CN103709872A - Environment-friendly and energy-saving heating coating and preparation method thereof - Google Patents
Environment-friendly and energy-saving heating coating and preparation method thereof Download PDFInfo
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- CN103709872A CN103709872A CN201410008310.8A CN201410008310A CN103709872A CN 103709872 A CN103709872 A CN 103709872A CN 201410008310 A CN201410008310 A CN 201410008310A CN 103709872 A CN103709872 A CN 103709872A
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Abstract
The invention discloses an environment-friendly and energy-saving heating coating, comprising deionized water, an acrylic emulsion, a TM mixing agent, a wetting agent, a dispersing agent, a defoamer, ultrafine graphite powder, a pH adjuster, and nano micro-beads. The invention also discloses a preparation method of the environment-friendly and energy-saving heating coating. The environment-friendly and energy-saving heating coating disclosed by the invention has excellent light and color retaining properties, is capable of heating and heat-resistant, good in heat-resistant property (used at 50-280 DEG C for a long period of time), weather fastness and wear resistance, and can be widely applied to industrial and civil fields.
Description
Technical field
The present invention relates to a kind of coating, be specifically related to a kind of environmental protection and energy saving exothermic paint and preparation method thereof.
Background technology
China buildings overwhelming majority is the non-energy-saving building of high energy consumption, and during use, the aspects such as heating, air-conditioning, ventilation, hot water service have consumed a large amount of energy to buildings.In order to keep the consumption of interior of building temperature, minimizing air conditioner energy source, tackle mutually building energy conservation requirement, active development development energy-saving material is of great practical significance and long-range social effect.
Meanwhile, energy-saving heating material is also widely used in all kinds of greenhouses, dries institute, storage tank heat.The fields such as steam oven, nichrome wire, electrothermal tube, but existing energy-saving and heat-insulating material under running under rapid heat cycle condition very easily cracking, the requirement that does not still reach many Application Areass.
Summary of the invention
For overcoming above-mentioned technological deficiency, the present invention discloses a kind of environmental protection and energy saving exothermic paint and preparation method thereof.
Environmental protection and energy saving exothermic paint disclosed by the invention, contains ACRYLIC EMULSION, deionized water, TM mixture, wetting agent, dispersion agent, defoamer, Graphite Powder 99, PH conditioning agent, nano microsphere.
By weight percentage, ACRYLIC EMULSION is that 35-45%, deionized water are that 18-30%, TM mixture are that 3-8%, wetting agent are that 1-5%, dispersion agent are that 1-3%, defoamer are that 1-3%, Graphite Powder 99 are that 15-25%, PH conditioning agent are that 1-3%, nano microsphere are 6-10%.Preferably, ACRYLIC EMULSION is 38%, deionized water is 22%, TM mixture is 5%, wetting agent is 3%, dispersion agent is 2%, defoamer is 1%, superfine graphite powder is 20%, PH conditioning agent is 1%, nano microsphere is 8%.
Further, described TM mixture is the mixture of ferric oxide and Manganse Dioxide, and the blending ratio of described ferric oxide and Manganse Dioxide is 1:1.
Described wetting agent be in alkylbenzene or unsaturated polyester siloxanes any one, play and reduce capillary effect; Described dispersion agent be in undersaturated polyacrylic acid sodium salt, amine amide any one, there is deflocculate color development function; Described defoamer is polysiloxane, can eliminate the bubble in material; Any in the ammoniacal liquor that described PH conditioning agent is concentration 28%, concentration 10% potassium hydroxide, described nano microsphere is high-temperature calcination hollow bead, is preferably nano-hollow glass microballon.
The invention also discloses the preparation method of above-mentioned environmental protection and energy saving exothermic paint, by adding TM mixture, Graphite Powder 99 to be ground to particle diameter after deionized water and the mixing of part acrylic acid emulsion, be 15-25 μ m, then add all the other components to carry out paint.
The content of described part emulsion is the 5-15% of coating total amount.
The content of described part emulsion is 10% of coating total amount.
Beneficial effect of the present invention is:
(1) coating of the present invention has excellent guarantor's light unfading, and heat insulation heatproof, has good weathering resistance and wearability; (2) coating of the present invention is of many uses, can be used for Industrial Transport oil-piping, wax storage, kiln, drying plant, and industrial application can replace heat-conducting oil furnace, steam oven, nichrome wire, electrothermal tube etc. to play heat retaining and exothermal effect; Aspect civilian, can be used for metope, ground heating, various heating decorative frescos, cultivation, plantation, nursery, greenhouse etc.; (3) coating brushing easy construction of the present invention, can make mantle, dura mater coating, that coating has is fire-retardant, waterproof, permanent antiseptic, algae removal, the liver moss of going out, super cleaning function, and releasing far infrared 2.5-25UM physiotherapy boils and negative oxygen ion body frequently, health-care warming, changes IAQ (indoor air quality); (4), after coating of the present invention is used, dissipation of heat is even, indoor moist, noiselessness pollutes, without electromagenetic wave radiation, film and use more than 10 years, can life-time service without damaging.
