CN103509507A - Environment-friendly epoxy seaming paste and preparation method thereof - Google Patents
Environment-friendly epoxy seaming paste and preparation method thereof Download PDFInfo
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- CN103509507A CN103509507A CN201310435281.9A CN201310435281A CN103509507A CN 103509507 A CN103509507 A CN 103509507A CN 201310435281 A CN201310435281 A CN 201310435281A CN 103509507 A CN103509507 A CN 103509507A
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Abstract
The invention relates to environment-friendly epoxy seaming paste and a preparation method thereof. The environment-friendly epoxy seaming paste is formed by mixing main paint with a curing agent according to a mass ratio of 2 to (0.8-1.2), wherein the main paint comprises the following components in parts by weight: 28-38 parts of epoxy resin, 1-6 parts of an epoxy reactive diluent, 1-5 parts of phemethylol, 0.1-0.5 part of a dispersant, 0.1-0.5 part of a defoamer, 0.5-2.5 parts of an anti-settling agent, 0.5-4 parts of bentonite, 10-20 parts of quartz sand, 20-50 parts of heavy calcium carbonate, 5-15 parts of talcum powder, 0.1-0.6 part of synthetic fibers and 8-10 parts of epoxy carbon black slurry; the curing agent comprises the following components in parts by weight: 28-38 parts of an amine-modified curing agent, 0.1-0.5 part of the dispersant, 0.1-0.5 part of the defoamer, 0.5-2.5 parts of the anti-settling agent, 0.5-4 parts of the bentonite, 2-5 parts of titanium dioxide, 10-20 parts of the quartz sand, 20-45 parts of heavy calcium carbonate, 5-15 parts of the talcum powder and 0.1-1 part of the synthetic fibers. The environment-friendly epoxy seaming paste prepared by the method has the advantages of very high bonding force, low possibility of cracking, water resistance and low harmful substance content, and is good in constructability.
Description
Technical field
The present invention relates to a kind of joint filler being used in the joint filling of house ornamentation furred ceiling, particularly a kind of environment-friendly epoxy seam cream.
Background technology
Seam cream is a kind of spackling of paste, is widely used in the joint filling of house ornamentation furred ceiling, and existing joint filler easily solidifies, and need to complete in the short period of time construction, causes the duration of service of seam cream shorter; And seam cream is smeared rear coating and is easily ftractureed, so will paste kraft paper after construction, cause operational procedure complicated, had a strong impact on decorative effect simultaneously.So need to research and develop a kind of joint mixture that cohesive force is extremely strong, the usage period long, have good application property, water-fast, firm wear-resisting advantage that has.
Summary of the invention
The object of the present invention is to provide a kind of environment-friendly epoxy seam cream and preparation method thereof, the environment-friendly epoxy seam cream that the present invention prepares not only has advantages of that cohesive force is extremely strong, not easy to crack, water-fast, harmful substance contents is low, and has good application property.
The present invention is achieved in that a kind of environment-friendly epoxy seam cream, by main paint and solidifying agent, by the mass ratio of 2:0.8-1.2, is mixed, and wherein main paint and solidifying agent are formulated by following component and ratio of weight and number:
Wherein main paint component and ratio of weight and number are as follows:
Wherein curing agent component and ratio of weight and number are as follows:
Further prioritization scheme is: described epoxy resin is E51, the E44 type that diphenylol propane tetraglycidel ether epoxy resin (bisphenol A epoxide resin) ，Ru Wuxi epoxy resin factory produces.
Further prioritization scheme is: described epoxy active diluent is glycidyl allyl ether; It adopts the AGE (glycidyl allyl ether) of the new Chemical Manufacture far away in Anhui.
Further prioritization scheme is: described dispersion agent is modified polyurethane solution.
Further prioritization scheme is: described anti-settling agent is hydrophobic type aerosil; It adopts the R972 type anti-settling agent of the production of German Degussa.
Further prioritization scheme is: described synthon are the chopped trevira of alkali-free that Hangzhou Jian Qing fibre product company limited produces.
Further prioritization scheme is: described amine modified firming agent is a kind of or its arbitrary combination of aliphatic amide family polyamines, alicyclic polyamine or its affixture of the production of Guangzhou Rui Qi Chemical Co., Ltd.; As R-3500, R-3501 type amine modified firming agent.
