CN101349021B - Reactive dye post treatment accessory ingredient and processing method using the same - Google Patents
Reactive dye post treatment accessory ingredient and processing method using the same Download PDFInfo
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- CN101349021B CN101349021B CN 200810119286 CN200810119286A CN101349021B CN 101349021 B CN101349021 B CN 101349021B CN 200810119286 CN200810119286 CN 200810119286 CN 200810119286 A CN200810119286 A CN 200810119286A CN 101349021 B CN101349021 B CN 101349021B
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Abstract
The invention discloses a post treatment addition agent for a reactive dye which comprises the following compositions : 5 to 80 percent of an amphiprotic ion surface active agent, 10 to 75 percent of non-ion surface active agent, and 0.5 to 50 percent of poly-amino compounds. The invention also discloses a method for post treating the reactive dye. The method comprises the following steps that: a. a dyed textile is added into acetic acid to be neutralized and pickled so that the surface of the textile is neutral; b. the post treatment addition agent is added, the temperature increases to between 85 and 90 DEG C, the concentration of the addition agent is between 0.3 and 0.8 gram per litre, the treatment lasts for 10 to 15 minutes; c. the dyed textile is washed by clear water for 3 to 7 minutes at a temperature of between 75 and 80 DEG C; d. the post treatment addition agent is added, the temperature increases up to between 85 and 90 DEG C, the concentration of the addition agent is between 0.8 and 1.5 gram per litre, the treatment lasts for 10 to 15 minutes; and e. the textile is washed by water at a room temperature for 3 to 8 minutes. The post treatment addition agent of the reactive dye achieves the fixation and washing effects after the reactive dye is dyed, replaces a fixing agent and a soaping agent of the prior art, simplifies the technique process and shortens the time.
Description
Technical field
The present invention relates to a kind of after treatment aid, particularly relate to a kind of REACTIVE DYES after treatment aid, the invention still further relates to a kind of processing method that adopts this after treatment aid.
Background technology
REACTIVE DYES need be washed fully to remove hydrolised dye and the loose colour on the fiber after dyeing, and some dark products need to carry out fixation treatment in order to improve dyefastness after dying.Therefore, the dyeing long flow path, the water consumption power consumption is bigger.For a long time, improve technology, research and development and improve the dyestuff quality, improve the dyeing dye-uptake, improve dyeing after washing effect, improve the dye fixing effect and reduce sewage discharge, energy-saving and cost-reducing product and technology, become the problem of needing solution badly.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of REACTIVE DYES after treatment aid, adopt this processing auxiliary agent can reach the effect of fixation and washing after the reactive dyeing simultaneously, can reach the standard of national dyefastness, and can shortened process and time.
For solving the problems of the technologies described above, the invention provides a kind of REACTIVE DYES after treatment aid, it comprises following component: 5～80% zwitterionic surfactant, 10～75% non-ionic surface active agent, 0.5～50% polyamine compounds, by weight.
Above-mentioned REACTIVE DYES after treatment aid, wherein, described zwitterionic surfactant is a 2-alkyl phosphoric acid ethoxycarbonyl imidazoline, and described non-ionic surface active agent is an isomerous tridecanol polyoxyethylene ether, and described polyamine compounds is a urea groups urea groups methylene nail polish acid amides.
Above-mentioned REACTIVE DYES after treatment aid can be by simple mixed with each component.
The present invention also provides a kind of post-processing approach of REACTIVE DYES, and it comprises the steps:
Add in the acetic acid after a textile dyeing and pickling, make fabric face become neutral, can save traditional handicraft and repeatedly wash, wherein Dichlorodiphenyl Acetate concentration does not have specific (special) requirements, is preferably glacial acetic acid;
B adds aforesaid after treatment aid, is warming up to 85～90 ℃, is preferably 90 ℃, and the concentration of auxiliary agent is 0.3～0.8 grams per liter, is preferably 0.5 grams per liter, handles 10～15 minutes, is preferably 10 minutes, removes hydrolised dye and loose colour;
C uses flushing with clean water 3～7 minutes at 75～80 ℃ to the fabric after the dyeing, removes raffinate, saves washing together than traditional handicraft;
D adds aforesaid after treatment aid, is warming up to 85～90 ℃, is preferably 90 ℃, and the concentration of auxiliary agent is 0.8～1.5 grams per liter, is preferably 1 grams per liter, handles 10～15 minutes, is preferably 10 minutes, further removes loose colour, takes into account fixation simultaneously;
E normal temperature washing 3～8 minutes is preferably 5 minutes, removes raffinate.
REACTIVE DYES after treatment aid of the present invention; can reach the effect of fixation and washing after the reactive dyeing simultaneously; the color-fixing agent and the soaping agent of former traditional handicraft have been substituted; can reach the standard of national dyefastness; and can shortened process and time, reduce energy resource consumption and water consumption in the dyeing, reduce the colourity of dyeing waste; reduce quantity of wastewater effluent, preserve the ecological environment.
The specific embodiment
Describe the present invention in detail below in conjunction with reaching embodiment.
