CN103787345A - 层数可调的多层囊泡状介孔二氧化硅及其合成方法 - Google Patents
层数可调的多层囊泡状介孔二氧化硅及其合成方法 Download PDFInfo
- Publication number
- CN103787345A CN103787345A CN201410032426.5A CN201410032426A CN103787345A CN 103787345 A CN103787345 A CN 103787345A CN 201410032426 A CN201410032426 A CN 201410032426A CN 103787345 A CN103787345 A CN 103787345A
- Authority
- CN
- China
- Prior art keywords
- mesoporous silicon
- silicon oxide
- adjustable
- synthetic method
- plies
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 238000010189 synthetic method Methods 0.000 title claims abstract description 13
- 239000000377 silicon dioxide Substances 0.000 title abstract description 9
- 235000012239 silicon dioxide Nutrition 0.000 title abstract description 8
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims abstract description 24
- 238000003756 stirring Methods 0.000 claims abstract description 23
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002244 precipitate Substances 0.000 claims abstract description 15
- 239000012153 distilled water Substances 0.000 claims abstract description 12
- 238000001354 calcination Methods 0.000 claims abstract description 7
- 238000005406 washing Methods 0.000 claims abstract description 7
- 239000000725 suspension Substances 0.000 claims abstract description 6
- 238000000967 suction filtration Methods 0.000 claims abstract description 4
- 238000000227 grinding Methods 0.000 claims abstract description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 34
- UMGXUWVIJIQANV-UHFFFAOYSA-M didecyl(dimethyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC UMGXUWVIJIQANV-UHFFFAOYSA-M 0.000 claims description 12
- 238000013019 agitation Methods 0.000 claims description 8
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 6
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 230000001105 regulatory effect Effects 0.000 abstract description 2
- PSLWZOIUBRXAQW-UHFFFAOYSA-M dimethyl(dioctadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC PSLWZOIUBRXAQW-UHFFFAOYSA-M 0.000 abstract 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 15
- 238000001914 filtration Methods 0.000 description 6
- 239000003814 drug Substances 0.000 description 4
- 239000013335 mesoporous material Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000003760 magnetic stirring Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229960001866 silicon dioxide Drugs 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229910001868 water Inorganic materials 0.000 description 2
- 240000007651 Rubus glaucus Species 0.000 description 1
- 235000011034 Rubus glaucus Nutrition 0.000 description 1
- 235000009122 Rubus idaeus Nutrition 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Images
Landscapes
- Silicon Compounds (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410032426.5A CN103787345B (zh) | 2014-01-23 | 2014-01-23 | 层数可调的多层囊泡状介孔二氧化硅及其合成方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410032426.5A CN103787345B (zh) | 2014-01-23 | 2014-01-23 | 层数可调的多层囊泡状介孔二氧化硅及其合成方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103787345A true CN103787345A (zh) | 2014-05-14 |
CN103787345B CN103787345B (zh) | 2015-06-17 |
Family
ID=50663472
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410032426.5A Active CN103787345B (zh) | 2014-01-23 | 2014-01-23 | 层数可调的多层囊泡状介孔二氧化硅及其合成方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103787345B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106044789A (zh) * | 2016-05-26 | 2016-10-26 | 齐鲁工业大学 | 多层壳蠕虫状介孔二氧化硅及其制备方法 |
