CN103789545A - 一种低共熔溶剂分离铅锑氧化物焙砂的方法 - Google Patents
一种低共熔溶剂分离铅锑氧化物焙砂的方法 Download PDFInfo
- Publication number
- CN103789545A CN103789545A CN201410017338.8A CN201410017338A CN103789545A CN 103789545 A CN103789545 A CN 103789545A CN 201410017338 A CN201410017338 A CN 201410017338A CN 103789545 A CN103789545 A CN 103789545A
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- Prior art keywords
- lead
- eutectic solvent
- oxide
- solvent
- oxide calcining
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- 239000002904 solvent Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 26
- 229910000410 antimony oxide Inorganic materials 0.000 title abstract 4
- 238000000926 separation method Methods 0.000 claims abstract description 22
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000004090 dissolution Methods 0.000 claims abstract description 14
- 150000001408 amides Chemical class 0.000 claims abstract description 13
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 13
- 238000001914 filtration Methods 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 239000012153 distilled water Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000005496 eutectics Effects 0.000 claims description 30
- 238000001354 calcination Methods 0.000 claims description 25
- 229910052787 antimony Inorganic materials 0.000 claims description 10
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 claims description 6
- HTZCNXWZYVXIMZ-UHFFFAOYSA-M benzyl(triethyl)azanium;chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC1=CC=CC=C1 HTZCNXWZYVXIMZ-UHFFFAOYSA-M 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 229910052756 noble gas Inorganic materials 0.000 claims description 6
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 4
- 239000001763 2-hydroxyethyl(trimethyl)azanium Substances 0.000 claims description 3
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 3
- 235000019743 Choline chloride Nutrition 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- SGMZJAMFUVOLNK-UHFFFAOYSA-M choline chloride Chemical group [Cl-].C[N+](C)(C)CCO SGMZJAMFUVOLNK-UHFFFAOYSA-M 0.000 claims description 3
- 229960003178 choline chloride Drugs 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 3
- 238000009856 non-ferrous metallurgy Methods 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 229910001245 Sb alloy Inorganic materials 0.000 description 2
- 239000002140 antimony alloy Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910052973 jamesonite Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 239000000374 eutectic mixture Substances 0.000 description 1
- 238000000703 high-speed centrifugation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
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Claims (4)
Priority Applications (1)
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CN201410017338.8A CN103789545B (zh) | 2014-01-15 | 2014-01-15 | 一种低共熔溶剂分离铅锑氧化物焙砂的方法 |
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CN201410017338.8A CN103789545B (zh) | 2014-01-15 | 2014-01-15 | 一种低共熔溶剂分离铅锑氧化物焙砂的方法 |
Publications (2)
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CN103789545A true CN103789545A (zh) | 2014-05-14 |
CN103789545B CN103789545B (zh) | 2015-07-22 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104213151A (zh) * | 2014-09-05 | 2014-12-17 | 昆明理工大学 | 一种直接电解铅锑氧化物制取铅锑合金的方法 |
CN105132713A (zh) * | 2015-09-15 | 2015-12-09 | 昆明理工大学 | 一种低共熔溶剂原位还原三氧化二锑制取锑的方法 |
CN105483389A (zh) * | 2016-01-13 | 2016-04-13 | 云南大学 | 一种废旧液晶面板中铟的浸出方法及浸出剂 |
CN106676583A (zh) * | 2017-03-29 | 2017-05-17 | 昆明理工大学 | 一种利用低共熔溶剂电解分离锡铅合金的方法 |
CN111675239A (zh) * | 2020-04-28 | 2020-09-18 | 廊坊师范学院 | 一种利用聚乙二醇型低共熔溶剂溶解提取碘化铅的方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5120523A (en) * | 1989-11-16 | 1992-06-09 | Agency Of Industrial Science & Technology, Ministry Of International Trade & Industry | Method for dissolution of metal |