Further prioritization scheme is: it is the defoamer of modified silicon ketone that described defoamer adopts major ingredient; The HX-2500 type defoamer that it adopts China to produce.Phenylcarbinol is that Hubei Green Homeland Fine Chemical Co., Ltd produces.
Further prioritization scheme is: it is the flow agent of polyacrylic ester interpolymer and fluorine-carbon modified polyacrylate(s) that described flow agent adopts main component; As the BYK306 type flow agent of German Bi Ke chemical production.Described wilkinite is the SD-1 type wilkinite of this production of hamming.Described coarse whiting is the 1083 type coarse whitings that Fujian Sannong Group Co., Ltd. produces.Described quartz sand is the 200 order quartz sands that Foshan Zhen Xinming section produces.
The preparation method of above-mentioned environment-friendly epoxy seam cream, comprises following step:
(1), main paint is prepared according to following preparation method:
Epoxy resin, epoxy active diluent, phenylcarbinol, dispersion agent, defoamer, anti-settling agent, wilkinite, quartz sand, coarse whiting, talcum powder, synthon, epoxy carbon black are sequentially added in container successively, in stirrer, with 1000-1200 rev/min, disperse 10-15 minute to mixing;
(2), solidifying agent is prepared according to following preparation method:
Amine modified firming agent (R-3500), dispersion agent, defoamer, anti-settling agent, wilkinite, titanium dioxide, quartz sand, coarse whiting, talcum powder, synthon are sequentially added in container successively, in stirrer, with 600-800 rev/min, disperse 10-15 minute to mixing;
(3) the above-mentioned main paint preparing and solidifying agent are mixed by the mass ratio of 2:0.8-1.2.
Environment-friendly epoxy seam cream of the present invention has the following advantages: the cohesive force of environment-friendly epoxy seam cream of the present invention is extremely strong, not only have advantages of not easy to crack, usage period length, water tolerance, firm wear-resisting, limits of harmful substances is very low, and there is good application property, the larger seam cream of aberration that environment-friendly epoxy seam cream of the present invention is a kind of main paint and solidifying agent simultaneously.
Embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail.
(1) embodiment is as follows:
A seam cream, is mixed by the mass ratio of 2:0.8-1.2 by main paint and solidifying agent, and wherein main paint and solidifying agent are formulated by following component and ratio of weight and number:
Wherein main paint component and ratio of weight and number are as follows:
Wherein curing agent component and ratio of weight and number are as follows:
The preparation method of above-mentioned environment-friendly epoxy seam cream, comprises following step:
(1), main paint is prepared according to following preparation method:
Epoxy resin, epoxy active diluent, phenylcarbinol, dispersion agent, defoamer, anti-settling agent, wilkinite, quartz sand, coarse whiting, talcum powder, synthon, epoxy carbon black are sequentially added in container successively, in stirrer, with 1000-1200 rev/min, disperse 10-15 minute to mixing;
(2), solidifying agent is prepared according to following preparation method:
Amine modified firming agent (R-3501), dispersion agent, defoamer, anti-settling agent, wilkinite, titanium dioxide, quartz sand, coarse whiting, talcum powder, synthon are sequentially added in container successively, in stirrer, with 600-800 rev/min, disperse 10-15 minute to mixing;
(3) the above-mentioned main paint preparing and solidifying agent are mixed by the mass ratio of 2:0.8-1.2.
Epoxy resin described in said components is E51, the E44 type that diphenylol propane tetraglycidel ether epoxy resin (bisphenol A epoxide resin) ，Ru Wuxi epoxy resin factory produces.Epoxy active diluent is glycidyl allyl ether; It adopts the AGE (glycidyl allyl ether) of the new Chemical Manufacture far away in Anhui.Dispersion agent is modified polyurethane solution.Anti-settling agent is hydrophobic type aerosil; It adopts the R972 type anti-settling agent of the production of German Degussa.Synthon are the chopped trevira of alkali-free that Hangzhou Jian Qing fibre product company limited produces.Amine modified firming agent is a kind of or its arbitrary combination of aliphatic amide family polyamines, alicyclic polyamine or its affixture of the auspicious strange Chemical Manufacture in Guangzhou; As R-3500, R-3501 type amine modified firming agent.It is the defoamer of modified silicon ketone that defoamer adopts major ingredient; The HX-2500 type defoamer that it adopts China to produce.Phenylcarbinol is that Hubei Green Homeland Fine Chemical Co., Ltd produces.It is the flow agent of polyacrylic ester interpolymer and fluorine-carbon modified polyacrylate(s) that flow agent adopts main component; As the BYK306 type flow agent of German Bi Ke chemical production.Described wilkinite is the SD-1 type wilkinite of this production of hamming.Described coarse whiting is the 1083 type coarse whitings that Fujian Sannong Group Co., Ltd. produces.Described quartz sand is the 200 order quartz sands that Foshan Zhen Xinming section produces.Described every kind of component also can adopt similar other type product.
