CN103555193B - A kind of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint and preparation method thereof - Google Patents
A kind of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint and preparation method thereof Download PDFInfo
- Publication number
- CN103555193B CN103555193B CN201310563688.XA CN201310563688A CN103555193B CN 103555193 B CN103555193 B CN 103555193B CN 201310563688 A CN201310563688 A CN 201310563688A CN 103555193 B CN103555193 B CN 103555193B
- Authority
- CN
- China
- Prior art keywords
- urethane acrylate
- elastic handfeel
- dumb light
- paint
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003973 paint Substances 0.000 title claims abstract description 64
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 title claims description 57
- 238000000576 coating method Methods 0.000 claims abstract description 34
- 239000011248 coating agent Substances 0.000 claims abstract description 33
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 8
- 238000001723 curing Methods 0.000 claims description 37
- 239000004417 polycarbonate Substances 0.000 claims description 21
- 239000000945 filler Substances 0.000 claims description 18
- 239000004814 polyurethane Substances 0.000 claims description 17
- 229920002635 polyurethane Polymers 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 15
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 14
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 14
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000002002 slurry Substances 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 12
- -1 ethoxyquin trimethylolpropane acrylates Chemical class 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 9
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 8
- FTALTLPZDVFJSS-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl prop-2-enoate Chemical compound CCOCCOCCOC(=O)C=C FTALTLPZDVFJSS-UHFFFAOYSA-N 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 239000004258 Ethoxyquin Substances 0.000 claims description 7
- 229940093500 ethoxyquin Drugs 0.000 claims description 7
- 235000019285 ethoxyquin Nutrition 0.000 claims description 7
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000007711 solidification Methods 0.000 claims description 5
- 230000008023 solidification Effects 0.000 claims description 5
- GZBSIABKXVPBFY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GZBSIABKXVPBFY-UHFFFAOYSA-N 0.000 claims description 4
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- FIOCEWASVZHBTK-UHFFFAOYSA-N 2-[2-(2-oxo-2-phenylacetyl)oxyethoxy]ethyl 2-oxo-2-phenylacetate Chemical compound C=1C=CC=CC=1C(=O)C(=O)OCCOCCOC(=O)C(=O)C1=CC=CC=C1 FIOCEWASVZHBTK-UHFFFAOYSA-N 0.000 claims description 3
- PCKZAVNWRLEHIP-UHFFFAOYSA-N 2-hydroxy-1-[4-[[4-(2-hydroxy-2-methylpropanoyl)phenyl]methyl]phenyl]-2-methylpropan-1-one Chemical compound C1=CC(C(=O)C(C)(O)C)=CC=C1CC1=CC=C(C(=O)C(C)(C)O)C=C1 PCKZAVNWRLEHIP-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims description 2
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 2
- 125000004494 ethyl ester group Chemical group 0.000 claims description 2
- 231100000252 nontoxic Toxicity 0.000 claims description 2
- 230000003000 nontoxic effect Effects 0.000 claims description 2
- 238000000016 photochemical curing Methods 0.000 claims description 2
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 abstract description 16
- 229920005989 resin Polymers 0.000 abstract description 16
- 239000011347 resin Substances 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 13
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000005457 optimization Methods 0.000 abstract 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 24
- 230000015572 biosynthetic process Effects 0.000 description 16
- 238000003786 synthesis reaction Methods 0.000 description 16
- 102100026735 Coagulation factor VIII Human genes 0.000 description 12
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 description 12
- IGWHDMPTQKSDTL-JXOAFFINSA-N TMP Chemical compound O=C1NC(=O)C(C)=CN1[C@H]1[C@H](O)[C@H](O)[C@@H](COP(O)(O)=O)O1 IGWHDMPTQKSDTL-JXOAFFINSA-N 0.000 description 12
- 239000000178 monomer Substances 0.000 description 8
- 239000002585 base Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 description 2
- UKQBWWAPJNHIQR-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.CCC(CO)(CO)CO UKQBWWAPJNHIQR-UHFFFAOYSA-N 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 1
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 description 1
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 1
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- RDHSUTIDSFVNJL-UHFFFAOYSA-N OC(=O)C=C.CCCCCCCCCCCC(O)=O Chemical compound OC(=O)C=C.CCCCCCCCCCCC(O)=O RDHSUTIDSFVNJL-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 125000002462 isocyano group Chemical group *[N+]#[C-] 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The present invention relates to a kind of ultraviolet curing type elastic handfeel dumb light paint and preparation method thereof.Its main component comprises matrix resin, reactive thinner, elastic handfeel auxiliary agent, flatting silica, light trigger and solvent, has good hand, outstanding chemical reagent resistance, and the product that can reach good matte effect, and manufactured experimently out optimization formula.This kind of ultraviolet curing type elastic handfeel dumb light paint also has both the curing speed of photo-cured coating soon simultaneously, and energy consumption is low, and efficiency is high, environment friendly and pollution-free grade " 5E " advantage.Can be used in the application of automotive trim, electronic product such as mobile phone, panel computer etc., prospects for commercial application is extensive.
Description
Technical field
The present invention relates to radiation curable coating technical field, be specifically related to a kind of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint and preparation method thereof, this coating excellent touch, elegant in appearance, can be used for automotive trim, the field of coating of electronic product.
