamine tetraacetate 2
Polycarboxylic acids sodium 0.5 secondary alcohol 90.5
Water 5.
Further, the compound method of described compound complex agent is: first organic phospho acid sodium, tetrasodium ethylenediamine tetraacetate, polycarboxylic acids sodium, secondary alcohol 9 being melted respectively with a small amount of hot water, the aquation adding surplus is opened.
Compared with prior art, the invention have the advantages that the blue or green floss whiteness after using discoloration method of the present invention, feel etc. are all better than former technique, and bleaching time is short, water-saving, power saving, low cost, made used additives does not contains APEO, Environmental Safety, does not use fluorescent whitening agent, meets the requirement that country's cleaning produces.
Detailed description of the invention
Describing the present invention below in conjunction with embodiment, the description of this part is only exemplary and explanatory, should not have any restriction effect to protection scope of the present invention.
The discoloration method of a kind of blue or green floss, comprises the following steps: for the most following concentration is all relatively blue or green floss weight,
1., enzyme washes: green grass or young crops floss being put under room temperature flock dyeing cylinder and adds soft water, bath raio is 1:10~15, stirring, is sequentially added into 1~the nonionic lotion of 3% and the mercerising protease immersion treatment of 0.1%~0.2%, and regulation pH value is 8~9;It is warming up to 40 DEG C~55 DEG C, is incubated 15~25 minutes, emptying, washing;
2., pretreatment: blue or green floss after step 1. being washed adds soft water, stirring, and adjusting pH value is 4~5, is sequentially added into the sodium hydrosulfite of 1~5%, adds 0.5~1% chelating agent, 1~2.5%FeSO4;It is warming up to 55~57 DEG C, is incubated 40~60 minutes, emptying, wash 1~2 time;
3., oxygen bleaching: the blue or green floss after 2. step washes adds soft water, stirring, is sequentially added into 10~20% hydrogen peroxide bleaching stabilizer, 3~6% cashmere protective agent and 24~36% hydrogen peroxide dipping washing, and adjusting pH value is 8~9;It is warming up to 55~57 DEG C, is incubated 40~60 minutes, emptying, wash 1~2 time;
4., reduction drift: the blue or green floss after 3. step washes adds soft water, stirring, be sequentially added into 1~3% formic acid, 1~3% sodium hydrosulfite, 0.2~0.5% chelating agent process, be warming up to 40~50 DEG C, be incubated 20~25 minutes;Wash 1~2 time;
Wherein, one or more during described chelating agent is organic phospho acid or its salt and tetrasodium ethylenediamine tetraacetate;Described organic phospho acid and salt thereof are 1-hydroxy ethylidene-1,1-diphosphonic acid or its sodium salt, ATMP or its sodium salt, ethylene diamine tetra methylene phosphonic acid sodium, diethylene triamine pentamethylene phosphonic or its sodium salt, 2-phosphonobutane-1,2,4-tricarboxylic acids four sodium, hexapotassium potassium salt, one or more in double hexamethylene triamine five methylenephosphonic acid sodium.
Concrete, described chelating agent is grouped into by the one-tenth that weight portion is following:
Organic phospho acid sodium 2 tetrasodium ethylenediamine tetraacetate 2
Polycarboxylic acids sodium 0.5 secondary alcohol 90.5
Water 5.
Its compound method is: first organic phospho acid sodium, tetrasodium ethylenediamine tetraacetate, polycarboxylic acids sodium, secondary alcohol 9 being melted respectively with a small amount of hot water, the aquation adding surplus is opened.
Above-mentioned blue or green floss discoloration method, the action principle of each auxiliary agent is as follows:
A, enzyme are washed in step:
1. in enzyme is washed, the purpose of nonionic lotion is to remove the oils and fats on blue or green floss surface, dirt, gives full play to mercerising protease and plays a role.
2. in enzyme is washed, regulate pH value 8-9, give full play to mercerising protease and play a role.
