CN103666403A - Vehicle engine cooling liquid - Google Patents

Vehicle engine cooling liquid Download PDF

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Publication number
CN103666403A
CN103666403A CN201310633309.XA CN201310633309A CN103666403A CN 103666403 A CN103666403 A CN 103666403A CN 201310633309 A CN201310633309 A CN 201310633309A CN 103666403 A CN103666403 A CN 103666403A
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China
Prior art keywords
percent
cooling liquid
engine cooling
vehicle engine
automobile engine
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Pending
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CN201310633309.XA
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Chinese (zh)
Inventor
韩军英
王强
王黎明
蒋威
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QINGDAO COPTON TECHNOLOGY Co Ltd
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QINGDAO COPTON TECHNOLOGY Co Ltd
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Priority to CN201310633309.XA priority Critical patent/CN103666403A/en
Publication of CN103666403A publication Critical patent/CN103666403A/en
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Abstract

The invention relates to the technical field of a cooling liquid and particularly relates to a vehicle engine cooling liquid. An additive composition consists of the following components in percentage by mass: 30 to 60 percent of glycol, 0.15 to 0.3 percent of benzotriazole, 0.05 to 0.1 percent of sodium benzoate, 0.5 to 1.5 percent of sebacic acid, 0.1 to 1.0 percent of azelaic acid, 0.5 to 1.0 percent of sodium metasilicate, 0.2 to 0.5 percent of a silicate stabilizer, 0.001 to 0.01 percent of an antifoaming agent, 0.05 to 0.8 percent of potassium hydroxide, 0.002 to 0.006 percent of dye and the balance of deionized water. The vehicle engine cooling liquid adopts a novel mixed formula which uses organic substances as the main materials and uses inorganic substances as the auxiliary materials, has a good anticorrosive effect and a stable performance, has no precipitates, does not comprise substances which pollute the environment and are harmful for human bodies, such as amine substances, nitrite, phosphate and the like, is low in cost, can be widely applied to a vehicle engine cooling system and is suitable to be used in various areas.

Description

A kind of automobile engine cooling liquid
Technical field
The present invention relates to cooling fluid technical field, particularly a kind of automobile engine cooling liquid.
Background technology
Engine-cooling system has water-cooled and air-cooled two kinds of types of cooling, and automobile generally adopts cooling by water.Automobile engine cooling liquid is the heat-eliminating medium of car water engine, is to make the requisite integral part of the normal operation of engine.There is the functions such as cooling, protection against corrosion, antiscale be antifreeze.
In recent years, along with the development of automobile technology and material, for reducing automotive dead weight, energy-saving and emission-reduction, the use of aluminum metal parts is more and more extensive, as aluminium alloy heat radiator, cylinder cap, water pump etc.Therefore the protection for engine aluminum alloy seems particularly important.
Meanwhile, people start pay attention to day by day environmental protection, for there being the material that environmental pollution or human body are harmful, as amine substance, nitrite, phosphoric acid salt etc. will progressively be eliminated.The use of conventional inorganic type cooling fluid can be restricted.At present, full organic engine deicing fluid is less, and because production cost is higher, is difficult to be widely used.
Summary of the invention
The present invention is directed to deficiency of the prior art, a kind of automobile engine cooling liquid that organic acid and inorganic inhibitor are used in conjunction with is provided.
Technical scheme of the present invention is:
An automobile engine cooling liquid, described compositions of additives forms according to following quality per distribution ratio: ethylene glycol 30-60%, benzotriazole 0.15-0.3%, Sodium Benzoate 0.05-0.1%, sebacic acid 0.5-1.5%, nonane diacid 0.1-1.0%, Starso 0.5-1.0%, silicate stabilizers 0.2-0.5%, defoamer 0.001-0.01%, potassium hydroxide 0.05-0.8%, dyestuff 0.002-0.006%, deionized water are surplus.
Preferably, described silicate stabilizers is organo-siloxane compounds.
Preferably, described silicate stabilizers is γ-(sodium sulfonate) propyl-siloxane.
Preferably, described defoamer is methyl-silicone oil or methacrylic ester.
Beneficial effect of the present invention:
(1) automobile engine cooling liquid of the present invention adopts and take organism as main, and inorganics is auxiliary novel mixed type formula, can reach long-acting object.
(2) favorable anti-corrosion effect of the present invention, stable performance, without precipitation.
(3) the present invention is containing the environmental pollutions such as amine substance, nitrite, phosphoric acid salt, material that human body is harmful.
(4) cost of the present invention is low, can be widely used in car engine cooling system, is applicable to each area and uses.
Embodiment
In order to understand better the present invention, by following examples, be described further:
Deicing fluid of the present invention is 3 trades mark such as NB/SH/T0521-2010 standard-No. 25 ,-No. 35 ,-No. 40, can be applicable to envrionment temperature and be the low temp area of-20 ℃~-40 ℃.
Embodiment 1
An automobile engine cooling liquid, described compositions of additives forms according to following quality per distribution ratio,
For-No. 25 deicing fluid:
Ethylene glycol 42%, benzotriazole 0.15%, Sodium Benzoate 0.05%, sebacic acid 0.5%, nonane diacid 0.1%, Starso 0.5%, γ-(sodium sulfonate) propyl-siloxane 0.2%, defoamer 0.001%, potassium hydroxide 0.05%, dyestuff 0.002%, deionized water 56.447%.
Preparation method:
1. get suitable quantity of water, first add Starso and dissolve, after add silicate stabilizers and stir, after dissolving, add Sodium Benzoate, stir, standby after dissolving;
2. by formula, get each raw material, first ethylene glycol added to reactor, after add sebacic acid, nonane diacid and benzotriazole, after stirring, slowly add the solution of step 1, stir; After finally adding other raw materials to stir, make cooling fluid.
By NB/SH/T0521-2010 standard, carry out glassware corrosion test, result is as following table:
Figure BDA0000428243650000021
Embodiment 2
An automobile engine cooling liquid, described compositions of additives forms according to following quality per distribution ratio, is-No. 35:
Ethylene glycol 50%, benzotriazole 0.2%, Sodium Benzoate 0.06%, sebacic acid 0.8%, nonane diacid 0.4%, Starso 0.7%, γ-(sodium sulfonate) propyl-siloxane 0.4%, defoamer 0.005%, potassium hydroxide 0.1%, dyestuff 0.002%, deionized water 47.333%.
Preparation method:
1. get suitable quantity of water, first add Starso and dissolve, after add silicate stabilizers and stir, after dissolving, add Sodium Benzoate, stir, standby after dissolving;
2. by formula, get each raw material, first ethylene glycol added to reactor, after add sebacic acid, nonane diacid and benzotriazole, after stirring, slowly add the solution of step 1, stir; After finally adding other raw materials to stir, make cooling fluid.
By NB/SH/T0521-2010 standard, carry out glassware corrosion test, result is as following table:
Figure BDA0000428243650000031
Embodiment 3
An automobile engine cooling liquid, described compositions of additives forms according to following quality per distribution ratio, is-No. 40:
Figure BDA0000428243650000032
Figure BDA0000428243650000041
By NB/SH/T0521-2010 standard, carry out glassware corrosion test, result is as following table:
Figure BDA0000428243650000042