Background technology
Along with growth in the living standard, the requirement of people to quality of life is also more and more higher.For articles for daily use, no matter in outward appearance or sense of touch, constantly pursue brand-new, comfortable experience.Therefore the many high-grade articles for use of current era, start with attractive in appearance, comfortable profile and sense of touch, attract popular attention.Elastic handfeel paint arises at the historic moment.It is with appearance attractive in appearance, and comfortable Human physiology sense of touch, gradually in the industry such as automotive trim, electronic product, gains a place, and day by day obtains more favor.But existing elastic handfeel paint is all adopt traditional bicomponent system without exception, utilize hydroxyl and isocyano reaction to be cured, production efficiency is low, environmental pollution is serious.
Use hydroxy component and the curing component containing vulcabond to mix in Chinese patent application CN101921538A, prepare the coloured elastic handfeel paint of band.But with hexamethylene diisocyanate (HDI) in its curing component, there is very large toxicity, harmful, bring environmental pollution.And this elastomeric paint adopts two-pack mixing, long reaction time, production efficiency is lower.
Also patent is had to adopt water-based system to replace organic solvent to prepare environment protection elastic coating.As Chinese patent CN102002166A has prepared a kind of polyurethane aqueous dispersion body of hydroxyl, it adopts the method for self-emulsifying to prepare, and reaches the requirement of environment protection.But still need to add isocyanates solidifying agent in curing of coating process, and need at high temperature toast or dry for a long time under normal temperature, fail finally to reach the environmental requirement of " Green Chemistry ".
[prior art document]:
[patent documentation]:
[patent documentation 1]: CN101921538A
[patent documentation 2]: CN102002166A
For problem noted earlier, the present invention, in the preparation of elastic handfeel paint, introduces UV-curing technology, and ultraviolet-curing paint has less energy-consumption, low solvent volatility, the advantages such as curing speed is fast, and production efficiency is high, and coating performance is excellent, the inefficiency that conventional curing method is brought can be overcome, with serious pollution problem, focusing on the present society of efficiency and quality, is subject to paying close attention to more and more widely.
The object of the invention is to prepare a kind of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint, it is fast that this paint has curing speed in the application, chemical reagent resistance is good, full dumb light, the advantages such as sense of touch is comfortable, can be described as and photo-cured coating is combined with elastic handfeel coating, the product of both's advantage.
Summary of the invention
In order to reach the above target, the present inventor is concentrated to be studied.Found that, with ultraviolet curing type urethane acrylate for matrix resin, auxiliaryly be equipped with the good active function monomer of chain snappiness, as EOEOEA, TPGDA, HDDA, TMP (3EO) EA etc., add appropriate light trigger as Irgacure184, Irgacure127, Irgacure7544, Irgacure819 etc., good solidification effect can be reached under ultraviolet light.Adding of dumb light powder, elastic handfeel filler, paint film can be made to have good matte effect, and excellent sense of touch.Find in performance test, this paint film has excellent chemical resistant properties (acid, alkali, alcohol, oleic acid), higher hardness and the sticking power good to plastic basis material equally.
That is, be to comprise according to the feature of the urethane acrylate elastic handfeel dumb light paint formulation for coating material of ultraviolet curing type of the present invention:
As the urethane acrylate of the matrix resin ultraviolet curing type of film forming component, active function monomer, elastic handfeel filler, flatting silica, light trigger, solvent etc.
Ultraviolet curing type urethane acrylate elastic handfeel dumb light paint described in the present invention, its composition and mass percent are:
The preparation of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint, one of them preferred version, mass percent consists of:
The preparation of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint, its slurry preparation method is:
Component (a) being weighed up by quality successively to component (e) adds in container, tentatively mix with the speed of 2000-2500r/min with homogenizer, add component (f) in the process in batches, to be mixed homogeneous after, speed is adjusted to 3500-4000r/min, stir 30min, the ultraviolet curing type urethane acrylate elastic handfeel dumb light mill base material that can be used for application can be obtained.
The preparation of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint, its paint film preparation method is:
By blade coating, the methods such as spraying, are coated on the base materials such as ABS or PC by gained slurry, place 20min and dry at 40-50 DEG C, then carry out photocuring under ultraviolet light, and solidification energy is not less than 150mj/cm
2, film thickness is 30-60 μm.
Described component (a) is the double bond containing ultraviolet curing type urethane acrylate of the end of the chain, the urethane acrylate of optional polyether-type, polyester type, polytetramethylene oxide, polycarbonate type.
Described component (b) mixes gained by a certain percentage by different functionality active function monomers such as ethoxyethoxyethyl acrylate (EOEOEA), tripropylene glycol diacrylate (TPGDA), 1,6 hexanediol diacrylate (HDDA), ethoxyquin trimethylolpropane acrylates (TMP3EOTA), tetramethylol methane tetraacrylates (PET4A).
The urethane feel filler that described component (c) is particle diameter 6 ~ 12 μm, according to the different demands of paint film, can select powder that is transparent or distinct colors.
Described component (d) is silica flatting agent, as TS-100, OK-520 etc.
Described component (e) is light trigger, can select Irgacure184, Irgacure754, Irgacure127, Irgacure819, TR-MPI1401 etc.
