CN103682193B - High capacity lithium ion battery - Google Patents

High capacity lithium ion battery Download PDF

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Publication number
CN103682193B
CN103682193B CN201210337493.9A CN201210337493A CN103682193B CN 103682193 B CN103682193 B CN 103682193B CN 201210337493 A CN201210337493 A CN 201210337493A CN 103682193 B CN103682193 B CN 103682193B
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Prior art keywords
housing
output pole
positive
liquid
battery
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CN201210337493.9A
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CN103682193A (en
Inventor
杨从明
仝志明
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Microvast Holdings Inc
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Microvast Power Systems Huzhou Co Ltd
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Priority to CN201210337493.9A priority Critical patent/CN103682193B/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/116Primary casings; Jackets or wrappings characterised by the material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/116Primary casings; Jackets or wrappings characterised by the material
    • H01M50/124Primary casings; Jackets or wrappings characterised by the material having a layered structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/342Non-re-sealable arrangements
    • H01M50/3425Non-re-sealable arrangements in the form of rupturable membranes or weakened parts, e.g. pierced with the aid of a sharp member
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Secondary Cells (AREA)

Abstract

A kind of high capacity lithium ion battery, it includes the housing of overall liquid-tight envelope, the multiple battery cells being arranged in described housing, is positioned at two collectors, positive output pole and the negative output pole of housing, the both positive and negative polarity of described battery cell is connected with a collector respectively, affiliated positive output pole and negative output pole are electrically connected with a collector respectively, are perfused with the liquid of flame-resistant insulation in described housing.The present invention uses perfusion flame-resistant insulation liquid in the cell housing, multiple battery cells infiltrate in flame-resistant insulation liquid, so that the temperature between battery cell is kept in balance, it is unlikely the internal focus of appearance thus causes thermal runaway, it addition, in this case, even if piercing through the accident of battery, the electrolyte of battery cell is surrounded by flame-resistant insulation liquid after overflowing, it is impossible to ingress of air, will not cause fire accident;Even if the flare having the external world enters into enclosure interior, flame-resistant insulation liquid is after volatilization of being heated, it is also possible to play the effect of fire extinguishing.

