CN103710055A - Alcohol-based liquid fuel and manufacturing method thereof - Google Patents

Alcohol-based liquid fuel and manufacturing method thereof Download PDF

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Publication number
CN103710055A
CN103710055A CN201310624060.6A CN201310624060A CN103710055A CN 103710055 A CN103710055 A CN 103710055A CN 201310624060 A CN201310624060 A CN 201310624060A CN 103710055 A CN103710055 A CN 103710055A
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Prior art keywords
liquid fuel
alcohol
additive
radical liquid
alcohol radical
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CN201310624060.6A
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CN103710055B (en
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熊绪军
熊剑飘
吴南方
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HUBEI LI RUI ENERGY TECHNOLOGY Co Ltd
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HUBEI LI RUI ENERGY TECHNOLOGY Co Ltd
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Abstract

The invention provides alcohol-based liquid fuel. The alcohol-based liquid fuel comprises methanol, an additive and a catalyst. The additive comprises, by mass, 31-35% of water, 5% of sodium hydroxide, 5% of sodium acetate, 35% of glycerol, 18% of hydrogen peroxide and 2-6% of ferric nitrate. The catalyst is ferrocene. The components in the additive and mass parts of the components are adjusted, content of hydrogen peroxide as an oxygenation agent is improved and water content is reduced. Through use of ferric nitrate, carbon formation of the existing alcohol-based liquid fuel is avoided and carbon deposit is not produced after continuous combustion for 12h. The invention also provides a manufacturing method of the alcohol-based liquid fuel. The manufacturing method comprises the following steps of additive mixing preparation, methanol addition and ferrocene addition. The manufacturing method has simple processes. All the components of the alcohol-based liquid fuel have good miscibility.