Described component (f) is esters solvent, as N-BUTYL ACETATE etc.
Accompanying drawing explanation
Fig. 1 take Japanese Asahi Kasei Corporation PCDL as the chemical structural formula of several matrix film-forming resins of soft section of synthesis according to the ultraviolet curing type urethane acrylate elastic handfeel dumb light paint of preferred version of the present invention.
Fig. 2 is the digital photograph of the black paint film prepared according to the ultraviolet curing type urethane acrylate elastic handfeel dumb light paint formula of preferred version of the present invention.Left figure base material is ABS plate, and right figure base material is PC plate.
Fig. 3 is that 200 times of the black paint film prepared according to the ultraviolet curing type urethane acrylate elastic handfeel dumb light paint formula of preferred version of the present invention amplify digital photographs.
Embodiment
In order to better explain the present invention, below in conjunction with embodiment, the present invention will be further described.It should be pointed out that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
[film forming matrix resin]
Ultraviolet curing type urethane acrylate elastic handfeel dumb light paint formula according to the present invention is as the matrix resin of film forming matter, for the urethane acrylate of light-cured type, can be the light-cured type urethane acrylate of commercial type, as the YTM5310 of Ya Tumei company, YTM4800, YTM4300, YTM4310, YTM4600, YTM5607, the UV cured polyurethane acrylate of YTM6318 series, or the SM6201 of the wooden company in Jiangsu three, SM6202, SM6203, SM6204, SM6318, SM6320, SM6322, SM6328, SM6329, SM6206, SM6330 series curable urethane acrylate etc.Embodiment used film forming matrix resin in the present invention is this laboratory synthesis PCDL base UV light-cured type urethane acrylate, with Japanese Asahi Kasei Corporation T5652, the PCDL product of the series such as G3452 is flexible polyurethane section, be the polyurethane prepolymer that hard section first synthesizes half end-blocking with the DURANATE of isophorone diisocyanate IPDI or Japanese Asahi Kasei Corporation series vulcabond A201H, then be that end-capping reagent carries out end-blocking with 2-hydroxyethyl methylacrylate or pentaerythritol triacrylate, obtain the ultraviolet curing type urethane acrylate of end containing the polycarbonate type of uV curable double bond as matrix film-forming resin.This resin is than noted earlier, and the urethane acrylate of the polyether-type more early come into the market, polyester type, polytetramethylene oxide has better mechanical property and chemical reagent resistance.
[reactive thinner]
Ultraviolet curing type urethane acrylate elastic handfeel dumb light paint formula according to the present invention, as the function monomer of reactive thinner, can select that molecular chain is long and flexibility is larger, the active function monomer that shrinkability is low and the larger active function monomer of functionality carry out composite, as ethoxyethoxyethyl acrylate (EOEOEA), lauric acid acrylate, 1,6 hexanediol diacrylate (HDDA), ethoxyquin 1,6 hexanediol diacrylate (HD2EODA), propylene glycol diacrylate (DPGDA), tripropylene glycol diacrylate (TPGDA), polyoxyethylene glycol (200) dimethacrylate (PEG (200) DMA), polyoxyethylene glycol (400) dimethacrylate (PEG (400) DMA), polyoxyethylene glycol (600) dimethacrylate (PEG (600) DMA), ethoxyquin-2-methyl isophthalic acid, ammediol diacrylate (MPD2EODA), third oxidation trimethylolpropane acrylates (TMP3POTA), ethoxyquin trimethylolpropane acrylates (TMP9EOTA), ethoxyquin Viscoat 295 (TMP1EOTA), ethoxyquin trimethylolpropane acrylates (TMP3EOTA), trimethylolpropane acrylates (TMPTA), tetramethylol methane tetraacrylate (PET4A), ethoxyquin tetramethylol methane tetraacrylate (PET5EO4A), two-trimethylolpropane tetra-acrylate (DiTMP4A), glycerol propoxylate triacrylate (G6.6POTA) etc.Composite by different functionality active function monomer, can at curing speed, between crosslink density and paint film elasticity, reaches good balance.In the embodiment of the present invention, reactive thinner used is EOEOEA, HDDA, TPGDA, TMP3EOTA and PET4A mixing gained.
[feel filler]
According to the elastic handfeel auxiliary agent of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint formula of the present invention, the embodiment of the present invention has selected the cross-linked polyurethane particle in the ARTPEARL series product of Negmi chemical industry company limited, this product adds in coating, effectively can improve the scratch resistance of paint film, weathering resistance, wearability, thermotolerance and resist adhesive.Find in invention process, the particle diameter of elastic handfeel auxiliary agent is less, and obtained paint film feel is better.Therefore particle diameter is that the C-800T transparent filler of 6 μm and C-800BK black filler show more excellent feel.In addition, the particle diameter in the RHU of the Co., Ltd. that refines large day series fine hair powder less as elasticity powder such as 5070D, can play phase same-action equally, the paint film obtained has good hand equally.
