CN103547363A - 包含截留在介孔结构氧化物基质中的金属纳米颗粒的球形材料及其作为烃精制工艺中的催化剂的用途 - Google Patents
包含截留在介孔结构氧化物基质中的金属纳米颗粒的球形材料及其作为烃精制工艺中的催化剂的用途 Download PDFInfo
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- CN103547363A CN103547363A CN201180068245.2A CN201180068245A CN103547363A CN 103547363 A CN103547363 A CN 103547363A CN 201180068245 A CN201180068245 A CN 201180068245A CN 103547363 A CN103547363 A CN 103547363A
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
-
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Abstract
Description
Claims (15)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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FR1005029 | 2010-12-22 | ||
FR1005029A FR2969511B1 (fr) | 2010-12-22 | 2010-12-22 | Materiau spherique comprenant des nanoparticules metalliques piegees dans une matrice oxyde mesostructuree et son utilisation comme catalyseur dans les procedes du raffinage |
PCT/FR2011/000653 WO2012085354A1 (fr) | 2010-12-22 | 2011-12-15 | Materiau spherique comprenant des nanoparticules metalliques piegees dans une matrice oxyde mesostructuree et son utilisation comme catalyseur dans les procedes du raffinage d'hydrocarbures |
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CN103547363A true CN103547363A (zh) | 2014-01-29 |
CN103547363B CN103547363B (zh) | 2017-05-03 |
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US (1) | US20140027346A1 (zh) |
EP (1) | EP2654945B1 (zh) |
JP (1) | JP5907992B2 (zh) |
CN (1) | CN103547363B (zh) |
FR (1) | FR2969511B1 (zh) |
WO (1) | WO2012085354A1 (zh) |
ZA (1) | ZA201304070B (zh) |
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CN107626323A (zh) * | 2017-09-07 | 2018-01-26 | 南京大学昆山创新研究院 | 一种固体催化剂、其制备方法及利用其制备甘油二酯的方法 |
CN109569453A (zh) * | 2018-11-27 | 2019-04-05 | 浙江大学 | 一种多用途锡、铁、锆掺杂二氧化硅微球的制备方法 |
CN111447995A (zh) * | 2017-09-29 | 2020-07-24 | 哈佛学院院长及董事 | 具有部分包埋的催化纳米颗粒的强化催化材料 |
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JP5678648B2 (ja) * | 2010-12-22 | 2015-03-04 | 東ソー株式会社 | Zsm−5微粒子及びその製造方法 |
KR102262349B1 (ko) * | 2013-07-04 | 2021-06-08 | 토탈 리서치 앤드 테크놀로지 펠루이 | 기공성 물질에 침적된 소규모 분자체 결정을 포함하는 촉매 조성물 |
CN105540608B (zh) * | 2014-11-03 | 2017-07-28 | 中国石油化工股份有限公司 | 一种双介孔结构的Y‑Beta复合分子筛及其制备方法 |
CN105363452B (zh) * | 2015-10-20 | 2018-02-27 | 太原理工大学 | 一种用于甲烷部分氧化反应的双介孔结构Ni/SiO2‑ZrO2催化剂制备方法 |
FR3044005B1 (fr) | 2015-11-23 | 2017-12-15 | Ifp Energies Now | Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt piege dans une matrice oxyde mesoporeuse et obtenu a partir d'au moins un precurseur monomerique |
FR3054454B1 (fr) * | 2016-07-26 | 2020-04-10 | IFP Energies Nouvelles | Catalyseur comprenant une zeolithe izm-2 ayant un rapport molaire si/al optimise pour l'isomerisation de coupes c8 aromatiques |
US11909046B2 (en) | 2017-03-07 | 2024-02-20 | The Research Foundation For The State University Of New York | Synthetic methods for crystallite size control of bimetallic polyanionic battery compositions |
CN110691650A (zh) * | 2017-05-31 | 2020-01-14 | 古河电气工业株式会社 | 加氢裂化用催化剂结构体、具备该加氢裂化用催化剂结构体的加氢裂化装置以及加氢裂化用催化剂结构体的制造方法 |
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FR3087357A1 (fr) * | 2018-10-23 | 2020-04-24 | IFP Energies Nouvelles | Nouveau procede d’oligomerisation des olefines utilisant des catalyseurs a base d'un materiau spherique comprenant des particules metalliques d’oxyde de nickel piegees dans une matrice mesostructuree |
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JPWO2021192960A1 (zh) * | 2020-03-23 | 2021-09-30 | ||
