CN103881626A - Tricresyl phosphate heat-resisting acrylic acid adhesive - Google Patents
Tricresyl phosphate heat-resisting acrylic acid adhesive Download PDFInfo
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- CN103881626A CN103881626A CN201410104332.4A CN201410104332A CN103881626A CN 103881626 A CN103881626 A CN 103881626A CN 201410104332 A CN201410104332 A CN 201410104332A CN 103881626 A CN103881626 A CN 103881626A
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- phenyl ester
- adhesive
- acrylic acid
- tricresyl phosphate
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Abstract
The invention discloses a tricresyl phosphate heat-resisting acrylic acid adhesive. The adhesive is characterized by consisting of formulas in parts by weight: 90-120 parts of methyl acrylate, 350-400 parts of isobutyl acrylate, 9-12 parts of salicylic acid, 9-12 parts of tricresyl phosphate, 150-200 parts of ethyl acrylate, 15-20 parts of acrylic acid, 13-30 parts of N- methacrylamide, 40-60 parts of nonylphenol polyoxyethylene ether, 1-5 parts of sodium metasulfite and 700-880 parts of water. The adhesive has the advantages of easily-available raw materials, low cost, environmental friendliness, convenience in use and good effect.
Description
Technical field
The invention belongs to a kind of tackiness agent.
Background technology
The features such as splicing (bonding, bonding, cementing, gluing) refers to that homogeneity or heterogeneous body surface stick with glue the technology that agent links together, and has stress distribution continuous, lightweight, or sealing, and most technological temperatures are low.Glued joint the connection that is specially adapted to unlike material, different thickness, ultra-thin specification and complex component.Glued joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide, and high-and-new science and technology progress and people's daily life improvement are had to great effect.Therefore, research, all kinds of tackiness agent of development and production are very important.Tackiness agent (Bonding agent) is one of most important subsidiary material, and in package handling, application is very extensive.Tackiness agent is the sticking material of tool, the material of two kinds of separation can be linked together by its viscosity.The kind of tackiness agent is a lot.1. natural glue it be taken from the material of occurring in nature.Comprise the biological adhesives such as starch, protein, dextrin, gelatin, shellac, hide glue, rosin; Also comprise the mineral binders such as pitch.2. artificial tackiness agent this be to use made material, comprise the inorganic adhesives such as water glass, and the organic binder bond such as synthetic resins, synthetic rubber.Service performance divides 1. Watersoluble Adhesive to use water as the tackiness agent of solvent, mainly contains starch, dextrin, polyvinyl alcohol, carboxymethyl cellulose etc.2. Hotmelt Adhesive makes to use after adhesive melts by heating, is a kind of solid binder.General thermoplastic resin all can use, as urethane, polystyrene, polyacrylic ester, ethene-acetate ethylene copolymer etc.3. Solvent Adhesive is water insoluble and be dissolved in the tackiness agent of certain solvent.As shellac, isoprene-isobutylene rubber etc.4. Emulsion Adhesive is many is suspension in water, as vinyl acetate resin, acrylic resin, chlorinated rubber etc.5. solvent-free liquid adhesive is thick liquid nano at normal temperatures, as epoxy resin etc.Tackiness agent is the medium between label material and bonding substrates, plays link effect.Can be divided into two kinds of permanent and removable property by its characteristic.It has multiple formulations, is applicable to different plane materiels and different occasions.Tackiness agent is the most important composition in adhesive material technology, is the key of tag application technology.The features such as splicing (bonding, bonding, cementing, gluing) refers to that homogeneity or heterogeneous body surface stick with glue the technology that agent links together, and has stress distribution continuous, lightweight, or sealing, and most technological temperatures are low.Glued joint the connection that is specially adapted to unlike material, different thickness, ultra-thin specification and complex component.Glued joint RECENT DEVELOPMENTS the fastest, application industry is extremely wide, and high-and-new science and technology progress and people's daily life improvement are had to great effect.Therefore, research, all kinds of tackiness agent of development and production are very important.
Through Chinese publication retrieval, do not find the scheme identical with present patent application.
Summary of the invention:
The object of the invention is to; A kind of adjacent sour front three phenyl ester heat-proof acrylic tackiness agent is proposed.
The sour front three phenyl ester of neighbour of the present invention heat-proof acrylic tackiness agent, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 90-120 part, isobutyl acrylate 350-400 part, Whitfield's ointment 9-12 part, adjacent sour front three phenyl ester 9-12 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, N-methacrylic acid acid amides 13-30 part, polyoxyethylene nonylphenol ether 40-60 part, sodium metabisulphite 1-5 part, water 700-880 part composition.
The sour front three phenyl ester of neighbour of the present invention heat-proof acrylic adhesive preparation method, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 90-120 part, isobutyl acrylate 350-400 part, Whitfield's ointment 9-12 part, adjacent sour front three phenyl ester 9-12 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, N-methacrylic acid acid amides 13-30 part, polyoxyethylene nonylphenol ether 40-60 part, sodium metabisulphite 1-5 part, water 700-880 part composition; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Product of the present invention, can adapt to the use of various occasions, and bond strength reaches the more than 2 times of prior art.
The present invention compared with prior art its beneficial effect is: have raw material and be easy to get, work simplification, is easy to manufacture the advantage such as cost is low, and environmental protection is easy to use, effective.
Embodiment:
Below in conjunction with embodiment, the invention will be further described, but embodiments of the present invention are not limited to this.
Product of the present invention is raw materials used buys acquisition.