[flatting silica]
Elasticity soft-feel coating generally can carry out height delustring, and compare traditional coating, visual effect is soft, more adds noble quality, exquisiteness, luxurious sense, more attractive.According to the matting agent of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint formula of the present invention, multiple silica flatting agent can be selected, as the ACEMATT series flatting silica of Degussa.Because the feel of solid filler to elastomeric paint has the effect of reduction, therefore when selection flatting silica, select extinction effect good and kind that particle diameter is little, as TS-100, OK-520, OK-607 etc. as far as possible.
[light trigger]
According to the light trigger of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint formula of the present invention, can multiple choices be had, in varnish system and pigmented system, also different.Wherein efficiency of initiation is high, color inhibition, smell are low DAROCUR1173, DAROCURMBF, IRGACURE184, IRGACURE754 etc. all have better solidification effect.And the applicable film such as IRGACURE907, IRGACURE369, Irgacure819, DarocurTPO is thicker, the light trigger of pigmented system, can better be cured coloured elastomeric paint.Carry out composite after light trigger, more can play excellent initiation performance, reach surface drying and inner dry balance.
[solvent]
According to the solvent of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint formula of the present invention, non-toxic ester class or solvent of ether ester type can be selected, as butyl ester, ethyl ester, 1-Methoxy-2-propyl acetate, ethylene glycol ether acetate etc.After the present invention, selected by appended embodiment, solvent is n-butyl acetate.
Embodiment 1
The present embodiment to embodiment 3 is adopt different PCDL as soft section, the ultraviolet curing type urethane acrylate elastic handfeel dumb light paint prepared as matrix resin with the urethane acrylate of HEMA end-blocking synthesis.
To be soft section with PCDL T5651 (molecular weight 1000), IPDI is that hard section synthesizes half blocked polyurethane, with the urethane acrylate 26 parts of HEMA end-blocking synthesis, mixed active thinner (EOEOEA20 part, HDDA10 part, TPGDA10 part, TMP (3EO) TA50 part, PET4A10 part) 8 parts, elastic handfeel filler (black) 10 parts, TS-1004 part, light trigger Irgacure1842 part, tentatively disperse under the speed of 2000-2500r/min with homogenizer, add N-BUTYL ACETATE 50 parts in batches, after all adding, 30min is stirred under 3500-4000r/min, obtain slurry.By method film forming on PC plate and ABS plate of blade coating, 50 DEG C are dried 20min, are then cured under ultraviolet lamp, obtain elastic handfeel paint film.
Embodiment 2
To be soft section with PCDL T5652 (molecular weight 2000), IPDI is that hard section synthesizes half blocked polyurethane, with the urethane acrylate 26 parts of HEMA end-blocking synthesis, mixed active thinner (EOEOEA20 part, HDDA10 part, TPGDA10 part, TMP (3EO) TA50 part, PET4A10 part) 8 parts, elastic handfeel filler (black) 10 parts, TS-1004 part, light trigger Irgacure1842 part, tentatively disperse under the speed of 2000-2500r/min with homogenizer, add N-BUTYL ACETATE 50 parts in batches, after all adding, 30min is stirred under 3500-4000r/min, obtain slurry.By method film forming on PC plate and ABS plate of blade coating, 50 DEG C are dried 20min, are then cured under ultraviolet lamp, obtain elastic handfeel paint film.
Embodiment 3
To be soft section with PCDL G3452 (molecular weight 2000), IPDI is that hard section synthesizes half blocked polyurethane, with the urethane acrylate 26 parts of HEMA end-blocking synthesis, mixed active thinner (EOEOEA20 part, HDDA10 part, TPGDA10 part, TMP (3EO) TA50 part, PET4A10 part) 8 parts, elastic handfeel filler (black) 10 parts, TS-1004 part, light trigger Irgacure1842 part, tentatively disperse under the speed of 2000-2500r/min with homogenizer, add N-BUTYL ACETATE 50 parts in batches, after all adding, 30min is stirred under 3500-4000r/min, obtain slurry.By method film forming on PC plate and ABS plate of blade coating, 50 DEG C are dried 20min, are then cured under ultraviolet lamp, obtain elastic handfeel paint film.
The physical and chemical index of the urethane acrylate elastic handfeel dumb light paint of above-described embodiment gained uV curable is in table 1:
Table 1 is with the coating parameter synopsis of each embodiment of HEMA end-blocking matrix resin
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Sticking power on PC plate | 0 | 0 | 0 |
| Glossiness (60 °) | 0.3 | 0.2 | 0.2 |
| Pendulum-rocker hardness | 18 | 17 | 12 |
| Chemical reagent resistance | Excellent | Excellent | Excellent |
| Feel | Good | Excellent | Excellent |
As seen from Table 1, the solidified coating of embodiments of the invention 1, embodiment 2, embodiment 3, all can reach the effect of full dumb light, chemical reagent-resistant performance is excellent, and has the sense of touch of soft comfortable.
Embodiment 4
The present embodiment to embodiment 6 is adopt different PCDL as soft section, the ultraviolet curing type urethane acrylate elastic handfeel dumb light paint prepared as matrix resin with the urethane acrylate of PET3A end-blocking synthesis.