US11384297B1 (en) | 2021-02-04 | 2022-07-12 | Saudi Arabian Oil Company | Systems and methods for upgrading pyrolysis oil to light aromatics over mixed metal oxide catalysts |
US11746299B1 (en) | 2022-07-11 | 2023-09-05 | Saudi Arabian Oil Company | Methods and systems for upgrading mixed pyrolysis oil to light aromatics over mixed metal oxide catalysts |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006128988A1 (fr) * | 2005-06-02 | 2006-12-07 | Institut Francais Du Petrole | Materiau inorganique presentant des nanoparticules metalliques piegees dans une matrice mesostructuree |
CN101541426A (zh) * | 2006-11-23 | 2009-09-23 | 法国石油公司 | 基于具有分级孔隙率的含硅材料的催化剂,以及烃进料的加氢裂化/加氢转化和加氢处理的方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070152181A1 (en) | 2001-07-27 | 2007-07-05 | Board Of Trustees Of Michigan State University | Mesostructured hydrated alumina - surfactant composite compositions and mesostructured transition alumina compositions derived therefrom |
FR2834978B1 (fr) | 2002-01-21 | 2004-04-09 | Rhodia Elect & Catalysis | Materiaux mesostructures integrant des particules cristallines nanometriques comprenant un metal en solution solide au sein de leur reseau cristallin |
FR2843050B1 (fr) | 2002-08-01 | 2005-04-15 | Inst Francais Du Petrole | Catalyseur a base de metaux du groupe vi et du groupe viii presents au moins en partie sous la forme d'heteropolyanions dans le precurseur oxyde |
FR2872151B1 (fr) * | 2004-06-24 | 2007-06-29 | Inst Francais Du Petrole | Materiau aluminosilicate mesostructure |
FR2886637B1 (fr) * | 2005-06-02 | 2007-08-03 | Inst Francais Du Petrole | Materiau mesostructure a forte teneur en aluminium |
FR2929264B1 (fr) * | 2008-03-31 | 2010-03-19 | Inst Francais Du Petrole | Materiau inorganique forme de particules spheriques de taille specifique et presentant des nanoparticules metalliques piegees dans une matrice mesostructuree |
FR2935139B1 (fr) * | 2008-08-19 | 2011-06-10 | Inst Francais Du Petrole | Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage |
-
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2011
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006128988A1 (fr) * | 2005-06-02 | 2006-12-07 | Institut Francais Du Petrole | Materiau inorganique presentant des nanoparticules metalliques piegees dans une matrice mesostructuree |
CN101189186A (zh) * | 2005-06-02 | 2008-05-28 | 法国石油公司 | 含有在中孔结构化基质内截留的金属纳米颗粒的无机材料 |
CN101541426A (zh) * | 2006-11-23 | 2009-09-23 | 法国石油公司 | 基于具有分级孔隙率的含硅材料的催化剂,以及烃进料的加氢裂化/加氢转化和加氢处理的方法 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107626323A (zh) * | 2017-09-07 | 2018-01-26 | 南京大学昆山创新研究院 | 一种固体催化剂、其制备方法及利用其制备甘油二酯的方法 |
CN107626323B (zh) * | 2017-09-07 | 2020-02-14 | 南京大学昆山创新研究院 | 一种固体催化剂、其制备方法及利用其制备甘油二酯的方法 |
CN111447995A (zh) * | 2017-09-29 | 2020-07-24 | 哈佛学院院长及董事 | 具有部分包埋的催化纳米颗粒的强化催化材料 |
US11590483B2 (en) | 2017-09-29 | 2023-02-28 | President And Fellows Of Harvard College | Enhanced catalytic materials with partially embedded catalytic nanoparticles |
CN112105456A (zh) * | 2018-02-21 | 2020-12-18 | 沙特***石油公司 | 多功能复合催化剂材料和合成催化材料的方法 |
CN109569453A (zh) * | 2018-11-27 | 2019-04-05 | 浙江大学 | 一种多用途锡、铁、锆掺杂二氧化硅微球的制备方法 |
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US20140027346A1 (en) | 2014-01-30 |
WO2012085354A1 (fr) | 2012-06-28 |
FR2969511B1 (fr) | 2012-12-28 |
EP2654945A1 (fr) | 2013-10-30 |
ZA201304070B (en) | 2014-02-26 |
FR2969511A1 (fr) | 2012-06-29 |
EP2654945B1 (fr) | 2019-08-21 |
JP5907992B2 (ja) | 2016-04-26 |
JP2014501219A (ja) | 2014-01-20 |
CN103547363B (zh) | 2017-05-03 |
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