Description

A kind of alcohol radical liquid fuel and preparation method thereof
Technical field
The invention belongs to liquid fuel field, particularly a kind of alcohol radical liquid fuel and preparation method thereof.
Background technology
Existing alcohol radical liquid fuel is to using methyl alcohol as matrix mostly, the each component of additive and mass fraction are: sodium hydroxide 5%, sodium-acetate 5%, glycerol 35%, hydrogen peroxide 15%, water 40%, the alcohol radical liquid fuel of this kind of composition can cause carbon distribution problem, and particularly carbon distribution problem is more serious during continuous burning.
Summary of the invention
The object of the invention is to solve the problem that prior art exists, a kind of alcohol radical liquid fuel is provided, adjust each component and mass fraction thereof in additive, improve the content of oxygenation agent hydrogen peroxide, the content that reduces water, in addition, adds iron nitrate, can be good at solving the carbon distribution problem of alcohol radical liquid fuel, can reach continuous burning 12h and not occur carbon distribution.The present invention also provides a kind of making method of alcohol radical liquid fuel, is first mixed and made into additive, adds methyl alcohol again, adds ferrocene, and manufacture craft is simple, and the Combination of each component is better.
In order to reach above-mentioned technical purpose, the concrete technical scheme that a kind of alcohol radical liquid fuel provided by the invention adopts is:
An alcohol radical liquid fuel, comprises methyl alcohol, additive and catalyzer, and the each component that described additive-package contains is according to the mass fraction: water 31-35%, sodium hydroxide 5%, sodium-acetate 5%, glycerol 35%, hydrogen peroxide 18%, iron nitrate 2%-6%, described catalyzer is ferrocene.
As such scheme preferably, the water in described additive and the mass fraction of iron nitrate are: water 31%, iron nitrate 6%.
As such scheme preferably, the water in described additive and the mass fraction of iron nitrate are: water 35%, iron nitrate 2%.
As such scheme preferably, the water in described additive and the mass fraction of iron nitrate are: water 33%, iron nitrate 4%.
As such scheme preferably, the purity of described methyl alcohol is 99.9%, and the ratio of quality and the number of copies of methyl alcohol and additive is 1000:5.
As such scheme preferably, the content of described ferrocene accounts for 0.025% of alcohol radical liquid fuel total mass.
As such scheme preferably, also comprise deodovization agent camphor, the content of described camphor accounts for 0.005% of alcohol radical liquid fuel total mass.
Compared with prior art, a kind of alcohol radical liquid fuel provided by the invention has the following advantages: adjust each component and mass fraction thereof in additive, improve the content of oxygenation agent hydrogen peroxide, reduce the content of water, in addition, add iron nitrate, can be good at solving the carbon distribution problem of alcohol radical liquid fuel, can reach continuous burning 12h and not occur carbon distribution; In fuel, add deodovization agent camphor, can remove the peculiar smell in fuel.
The present invention also provides a kind of making method of alcohol radical liquid fuel, comprises following steps: a, mixes additive by the order of water, sodium hydroxide, sodium-acetate, glycerol, hydrogen peroxide, iron nitrate; B adds methyl alcohol in the additive after mixing; C, adds ferrocene, obtains alcohol radical liquid fuel.
As such scheme preferably, also comprise steps d, in alcohol-group fuel, add deodovization agent camphor.
The making method of a kind of alcohol radical liquid fuel provided by the invention, manufacture craft is simple, and the Combination of each component is better; Add deodovization agent camphor to remove the peculiar smell in fuel.
Embodiment
Below in conjunction with specific embodiments of the invention, technical scheme of the present invention is clearly and completely described.Obviously, described embodiment is only part embodiment of the present invention, rather than whole embodiment.Embodiment based in the present invention, the every other embodiment that those of ordinary skills obtain under the prerequisite of not making creative work, belongs to protection scope of the present invention.
Embodiment 1
A kind of alcohol radical liquid fuel, comprise methyl alcohol, additive and catalyzer, the each component that described additive-package contains is according to the mass fraction: water 35%, sodium hydroxide 5%, sodium-acetate 5%, glycerol 35%, hydrogen peroxide 18%, iron nitrate 2%, described catalyzer is ferrocene, the content of described ferrocene accounts for 0.025% of alcohol radical liquid fuel total mass, and the purity of described methyl alcohol is 99.9%, and the ratio of quality and the number of copies of methyl alcohol and additive is 1000:5.
Embodiment 2:
A kind of alcohol radical liquid fuel, comprise methyl alcohol, additive and catalyzer, the each component that described additive-package contains is according to the mass fraction: water 33%, sodium hydroxide 5%, sodium-acetate 5%, glycerol 35%, hydrogen peroxide 18%, iron nitrate 4%, described catalyzer is ferrocene, the content of described ferrocene accounts for 0.025% of alcohol radical liquid fuel total mass, and the purity of described methyl alcohol is 99.9%, and the ratio of quality and the number of copies of methyl alcohol and additive is 1000:5.
Embodiment 3:
A kind of alcohol radical liquid fuel, comprise methyl alcohol, additive and catalyzer, the each component that described additive-package contains is according to the mass fraction: water 31%, sodium hydroxide 5%, sodium-acetate 5%, glycerol 35%, hydrogen peroxide 18%, iron nitrate 6%, described catalyzer is ferrocene, the content of described ferrocene accounts for 0.025% of alcohol radical liquid fuel total mass, and the purity of described methyl alcohol is 99.9%, and the ratio of quality and the number of copies of methyl alcohol and additive is 1000:5.
Embodiment 4
A kind of alcohol radical liquid fuel is provided, on the basis of the component of embodiment 1 or embodiment 2 or embodiment 3, also comprises deodovization agent camphor, the content of described camphor accounts for 0.005% of alcohol radical liquid fuel total mass.
Embodiment 5
A making method for alcohol radical liquid fuel, the each component of usining in arbitrary in embodiment 1-3, as raw material, comprises following steps:
A, mixes additive by the order of water, sodium hydroxide, sodium-acetate, glycerol, hydrogen peroxide, iron nitrate;
B adds methyl alcohol in the additive after mixing;
C, adds ferrocene, obtains alcohol radical liquid fuel.
Embodiment 6
A making method for alcohol radical liquid fuel, the each component of usining in embodiment 4, as raw material, comprises following steps:
A, mixes additive by the order of water, sodium hydroxide, sodium-acetate, glycerol, hydrogen peroxide, iron nitrate;
B adds methyl alcohol in the additive after mixing;
C, adds ferrocene, obtains alcohol radical liquid fuel;
D adds deodovization agent camphor in alcohol-group fuel.
The foregoing is only several embodiment of the present invention; but protection scope of the present invention is not limited to this; in the technical scope that the those of ordinary skill of any skilled discloses in the present invention; the variation that can expect easily or replacement, all should be encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of described claim.

Claims (9)