CN106744994A (zh) * | 2017-02-28 | 2017-05-31 | 齐鲁工业大学 | 一种毛刷状介孔二氧化硅纤维材料及其制备方法 |
CN108745217A (zh) * | 2018-05-11 | 2018-11-06 | 苏州泽漫生物技术有限公司 | 多壳层中空磁性微球的制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101638238A (zh) * | 2008-07-30 | 2010-02-03 | 中国科学院理化技术研究所 | 形貌和结构可控的含有有序介孔孔道的二氧化硅纳米材料的制备方法 |
CN103011182A (zh) * | 2012-12-20 | 2013-04-03 | 山东轻工业学院 | 一种囊泡状介孔二氧化硅的合成方法 |
-
2014
- 2014-01-23 CN CN201410032426.5A patent/CN103787345B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101638238A (zh) * | 2008-07-30 | 2010-02-03 | 中国科学院理化技术研究所 | 形貌和结构可控的含有有序介孔孔道的二氧化硅纳米材料的制备方法 |
CN103011182A (zh) * | 2012-12-20 | 2013-04-03 | 山东轻工业学院 | 一种囊泡状介孔二氧化硅的合成方法 |
Non-Patent Citations (1)
Title |
---|
GUOWEI ZHOU,ET AL.: "From cylindrical-channel mesoporous silica to vesicle-like silica with well-defined multilamella shells and large inter-shell mesopores", 《JOURNAL OF MATERIALS CHEMISTRY》, vol. 17, 14 May 2007 (2007-05-14), pages 2839 - 2844 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106044789A (zh) * | 2016-05-26 | 2016-10-26 | 齐鲁工业大学 | 多层壳蠕虫状介孔二氧化硅及其制备方法 |
CN106044789B (zh) * | 2016-05-26 | 2017-11-14 | 齐鲁工业大学 | 多层壳蠕虫状介孔二氧化硅及其制备方法 |
CN106744994A (zh) * | 2017-02-28 | 2017-05-31 | 齐鲁工业大学 | 一种毛刷状介孔二氧化硅纤维材料及其制备方法 |
CN106744994B (zh) * | 2017-02-28 | 2018-12-14 | 齐鲁工业大学 | 一种毛刷状介孔二氧化硅纤维材料及其制备方法 |
CN108745217A (zh) * | 2018-05-11 | 2018-11-06 | 苏州泽漫生物技术有限公司 | 多壳层中空磁性微球的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN103787345B (zh) | 2015-06-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104211127B (zh) | 一种α-Fe2O3中空微球的制备方法 | |
CN104607231B (zh) | 具有三维有序大孔结构的氮化碳光催化剂及其制备方法 | |
CN102633265B (zh) | 一种可控中空介孔二氧化硅纳米球的制备方法 | |
CN105399150B (zh) | 一种钴酸镍纳米材料及其制备方法和应用 | |
CN108238605B (zh) | 一种三维花状碱式硅酸镍微球及其制备方法 | |
CN101792164A (zh) | 一种真空冷冻干燥制备纳米氧化铝的方法 | |
CN104692399A (zh) | 一种高度有序放射状球形具皱介孔二氧化硅材料及其制备方法 | |
CN109942012B (zh) | 一种纳米级片状勃姆石及其制备方法 | |
CN110921708B (zh) | 一种MoO3自组装六棱柱结构的制备方法及其应用 | |
CN103787345B (zh) | 层数可调的多层囊泡状介孔二氧化硅及其合成方法 | |
CN103771427A (zh) | 一种类球状介孔二氧化硅的制备方法 | |
CN104439276B (zh) | 一种快速制备中空多孔二氧化硅/银纳米复合材料的方法及产品 | |
CN108147456A (zh) | 一种单分散二氧化锆微球的制备方法 | |
CN106167254B (zh) | 一种金属磷酸盐及其制备方法 | |
CN104971703A (zh) | 一种聚吡咯包覆磁性还原石墨烯纳米材料的制备方法 | |
CN107298444A (zh) | 一种以松香基双子表面活性剂为模板的介孔二氧化硅材料的制备及其性能 | |
CN106994345B (zh) | 一种粒子自组装TiO2/Fe2O3链状复合粉体的制备方法 | |
CN106830069B (zh) | 一种花状介孔二氧化钛分级结构及其制备方法 | |
CN108083334A (zh) | 一种单分散球形纳米二氧化锆粉体材料的制备方法 | |
CN101774603B (zh) | 一种介孔硼酸镁微球的制备方法 | |
CN104098144B (zh) | 四氧化三铁空心球的制备方法 | |
CN104195642B (zh) | 一种制备单晶BiFeO3纳米片的方法 | |
CN105439205B (zh) | 方框状Mn3O4的制备方法 | |
CN103641121A (zh) | 一种纳米磁性大孔二氧化硅复合材料及其制备方法 | |
CN105622066B (zh) | 一种微乳-水热法合成热敏电阻粉体材料的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20221226 Address after: Room 3115, No. 135, Ward Avenue, Ping'an Street, Changqing District, Jinan, Shandong 250300 Patentee after: Shandong Jiqing Technology Service Co.,Ltd. Address before: 250353 Science Park, West New Town University, Changqing District, Shandong, Ji'nan Patentee before: Qilu University of Technology |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240717 Address after: 250353 University Road, Changqing District, Ji'nan, Shandong Province, No. 3501 Patentee after: Qilu University of Technology (Shandong Academy of Sciences) Country or region after: China Address before: 250306 Room 3115, No. 135, Ward Avenue, Ping'an Street, Changqing District, Jinan City, Shandong Province Patentee before: Shandong Jiqing Technology Service Co.,Ltd. Country or region before: China |