CN1036746A - Produce the novel process of white carbon black with silica sand - Google Patents
Produce the novel process of white carbon black with silica sand Download PDFInfo
- Publication number
- CN1036746A CN1036746A CN 89105875 CN89105875A CN1036746A CN 1036746 A CN1036746 A CN 1036746A CN 89105875 CN89105875 CN 89105875 CN 89105875 A CN89105875 A CN 89105875A CN 1036746 A CN1036746 A CN 1036746A
- Authority
- CN
- China
- Prior art keywords
- carbon black
- white carbon
- silica sand
- novel process
- ageing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/186—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof from or via fluosilicic acid or salts thereof by a wet process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicon Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The present invention is a kind of novel process of producing white carbon black with silica sand, comprise reaction, in and ageing, filtration washing, drying and crushing and NH
4F and NH
3Reclaim the circulation plurality of units.The present invention removes the firstling production that feeds intake first need add a certain amount of NH
4F and NH
3Outward, continue after batch process in only need outside system, to replenish the NH of minute quantity
4F and NH
3Technology raw materials consumption of the present invention and less energy consumption, low in the pollution of the environment, cost is low, good product quality.After realizing industrialization, it might partly or entirely replace traditional white carbon black production technology.
Description
The invention belongs to the oxide compound of silicon, specifically produce the novel process of white carbon black with silica sand.
White carbon black has another name called light silicon dioxide, is the good strengthening agent of rubber, and its reinforcing property is only second to carbon black; Also as lubricant, insulating material, and the stopping composition or the white pigment of plastics, paper, paint, textiles.The traditional method that with the silica sand is the raw material production white carbon black is that silica sand, soda ash are placed reverberatory furnace high-temperature fusion system water glass, make rare sodium silicate solution with water dissolution then, carry out maturation process with mineral acid again, after washing filtering, drying and crushing and the white carbon black product.This traditional technology not only expends a large amount of industrial chemicals, and the energy consumption height, the production cost height.
The objective of the invention is to create a kind of is raw material with the silica sand, few other industrial chemicals that consume in the production process, and the novel process of the obvious production white carbon black that reduces of the above-mentioned traditional technology of energy loss-rate.
The present invention is achieved in that
Will be through deironing deliming pre-treatment, SiO
2Content is not less than 98%(weight, and is as follows) silica sand and solid NH
2F(100%) press NH
4F and SiO
2Weight ratio 1: the 0.30-0.48 thorough mixing adds in the reactor, reacts at least 40 minutes in 100-200 ℃ of temperature range, generates (NH
4)
2SiF
6Solid, NH simultaneously overflows
3And water vapor; In reactor, restrain (NH then with 170-190
4)
2SiF
6The NH that adds 25-35%
41 liter of heating of F solution makes (NH
4)
2SiF
6Solid dissolves fully, filtered while hot.Reaction equation in reaction workshop section is as follows:
Filter residue (unreacted silica sand) is stayed in the reactor, with ageing workshop section, added the ammoniacal liquor of 25-28% rapidly under 60-80 ℃ of agitation condition during gained filtrate is introduced, the volumetric ratio of filtrate and ammoniacal liquor is 1: 0.35-0.45; Naturally cool to normal temperature then, ageing is 3 hours at least.In and the reaction equation of ageing workshop section as follows:
Subsequent filtration, filtrate (NH
4F solution) be collected in a NH
4In the F solution storage trough, filter Pie successively uses the NH of 30-3% different concns again
4The F solution washing is washed till NH among the filter Pie
4F content is not more than 5%, and each washings is collected in the NH of respective concentration respectively
4In the F solution storage trough, produce (NH in the solubilizing reaction still for following batch
4)
2SiF
6Select for use when solid and washing filter Pie; Further wash filter Pie with clear water then and contain F to wash water
-Below 0.005%, can think that filter Pie washing is qualified; Contain F
-Recycle in that the wash water more than 0.03% is recyclable.Washing qualified filter Pie is the wet product of white carbon black, send drying and crushing workshop section to be dried to water content 5-7% at 120-150 ℃, and final powder is broken to and promptly gets the white carbon black product below 200 orders.With a NH
4Solution in the F solution storage trough (concentration is more than 35%) is sent into thickener, is concentrated into 20-22Be °, crystallisation by cooling, Separation and Recovery solid NH
4F returns reactor and does following batch of production cycle use.NH
4The NH that F thickener and reactor are overflowed
3All send the ammonia recovery tower to make ammoniacal liquor (NH
3〉=30%), offer in and ageing workshop section recycle.
Accompanying drawing is produced the block diagram of white carbon black novel process with silica sand for the present invention.