Description

High capacity lithium ion battery
[technical field]
The present invention relates to a kind of lithium ion battery, especially, relate to a kind of jumbo lithium ion battery 。
[background technology]
Along with the pollution of minimizing and the environment day by day of petroleum resources is day by day serious, protect environment, energy-saving and emission-reduction Trend the most in the world and trend are become.In this context, in recent years, based on battery Want power source or partial power source electric vehicle (mainly include hybrid electric vehicle, plug-in Hybrid electric vehicle, pure electric vehicle) engender and increasing, the carbon emission amount of electric vehicle It is less than traditional combustion engine automobile, the carbon emission of pure electric vehicle even zero, and there is energy The feature that conversion efficiency is high, this makes people that electric automobile be considered as following replacement diesel locomotive One important selection.
The power of current electric automobile mainly selects lithium ion battery bag, and lithium ion battery bag is by multiple Lithium-ion battery monomer is constituted, carrying out the design of battery bag when, if using relatively low capacity Lithium-ion battery monomer, then the connection between lithium-ion battery monomer is more complicated, BMS(electricity Pond management system) design the most more complicated;And if using the lithium ion battery of larger capacity Monomer, then the connection between lithium-ion battery monomer is more convenient, and the design of BMS system is the most relative Simply.The lithium-ion battery monomer of relatively low capacity mentioned here, is primarily referred to as traditional 1865 The conventional lithium ion battery monomers such as 0 type, 26650 types, they typically store energy less than 10Wh. And high capacity lithium ion battery monomer is primarily referred to as the bigger Soft Roll or the box hat that occur in recent years Rectangular cell monomer, they typically store energy more than 10Wh.
But first existing jumbo lithium-ion battery monomer has the disadvantage that, it stores energy More, once break down, after only needing several even one battery cells just can cause seriously Really, secondly, under conditions of overcharging or excessively putting, high capacity lithium ion battery monomer is easily sent out Raw overheated, and in the case of puncturing, after substantial amounts of electrolyte overflows ingress of air rapidly, High capacity lithium ion battery monomer may even happen that the situations such as blast on fire.
Part producer is had to use the little battery cell that multiple parallel connection is set in a battery container, from And constitute the way of a big battery cell, but this way is easily caused enclosure interior Generate heat uneven between battery cell thus cause thermal runaway.Further, this way equally can not gram Take the explosion issues on fire in the case of above-mentioned puncture.
[summary of the invention]
It is an object of the invention to provide the high capacity lithium ion battery that a kind of safety is high.
For above-mentioned purpose, the technical solution used in the present invention is:
A kind of high capacity lithium ion battery, it includes the housing of overall liquid-tight envelope, is arranged on described housing In multiple battery cells, be positioned at two collectors, positive output pole and the negative output pole of housing , wherein the both positive and negative polarity of battery cell is connected with a collector respectively, described positive output pole It is electrically connected with a collector respectively with negative output pole, in housing, is perfused with flame-resistant insulation liquid , the liquid level of described flame-resistant insulation liquid is higher than the both positive and negative polarity of battery cell and the junction point of collector , the liquid level of described flame-resistant insulation liquid is higher than the both positive and negative polarity of battery cell and the junction point of collector , positive output pole and negative output extremely on be provided with ptc material or fuse.
As preferred technical scheme: be provided with pressure valve on described housing.
As preferred technical scheme: be provided with copper sealing coat between described battery cell.
As preferred technical scheme: be provided with compound insulation layer, institute between described battery cell The compound insulation layer stated is wrapped up in paraffin by copper-clad and is constituted.
As preferred technical scheme: described flame-resistant insulation liquid is silicone oil.
As preferred technical scheme: described flame-resistant insulation liquid is fire resistant oil.
The present invention uses perfusion flame-resistant insulation liquid in the cell housing, and the infiltration of multiple battery cells is in insulation In fire resistant fluid, so that the temperature between battery cell is kept in balance, it is unlikely appearance internal Focus thus cause thermal runaway, it addition, in this case, even if piercing through the thing of battery Therefore, the electrolyte of battery cell is surrounded by flame-resistant insulation liquid after overflowing, it is impossible to ingress of air, Fire accident will not be caused;Even if the flare having the external world enters into enclosure interior, flame-resistant insulation liquid After volatilization of being heated, it is also possible to play the effect of fire extinguishing.So, the high-capacity lithium of the present invention from Sub-battery has the effect of Large Copacity and high safety.It addition, by flame-resistant insulation liquid in housing Liquid level arranges the junction point of the both positive and negative polarity higher than battery cell and collector.Due at junction point It is usually the place that the bigger heating of electric current is bigger, is also the place being prone to accidents, so will The liquid level of flame-resistant insulation liquid is arranged Higher than junction point, further assure that the safety of whole high capacity lithium ion battery.Finally, exist Positive output pole and negative output extremely on be provided with ptc material or fuse, work as high-capacity lithium-ion Battery occurs abnormal, such as, the when of having abnormal High-current output, ptc material can be become by thermal resistance Greatly, thus reaching the purpose of current limliting, fuse then can occur fusing thus turn-off current, more Add the safety improving whole high capacity lithium ion battery.