Embodiment
Below by specific embodiment, the present invention is described in detail.
Embodiment 1:
Component proportion: by weight percentage; get ACRYLIC EMULSION and be 38%, deionized water is 22%, TM mixture (mixture of ferric oxide and Manganse Dioxide, blending ratio is 1:1) is 5%, wetting agent (alkylbenzene or unsaturated polyester siloxanes) is 3%, dispersion agent (undersaturated polyacrylic acid sodium salt, amine amide) is 2%, defoamer (polysiloxane) is 2%, Graphite Powder 99 is 20%, PH conditioning agent (ammoniacal liquor of concentration 28%, concentration 10% potassium hydroxide) is 1%, nano-hollow glass microballon is 8%.
Preparation method: add TM mixture, Graphite Powder 99 to be ground to particle diameter after 10% ACRYLIC EMULSION of deionized water and coating total amount is mixed and be 15-25 μ m, then add all the other components to carry out paint.
Embodiment 2:
Component proportion: by weight percentage; get ACRYLIC EMULSION and be 35%, deionized water is 25%, TM mixture (mixture of ferric oxide and Manganse Dioxide, blending ratio is 1:1) is 8%, wetting agent (alkylbenzene or unsaturated polyester siloxanes) is 1%, dispersion agent (undersaturated polyacrylic acid sodium salt, amine amide) is 1%, defoamer (polysiloxane) is 3%, Graphite Powder 99 is 18%, PH conditioning agent (ammoniacal liquor of concentration 28%, concentration 10% potassium hydroxide) is 3%, nano-hollow glass microballon is 6%.
Preparation method: add TM mixture, Graphite Powder 99 to be ground to particle diameter after 15% ACRYLIC EMULSION of deionized water and coating total amount is mixed and be 15-25 μ m, then add all the other components to carry out paint.
Its mass parameter of environmental protection and energy saving exothermic paint of the present invention is as shown in table 1
Table 1
| Project | Technical indicator |
| Under condition in container | Without journey uniform state after piece, stirring |
| Workability | Brush two roads accessible |
| Appearance of film design | Normally |
| Time of drying (surface drying) | ≤2h |
| Alkali resistance (24h) | Without abnormal |
| Low-temperature stability (3 circulations) | Never degenerate |
| Wash-resistant property | >=500 times |
| Coating temp. variation resistant performance | Without abnormal |
| Thermotolerance (110 ℃, 96h) | Unchanged |
| The anti-intestinal bacteria of going out | ＞99.9 |
| The anti-streptococcus aureus of going out | ＞99.6 |
| Surface resistivity | 1.04×10 3Ω |
| Volume resistance | 9.40×10 2Ω |
| Volatile organic compounds (VOC)/(g/L) | 21.1g/L is unchanged |
| Soluble heavy metal (mg/kg) | Lead, cadmium, chromium, mercury, nothing |
| Current consumption | 0.2-0.6kWh/m 2/h |
Environmental protection and energy saving exothermic paint of the present invention is of many uses, can be used for Industrial Transport oil-piping, wax storage, kiln, drying plant.Civilian metope, the ground heating of can be used for, various heating decorative frescos, cultivation, plantation, nursery, greenhouse etc.Coating brushing easy construction of the present invention, can make mantle, dura mater coating, that coating has is fire-retardant, waterproof, permanent antiseptic, algae removal, the liver moss of going out, super cleaning function, and releasing far infrared 2.5-25UM physiotherapy boils and negative oxygen ion body frequently, health-care warming, changes IAQ (indoor air quality).Product is evenly brushed to the place that needs heating.Heating temp is determined (or regulating and controlling with temperature controller) according to brushing thickness.Dissipation of heat is even, indoor moist, noiselessness pollutes, without electromagenetic wave radiation, film and use more than 10 years, can life-time service without damaging.Industrial application can replace heat-conducting oil furnace, steam oven, nichrome wire, electrothermal tube etc.Brushing application method is simple, is brushed to the object plane that will generate heat, and strip copper conductor is pasted at two ends, connects power-supply controller of electric (temperature controller), switches on heatable.
In sum; although the specific embodiment of the present invention have been described in detail the present invention; but persons skilled in the art should be understood that; above-described embodiment is only the description to the preferred embodiments of the present invention; but not limiting the scope of the invention; persons skilled in the art are in the disclosed technical scope of the present invention, and the variation that can expect easily, all within protection scope of the present invention.
Claims (10)
1. an environmental protection and energy saving exothermic paint, is characterized in that: contain ACRYLIC EMULSION, deionized water, TM mixture, wetting agent, dispersion agent, defoamer, Graphite Powder 99, PH conditioning agent, nano microsphere.