3. adding mercerising protease in enzyme is washed is to remove the secondary protein on cashmere fiber surface and hydrolyzed protein, effectively gets through second step pretreatment ferrous ion and enters the passage within cashmere fiber.
In B, pre-treatment step:
1. the take a policy purpose of powder of pretreatment is the reducing environment maintaining treatment fluid, prevents ferrous ion to be oxidized to insoluble ferric ion.
2. the alkali remained in regulation PH=4-5 and when enzyme is washed, as used acetic acid to regulate.
3. add the purpose of chelating agent
(1) efficient complexation ferrous ion, and ferrous ion forms coordinate bond and combines, and shields the positive charge around ferrous ion, decreases the damage to fiber of the positive charge ferrous ion, eliminate fiber protection agent.
(2) adding chelating agent makes treatment fluid stable: owing to chelating agent makes the surrounding of ferrous ion present elecrtonegativity, add the water solublity of ferrous ion, stability, experiment finding, the treatment fluid adding chelating agent is the limpidest, and does not add the treatment fluid surface of chelating agent due to air oxidation jaundice, muddiness;
(3) ferrous ion is made to change charged character (negative charge) after adding chelating agent so that ferrous ion more easily enters fiber and pigment combines.During owing to adding acetic acid in second step, cashmere surface is positively charged, in electronegative complexation ferrous ion because attractive coulombic force electrical attraction (having got through passage owing to adding enzyme in the first step) more easily enters fiber combines (pigment in blue or green floss is better than chelating agent and ferrous ion binding ability with the ability that ferrous ion combines) with pigment;
(4) jointly act on due to chelating agent and first step ferment treatment so that the effective rate of utilization of ferrous salt increases, and decreases ferrous salt consumption, reduces cost, decreases the washing time after second step,
(5) use chelating agent make not with ferrous ion and the chelating agent generation complexation of the excess of pigment complexation, the ferrous ion good water solubility of complexation, be prone to rinse, decrease washing time, it is to avoid the unnecessary iron ion catalysis damage to fiber in oxygen bleaching.More than original at least flushing 5 cylinder water, it is reduced to have only to rinse 1-2 cylinder water;
In C, oxygen bleaching step:
1. adding stabilizer is to maintain a stable pH environment, it is to avoid during oxygen bleaching, iron ion is excessively catalyzed.
2. damage cashmere fiber when the purpose of addition fiber protection agent is to prevent oxygen bleaching.
3. adding hydrogen peroxide is to bleach, owing to the comparison of the second step ferrous ion after improving and pigment complexation is abundant, therefore new technology hydrogen peroxide consumption is by original opposed fabric weight 60%, it is reduced to opposed fabric weight about 30%, save the hydrogen peroxide of half, reducing cost, bleaching time was shortened to 60 minutes by original 90 minutes, decreased the damage to fiber.
In D, reduction step:
1. the purpose adding formic acid is the residual alkali in order to neutralize oxygen bleaching, controls the condition of reduction to carry out under sour environment, and formic acid has certain reproducibility, beneficially ferric ion to be reduced into ferrous ion.
2. the purpose of powder of taking a policy is the reducing environment maintaining treatment fluid, the hydrogen peroxide that reduction is not rinsed well.The ferrous ion that insoluble ferric ion oxygen bleaching caused is reduced into.
3. the purpose adding chelating agent is to make ferrous ion complexation disperse, more fully (traditional method uses oxalic acid to go iron ions to make iron ions, owing to the corrosivity of oxalic acid is strong, cashmere feel after process is very poor), even and if have minimal amount of iron ion to remain, not interfering with the coloured light (metal ion can cause dyeing after gloomy) of rear road dyeing owing to iron ion is complexed, unnecessary chelated iron ion is rinsed removal after having dyeed.Therefore, the method protects the feel of fiber, strongly, adds the whiteness of final fiber.
Above-mentioned blue or green floss discoloration method, has the following characteristics that
1, in front washing, add mercerising protease and remove secondary protein and the hydrolyzed protein on cashmere fiber surface, effectively get through second step pretreatment ferrous ion and enter the passage within cashmere fiber.