To be soft section with PCDL T5651 (molecular weight 1000), IPDI is that hard section synthesizes half blocked polyurethane, with the urethane acrylate 26 parts of PET3A end-blocking synthesis, mixed active thinner (EOEOEA20 part, HDDA10 part, TPGDA10 part, TMP (3EO) TA50 part, PET4A10 part) 8 parts, elastic handfeel filler (black) 10 parts, TS-1004 part, light trigger Irgacure1842 part, tentatively disperse under the speed of 2000-2500r/min with homogenizer, add N-BUTYL ACETATE 50 parts in batches, after all adding, 30min is stirred under 3500-4000r/min, obtain slurry.By method film forming on PC plate and ABS plate of blade coating, 50 DEG C are dried 20min, are then cured under ultraviolet lamp, obtain elastic handfeel paint film.
Embodiment 5
To be soft section with PCDL T5652 (molecular weight 2000), IPDI is that hard section synthesizes half blocked polyurethane, with the urethane acrylate 26 parts of PET3A end-blocking synthesis, mixed active thinner (EOEOEA20 part, HDDA10 part, TPGDA10 part, TMP (3EO) TA50 part, PET4A10 part) 8 parts, elastic handfeel filler (black) 10 parts, TS-1004 part, light trigger Irgacure1842 part, tentatively disperse under the speed of 2000-2500r/min with homogenizer, add N-BUTYL ACETATE 50 parts in batches, after all adding, 30min is stirred under 3500-4000r/min, obtain slurry.By method film forming on PC plate and ABS plate of blade coating, 50 DEG C are dried 20min, are then cured under ultraviolet lamp, obtain elastic handfeel paint film.
Embodiment 6
To be soft section with PCDL G3452 (molecular weight 2000), IPDI is that hard section synthesizes half blocked polyurethane, with the urethane acrylate 26 parts of PET3A end-blocking synthesis, mixed active thinner (EOEOEA20 part, HDDA10 part, TPGDA10 part, TMP (3EO) TA50 part, PET4A10 part) 8 parts, elastic handfeel filler (black) 10 parts, TS-1004 part, light trigger Irgacure1842 part, tentatively disperse under the speed of 2000-2500r/min with homogenizer, add N-BUTYL ACETATE 50 parts in batches, after all adding, 30min is stirred under 3500-4000r/min, obtain slurry.By method film forming on PC plate and ABS plate of blade coating, 50 DEG C are dried 20min, are then cured under ultraviolet lamp, obtain elastic handfeel paint film.
The physical and chemical index of the urethane acrylate elastic handfeel dumb light paint of 4-6 embodiment gained uV curable is in table 2:
Table 2 is with the coating parameter synopsis of each embodiment of PET3A end-blocking matrix resin
| Project | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Sticking power on PC plate | 0 | 0 | 0 |
| Glossiness (60 °) | 0.3 | 0.4 | 0.3 |
| Pendulum-rocker hardness | 28 | 25 | 20 |
| Chemical reagent resistance | Excellent | Excellent | Excellent |
| Feel | Good | Good | Excellent |
As seen from Table 2, the solidified coating of embodiments of the invention 4, embodiment 5, embodiment 6, the effect of full dumb light can be reached equally, chemical reagent-resistant performance is excellent, and there is the sense of touch of soft comfortable, the elastic handfeel paint film that HEMA end-blocking matrix resin-made of comparing is standby, elastic handfeel paint film pendulum-rocker hardness prepared by the matrix resin of PET3A end-blocking is slightly slightly larger.
Embodiment 7
The present embodiment and embodiment 2, embodiment 8, for adopt PCDL T5652 as soft section, add ultraviolet curing type urethane acrylate elastic handfeel dumb light paint prepared by different light trigger with the urethane acrylate of HEMA end-blocking synthesis as matrix resin.
To be soft section with PCDL T5652 (molecular weight 2000), IPDI is that hard section synthesizes half blocked polyurethane, with the urethane acrylate 26 parts of HEMA end-blocking synthesis, mixed active thinner (EOEOEA20 part, HDDA10 part, TPGDA10 part, TMP (3EO) TA50 part, PET4A10 part) 8 parts, elastic handfeel filler (black) 10 parts, TS-1004 part, light trigger Irgacure1841.5 part, Irgacure8190.5 part, tentatively disperse under the speed of 2000-2500r/min with homogenizer, add N-BUTYL ACETATE 50 parts in batches, after all adding, 30min is stirred under 3500-4000r/min, obtain slurry.By method film forming on PC plate and ABS plate of blade coating, 50 DEG C are dried 20min, are then cured under ultraviolet lamp, obtain elastic handfeel paint film.
Embodiment 8
To be soft section with PCDL T5652 (molecular weight 2000), IPDI is that hard section synthesizes half blocked polyurethane, with the urethane acrylate 26 parts of HEMA end-blocking synthesis, mixed active thinner (EOEOEA20 part, HDDA10 part, TPGDA10 part, TMP (3EO) TA50 part, PET4A10 part) 8 parts, elastic handfeel filler (black) 10 parts, TS-1004 part, light trigger Irgacure7542 part, tentatively disperse under the speed of 2000-2500r/min with homogenizer, add N-BUTYL ACETATE 50 parts in batches, after all adding, 30min is stirred under 3500-4000r/min, obtain slurry.By method film forming on PC plate and ABS plate of blade coating, 50 DEG C are dried 20min, are then cured under ultraviolet lamp, obtain elastic handfeel paint film.