In one of preferred technical scheme, housing is provided with pressure valve, when high-capacity lithium from The when that sub-cell internal pressure being excessive, release can be carried out by pressure valve, prevent inside Pressure is excessive to set off an explosion.
In one of preferred technical scheme, between described battery cell, it is provided with copper sealing coat. Copper is the excellence conductor of heat, and adding copper sealing coat can be further such that temperature between battery cell Degree is kept in balance, on the other hand, when an accident occurs, such as have hard thing thrust high-capacity lithium from The when of sub-battery, copper sealing coat can stop hard thing so that hard thing is difficult to run through whole great Rong Amount lithium ion battery.So can improve high capacity lithium ion battery further when being punctured Safety.
In one of preferred technical scheme, between described battery cell, it is provided with compound insulation layer , described compound insulation layer is wrapped up in paraffin by copper-clad and is constituted.Paraffin is a kind of phase-change material, is being subject to Can absorb heat during heat and become liquid, use copper-clad to wrap up in paraffin, can have above-mentioned copper sealing coat Advantage, it is also possible to absorb the heating of battery cell further with paraffin liquefaction, so that whole Individual high capacity lithium ion battery is under good temperature conditions and is operated.
[accompanying drawing explanation]
Fig. 1 is the schematic diagram of one embodiment of the invention;
Fig. 2 is the schematic diagram of another embodiment of the present invention;
Fig. 3 is the schematic diagram of another embodiment of the present invention;
Fig. 4 is the schematic diagram of another embodiment of the present invention;
Wherein:
1. housing;2. battery cell;3. collector;4. positive output pole or negative output pole;5. insulation resistance Combustion liquid liquid level;6. the both positive and negative polarity of battery cell and the junction point of collector;7.PTC material;8. molten Disconnected device;9. pressure valve;10. copper sealing coat;11. compound insulation layers;111. compound insulation layer Copper outer layer;The paraffin internal layer of 112. compound insulation layers.
[detailed description of the invention]
Embodiment 1
A kind of high capacity lithium ion battery, it includes the housing 1 of overall liquid-tight envelope, is arranged on described housing Multiple battery cells 2 in 1, it is positioned at two collectors 3, positive output pole and the negative output of housing Pole 4, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated just Output stage and negative output pole 4 are electrically connected with a collector 3 respectively, fill in described housing 1 It is marked with silicone oil.
Embodiment 2
As schematically shown in Figure 1: a kind of high capacity lithium ion battery, it include overall liquid-tight envelope housing 1, Multiple battery list 2 bodies being arranged in described housing 1, two collectors 3 being positioned at housing, just Output stage and negative output pole 4, the both positive and negative polarity of described battery cell 2 respectively with collector 3 phase Connecting, affiliated positive output pole and negative output pole 4 are electrically connected with a collector 3 respectively, It is perfused with dimethicone in described housing 1.The liquid level 5 of described dimethicone is higher than battery The both positive and negative polarity of monomer and the junction point 6 of collector.
Embodiment 3
As schematically shown in Figure 2: a kind of high capacity lithium ion battery, it include overall liquid-tight envelope housing 1, Multiple battery list 2 bodies being arranged in described housing 1, two collectors 3 being positioned at housing, just Output stage and negative output pole 4, the both positive and negative polarity of described battery cell 2 respectively with collector 3 phase Connecting, affiliated positive output pole and negative output pole 4 are electrically connected with a collector 3 respectively, It is perfused with dimethicone in described housing 1.The liquid level 5 of described dimethicone is higher than battery The both positive and negative polarity of monomer and the junction point 6 of collector.
Positive output pole and negative output pole 4 are provided with ptc material 7.
Embodiment 4
A kind of high capacity lithium ion battery, it includes the housing 1 of overall liquid-tight envelope, is arranged on described housing Multiple battery list 2 bodies in 1, it is positioned at two collectors 3, positive output pole and the negative output of housing Pole 4, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated just Output stage and negative output pole 4 are electrically connected with a collector 3 respectively, fill in described housing 1 It is marked with EH fire resistant oil.The liquid level 5 of described EH fire resistant oil is higher than both positive and negative polarity and the collector of battery cell Junction point 6.
Positive output pole and negative output pole 4 are provided with fuse 8.