2, add a kind of compound complex agent during pretreatment, be not only pretreatment fluid stable, and make ferrous salt consumption reduce, decrease the washing time after second step.
3, during oxygen bleaching, hydrogen peroxide consumption reduces a lot, and bleaching time shortens, and reduces cost.Owing to the comparison of the second step ferrous ion after improving and pigment complexation is abundant, therefore new technology hydrogen peroxide consumption is by original opposed fabric weight 60%, it is reduced to opposed fabric weight about 30%, save the hydrogen peroxide that half is many, reduce cost, bleaching time was shortened to 60 minutes by original 90 minutes, decreased the damage to fiber.
4, reducing bleach employs the 2-cyclopenten-2,3-diol-1-one .-formic acid of small-molecular-weight instead of composite decoloration acid and reduce cost, be simultaneously used a small amount of efficient chelating agent so that go removing rust more abundant, protect fiber strength, add the whiteness of final fiber.
Compare the blue or green floss decoloration process of routine, the invention have the advantages that
One, introduce biological enzyme technology, front washing adds mercerising protease.
Enzyme is always the emphasis of textile science research, and biological enzyme formulation has the distinguishing features such as single-minded, efficient, environmental protection.(this mercerising protease is for Pilus Caprae seu Ovis mercerising soft treatment for the mercerising protease used in present invention process, in the washing pre-treatment extended) consumption is considerably less, but effectively get through second step pretreatment ferrous ion and entered the passage within cashmere fiber, effectively processed for second step and lay a good foundation.
Two, efficient chelating agent has been selected during pretreatment.
This efficient chelating agent can efficient complexation ferrous ion, and ferrous ion forms coordinate bond and combines, and shields the positive charge around ferrous ion.The benefit using this efficient chelating agent to bring has:
The fiber protection agent used in A, the former technique eliminated.Owing to the positive charge of ferrous ion is shielded, decrease the damage to fiber of the positive charge ferrous ion.Therefore, this step eliminates fiber protection agent, in its postpose oxygen bleaching, uses the best steel to make the knife's edge, reduce fibre damage;
B, the treatment fluid adding efficient chelating agent are stable.Owing to efficient chelating agent makes the surrounding of ferrous ion present elecrtonegativity, add the water solublity of ferrous ion, stability, experiment finding, the treatment fluid adding efficient chelating agent is the limpidest, and does not add the treatment fluid surface of efficient chelating agent due to air oxidation jaundice, muddiness;
Make ferrous ion more easily enter fiber after C, addition chelating agent and pigment combines.During owing to adding acetic acid in second step, cashmere surface is positively charged, in electronegative ferrous ion because attractive coulombic force electrical attraction (and in the first step, addition enzyme has got through passage) more easily enters fiber with pigment complexation;
D, jointly act on due to efficient chelating agent and first step ferment treatment so that the consumption of ferrous salt decreases 3/4, and the time of second step pretreatment is greatly shortened, and is reduced to about 40 minutes by original 120 minutes.Simultaneously because the consumption of ferrous salt reduces, decrease the washing time after second step, more than original at least flushing 5 cylinder water, be reduced to have only to rinse 2 cylinder water;
Three, during oxygen bleaching, hydrogen peroxide consumption reduces a lot, and bleaching time shortens, and reduces cost.
Owing to the comparison of the second step ferrous ion after improving and pigment complexation is abundant, therefore present invention process hydrogen peroxide consumption is by original opposed fabric weight 60%, it is reduced to opposed fabric weight 30%, save the hydrogen peroxide that half is many, reduce cost, bleaching time was shortened to 60 minutes by original 90 minutes, decreased the damage to fiber.
Four, reducing bleach employs the 2-cyclopenten-2,3-diol-1-one. (formic acid) of small-molecular-weight instead of composite decoloration acid and reduce cost, be simultaneously used a small amount of efficient chelating agent so that go removing rust more abundant, protect fiber strength, add the whiteness of final fiber.