WO2007147222A2 (en) * | 2006-06-21 | 2007-12-27 | Katholieke Universiteit Leuven | Novel ionic liquids |
CN101928034A (zh) * | 2010-09-07 | 2010-12-29 | 辽宁石油化工大学 | 一种制备氯化亚铜的方法 |
EP2597099A1 (en) * | 2011-11-23 | 2013-05-29 | King Saud University | Deep eutectic solvent and method for its preparation |
-
2014
- 2014-01-15 CN CN201410017338.8A patent/CN103789545B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5120523A (en) * | 1989-11-16 | 1992-06-09 | Agency Of Industrial Science & Technology, Ministry Of International Trade & Industry | Method for dissolution of metal |
WO2007147222A2 (en) * | 2006-06-21 | 2007-12-27 | Katholieke Universiteit Leuven | Novel ionic liquids |
CN101928034A (zh) * | 2010-09-07 | 2010-12-29 | 辽宁石油化工大学 | 一种制备氯化亚铜的方法 |
EP2597099A1 (en) * | 2011-11-23 | 2013-05-29 | King Saud University | Deep eutectic solvent and method for its preparation |
Non-Patent Citations (2)
Title |
---|
张盈盈 等: "胆碱类低共熔溶剂的物性及应用", 《化学进展》 * |
田国才 等: "离子液体在有色金属冶金中的应用", 《过程工程学报》 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104213151A (zh) * | 2014-09-05 | 2014-12-17 | 昆明理工大学 | 一种直接电解铅锑氧化物制取铅锑合金的方法 |
CN104213151B (zh) * | 2014-09-05 | 2017-05-10 | 昆明理工大学 | 一种直接电解铅锑氧化物制取铅锑合金的方法 |
CN105132713A (zh) * | 2015-09-15 | 2015-12-09 | 昆明理工大学 | 一种低共熔溶剂原位还原三氧化二锑制取锑的方法 |
CN105483389A (zh) * | 2016-01-13 | 2016-04-13 | 云南大学 | 一种废旧液晶面板中铟的浸出方法及浸出剂 |
CN106676583A (zh) * | 2017-03-29 | 2017-05-17 | 昆明理工大学 | 一种利用低共熔溶剂电解分离锡铅合金的方法 |
CN106676583B (zh) * | 2017-03-29 | 2019-01-04 | 昆明理工大学 | 一种利用低共熔溶剂电解分离锡铅合金的方法 |
CN111675239A (zh) * | 2020-04-28 | 2020-09-18 | 廊坊师范学院 | 一种利用聚乙二醇型低共熔溶剂溶解提取碘化铅的方法 |
CN111675239B (zh) * | 2020-04-28 | 2022-07-08 | 廊坊师范学院 | 一种利用聚乙二醇型低共熔溶剂溶解提取碘化铅的方法 |
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CN103789545B (zh) | 2015-07-22 |
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Address after: 650051 50 Huancheng East Road, Kunming City, Yunnan Province (inside Kunming University of Science and Technology) Patentee after: Kunming University of Technology Design and Research Institute Co.,Ltd. Address before: 650051 50 Huancheng East Road, Kunming City, Yunnan Province (inside Kunming University of Science and Technology) Patentee before: Design and Research Institute of Kunming University of Science and Technology |
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Application publication date: 20140514 Assignee: YUNNAN YARONG MINING TECHNOLOGY CO.,LTD. Assignor: Kunming University of Technology Design and Research Institute Co.,Ltd. Contract record no.: X2023980041498 Denomination of invention: A method for separating lead antimony oxide calcine with low eutectic solvent Granted publication date: 20150722 License type: Common License Record date: 20230908 Application publication date: 20140514 Assignee: Yunnan Tangyuan Biotechnology Co.,Ltd. Assignor: Kunming University of Technology Design and Research Institute Co.,Ltd. Contract record no.: X2023980041492 Denomination of invention: A method for separating lead antimony oxide calcine with low eutectic solvent Granted publication date: 20150722 License type: Common License Record date: 20230908 Application publication date: 20140514 Assignee: Kunyu environment development (Yunnan) Co.,Ltd. Assignor: Kunming University of Technology Design and Research Institute Co.,Ltd. Contract record no.: X2023980041466 Denomination of invention: A method for separating lead antimony oxide calcine with low eutectic solvent Granted publication date: 20150722 License type: Common License Record date: 20230908 |
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Application publication date: 20140514 Assignee: Yunnan Huawei Waste Resource Co.,Ltd. Assignor: Kunming University of Technology Design and Research Institute Co.,Ltd. Contract record no.: X2023980041587 Denomination of invention: A method for separating lead antimony oxide calcine with low eutectic solvent Granted publication date: 20150722 License type: Common License Record date: 20230911 |