Embodiment 5
A kind of high capacity lithium ion battery, it includes the housing 1 of overall liquid-tight envelope, is arranged on described housing Multiple battery list 2 bodies in 1, it is positioned at two collectors 3, positive output pole and the negative output of housing Pole 4, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated just Output stage and negative output pole 4 are electrically connected with a collector 3 respectively, fill in described housing 1 It is marked with dimethicone.The liquid level 5 of described dimethicone is higher than both positive and negative polarity and the collection of battery cell The junction point 6 of fluid.
Positive output pole and negative output pole 4 are provided with ptc material 7.
Described housing 1 is provided with pressure valve 9.
Embodiment 6
A kind of high capacity lithium ion battery, it includes the housing 1 of overall liquid-tight envelope, is arranged on described housing Multiple battery list 2 bodies in 1, it is positioned at two collectors 3, positive output pole and the negative output of housing Pole 4, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated just Output stage and negative output pole 4 are electrically connected with a collector 3 respectively, fill in described housing 1 It is marked with dimethicone.The liquid level 5 of described dimethicone is higher than both positive and negative polarity and the collection of battery cell The junction point 6 of fluid.
Positive output pole and negative output pole 4 are provided with fuse 8.
Described housing 1 is provided with pressure valve 9.
Embodiment 7
As schematically shown in Figure 3: a kind of high capacity lithium ion battery, it include overall liquid-tight envelope housing 1, Multiple battery list 2 bodies being arranged in described housing 1, two collectors 3 being positioned at housing, just Output stage and negative output pole 4, the both positive and negative polarity of described battery cell 2 respectively with collector 3 phase Connecting, affiliated positive output pole and negative output pole 4 are electrically connected with a collector 3 respectively, It is perfused with EH fire resistant oil in described housing 1.The liquid level 5 of described EH fire resistant oil is higher than battery cell The junction point 6 of both positive and negative polarity and collector.
Positive output pole and negative output pole 4 are provided with ptc material 7.
Described housing 1 is provided with pressure valve 9.
It is provided with copper sealing coat 10 between described battery cell 2.
Embodiment 8
A kind of high capacity lithium ion battery, it includes the housing 1 of overall liquid-tight envelope, is arranged on described housing Multiple battery list 2 bodies in 1, it is positioned at two collectors 3, positive output pole and the negative output of housing Pole 4, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated just Output stage and negative output pole 4 are electrically connected with a collector 3 respectively, fill in described housing 1 It is marked with dimethicone.The liquid level 5 of described dimethicone is higher than both positive and negative polarity and the collection of battery cell The junction point 6 of fluid.
Positive output pole and negative output pole 4 are provided with fuse 8.
Described housing 1 is provided with pressure valve 9.
It is provided with copper sealing coat 10 between described battery cell 2.
Embodiment 9
As schematically shown in Figure 4: a kind of high capacity lithium ion battery, it include overall liquid-tight envelope housing 1, Multiple battery list 2 bodies being arranged in described housing 1, two collectors 3 being positioned at housing, just Output stage and negative output pole 4, the both positive and negative polarity of described battery cell 2 respectively with collector 3 phase Connecting, affiliated positive output pole and negative output pole 4 are electrically connected with a collector 3 respectively, It is perfused with EH fire resistant oil in described housing 1.The liquid level 5 of described EH fire resistant oil is higher than battery cell The junction point 6 of both positive and negative polarity and collector.
Positive output pole and negative output pole 4 are provided with ptc material 7.
Described housing 1 is provided with pressure valve 9.
Between described battery cell, be provided with compound insulation layer 11, described compound insulation layer 11 by The outer layer 111 that copper is constituted wraps up the internal layer 112 being made up of paraffin and is constituted.
Embodiment 10
A kind of high capacity lithium ion battery, it includes the housing 1 of overall liquid-tight envelope, is arranged on described housing Multiple battery lists 2 in 1 Body, it is positioned at two collectors 3, positive output pole and the negative output pole 4 of housing, described battery The both positive and negative polarity of monomer 2 is connected with a collector 3 respectively, affiliated positive output pole and negative output Pole 4 is electrically connected with a collector 3 respectively, is perfused with dimethicone in described housing 1 .The liquid level 5 of described dimethicone is higher than the both positive and negative polarity of battery cell and the junction point 6 of collector 。
Positive output pole and negative output pole 4 are provided with fuse 8.
Described housing 1 is provided with pressure valve 9.
Between described battery cell, be provided with compound insulation layer 11, described compound insulation layer 11 by The outer layer 111 that copper is constituted wraps up the internal layer 112 being made up of paraffin and is constituted.
Protection scope of the present invention is not limited in above-described embodiment, all is done under spirit of the present invention Change and change, all should fall within the scope of the present application.