2. environmental protection and energy saving exothermic paint as claimed in claim 1, it is characterized in that: by weight percentage, ACRYLIC EMULSION is that 35-45%, deionized water are that 18-30%, TM mixture are that 3-8%, wetting agent are that 1-5%, dispersion agent are that 1-3%, defoamer are that 1-3%, Graphite Powder 99 are that 15-25%, PH conditioning agent are that 1-3%, nano microsphere are 6-10%.
3. environmental protection and energy saving exothermic paint as claimed in claim 2, is characterized in that: ACRYLIC EMULSION is 38%, deionized water is 22%, TM mixture is 5%, wetting agent is 3%, dispersion agent is 2%, defoamer is 1%, Graphite Powder 99 is 20%, PH conditioning agent is 1%, nano microsphere is 8%.
4. environmental protection and energy saving exothermic paint as claimed in claim 1, is characterized in that: described TM mixture is the mixture of ferric oxide and Manganse Dioxide.
5. environmental protection and energy saving exothermic paint as claimed in claim 1, is characterized in that: the blending ratio of described ferric oxide and Manganse Dioxide is 1:1.
6. environmental protection and energy saving exothermic paint as claimed in claim 1, it is characterized in that: described wetting agent be in alkylbenzene or unsaturated polyester siloxanes any one, described dispersion agent be in undersaturated polyacrylic acid sodium salt, amine amide any one, described defoamer is polysiloxane, any in the ammoniacal liquor that described PH conditioning agent is concentration 28%, concentration 10% potassium hydroxide, described nano microsphere is high-temperature calcination hollow bead.
7. environmental protection and energy saving exothermic paint as claimed in claim 1, is characterized in that: described nano microsphere is nano-hollow glass microballon.
8. the preparation method of environmental protection and energy saving exothermic paint as claimed in claim 1, it is characterized in that: by adding TM mixture, Graphite Powder 99 to be ground to particle diameter after deionized water and the mixing of part acrylic acid emulsion, be 15-25 μ m, then add all the other components to carry out paint.
9. the preparation method of environmental protection and energy saving exothermic paint as claimed in claim 8, is characterized in that: the content of described part emulsion is the 5-15% of coating total amount.
10. the preparation method of environmental protection and energy saving exothermic paint as claimed in claim 9, is characterized in that: the content of described part emulsion is 10% of coating total amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410008310.8A CN103709872B (en) | 2014-01-08 | 2014-01-08 | A kind of environment-friendlyand and energy-saving heating coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410008310.8A CN103709872B (en) | 2014-01-08 | 2014-01-08 | A kind of environment-friendlyand and energy-saving heating coating and preparation method thereof |
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| CN103709872A true CN103709872A (en) | 2014-04-09 |
| CN103709872B CN103709872B (en) | 2016-08-17 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111269627A (en) * | 2020-03-06 | 2020-06-12 | 荆门市诺维英新材料科技有限公司 | Energy-saving and environment-friendly heating coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101195725A (en) * | 2007-12-29 | 2008-06-11 | 株洲时代新材料科技股份有限公司 | Heat-insulating energy-saving paint for vehicle and method for producing the same |
| CN101200611A (en) * | 2007-11-30 | 2008-06-18 | 江南大学 | Insulation paint having both radiation heat insulation and obstructing type heat insulation and method for making same |
| CN102850936A (en) * | 2012-08-30 | 2013-01-02 | 青岛保利康新材料有限公司 | Multifunctional polymer coating material |
| CN102850887A (en) * | 2012-08-30 | 2013-01-02 | 青岛保利康新材料有限公司 | High-polymer coating material |
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2014
- 2014-01-08 CN CN201410008310.8A patent/CN103709872B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101200611A (en) * | 2007-11-30 | 2008-06-18 | 江南大学 | Insulation paint having both radiation heat insulation and obstructing type heat insulation and method for making same |
| CN101195725A (en) * | 2007-12-29 | 2008-06-11 | 株洲时代新材料科技股份有限公司 | Heat-insulating energy-saving paint for vehicle and method for producing the same |
| CN102850936A (en) * | 2012-08-30 | 2013-01-02 | 青岛保利康新材料有限公司 | Multifunctional polymer coating material |
| CN102850887A (en) * | 2012-08-30 | 2013-01-02 | 青岛保利康新材料有限公司 | High-polymer coating material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111269627A (en) * | 2020-03-06 | 2020-06-12 | 荆门市诺维英新材料科技有限公司 | Energy-saving and environment-friendly heating coating and preparation method thereof |
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| CN103709872B (en) | 2016-08-17 |
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Effective date of registration: 20160902 Address after: 361111 No. 6 New Bridge Road, Xiangan District, Fujian, Xiamen Patentee after: Xiamen friend Technology Co., Ltd. Address before: Ping Town Longgang District of Shenzhen City, Guangdong province 518117 six Lian Shi al Ling Industrial Park in Shenzhen City Gu Konny Chemical Co. Ltd. Patentee before: Li Zhanyi |