Embodiment 1
The discoloration method of a kind of blue or green floss, comprises the following steps:
1., enzyme is washed: under room temperature, green grass or young crops floss is put into flock dyeing cylinder add soft water; bath raio is 1:10~15; stirring; be sequentially added into 2%(owf) nonionic lotion (FK-9508D1; in spin chemical industry) and 0.1%(owf) mercerising protease (cta-b; in spin chemical industry) immersion treatment, regulation pH value be 8;Intensification per minute 2 DEG C is warming up to 55 DEG C, maintains 15 minutes, emptying mixing lotion;Wash 1 time;
2., pretreatment: blue or green floss after step 1. being washed adds soft water, stirring, and adjusting pH value is 5, is sequentially added into 5%(owf) sodium hydrosulfite, add 1%(owf) chelating agent, 2.5%(owf) FeSO4;Intensification per minute 3 DEG C is warming up to 55 DEG C, is incubated 60 minutes, emptying, washes 1 time;
3., oxygen bleaching: the blue or green floss after 2. step washes adds soft water; stirring; it is sequentially added into 20%(owf) hydrogen peroxide bleaching stabilizer (montelai; Meng Telai company), 3%(owf) cashmere protective agent (montelai2706; Meng Telai company) and 36%(owf) hydrogen peroxide dipping washing, adjusting pH value is 8;Intensification per minute 1 DEG C is warming up to 57 DEG C, is incubated 40 minutes, emptying, washes 2 times;
4. the blue or green floss, after 3. step washes adds soft water, stirring, is sequentially added into 1%(owf) formic acid, 3%(owf) sodium hydrosulfite, 0.2%(owf) chelating agent processes, intensification per minute 2 DEG C is warming up to 55 DEG C, is incubated 20 minutes;Wash 2 times;
Wherein, described chelating agent is grouped into by the one-tenth that weight portion is following:
Organic phospho acid sodium 2 tetrasodium ethylenediamine tetraacetate 2
Polycarboxylic acids sodium 0.5 secondary alcohol 90.5
Water 5.
Its compound method is: first organic phospho acid sodium, tetrasodium ethylenediamine tetraacetate, polycarboxylic acids sodium, secondary alcohol 9 being melted respectively with a small amount of hot water, the aquation adding surplus is opened.
Described organic phospho acid sodium is 1-hydroxy ethylidene-1,1-diphosphonic acid disodium, may be used without ATMP sodium, ethylene diamine tetra methylene phosphonic acid sodium, diethylene triamine pentamethylene phosphonic sodium, 2-phosphonobutane-1,2,4-tricarboxylic acids four sodium, hexapotassium potassium, one or more in double hexamethylene triamine five methylenephosphonic acid sodium.
Embodiment 2
The discoloration method of a kind of blue or green floss, comprises the following steps:
1., enzyme washes: green grass or young crops floss being put under room temperature flock dyeing cylinder and adds soft water, bath raio is 1:10~15, and stirring is sequentially added into 1%(owf) nonionic lotion and 0.2%(owf) mercerising protease immersion treatment, regulation pH value is 9;Intensification per minute 2 DEG C is warming up to 40 DEG C, is incubated 25 minutes, emptying, washing;
2., pretreatment: blue or green floss after step 1. being washed adds soft water, stirring, and adjusting pH value is 4, is sequentially added into 4.5%(owf) sodium hydrosulfite, add 0.5%(owf) chelating agent, 2%(owf) FeSO4;Intensification per minute 1 DEG C is warming up to 57 DEG C, is incubated 40 minutes, emptying, washes 2 times;
3., oxygen bleaching: the blue or green floss after 2. step washes adds soft water, stirring, is sequentially added into 10%(owf) hydrogen peroxide bleaching stabilizer, 6%(owf) cashmere protective agent and 24%(owf) hydrogen peroxide dipping washing, adjusting pH value is 9;Intensification per minute 1 DEG C is warming up to 55 DEG C, is incubated 60 minutes, emptying, washes 1 time;
4., reduction drift: the blue or green floss after 3. step washes adds soft water, stirring, be sequentially added into 3%(owf) formic acid, 1%(owf) sodium hydrosulfite, 0.5%(owf) chelating agent process, intensification per minute 3 DEG C is warming up to 45 DEG C, is incubated 25 minutes;Wash 1 time;Wherein, described chelating agent is 1-hydroxy ethylidene-1,1-diphosphonic acid disodium.
