CN103666836A - Novel special antibacterial cleaning agent for children toys - Google Patents
Novel special antibacterial cleaning agent for children toys Download PDFInfo
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- CN103666836A CN103666836A CN201210354299.1A CN201210354299A CN103666836A CN 103666836 A CN103666836 A CN 103666836A CN 201210354299 A CN201210354299 A CN 201210354299A CN 103666836 A CN103666836 A CN 103666836A
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Abstract
The invention relates to a novel special antibacterial cleaning agent for children toys. The novel special antibacterial cleaning agent for children toys provided by the invention has the following advantages that (1) the detergency is strong, the sterilization rate is high, and the novel special antibacterial cleaning agent is suitable for sterilizing and cleaning various toys and particularly has efficient decontamination, sterilization and mite removal effects on stuffed toys; (2) the novel special antibacterial cleaning agent is detected to be qualified in an animal toxicity test and generates no strong stimulation on infants; (3) the efficiency is high, the concentration is low, the stability is good, and a sterilization target is achieved while decontaminating, thereby saving resources and reducing the cost; and (4) the novel special antibacterial cleaning agent is convenient to use and can be used for sterilizing and cleaning toys in households and nurseries.
Description
technical fieldthe present invention relates to the special-purpose antibacterial cleanser of a kind of New children toy, its effective constituent is algal polysaccharide sulfate, brown alga oligose, brown algae polyphenols and anhydrous sorbitol mono fatty acid ester Soxylat A 25-7 quaternary ammonium salt, ethoxylated dodecyl alcohol, tween-80, AMONYL 380LC, through special process, is prepared from.Be mainly used in various toys for children clean and antibacterial of family or Kindergartens.Toy is the directly frequent contactant of baby, 6 years old following baby has the time of nearly 1.5 ten thousand hours to spend together with toy according to investigations, and the bite phenomenon of toy of baby's ubiquity, resistibility is more weak in addition, is easy to infect the pathogenic bacterium that carry on toy surface.According to scientist, measure, the toy bacterium colony of playing one day can reach 200-2000, especially down toy, that large people like best the toy of buying to baby, bacterium colony number is the highest, can detect the microorganisms such as flu bacterial debris, intestinal bacteria, hepatitis B virus on 70% toy.More seriously in Kindergartens, toy is all that all children share together, and their hygiene consciousness is very low, is very easy to cause the organizational communication of the transmissible diseases such as hand foot mouth disease.Can see thus, the cleaning and disinfection of toy for children is very important, is to guarantee the healthy indispensable step of infant.The present invention be just to provide a kind of can either clean and can sterilize, antibacterial toy for children scavenger specially.
background technologyon market, existing baby toy Special sterilizing liquid is very many, can be for various plastics, wooden, down toy disinfection.But the function of thimerosal differs, have the strong oxidation class sterilizing agent of the microorganism that can thoroughly kill toy surface, but this type of sterilizing agent is also very large to toy superficial injury, easily causes decolouring, breakage; The thimerosal of pure Chinese herbal medicine formula that in addition can be comprehensively antibacterial, but not obvious for the more intense transmissible disease effect of burst.A little less than infant's skin, mucous membrane are all highly brittle, the thimerosal that corrodibility is stronger also can be stronger to infant's stimulation, and many thimerosals can not be mutually composite with tensio-active agent, this just causes the cleaning and disinfection more complicated of toy, to first clean the decontamination degerming of sterilizing again, not only waste the damage that resource also causes toy.Therefore the biotype thimerosal that contains bioactive marine microalgae essence can be compatible with tensio-active agent, and the antibacterial cleanser being re-dubbed just becomes the first-selection of baby toy sterilization.The object of the present invention is to provide a kind of containing bioactive toy cleaning and sterilizing agent, easy to use, efficient sterilizing, decontamination and sterilization are synchronously completed, and be suitable for the use of the toy of various materials.
summary of the inventionmain points of the present invention are to select suitable high-effective cleansing tensio-active agent, mutually composite with bioactive marine natural product, the special-purpose antibacterial cleanser of a kind of New children toy forming through emulsification, fusion reaction.This antibacterial cleanser viscosity is low, easy cleaning, is suitable for the antibiotic cleaning of the toy of various materials.
The formula following (component and weight percent % thereof) that the present invention selects: algal polysaccharide sulfate 5.0-8.0, brown alga oligose 4.5-6.0, brown algae polyphenols 6.0-8.0, anhydrous sorbitol mono fatty acid ester Soxylat A 25-7 quaternary ammonium salt 8.0-12.0, ethoxylated dodecyl alcohol 12.0-14.0, tween-80 5.0-7.0, AMONYL 380LC 3.0-5.0, purified water adds to 100.