1. an alcohol radical liquid fuel, comprises methyl alcohol, additive and catalyzer, it is characterized in that, the each component that described additive-package contains is according to the mass fraction: water 31-35%, sodium hydroxide 5%, sodium-acetate 5%, glycerol 35%, hydrogen peroxide 18%, iron nitrate 2%-6%, described catalyzer is ferrocene.
2. alcohol radical liquid fuel according to claim 1, is characterized in that, the water in described additive and the mass fraction of iron nitrate are: water 31%, iron nitrate 6%.
3. alcohol radical liquid fuel according to claim 1, is characterized in that, the water in described additive and the mass fraction of iron nitrate are: water 35%, iron nitrate 2%.
4. alcohol radical liquid fuel according to claim 1, is characterized in that, the water in described additive and the mass fraction of iron nitrate are: water 33%, iron nitrate 4%.
5. according to the alcohol radical liquid fuel described in any one in claim 1-4, it is characterized in that, the purity of described methyl alcohol is 99.9%, and the ratio of quality and the number of copies of methyl alcohol and additive is 1000:5.
6. alcohol radical liquid fuel according to claim 5, is characterized in that, the content of described ferrocene accounts for 0.025% of alcohol radical liquid fuel total mass.
7. alcohol radical liquid fuel according to claim 5, is characterized in that, also comprises deodovization agent camphor, and the content of described camphor accounts for 0.005% of alcohol radical liquid fuel total mass.
8. a making method for alcohol radical liquid fuel, is characterized in that, the each component in right to use requirement 1-6 any one, as raw material, comprises following steps:
A, mixes additive by the order of water, sodium hydroxide, sodium-acetate, glycerol, hydrogen peroxide, iron nitrate;
B adds methyl alcohol in the additive after mixing;
C, adds ferrocene, obtains alcohol radical liquid fuel.
9. the making method of alcohol radical liquid fuel according to claim 8, is characterized in that, also comprises steps d, adds deodovization agent camphor in alcohol-group fuel.
CN201310624060.6A 2013-11-27 2013-11-27 Alcohol-based liquid fuel and manufacturing method thereof Expired - Fee Related CN103710055B (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104357099A (en) * 2014-11-10 2015-02-18 湖北德美科技有限公司 Alcohol-based fuel and preparation method thereof
CN105779031A (en) * 2015-06-19 2016-07-20 潍坊桂禾散热片科技有限公司 Liquid fuel
CN107892957A (en) * 2017-12-19 2018-04-10 山东联星能源集团有限公司 A kind of alcohol-based fuel with high heat value and preparation method thereof
CN108359511A (en) * 2018-02-12 2018-08-03 北京欧美中科学技术研究院 A kind of military solid alcohol fuel of environment-friendly type
CN108485727A (en) * 2018-02-12 2018-09-04 北京欧美中科学技术研究院 A kind of typed high-energy liquid fuel in alcohol group
CN108843969A (en) * 2018-08-17 2018-11-20 熊绪军 A kind of alcohol radical liquid fuel bottle placer
CN108998113A (en) * 2018-06-14 2018-12-14 安徽大学 A kind of monatomic cobalt-based methanol fuel and preparation method thereof
CN109628172A (en) * 2019-01-16 2019-04-16 宁夏拓森环保能源有限公司 A kind of Environment-friendlyfuel fuel and preparation method thereof

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CN1458246A (en) * 2002-05-15 2003-11-26 吉恒 Liquid fuel and its compounding process
WO2011123793A1 (en) * 2010-04-02 2011-10-06 Envirosource, Inc. Systems and methods for processing glycerol
US8062389B2 (en) * 2006-02-08 2011-11-22 The Board Of Regents Of The University Of Texas System Low vapor pressure fuels for use in catalytic burners
CN103160336A (en) * 2013-03-12 2013-06-19 海口腾旭中天科技有限公司 Catering industry waste oil-based biological alcohol oil and preparation method thereof
CN103305289A (en) * 2013-07-02 2013-09-18 陈惠良 High-energy low-carbon synthetic fuel for kiln

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Publication number Priority date Publication date Assignee Title
CN1458246A (en) * 2002-05-15 2003-11-26 吉恒 Liquid fuel and its compounding process
US8062389B2 (en) * 2006-02-08 2011-11-22 The Board Of Regents Of The University Of Texas System Low vapor pressure fuels for use in catalytic burners
WO2011123793A1 (en) * 2010-04-02 2011-10-06 Envirosource, Inc. Systems and methods for processing glycerol
CN103160336A (en) * 2013-03-12 2013-06-19 海口腾旭中天科技有限公司 Catering industry waste oil-based biological alcohol oil and preparation method thereof
CN103305289A (en) * 2013-07-02 2013-09-18 陈惠良 High-energy low-carbon synthetic fuel for kiln

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104357099A (en) * 2014-11-10 2015-02-18 湖北德美科技有限公司 Alcohol-based fuel and preparation method thereof
CN104357099B (en) * 2014-11-10 2016-04-13 湖北德美科技有限公司 A kind of alcohol-group fuel and preparation method thereof
CN105779031A (en) * 2015-06-19 2016-07-20 潍坊桂禾散热片科技有限公司 Liquid fuel
CN105779031B (en) * 2015-06-19 2018-02-27 潍坊桂禾散热片科技有限公司 A kind of liquid fuel
CN107892957A (en) * 2017-12-19 2018-04-10 山东联星能源集团有限公司 A kind of alcohol-based fuel with high heat value and preparation method thereof
CN108359511A (en) * 2018-02-12 2018-08-03 北京欧美中科学技术研究院 A kind of military solid alcohol fuel of environment-friendly type
CN108485727A (en) * 2018-02-12 2018-09-04 北京欧美中科学技术研究院 A kind of typed high-energy liquid fuel in alcohol group
CN108998113A (en) * 2018-06-14 2018-12-14 安徽大学 A kind of monatomic cobalt-based methanol fuel and preparation method thereof
CN108998113B (en) * 2018-06-14 2020-10-27 安徽大学 Monoatomic cobalt-based methanol fuel and preparation method thereof
CN108843969A (en) * 2018-08-17 2018-11-20 熊绪军 A kind of alcohol radical liquid fuel bottle placer
CN108843969B (en) * 2018-08-17 2024-04-19 熊绪军 Alcohol-based liquid fuel filling machine
CN109628172A (en) * 2019-01-16 2019-04-16 宁夏拓森环保能源有限公司 A kind of Environment-friendlyfuel fuel and preparation method thereof

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