Biodegradation type deicing or snow melting agent and preparation method thereof
Technical field
The present invention relates to a kind of deicing or snow melting agent and preparation method thereof, especially a kind of biodegradation type deicing or snow melting agent and preparation method thereof, belongs to technical field of chemistry.
Background technology
At China and the extremely frigid zones of many countries in the world, winter, ice and snow became serious public hazards, deep accumulated snow and smooth road surface, caused traffic jam, accident repeatedly, motorway stops transport, the serious consequences such as socked-in.Generally adopt the mode of the surface sprinkling deicing or snow melting agent after snow to reach deicing or snow melting effect.The exploitation of deicing or snow melting agent has been experienced single salt type, inorganic villaumite type to organic type, anticorrosion type.But the Snow Agent of the above-mentioned type, cannot be degradable, and environment is had to certain harm.
Summary of the invention
The technical problem to be solved in the present invention is the defect existing for prior art, proposes a kind of biodegradation type deicing or snow melting agent and preparation method thereof, can reach complete biodegradable, and environment zero is endangered.
The present invention is technical solution problem by the following technical programs: the agent of biodegradation type deicing or snow melting, and the component that contains following weight percent:
In said components, described in to fall freezing point agent be ethylene glycol or propylene glycol.
Described ice crystal lattice disrupting agent is polyether-modified heptamethyltrisiloxane or 1,2-bis-(triethoxy is silica-based) ethane.
Described anti-ice adhesive agent is 2,6,10,14-tetramethyl-pentadecane, squalene, 2,6,10,15,19, the one in 23-squalane.
Described thickening material is the one in starch, xanthan gum, Mierocrystalline cellulose.
Described tensio-active agent is the one in cholesterol, tea saponin, alkylglycoside.
Described solvent is methyl alcohol or ethanol.
The present invention further provides the preparation method of biodegradation type deicing or snow melting agent, each raw material is taken in described ratio, for subsequent use, in reaction vessel, add solvent, after whipping appts in unlatching reaction vessel, add and fall freezing point agent, add again ice crystal lattice disrupting agent, being stirred to ice crystal lattice disrupting agent is dispersed in solution, add anti-ice adhesive agent, be stirred to after anti-ice adhesive agent dissolves and add tensio-active agent, be stirred to after tensio-active agent is uniformly dispersed in solution and add thickening material, be stirred to thickening material and be uniformly dispersed in solution, be finished product.
Biodegradation type deicing or snow melting of the present invention agent, not only deicing or snow melting ability is strong, and minimum to metal, concrete erosion.Importantly Snow Agent of the present invention is easily biodegradable, almost harmless to human body, animals and plants and microorganism, is a kind of all biological degradation type Snow Agent that can thaw ice and snow fast.
Embodiment
In the embodiment of the present invention, each component is commercially available, below repeats no more.
Embodiment mono-
The component proportion of this example is in Table 1(by weight percentage):
Table 1
Embodiment bis-
The component proportion of this example is in Table 2(by weight percentage):
Table 2
Embodiment tri-
The component proportion of this example is in Table 3(by weight percentage):
Table 3
By the following method the product of above-described embodiment is tested:
One, experiment
1, deicing or snow melting aptitude tests
Experimental technique and step are shown in GB/T23851-2009
By deicing or snow melting aptitude tests, its evaluation of result is in table 4:
Table 4
Sequence number |
Deicing or snow melting ability W/% |
Embodiment mono- |
188 |
Embodiment bis- |
179 |
Embodiment tri- |
181 |
Can be found out by upper table result, all biological degradation type deicing or snow melting agent the present invention relates to possesses excellent deicing or snow melting ability.
2, biodegradability test
Experimental technique and step are shown in " water and examination of wastewater standard method " American Public Health Association (APHA) (APAH)
Test by biodegradability, its evaluation of result is in table 5:
Table 5
Sequence number |
15 days artifact degradation rate/% |
Embodiment mono- |
93 |
Embodiment bis- |
90 |
Embodiment tri- |
91 |
Can be found out by upper table result, all biological degradation type deicing or snow melting agent the present invention relates to possesses excellent biodegradability.
3, corrosion of carbon steel rate
Experimental technique and step are shown in GB/T18175-2000
Test by corrosion of carbon steel rate, its evaluation of result is in table 6:
Table 6
Sequence number |
Corrosion rate X/ (mm/a) |
Embodiment mono- |
0.0178 |
Embodiment bis- |
0.0220 |
Embodiment tri- |
0.0195 |
Can be found out by upper table result, all biological degradation type deicing or snow melting agent the present invention relates to possesses excellent anti-metallic corrosion ability.
4, concrete erosion rate
Experimental technique and step are shown in GBJ82-1985
Test by concrete erosion rate, its evaluation of result is in table 7:
Table 7
Sequence number |
Steel bar corrosion rate of weight loss Lw/% |
Embodiment mono- |
0.18 |
Embodiment bis- |
0.15 |
Embodiment tri- |
0.20 |
Can be found out by upper table result, all biological degradation type deicing or snow melting agent the present invention relates to possesses excellent anti-concrete erosion ability.
Except above-mentioned enforcement, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of requirement of the present invention.