Claims (4)

1. an automobile engine cooling liquid, it is characterized in that, described compositions of additives forms according to following quality per distribution ratio: ethylene glycol 30-60%, benzotriazole 0.15-0.3%, Sodium Benzoate 0.05-0.1%, sebacic acid 0.5-1.5%, nonane diacid 0.1-1.0%, Starso 0.5-1.0%, silicate stabilizers 0.2-0.5%, defoamer 0.001-0.01%, potassium hydroxide 0.05-0.8%, dyestuff 0.002-0.006%, deionized water are surplus.
2. automobile engine cooling liquid according to claim 1, is characterized in that, described silicate stabilizers is organo-siloxane compounds.
3. automobile engine cooling liquid according to claim 2, is characterized in that, described silicate stabilizers is γ-(sodium sulfonate) propyl-siloxane.
4. according to power, require the automobile engine cooling liquid described in 1, it is characterized in that, described defoamer is methyl-silicone oil or methacrylic ester.
CN201310633309.XA 2013-12-02 2013-12-02 Vehicle engine cooling liquid Pending CN103666403A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310633309.XA CN103666403A (en) 2013-12-02 2013-12-02 Vehicle engine cooling liquid

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Application Number Priority Date Filing Date Title
CN201310633309.XA CN103666403A (en) 2013-12-02 2013-12-02 Vehicle engine cooling liquid