Algal polysaccharide sulfate is the class sulfated polysaccharides extracting from brown alga, mainly by algal polysaccharide and sulfate, formed, (1-2) or the α-L-fucose-4-sulfuric ester (1-3) connecting of height 3-collateralization, there is antibacterial and antiviral effect, bacteria cell wall is had to selective permeability, thus the growth of anti-bacteria, breeding.Brown alga oligose is mainly the oligosaccharide kind material after extract from go back sea-tangle purified, can suppress the growth of intestinal bacteria, streptococcus aureus in vitro, because it can form thin film at bacterium surface, hinder the eupnea of bacterium, suppress its death, thereby stop the propagation of bacterium.Brown algae polyphenols is also the bioactive ingredients extracting from ocean brown alga and sea-tangle, and gram-positive microorganism and Gram-negative bacteria are had to restraining effect; And actives composition is very high, can increase the usefulness of washing decontamination.
Ethoxylated dodecyl alcohol belongs to nonionogenic tenside, has the functions such as good washing, emulsification, dispersion, wetting, solubilising, and easily rinsing, and detersive power is excellent; Be in tensio-active agent to one of minimum kind of skin irritation, be suitable for disappearing, washing of toy for children, can not stimulate infant's skin.And it can with various surfactant compounds, reduce their pungency, improve the performance of product.And anhydrous sorbitol mono fatty acid ester Soxylat A 25-7 quaternary ammonium salt belongs to cats product, there is the efficient fungistatic effect of cats product, make washing composition itself just in sterile state; And it has the high-effective cleansing effect of tensio-active agent, its contained group material, can reduce the electric density of surface active agent ion, make the cationic and anionic surfactant can complete miscibility and do not produce precipitation, make negative and positive mixture obtain good application, thereby the various materials of this product are better merged, performance special efficacy separately.Tween-80 also belongs to nonionic surface active agent, is good emulsion adjuvant in, can increase the emulsifying effect of various material compositions, thereby it is low to reach content, the special efficacy that effect is high.AMONYL 380LC is a kind of zwitterionics, all has good stability under acidity and alkaline condition, can with yin, yang ion and nonionogenic tenside use, its compatibility is good; And pungency is little, soluble in water, strong detergency, has good bactericidal properties, thickening property, flexibility, static resistance, anti-hard water, can significantly improve softness, conditioning and the low-temperature stability of this product; Its bactericidal property is superior, can kill the various pathogenic bacterium in toy surface.
The preparation method of product of the present invention is:
(1) respectively finished product algal polysaccharide sulfate, brown alga oligose, brown algae polyphenols are mixed in the aqueous solution by the proportioning of 1:2, stir and be transparence;
(2) to the purified water of note 1/2 in emulsion tank, then ethoxylated dodecyl alcohol and AMONYL 380LC are joined in emulsion tank respectively slowly, be heated to 40 ℃, emulsification is to transparence;
(3) respectively the algal polysaccharide sulfate being proportionally stirred, brown alga oligose, brown algae polyphenols are joined in emulsion tank slowly, stir;
(4) by proportioning, water sorbyl alcohol mono fatty acid ester Soxylat A 25-7 quaternary ammonium salt is joined in emulsion tank and carries out adding other 1/2 purified water after emulsion reaction 30min, then proportionally add tween-80, be heated to 48 ℃, stir 10 minutes;
(5) cooling 24 hours, to this product to transparent colloid shape, streamline packing.
The present invention has the following advantages: (1) decontamination row is strong, sterilizing rate is high, is applicable to the antibacterial and clean of various toys, especially to down toy there is efficient decontamination, sterilization, except the effect of mite; (2) qualified to animal toxicology experiment detection, to infant, can not produce strong impulse; (3) efficiency is high, concentration is low, good stability, reaches the object of sterilization in decontamination, economizes on resources, reduces costs; (4) easy to use, the toy that can be used for family and Kindergartens is antibacterial, clean.
embodimentbelow in conjunction with embodiment, the present invention is described in further detail:
According to following table institute column data (weight percent %) and affiliated step thereof, be configured:
Formula one:
Algal polysaccharide sulfate 5.0-8.0, brown alga oligose 4.5-6.0, brown algae polyphenols 6.0-8.0, anhydrous sorbitol mono fatty acid ester Soxylat A 25-7 quaternary ammonium salt 8.0-12.0, ethoxylated dodecyl alcohol 12.0-14.0, tween-80 5.0-7.0, AMONYL 380LC 3.0-5.0, purified water adds to 100.