Embodiment 1
The sour front three phenyl ester of neighbour of the present invention heat-proof acrylic adhesive preparation method, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 90-120 part, isobutyl acrylate 350-400 part, Whitfield's ointment 9-12 part, adjacent sour front three phenyl ester 9-12 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, N-methacrylic acid acid amides 13-30 part, polyoxyethylene nonylphenol ether 40-60 part, sodium metabisulphite 1-5 part, water 700-880 part composition; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Embodiment 2
The sour front three phenyl ester of neighbour of the present invention heat-proof acrylic adhesive preparation method, it is characterized in that: it is filled a prescription by weight, by 90 parts of methyl acrylates, 350 parts of isobutyl acrylate, 9 parts of Whitfield's ointments, 9 parts of adjacent sour front three phenyl esters, 150 parts of ethyl propenoates, 15 parts, vinylformic acid, 13 parts of N-methacrylic acid acid amides, 40 parts of polyoxyethylene nonylphenol ethers, sodium metabisulphite 1-5 part, water 700-880 part composition; Whole materials are added to mixing, and at 80-90 ℃, reaction 60-90 minute, obtains product.
Embodiment 3
The sour front three phenyl ester of neighbour of the present invention heat-proof acrylic adhesive preparation method, it is characterized in that: it is filled a prescription by weight, by 120 parts of methyl acrylates, 400 parts of isobutyl acrylate, 12 parts of Whitfield's ointments, 12 parts of adjacent sour front three phenyl esters, 200 parts of ethyl propenoates, 20 parts, vinylformic acid, 30 parts of N-methacrylic acid acid amides, 60 parts of polyoxyethylene nonylphenol ethers, sodium metabisulphite 1-5 part, water 700-880 part composition; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Embodiment 4
The sour front three phenyl ester of neighbour of the present invention heat-proof acrylic adhesive preparation method, it is characterized in that: it is filled a prescription by weight, by 90 parts of methyl acrylates, 400 parts of isobutyl acrylate, 9 parts of Whitfield's ointments, 12 parts of adjacent sour front three phenyl esters, 150 parts of ethyl propenoates, 20 parts, vinylformic acid, 13 parts of N-methacrylic acid acid amides, 60 parts of polyoxyethylene nonylphenol ethers, sodium metabisulphite 1-5 part, water 700-880 part composition; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Embodiment 5
The sour front three phenyl ester of neighbour of the present invention heat-proof acrylic adhesive preparation method, it is characterized in that: it is filled a prescription by weight, by 120 parts of methyl acrylates, 350 parts of isobutyl acrylate, 12 parts of Whitfield's ointments, 9 parts of adjacent sour front three phenyl esters, 200 parts of ethyl propenoates, 15 parts, vinylformic acid, 30 parts of N-methacrylic acid acid amides, 60 parts of polyoxyethylene nonylphenol ethers, sodium metabisulphite 1-5 part, water 700-880 part composition; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.At room temperature stirring reaction 12-22 hour, obtains product.
Product specification of the present invention, quality: solid content is more than 80%, and its 1% solution pH value is 7.0-7.5; Viscosity 120-130 centipoise.
Claims (2)
1. the sour front three phenyl ester of a neighbour heat-proof acrylic tackiness agent, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 90-120 part, isobutyl acrylate 350-400 part, Whitfield's ointment 9-12 part, adjacent sour front three phenyl ester 9-12 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, N-methacrylic acid acid amides 13-30 part, polyoxyethylene nonylphenol ether 40-60 part, sodium metabisulphite 1-5 part, water 700-880 part composition.
2. the sour front three phenyl ester of a neighbour heat-proof acrylic adhesive preparation method, it is characterized in that: it is filled a prescription by weight, by methyl acrylate 90-120 part, isobutyl acrylate 350-400 part, Whitfield's ointment 9-12 part, adjacent sour front three phenyl ester 9-12 part, ethyl propenoate 150-200 part, vinylformic acid 15-20 part, N-methacrylic acid acid amides 13-30 part, polyoxyethylene nonylphenol ether 40-60 part, sodium metabisulphite 1-5 part, water 700-880 part composition; Whole materials are added to mixing, react 60-90 minute at 80-90 ℃, obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410104332.4A CN103881626A (en) | 2014-03-20 | 2014-03-20 | Tricresyl phosphate heat-resisting acrylic acid adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410104332.4A CN103881626A (en) | 2014-03-20 | 2014-03-20 | Tricresyl phosphate heat-resisting acrylic acid adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103881626A true CN103881626A (en) | 2014-06-25 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410104332.4A Pending CN103881626A (en) | 2014-03-20 | 2014-03-20 | Tricresyl phosphate heat-resisting acrylic acid adhesive |
Country Status (1)
| Country | Link |
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| CN (1) | CN103881626A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1032617B1 (en) * | 1997-11-20 | 2003-05-28 | Lucent Technologies Inc. | Pressure-sensitive flame retardant adhesive |
| CN103525341A (en) * | 2013-10-10 | 2014-01-22 | 杨毅 | Acrylate bonding agent |
-
2014
- 2014-03-20 CN CN201410104332.4A patent/CN103881626A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1032617B1 (en) * | 1997-11-20 | 2003-05-28 | Lucent Technologies Inc. | Pressure-sensitive flame retardant adhesive |
| CN103525341A (en) * | 2013-10-10 | 2014-01-22 | 杨毅 | Acrylate bonding agent |
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Application publication date: 20140625 |