The physical and chemical index of the urethane acrylate elastic handfeel dumb light paint of embodiment 2, embodiment 7 and embodiment 8 gained uV curable is in table 3:
The coating parameter synopsis of each embodiment that table 3 solidifies with different light trigger
| Project | Embodiment 2 | Embodiment 7 | Embodiment 8 |
| Solidification energy (mj/cm 2) | 300 | 150 | 900 |
| Sticking power on PC plate | 0 | 0 | 0 |
| Glossiness (60 °) | 0.2 | 0.4 | 0.3 |
| Pendulum-rocker hardness | 17 | 21 | 20 |
| Chemical reagent resistance | Excellent | Excellent | Excellent |
As seen from Table 3, the solidified coating of embodiments of the invention 2, embodiment 7, embodiment 8, can reach the effect of full dumb light equally, chemical reagent-resistant performance is excellent, and has the sense of touch of soft comfortable.For the efficiency of initiation of different initiator, with the composite the best of Irgacure184 and Irgacure819.
Embodiment 9
The present embodiment and embodiment 2, embodiment 10, for adopt PCDL T5652 as soft section, are made matrix resin with the urethane acrylate of HEMA end-blocking synthesis and are added ultraviolet curing type urethane acrylate elastic handfeel dumb light paint prepared by different activities thinner.
To be soft section with PCDL T5652 (molecular weight 2000), IPDI is that hard section synthesizes half blocked polyurethane, with the urethane acrylate 26 parts of HEMA end-blocking synthesis, mixed active thinner (EOEOEA20 part, HDDA30 part, TPGDA10 part, TMP (3EO) TA30 part, PET4A10 part) 8 parts, elastic handfeel filler (black) 10 parts, TS-1004 part, light trigger Irgacure1842 part, tentatively disperse under the speed of 2000-2500r/min with homogenizer, add N-BUTYL ACETATE 50 parts in batches, after all adding, 30min is stirred under 3500-4000r/min, obtain slurry.By method film forming on PC plate and ABS plate of blade coating, 50 DEG C are dried 20min, are then cured under ultraviolet lamp, obtain elastic handfeel paint film.
Embodiment 10
To be soft section with PCDL T5652 (molecular weight 2000), IPDI is that hard section synthesizes half blocked polyurethane, with the urethane acrylate 26 parts of HEMA end-blocking synthesis, mixed active thinner (EOEOEA20 part, HDDA50 part, TPGDA10 part, TMP (3EO) TA10 part, PET4A10 part) 8 parts, elastic handfeel filler (black) 10 parts, TS-1004 part, light trigger Irgacure1842 part, tentatively disperse under the speed of 2000-2500r/min with homogenizer, add N-BUTYL ACETATE 50 parts in batches, after all adding, 30min is stirred under 3500-4000r/min, obtain slurry.By method film forming on PC plate and ABS plate of blade coating, 50 DEG C are dried 20min, are then cured under ultraviolet lamp, obtain elastic handfeel paint film.
The physical and chemical index of the urethane acrylate elastic handfeel dumb light paint of embodiment 2, embodiment 9 and embodiment 10 gained uV curable is in table 4:
The table 4 coating parameter synopsis of each embodiment of different activities thinner
| Project | Embodiment 2 | Embodiment 9 | Embodiment 10 |
| Sticking power on PC plate | 0 | 0 | 0 |
| Glossiness (60 °) | 0.2 | 0.3 | 0.3 |
| Pendulum-rocker hardness | 17 | 15 | 12 |
| Chemical reagent resistance | Excellent | Excellent | Excellent |
| Pencil hardness | 3H | 2H | 2H |
| Feel | Excellent | Excellent | Excellent |
As seen from Table 4, the solidified coating of embodiments of the invention 2, embodiment 9, embodiment 10, can reach the effect of full dumb light equally, chemical reagent-resistant performance is excellent, and has the sense of touch of soft comfortable.Add different activities thinner, wherein polyfunctionality active function monomer content is more, and the hardness of coating is higher.
Above-described is only the preferred embodiment of the present invention, the invention is not restricted to above embodiment.Be appreciated that the oher improvements and changes that those skilled in the art directly derive without departing from the spirit and concept in the present invention or associate, all should think and be included within protection scope of the present invention.
Claims (3)
1. a ultraviolet curing type urethane acrylate elastic handfeel dumb light paint, is characterized in that:
There is following composition and mass percent:
Wherein, the urethane acrylate that component (a) is polycarbonate type, namely with the PCDL product of Japanese Asahi Kasei Corporation T5652, G3452 series for flexible polyurethane section, be the polyurethane prepolymer that hard section first synthesizes half end-blocking with the DURANATE of isophorone diisocyanate IPDI or Japanese Asahi Kasei Corporation series vulcabond A201H, then be that end-capping reagent carries out end-blocking with 2-hydroxyethyl methylacrylate or pentaerythritol triacrylate, obtain the ultraviolet curing type urethane acrylate of end containing the polycarbonate type of uV curable double bond;
Component (b) is mixed in proportion obtained by ethoxyethoxyethyl acrylate (EOEOEA), tripropylene glycol diacrylate (TPGDA), 1,6 hexanediol diacrylate (HDDA), ethoxyquin trimethylolpropane acrylates (TMP3EOTA), tetramethylol methane tetraacrylate (PET4A);
The polyurethanes feel filler that component (c) is particle diameter 6 ~ 12 μm, is the cross-linked polyurethane particle in the ARTPEARL series product of Negmi chemical industry company limited;
Component (d) is silica flatting agent, as TS-100, OK-520;
Component (e) light trigger, can select Irgacure184, Irgacure754, Irgacure127, Irgacure819, TR-MPI1401;
Component (f) can be non-toxic ester kind solvent, as butyl ester, ethyl ester, 1-Methoxy-2-propyl acetate, ethylene glycol ether acetate.