Embodiment 3
The discoloration method of a kind of blue or green floss, comprises the following steps: for the most following concentration is relatively blue or green floss weight,
1., enzyme washes: green grass or young crops floss being put under room temperature flock dyeing cylinder and adds soft water, bath raio is 1:10~15, and stirring is sequentially added into 3%(owf) nonionic lotion and 0.1%(owf) mercerising protease immersion treatment, regulation pH value is 9;It is warming up to 45 DEG C, is incubated 20 minutes, emptying, washing;
2., pretreatment: blue or green floss after step 1. being washed adds soft water, stirring, and adjusting pH value is 5, is sequentially added into 3%(owf) sodium hydrosulfite, add 0.7%(owf) chelating agent, 1.5%(owf) FeSO4;It is warming up to 56 DEG C, is incubated 50 minutes, emptying, wash 2 times;
3., oxygen bleaching: the blue or green floss after 2. step washes adds soft water, stirring, is sequentially added into 15%(owf) hydrogen peroxide bleaching stabilizer, 5%(owf) cashmere protective agent and 30%(owf) hydrogen peroxide dipping washing, adjusting pH value is 8;It is warming up to 55 DEG C, is incubated 45 minutes, emptying, wash 1 time;
4., reduction drift: the blue or green floss after 3. step washes adds soft water, stirring, be sequentially added into 2%(owf) formic acid, 1.5%(owf) sodium hydrosulfite, 0.3%(owf) chelating agent process, be warming up to 40 DEG C, be incubated 22 minutes;Wash 2 times.Wherein, described chelating agent is tetrasodium ethylenediamine tetraacetate.
Test example 1
The Cost comparisons of the new old technology of blue or green floss decolouring analyzes: (the cost lists of de-1000 kilograms of blue or green flosss)
1, the auxiliary agent cost accounting of conventional blue or green floss heat decoloring technique:
2, the auxiliary agent cost accounting of present invention process:
3, the accounting of conventional blue or green floss heat decoloring technique water power vapour cost:
4, the accounting of present invention process water power vapour cost:
Test example 2
Loss after blue or green floss decolouring
1, the data of conventional blue or green floss heat decoloring technique
2, present invention process data
3. the index such as the whiteness of blue or green floss decolouring, strength.
Test example 3
In big production, use the decolouring green grass or young crops floss of present invention process, carry out the trial production of 2 colors:
Experimental data from above is found out: the whiteness after green grass or young crops floss decoloration process of the present invention decolouring is whiter than common process, and scale basic not damaged is lost little after decolouring, good hand touch, and cost is lower than common process.Using light color in hair activity, weak acid dye dye to observe Color, staining conditions is good.De-1000 kilograms of blue or green floss auxiliary agent cost savings 2941 yuan, water power saves 986 yuan;Due to the reduction of loss, being dropped to 0.6% by former average 2.46%, reduce 1.86%, calculate according to de-1000 kilograms of blue or green flosss, the blue or green floss of saving is worth: 1000*0.0186*730=13578 unit (blue or green floss calculates according to 730 yuan/kilogram);Present invention process amounts to cost-effective 17505 yuan (de-1000 kilograms of blue or green flosss) than common process.