Claims (3)

1. a high capacity lithium ion battery, it is characterised in that: it includes the housing of overall liquid-tight envelope, is arranged on Multiple battery cells in described housing, it is positioned at two collectors, positive output pole and the negative output pole of housing, The both positive and negative polarity of described battery cell is connected with a collector respectively, described positive output pole and negative output pole It is electrically connected with a collector respectively, in described housing, is perfused with flame-resistant insulation liquid, described insulation resistance The liquid level of the combustion liquid both positive and negative polarity higher than battery cell and the junction point of collector, extremely go up in positive output pole and negative output It is provided with ptc material or fuse;Compound insulation layer, institute it is provided with between described battery cell The compound insulation layer stated is wrapped up in paraffin by copper-clad and is constituted.
2. high capacity lithium ion battery as claimed in claim 1, it is characterised in that: set on described housing It is equipped with pressure valve.
3. high capacity lithium ion battery as claimed in claim 1, it is characterised in that: described flame-resistant insulation liquid For any one in silicone oil or fire resistant oil.
CN201210337493.9A 2012-09-13 2012-09-13 High capacity lithium ion battery Active CN103682193B (en)

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CN103682193B true CN103682193B (en) 2016-08-10

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105470442A (en) * 2015-11-13 2016-04-06 王晓秋 Lithium battery pack module with high safety design
CN108550720A (en) * 2018-03-16 2018-09-18 深圳市前海星火同为科技有限公司 A kind of navigation anticorrosion large-capacity battery and manufacturing method
CN109524586A (en) * 2018-11-19 2019-03-26 颍上北方动力新能源有限公司 Compact battery mould group protecting box
CN110609235A (en) * 2019-10-14 2019-12-24 中国民用航空飞行学院 Lithium battery thermal safety monitoring system based on optical fiber detection technology
CN116404117B (en) * 2023-06-07 2023-08-11 四川富临新能源科技有限公司 Method for improving capacity of sodium ion positive electrode material

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CN102157716A (en) * 2011-03-18 2011-08-17 南京双登科技发展研究院有限公司 Battery combination device
CN102544406A (en) * 2012-02-15 2012-07-04 中国电力科学研究院 Flexibly-packaged battery module group
CN202817051U (en) * 2012-09-13 2013-03-20 微宏动力***(湖州)有限公司 High-capacity lithium ion battery

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CN101325269A (en) * 2007-06-13 2008-12-17 深圳市比克电池有限公司 Lithium ion battery
CN102157716A (en) * 2011-03-18 2011-08-17 南京双登科技发展研究院有限公司 Battery combination device
CN102544406A (en) * 2012-02-15 2012-07-04 中国电力科学研究院 Flexibly-packaged battery module group
CN202817051U (en) * 2012-09-13 2013-03-20 微宏动力***(湖州)有限公司 High-capacity lithium ion battery

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Address after: 313000 Huzhou economic and Technological Development Zone, Zhejiang, Hung Fung Road, No. 2198

Patentee after: MICROVAST POWER SYSTEMS Co.,Ltd.

Address before: 313000 Zhejiang Province, Huzhou City Road No. 1555 sunny Industrial Science and Technology Park 1

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