2. the urethane acrylate elastic handfeel dumb light paint of uV curable according to claim 1, is characterized in that the preparation method of described dumb light mill base material is:
Component (a) being weighed up by quality successively to component (e) adds in container, tentatively mix with the speed of 2000-2500r/min with homogenizer, add component (f) in the process in batches, to be mixed homogeneous after, speed is adjusted to 3500-4000r/min, continue dispersed with stirring 30min, the ultraviolet curing type urethane acrylate elastic handfeel dumb light mill base material that can be used for application can be obtained.
3. the urethane acrylate elastic handfeel dumb light paint of uV curable according to claim 1, is characterized in that the preparation method of described dumb light paint paint film is:
By blade coating, spraying method, be coated in by gained slurry on ABS or PC base material, place 20-30min and dry at 40-50 DEG C, then carry out photocuring under ultraviolet light, solidification energy is not less than 150mj/cm
2, film thickness 30-60 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310563688.XA CN103555193B (en) | 2013-11-12 | 2013-11-12 | A kind of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310563688.XA CN103555193B (en) | 2013-11-12 | 2013-11-12 | A kind of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103555193A CN103555193A (en) | 2014-02-05 |
| CN103555193B true CN103555193B (en) | 2016-01-27 |
Family
ID=50009568
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310563688.XA Active CN103555193B (en) | 2013-11-12 | 2013-11-12 | A kind of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103555193B (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881556A (en) * | 2014-02-26 | 2014-06-25 | 金甲化工企业(中山)有限公司 | UV elastic coating |
| CN104087127A (en) * | 2014-07-15 | 2014-10-08 | 苏州市明大高分子科技材料有限公司 | Ultraviolet curing antique roller coating matt base coat and preparation method thereof |
| CN104152031B (en) * | 2014-07-30 | 2016-06-22 | 无锡卡秀堡辉涂料有限公司 | A kind of Ultraviolet light cured ceramic paint |
| SE1400571A1 (en) | 2014-12-04 | 2015-11-24 | Perstorp Ab | Radiation curing coating composition |
| CN104559750B (en) * | 2014-12-31 | 2017-07-11 | 武汉工程大学 | A kind of UV hand-feeling coatings based on elastic polyurethane acrylate and preparation method thereof |
| CN105754469A (en) * | 2015-12-18 | 2016-07-13 | 广州源辉化工有限公司 | UV hand-feeling coating and spraying construction method thereof |
| CN107057556A (en) * | 2017-05-23 | 2017-08-18 | 安徽康瑞高科新材料技术工程有限公司 | Ultraviolet light UV feel elastomeric paints |
| CN109486404A (en) * | 2018-09-10 | 2019-03-19 | 韶关市连邦环保新材料股份有限公司 | A kind of ultraviolet-curing paint of elastic tactility |
| CN109880508A (en) * | 2019-01-15 | 2019-06-14 | 东莞市亿森居环保科技有限公司 | A kind of composition, preparation method and the application in photocuring woodcare paint paint field |
| CN111040600B (en) * | 2019-12-23 | 2021-09-14 | 东莞市涂芭新材料有限公司 | Water-based scratch-resistant full-matte solid-color wood coating and preparation method thereof |
| CN112358805A (en) * | 2020-11-11 | 2021-02-12 | 卡秀万辉(无锡)高新材料有限公司 | High-transparency anode-like particle anti-scratching UV coating and preparation method and application thereof |
| CN112457695A (en) * | 2020-11-16 | 2021-03-09 | 深圳市方润环境科技有限公司 | Emulsion paint applied to leather |
| CN112694828A (en) * | 2020-12-25 | 2021-04-23 | 佛山阳光逸采涂料科技有限公司 | UV LED ultraviolet light curing skin-feel coating, preparation method thereof and skin-feel material |
| CN112980318A (en) * | 2021-03-01 | 2021-06-18 | 江西赐彩新材料股份有限公司 | Composite board high-wear-resistance fingerprint-resistant matte UV (ultraviolet) hardening liquid and preparation method thereof |
| CN113956782A (en) * | 2021-11-10 | 2022-01-21 | 广州亦盛环保科技有限公司 | Water-based ultraviolet-curing elastic coating and preparation method thereof |
| CN115417954A (en) * | 2022-09-07 | 2022-12-02 | 万华化学（北京）有限公司 | Photo-thermal dual-curable polyurethane polymer, preparation method and composite material thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1477168A (en) * | 2002-08-20 | 2004-02-25 | 北京英力科技发展有限公司 | Photocurable water coating agent |
| CN1778852A (en) * | 2004-11-25 | 2006-05-31 | 比亚迪股份有限公司 | Ultraviolet light curing yaguang coating and its production thereof |
| EP1743909A1 (en) * | 2005-07-13 | 2007-01-17 | REHAU AG + Co | Extrudate containing a coating |
| CN101210144A (en) * | 2006-12-30 | 2008-07-02 | 比亚迪股份有限公司 | Ultraviolet light solidifying matt coating and preparation method thereof |