Calculate per ton 100,000 according to the price difference of the blueest or green floss and white floss, the fund that 1 ton of blue or green floss replaces white floss to save is taken off: 100000-{6289(auxiliary agent cost according to present invention process)+1906(water power cost)+730000*0.6%(loss)+2.5*1000(is artificial)=84925 yuan. adjust according to above, as long as the cylinder of 100 kilograms successfully takes off a cylinder every day and can earn the profit of nearly 8000 yuan for company, 1 year de-10 tons calculate the funds nearly 850,000 yuan saved;30 tons of blue or green flosss of decolouring within 1 year, are used to replace white floss can be that company brings indirectly economic benefit to reach 2,500,000 yuan.As can be seen here, the most worth big production application of green grass or young crops floss decoloration process of the present invention.
Claims (6)
1. a discoloration method for blue or green floss, comprises the following steps: for the most following concentration is all relatively blue or green floss weight,
1., enzyme washes: green grass or young crops floss being put under room temperature flock dyeing cylinder and adds soft water, bath raio is 1:10~15, stirring, is sequentially added into 1~the nonionic lotion of 3% and the mercerising protease immersion treatment of 0.1%~0.2%, and regulation pH value is 8~9;It is warming up to 40 DEG C~55 DEG C, is incubated 15~25 minutes, emptying, washing;
2., pretreatment: blue or green floss after step 1. being washed adds soft water, stirring, and adjusting pH value is 4~5, is sequentially added into the sodium hydrosulfite of 1~5%, adds 0.5~1% chelating agent, 1~2.5%FeSO4;It is warming up to 55~57 DEG C, is incubated 40~60 minutes, emptying, wash 1~2 time;
3., oxygen bleaching: the blue or green floss after 2. step washes adds soft water, stirring, is sequentially added into 10~20% hydrogen peroxide bleaching stabilizer, 3~6% cashmere protective agent and 24~36% hydrogen peroxide dipping washing, and adjusting pH value is 8~9;It is warming up to 55~57 DEG C, is incubated 40~60 minutes, emptying, wash 1~2 time;
4., reduction drift: the blue or green floss after 3. step washes adds soft water, stirring, be sequentially added into 1~3% formic acid, 1~3% sodium hydrosulfite, 0.2~0.5% chelating agent process, be warming up to 40~50 DEG C, be incubated 20~25 minutes;Wash 1~2 time.
2. the discoloration method of as claimed in claim 1 blue or green floss, it is characterised in that: temperature-rise period is intensification 1 per minute~3 DEG C.
3. the discoloration method of as claimed in claim 1 or 2 blue or green floss, it is characterised in that: described chelating agent is one or more in organic phospho acid or its salt and tetrasodium ethylenediamine tetraacetate.
4. the discoloration method of the blueest or green floss, it is characterized in that: described organic phospho acid and sodium salt thereof are 1-hydroxy ethylidene-1,1-diphosphonic acid or its sodium salt, ATMP or its sodium salt, ethylene diamine tetra methylene phosphonic acid sodium, diethylene triamine pentamethylene phosphonic or its sodium salt, 2-phosphonobutane-1,2,4-tricarboxylic acids four sodium, hexapotassium potassium salt, one or more in double hexamethylene triamine five methylenephosphonic acid sodium.
5. the discoloration method of the blueest or green floss, it is characterised in that: described chelating agent is made up of than component following weight:
Organic phospho acid sodium 2 tetrasodium ethylenediamine tetraacetate 2
Polycarboxylic acids sodium 0.5 secondary alcohol 90.5
Water 5.
6. the discoloration method of the blueest or green floss, it is characterised in that: the compound method of described chelating agent is: first organic phospho acid sodium, tetrasodium ethylenediamine tetraacetate, polycarboxylic acids sodium, secondary alcohol 9 being melted respectively with a small amount of hot water, the aquation adding surplus is opened.
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CN105603749A (en) * | 2015-12-22 | 2016-05-25 | 上海婉静纺织科技有限公司 | Wedding dress fabric |
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CN108425235A (en) * | 2018-04-13 | 2018-08-21 | 浙江玛戈利亚羊绒世家有限公司 | A kind of low temperature cashmere method for bleaching |
CN109082877A (en) * | 2018-08-27 | 2018-12-25 | 江苏阳光股份有限公司 | A kind of bleaching process of purple cashmere |
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