The white carbon that makes by technique of the present invention is the transparent white carbon of high reinforcement, and the quality index that reaches is as follows:
SiO
2% ≥94
Moisture content %≤8
Burning decrement %≤7
Specific surface area (volumetry) m/g 〉=300
PH value 7.0-7.5
Look specific volume (centrifuging) g/ml≤0.22
Refractive index 4.5-5.6
More than every index all meet or exceed white carbon black quality index with produced in conventional processes.The present invention is owing to reclaimed the NH in the production process
3NH
4F and NH
3And recycle in system, therefore, remove the firstling production that feeds intake first and need add a certain amount of NH
4F and NH
3Outside the industrial chemicals, continue after batch process in only need outside system, to replenish the NH of minute quantity
4F and NH
3Technology of the present invention is compared with the traditional method that with silica sand and soda ash is the raw material production white carbon black, to produce 1000 tons of white carbon blacks per year, adopts the technology of the present invention 500-1000 unit/ton that can reduce production costs.The present invention have raw material consumption and less energy consumption, low in the pollution of the environment, cost is low, the characteristics of good product quality.Can expect that after novel process of the present invention realized industrialization, it might partly or entirely replace traditional white carbon black production technology, makes white carbon black production enter a new stage.
Claims (5)
1, a kind of novel process of producing white carbon black with silica sand, comprise reaction, in and ageing, filtration washing, drying and crushing and NH
4F and NH
3Reclaim the circulation plurality of units.It is characterized in that reaction is with silica sand and solid NH
4F presses NH
4F and SiO
2Weight ratio 1: the 0.30-0.48 thorough mixing adds in the reactor, reacts at least 40 minutes in 100-200 ℃ of temperature range.
2, according to the described novel process of producing white carbon black of claim 1, it is characterized in that (the NH that above-mentioned reaction generates with silica sand
4)
2SiF
6Solid is with 170-190 gram (NH in reactor
4)
2SiF
6The NH that adds 25-35%
41 liter of heating for dissolving of F solution and filtered while hot are in the introducing and ageing workshop section.
3, according to claim 1 and 2 described novel procesies of producing white carbon black, it is characterized in that said filtration washing is at a NH with filtrate collection with silica sand
4In the F solution storage trough, filter Pie successively uses the NH of 30-3% different concns again
4The F solution washing is washed till NH among the filter Pie
4F content is not more than 5%, and each washings is collected in the NH of respective concentration respectively
4In the F solution storage trough; Further with clear water washing filter Pie, to wash water, contain F then
-Qualified below 0.005% for filter Pie washing.
4, according to the described novel process of producing white carbon black of claim 1, said NH with silica sand
4F and NH
3Reclaiming circulation is with a NH
4Solution in the F solution storage trough is through condensing crystal, Separation and Recovery solid NH
4F returns reactor and does following batch of production cycle use; With NH
4The solution of the respective concentration of collecting in the F solution storage trough offers down (NH in batch production solubilizing reaction still
4)
2SiF
6Select for use when solid and washing filter Pie, with reactor and NH
4The NH that the F thickener is overflowed
3Reclaim system ammoniacal liquor, recycle with ageing workshop section in offering.
5, according to the described novel process of producing white carbon black of claim 1 with silica sand, it is characterized in that said in and ageing be the ammoniacal liquor that under 60-80 ℃ of agitation condition, adds 25-28% rapidly, the volumetric ratio of filtrate and ammoniacal liquor is 1: 0.35-0.45; Naturally cool to normal temperature then, ageing is 3 hours at least.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 89105875 CN1016154B (en) | 1989-03-13 | 1989-03-13 | Process of producing white carbon using siliceous sand |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 89105875 CN1016154B (en) | 1989-03-13 | 1989-03-13 | Process of producing white carbon using siliceous sand |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1036746A true CN1036746A (en) | 1989-11-01 |
CN1016154B CN1016154B (en) | 1992-04-08 |
Family
ID=4856509
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 89105875 Expired CN1016154B (en) | 1989-03-13 | 1989-03-13 | Process of producing white carbon using siliceous sand |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1016154B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006131066A1 (en) * | 2005-06-08 | 2006-12-14 | Degussa Wellink Silica (Nanping) Co. Ltd. | A process for producing silica and sodium sulfite with sodium sulfate |
CN102701219A (en) * | 2012-07-11 | 2012-10-03 | 郭雨 | High-pressure microwave digested quartz sand and method for preparing nano-amorphous silicon oxide |
CN108996510A (en) * | 2018-06-25 | 2018-12-14 | 确成硅化学股份有限公司 | The preparation method of dustless easy dispersed silicon dioxide |
-
1989
- 1989-03-13 CN CN 89105875 patent/CN1016154B/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006131066A1 (en) * | 2005-06-08 | 2006-12-14 | Degussa Wellink Silica (Nanping) Co. Ltd. | A process for producing silica and sodium sulfite with sodium sulfate |
CN102701219A (en) * | 2012-07-11 | 2012-10-03 | 郭雨 | High-pressure microwave digested quartz sand and method for preparing nano-amorphous silicon oxide |
CN108996510A (en) * | 2018-06-25 | 2018-12-14 | 确成硅化学股份有限公司 | The preparation method of dustless easy dispersed silicon dioxide |
Also Published As
Publication number | Publication date |
---|---|
CN1016154B (en) | 1992-04-08 |
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