Embodiment 1
With the 2-alkyl phosphoric acid ethoxycarbonyl imidazoline of 5% weight, the isomerous tridecanol polyoxyethylene ether of 45% weight and the mixed REACTIVE DYES after treatment aid that gets of urea groups urea groups methylene nail polish acid amides of 50% weight.
Glacial acetic acid is joined through in the fabric after the reactive dyeing, in and pickling once, make fabric face be neutral; Add the above-mentioned after treatment aid that makes afterwards, be warming up to 85 ℃, the concentration of auxiliary agent is 0.8 grams per liter, handles 10 minutes; Under 75 ℃, fabric is used flushing with clean water 7 minutes then, remove raffinate; Continue to add aforesaid after treatment aid, be warming up to 85 ℃, the concentration of auxiliary agent is 1.5 grams per liters, handles 10 minutes; Fabric after handling was washed 3 minutes at normal temperatures, removed raffinate.
Fabric color fastness to water after treatment (variable color, staining) is 3 grades, acidproof sweat stain (variable color, staining) COLOR FASTNESS is 3 grades, alkaline-resisting sweat stain (variable color, staining) COLOR FASTNESS is 3 grades, and anti-dry friction COLOR FASTNESS is 4 grades, and anti-saliva (variable color, staining) COLOR FASTNESS is 4 grades.
Embodiment 2
With the 2-alkyl phosphoric acid ethoxycarbonyl imidazoline of 80% weight, the isomerous tridecanol polyoxyethylene ether of 10% weight and the mixed REACTIVE DYES after treatment aid that gets of urea groups urea groups methylene nail polish acid amides of 10% weight.
Glacial acetic acid is joined through in the fabric after the reactive dyeing, in and pickling once, make fabric face be neutral; Add the above-mentioned after treatment aid that makes afterwards, be warming up to 90 ℃, the concentration of auxiliary agent is 0.3 grams per liter, handles 15 minutes; Under 77 ℃, fabric is used flushing with clean water 5 minutes then, remove raffinate; Continue to add aforesaid after treatment aid, be warming up to 90 ℃, the concentration of auxiliary agent is 0.8 grams per liter, handles 15 minutes; Fabric after handling was washed 5 minutes at normal temperatures, removed raffinate.
Fabric color fastness to water after treatment (variable color, staining) is 4 grades, acidproof sweat stain (variable color, staining) COLOR FASTNESS is 3 grades, alkaline-resisting sweat stain (variable color, staining) COLOR FASTNESS is 3 grades, and anti-dry friction COLOR FASTNESS is 4 grades, and anti-saliva (variable color, staining) COLOR FASTNESS is 4 grades.
Embodiment 3
With the 2-alkyl phosphoric acid ethoxycarbonyl imidazoline of 24.5% weight, the isomerous tridecanol polyoxyethylene ether of 75% weight and the mixed REACTIVE DYES after treatment aid that gets of urea groups urea groups methylene nail polish acid amides of 0.5% weight.
Glacial acetic acid is joined through in the fabric after the reactive dyeing, in and pickling once, make fabric face be neutral; Add the above-mentioned after treatment aid that makes afterwards, be warming up to 87 ℃, the concentration of auxiliary agent is 0.6 grams per liter, handles 12 minutes; Under 80 ℃, fabric is used flushing with clean water 3 minutes then, remove raffinate; Continue to add aforesaid after treatment aid, be warming up to 87 ℃, the concentration of auxiliary agent is 1 grams per liter, handles 12 minutes; Fabric after handling was washed 8 minutes at normal temperatures, removed raffinate.
Fabric color fastness to water after treatment (variable color, staining) is 3 grades, acidproof sweat stain (variable color, staining) COLOR FASTNESS is 4 grades, alkaline-resisting sweat stain (variable color, staining) COLOR FASTNESS is 4 grades, and anti-dry friction COLOR FASTNESS is 4 grades, and anti-saliva (variable color, staining) COLOR FASTNESS is 4 grades.
Embodiment 4
With the 2-alkyl phosphoric acid ethoxycarbonyl imidazoline of 50% weight, the isomerous tridecanol polyoxyethylene ether of 20% weight and the mixed REACTIVE DYES after treatment aid that gets of urea groups urea groups methylene nail polish acid amides of 30% weight.
Glacial acetic acid is joined through in the fabric after the reactive dyeing, in and pickling once, make fabric face be neutral; Add the above-mentioned after treatment aid that makes afterwards, be warming up to 90 ℃, the concentration of auxiliary agent is 0.5 grams per liter, handles 10 minutes; Under 80 ℃, fabric is used flushing with clean water 5 minutes then, remove raffinate; Continue to add aforesaid after treatment aid, be warming up to 90 ℃, the concentration of auxiliary agent is 1 grams per liter, handles 10 minutes; Fabric after handling was washed 5 minutes at normal temperatures, removed raffinate.
Fabric color fastness to water after treatment (variable color, staining) is 4 grades, acidproof sweat stain (variable color, staining) COLOR FASTNESS is 4 grades, alkaline-resisting sweat stain (variable color, staining) COLOR FASTNESS is 4 grades, and anti-dry friction COLOR FASTNESS is 4 grades, and anti-saliva (variable color, staining) COLOR FASTNESS is 4 grades.