Formula two:
Algal polysaccharide sulfate 5.0-6.5, brown alga oligose 4.5-5.0, brown algae polyphenols 6.0-7.0, anhydrous sorbitol mono fatty acid ester Soxylat A 25-7 quaternary ammonium salt 8.0-10.0, ethoxylated dodecyl alcohol 12.0-13.0, tween-80 5.0-6.0, AMONYL 380LC 3.0-4.0, purified water adds to 100.
Formula three:
Algal polysaccharide sulfate 6.5-8.0, brown alga oligose 5.0-6.0, brown algae polyphenols 7.0-8.0, anhydrous sorbitol mono fatty acid ester Soxylat A 25-7 quaternary ammonium salt 10.0-12.0, ethoxylated dodecyl alcohol 13.0-14.0, tween-80 6.0-7.0, AMONYL 380LC 4.0-5.0, purified water adds to 100.
Claims (2)
1. the present invention relates to the special-purpose antibacterial cleanser of a kind of New children toy, it is characterized in that thering is following formula (component and weight percent % thereof): algal polysaccharide sulfate 5.0-8.0, brown alga oligose 4.5-6.0, brown algae polyphenols 6.0-8.0, anhydrous sorbitol mono fatty acid ester Soxylat A 25-7 quaternary ammonium salt 8.0-12.0, ethoxylated dodecyl alcohol 12.0-14.0, tween-80 5.0-7.0, AMONYL 380LC 3.0-5.0, purified water adds to 100.
2. the special-purpose antibacterial cleanser of New children toy described in claim 1, is characterized in that having following step:
(1) respectively finished product algal polysaccharide sulfate, brown alga oligose, brown algae polyphenols are mixed in the aqueous solution by the proportioning of 1:2, stir and be transparence;
(2) to the purified water of note 1/2 in emulsion tank, then ethoxylated dodecyl alcohol and AMONYL 380LC are joined in emulsion tank respectively slowly, be heated to 40 ℃, emulsification is to transparence;
(3) respectively the algal polysaccharide sulfate being proportionally stirred, brown alga oligose, brown algae polyphenols are joined in emulsion tank slowly, stir;
(4) by proportioning, water sorbyl alcohol mono fatty acid ester Soxylat A 25-7 quaternary ammonium salt is joined in emulsion tank and carries out adding other 1/2 purified water after emulsion reaction 30min, then proportionally add tween-80, be heated to 48 ℃, stir 10 minutes;
(5) cooling 24 hours, to this product to transparent colloid shape, streamline packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210354299.1A CN103666836A (en) | 2012-09-21 | 2012-09-21 | Novel special antibacterial cleaning agent for children toys |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210354299.1A CN103666836A (en) | 2012-09-21 | 2012-09-21 | Novel special antibacterial cleaning agent for children toys |
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| CN103666836A true CN103666836A (en) | 2014-03-26 |
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| CN201210354299.1A Pending CN103666836A (en) | 2012-09-21 | 2012-09-21 | Novel special antibacterial cleaning agent for children toys |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109456853A (en) * | 2018-10-23 | 2019-03-12 | 华东理工大学 | Inhibit the cleaning agent and the preparation method and application thereof of Cronobacter sakazakii biofilm |
| CN110655993A (en) * | 2018-06-29 | 2020-01-07 | 3M创新有限公司 | Detergent composition having long-term antibacterial properties |
| CN110951548A (en) * | 2019-12-27 | 2020-04-03 | 佛山科学技术学院 | Washing-free cleaning spray for infant toys |
| CN111450298A (en) * | 2020-04-26 | 2020-07-28 | 青岛明月海藻生物健康科技集团有限公司 | Marine brown algae oligosaccharide herbal atomizing agent and preparation method thereof |
-
2012
- 2012-09-21 CN CN201210354299.1A patent/CN103666836A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110655993A (en) * | 2018-06-29 | 2020-01-07 | 3M创新有限公司 | Detergent composition having long-term antibacterial properties |
| CN109456853A (en) * | 2018-10-23 | 2019-03-12 | 华东理工大学 | Inhibit the cleaning agent and the preparation method and application thereof of Cronobacter sakazakii biofilm |
| CN110951548A (en) * | 2019-12-27 | 2020-04-03 | 佛山科学技术学院 | Washing-free cleaning spray for infant toys |
| CN111450298A (en) * | 2020-04-26 | 2020-07-28 | 青岛明月海藻生物健康科技集团有限公司 | Marine brown algae oligosaccharide herbal atomizing agent and preparation method thereof |
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Application publication date: 20140326 |