| CN101781502A (en) * | 2009-01-16 | 2010-07-21 | 比亚迪股份有限公司 | Paint |
| CN102101945A (en) * | 2009-12-16 | 2011-06-22 | 比亚迪股份有限公司 | Ultraviolet curing paint and preparation method thereof |
| CN102229779A (en) * | 2011-06-20 | 2011-11-02 | 上虞市佑谦特种材料有限公司 | UV (Ultraviolent) deglossing paint and preparation method thereof |
-
2013
- 2013-11-12 CN CN201310563688.XA patent/CN103555193B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1477168A (en) * | 2002-08-20 | 2004-02-25 | 北京英力科技发展有限公司 | Photocurable water coating agent |
| CN1778852A (en) * | 2004-11-25 | 2006-05-31 | 比亚迪股份有限公司 | Ultraviolet light curing yaguang coating and its production thereof |
| EP1743909A1 (en) * | 2005-07-13 | 2007-01-17 | REHAU AG + Co | Extrudate containing a coating |
| CN101210144A (en) * | 2006-12-30 | 2008-07-02 | 比亚迪股份有限公司 | Ultraviolet light solidifying matt coating and preparation method thereof |
| CN101781502A (en) * | 2009-01-16 | 2010-07-21 | 比亚迪股份有限公司 | Paint |
| CN102101945A (en) * | 2009-12-16 | 2011-06-22 | 比亚迪股份有限公司 | Ultraviolet curing paint and preparation method thereof |
| CN102229779A (en) * | 2011-06-20 | 2011-11-02 | 上虞市佑谦特种材料有限公司 | UV (Ultraviolent) deglossing paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103555193A (en) | 2014-02-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103555193B (en) | A kind of ultraviolet curing type urethane acrylate elastic handfeel dumb light paint and preparation method thereof | |
| CN102863829B (en) | Humidity and ultraviolet dual-cured polyurethane woodware coating and preparation method thereof | |
| CN105802483B (en) | A kind of double curing coating and preparation method and application | |
| CN101407651B (en) | UV curing color decorative coating | |
| CN101659785B (en) | High-functionality water-based UV resin composition with 100% solid content and preparation method thereof | |
| CN100448939C (en) | Coating material solidified by ultraviolet light and prepartion method | |
| CN101837667B (en) | Ultraviolet cured coating and application thereof | |
| CN101481448B (en) | Active oligomer, preparation thereof and white board erasable ultraviolet cured paint containing the same | |
| CN102206462B (en) | Metal UV (Ultraviolet) coating | |
| CN104817879A (en) | Ultraviolet curing full-shielding protection printing ink | |
| CN102020913B (en) | Ultraviolet cured wood paint and preparation method thereof | |
| CN104817878A (en) | Ultraviolet curing anti-sandblasting shielding protection printing ink | |
| CN101638553B (en) | Ultraviolet curing coating | |
| CN101781502B (en) | Paint | |
| CN104194613A (en) | Recoatable UV-curing colored one-step-coating aluminum powder paint and preparation method thereof | |
| CN102153899A (en) | Ultraviolet-curable water-based colored paint composition | |
| CN101659809A (en) | Water-based UV black ink with super-high solid content and preparation method thereof | |
| CN101153155A (en) | Priming coating composition and preparation method thereof | |
| CN101463222A (en) | UV curing color coating | |
| CN102977748B (en) | A kind of not containing the UV furniture spray paint light top coat top coat of volatile organic solvent | |
| CN105419624A (en) | UV cured aqueous plastic coating and preparation method thereof | |
| CN102101945A (en) | Ultraviolet curing paint and preparation method thereof | |
| CN103589324B (en) | The anti-scratch matte varnish of a kind of UV | |
| CN103224722A (en) | UV-curable fluorocarbon solar cell back-side protective film paint | |
| CN102206463A (en) | Vacuum plating UV cured primer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240207 Address after: 101200 room 205-211526, No. 40, Fuqian West Street, Pinggu town, Pinggu District, Beijing (cluster registration) Patentee after: BEIJING YONGBO TECHNOLOGY CO.,LTD. Country or region after: China Address before: College of chemistry and material engineering Jiangnan University No. 1800 214122 Jiangsu city of Wuxi Province Li Lake Avenue Patentee before: Jiangnan University Country or region before: China |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240308 Address after: No. 228 Yuegong Road, Caojing Town, Jinshan District, Shanghai, 201500 Patentee after: Jincai New Materials (Shanghai) Co.,Ltd. Country or region after: China Address before: 101200 room 205-211526, No. 40, Fuqian West Street, Pinggu town, Pinggu District, Beijing (cluster registration) Patentee before: BEIJING YONGBO TECHNOLOGY CO.,LTD. Country or region before: China |
|
| TR01 | Transfer of patent right |