Publications (1)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031620A (en) * 2014-07-02 2014-09-10 宝捷润滑油镇江有限公司 Anti-boiling, anti-scale and anti-freeze solution and preparation method thereof
CN105860941A (en) * 2016-05-24 2016-08-17 中山市绿浪助剂有限公司 Novel engine coolant corrosion inhibitor formula
CN106010470A (en) * 2016-05-17 2016-10-12 张家港迪克汽车化学品有限公司 Solar heat conduction liquid
CN106634868A (en) * 2016-11-27 2017-05-10 青岛康普顿科技股份有限公司 Fullerol containing organic type engine liquid coolant and preparation method thereof
CN106905933A (en) * 2016-11-27 2017-06-30 青岛康普顿科技股份有限公司 A kind of organic engine cooling liquid of carboxylated fullerene and preparation method thereof
CN109666459A (en) * 2017-10-16 2019-04-23 中国石油化工股份有限公司 A kind of long-life engine coolant liquid resistant to high temperatures
CN109666458A (en) * 2017-10-17 2019-04-23 中国石油化工股份有限公司 A kind of siliceous organic engine cooling liquid and its application
CN110157390A (en) * 2019-05-28 2019-08-23 司能石油化工有限公司 A kind of automobile long-acting liquid coolant and preparation method thereof
CN112574720A (en) * 2019-09-30 2021-03-30 中国石油化工股份有限公司 Low-temperature heat transfer medium with function of inhibiting deposit formation and preparation method and application thereof
CN112574721A (en) * 2020-11-19 2021-03-30 江苏艾德露环保科技有限公司 Multi-effect environment-friendly glycol type automobile cooling liquid and preparation method thereof
CN113214800A (en) * 2021-04-09 2021-08-06 浙江嘉富力环保科技有限公司 Electric vehicle battery cooling liquid
CN113831901A (en) * 2021-11-26 2021-12-24 纯牌科技股份有限公司 Organic acid type heat dissipation liquid for engine and new energy automobile cooling system and preparation method thereof
CN116218485A (en) * 2023-03-09 2023-06-06 山东莱克科技有限公司 High-performance automobile antifreeze fluid and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1594490A (en) * 2004-06-17 2005-03-16 长城润滑油应用研究中心有限公司 Engine cooling liquid
CN1872944A (en) * 2006-06-12 2006-12-06 北京蓝星精细化工有限责任公司 Cooling fluid of engine
CN101629070A (en) * 2008-07-16 2010-01-20 中国石油天然气股份有限公司 Engine coolant
CN101948676A (en) * 2010-08-30 2011-01-19 蓝星环境工程有限公司 High reserve alkalinity engine cooling liquid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1594490A (en) * 2004-06-17 2005-03-16 长城润滑油应用研究中心有限公司 Engine cooling liquid
CN1872944A (en) * 2006-06-12 2006-12-06 北京蓝星精细化工有限责任公司 Cooling fluid of engine
CN101629070A (en) * 2008-07-16 2010-01-20 中国石油天然气股份有限公司 Engine coolant
CN101948676A (en) * 2010-08-30 2011-01-19 蓝星环境工程有限公司 High reserve alkalinity engine cooling liquid

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
包华辉等: "硅酸盐型汽车冷却液的研制", 《润滑油》 *
周建军等: "《汽车冷却液》", 31 May 2003 *
周艳梅等: "一种新型发动机冷却液缓蚀剂配方的研究", 《清洗世界》 *
王晓波等: "车用防冻液概述", 《化工科技》 *
石俊峰,江善钟: "《汽车润滑解码》", 31 August 2012 *

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031620A (en) * 2014-07-02 2014-09-10 宝捷润滑油镇江有限公司 Anti-boiling, anti-scale and anti-freeze solution and preparation method thereof
CN106010470A (en) * 2016-05-17 2016-10-12 张家港迪克汽车化学品有限公司 Solar heat conduction liquid
CN105860941A (en) * 2016-05-24 2016-08-17 中山市绿浪助剂有限公司 Novel engine coolant corrosion inhibitor formula
CN106634868A (en) * 2016-11-27 2017-05-10 青岛康普顿科技股份有限公司 Fullerol containing organic type engine liquid coolant and preparation method thereof
CN106905933A (en) * 2016-11-27 2017-06-30 青岛康普顿科技股份有限公司 A kind of organic engine cooling liquid of carboxylated fullerene and preparation method thereof
CN109666459B (en) * 2017-10-16 2021-01-15 中国石油化工股份有限公司 High-temperature-resistant long-life engine coolant
CN109666459A (en) * 2017-10-16 2019-04-23 中国石油化工股份有限公司 A kind of long-life engine coolant liquid resistant to high temperatures
CN109666458A (en) * 2017-10-17 2019-04-23 中国石油化工股份有限公司 A kind of siliceous organic engine cooling liquid and its application
CN110157390A (en) * 2019-05-28 2019-08-23 司能石油化工有限公司 A kind of automobile long-acting liquid coolant and preparation method thereof
CN112574720A (en) * 2019-09-30 2021-03-30 中国石油化工股份有限公司 Low-temperature heat transfer medium with function of inhibiting deposit formation and preparation method and application thereof
CN112574721A (en) * 2020-11-19 2021-03-30 江苏艾德露环保科技有限公司 Multi-effect environment-friendly glycol type automobile cooling liquid and preparation method thereof
CN113214800A (en) * 2021-04-09 2021-08-06 浙江嘉富力环保科技有限公司 Electric vehicle battery cooling liquid
CN113831901A (en) * 2021-11-26 2021-12-24 纯牌科技股份有限公司 Organic acid type heat dissipation liquid for engine and new energy automobile cooling system and preparation method thereof
CN116218485A (en) * 2023-03-09 2023-06-06 山东莱克科技有限公司 High-performance automobile antifreeze fluid and preparation method thereof

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