Claims (10)
1. REACTIVE DYES after treatment aid, it comprises following component:
Zwitterionic surfactant 5～80%
Non-ionic surface active agent 10～75%
Polyamine compounds 0.5～50%
By weight.
2. REACTIVE DYES after treatment aid as claimed in claim 1, wherein, described zwitterionic surfactant is a 2-alkyl phosphoric acid ethoxycarbonyl imidazoline.
3. REACTIVE DYES after treatment aid as claimed in claim 1, wherein, described non-ionic surface active agent is an isomerous tridecanol polyoxyethylene ether.
4. REACTIVE DYES after treatment aid as claimed in claim 1, wherein, described polyamine compounds is a urea groups urea groups methylene nail polish acid amides.
5. the post-processing approach of a REACTIVE DYES, it comprises the steps:
Add in the acetic acid after a textile dyeing and pickling, make fabric face be neutral;
B adds the described after treatment aid of claim 1, is warming up to 85～90 ℃, and the concentration of auxiliary agent is 0.3～0.8 grams per liter, handles 10～15 minutes;
C uses flushing with clean water 3～7 minutes at 75～80 ℃ to the fabric after the dyeing;
D adds the described after treatment aid of claim 1, is warming up to 85～90 ℃, and the concentration of auxiliary agent is 0.8～1.5 grams per liter, handles 10～15 minutes;
E normal temperature washing 3～8 minutes.
6. post-processing approach as claimed in claim 5, wherein, the acetic acid that adds among the described step a is glacial acetic acid.
7. post-processing approach as claimed in claim 5, wherein, described step b is warming up to 90 ℃ for adding the described after treatment aid of claim 1, and the concentration of auxiliary agent is 0.5 grams per liter, handles 10 minutes.
8. post-processing approach as claimed in claim 5, wherein, described step c uses flushing with clean water 5 minutes at 80 ℃ to the fabric after the dyeing, removes raffinate.
9. post-processing approach as claimed in claim 5, wherein, described steps d is warming up to 90 ℃ for adding the described after treatment aid of claim 1, and the concentration of auxiliary agent is 1 grams per liter, and the processing time is 10 minutes.
10. post-processing approach as claimed in claim 5, wherein, described step e is normal temperature washing 5 minutes.
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| CN 200810119286 CN101349021B (en) | 2008-09-02 | 2008-09-02 | Reactive dye post treatment accessory ingredient and processing method using the same |
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| CN 200810119286 CN101349021B (en) | 2008-09-02 | 2008-09-02 | Reactive dye post treatment accessory ingredient and processing method using the same |
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| CN101349021A CN101349021A (en) | 2009-01-21 |
| CN101349021B true CN101349021B (en) | 2011-02-09 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101514304B (en) * | 2009-04-08 | 2011-05-11 | 宋子奎 | Colored textile hyperchromic washing agent |
| CN102535205B (en) * | 2011-12-28 | 2013-09-11 | 浙江纺织服装职业技术学院 | Post-treatment fixation process for fabric dyeing |
| CN104562802B (en) * | 2015-01-08 | 2016-05-18 | 广东溢达纺织有限公司 | A kind of reactive dyeing thing is soaped and is removed the method for loose colour |
| CN108048253A (en) * | 2017-12-07 | 2018-05-18 | 刘曼华 | A kind of reactive dye processing auxiliary agent and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1426295A (en) * | 2000-04-28 | 2003-06-25 | 汉高两合股份公司 | Use of sugar surfactants and fatty acid partial glycerides |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1426295A (en) * | 2000-04-28 | 2003-06-25 | 汉高两合股份公司 | Use of sugar surfactants and fatty acid partial glycerides |
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Owner name: BEIJING GLARY TEXTILE GROUP CO.,LTD. Free format text: FORMER OWNER: BEIJING GLARY WUZHOU WEAVING GROUP CO.,LTD. Effective date: 20100115 |
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Effective date of registration: 20100115 Address after: Postal code 8, Guanghua Road, Beijing, Chaoyang District: 100026 Applicant after: Beijing Guanghua Textile Group Co., Ltd. Co-applicant after: Beijing Zhongfang Haitian Dyeing And Weaving Technology Co., Ltd. Address before: Postal code 8, Guanghua Road, Beijing, Chaoyang District: 100026 Applicant before: Beijing Guanghua Wuzhou Textile Group Corporation Co-applicant before: Beijing Zhongfang Haitian Dyeing And Weaving Technology Co., Ltd. |
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Address after: Beijing City Guanghua Building No. 8 Guanghua Road, Chaoyang District 100026 Co-patentee after: Beijing Zhongfang Haitian New Material Technology Co. Ltd. Patentee after: Beijing Guanghua Textile Group Co., Ltd. Address before: 100026 No. 8 Guanghua Road, Beijing, Chaoyang District Co-patentee before: Beijing Zhongfang Haitian Dyeing And Weaving Technology Co., Ltd. Patentee before: Beijing Guanghua Textile Group Co., Ltd. |