(2) embodiment is as follows:
Embodiment 1: a kind of environment-friendly epoxy seam cream, by main paint and solidifying agent, by the mass ratio of 2:1, mixed, and wherein main paint and solidifying agent are formulated by following component and ratio of weight and number:
Wherein main paint component and ratio of weight and number are as follows:
Wherein curing agent component and ratio of weight and number are as follows:
A kind of preparation method of environment-friendly epoxy seam cream comprises following step:
(1), main paint is prepared according to following preparation method:
28 parts of epoxy resin, 4 parts of epoxy active diluents, 3 parts of phenylcarbinols, 0.3 part of dispersion agent, 0.3 part of defoamer, 1 portion of anti-settling agent, 2.5 parts of wilkinites, 13 parts of quartz sands, 30 parts of coarse whitings, 9.7 parts of talcum powder, 0.2 part of synthon, 8 parts of epoxy carbon blacks are sequentially added in container successively, in stirrer, with 1000 revs/min, disperse 10 minutes to mixing;
(2), solidifying agent is prepared according to following preparation method:
32 parts of amine modified firming agents, 0.3 part of dispersion agent, 0.3 part of defoamer, 1 portion of anti-settling agent, 2.5 parts of wilkinites, 3 parts of titanium dioxides, 12 parts of quartz sands, 34.7 parts of coarse whitings, 14 parts of talcum powder, 0.2 part of synthon are sequentially added in container successively, in stirrer, with 700 revs/min, disperse 12 minutes to mixing;
(3) the above-mentioned main paint preparing and solidifying agent are mixed by the mass ratio of 2:1.
Epoxy resin described in said components is the diphenylol propane tetraglycidel ether epoxy resin that Wuxi epoxy resin factory produces.Epoxy active diluent is the AGE (glycidyl allyl ether) of the new Chemical Manufacture far away in Anhui.Dispersion agent is modified polyurethane solution.Anti-settling agent is the R972 type anti-settling agent of the production of German Degussa.Synthon are the chopped trevira of alkali-free that Hangzhou Jian Qing fibre product company limited produces.Amine modified firming agent is the R-3500 type aliphatic amide family modified polyamine solidifying agent of the auspicious strange Chemical Manufacture in Guangzhou.The HX-2500 type defoamer that defoamer adopts China to produce.Phenylcarbinol is the phenylcarbinol that Hubei Green Homeland Fine Chemical Co., Ltd produces.Flow agent adopts the BYK306 type flow agent of German Bi Ke chemical production.Described wilkinite is the SD-1 type wilkinite of this production of hamming.Described coarse whiting is the 1083 type coarse whitings that Fujian Sannong Group Co., Ltd. produces.Described quartz sand is the 200 order quartz sands that Foshan Zhen Xinming section produces.Described every kind of component also can adopt similar other type product.
Through the test to the present embodiment, every technical performance index and the experimental data of environment-friendly epoxy seam cream of the present invention are as shown in the table:
Embodiment 2: a kind of environment-friendly epoxy seam cream, by main paint and solidifying agent, by the mass ratio of 2:0.8, mixed, and wherein main paint and solidifying agent are formulated by following component and ratio of weight and number:
Wherein main paint component and ratio of weight and number are as follows:
Wherein curing agent component and ratio of weight and number are as follows:
A kind of preparation method of environment-friendly epoxy seam cream comprises following step:
(1), main paint is prepared according to following preparation method:
32 parts of epoxy resin, 3 parts of epoxy active diluents, 4 parts of phenylcarbinols, 0.3 part of dispersion agent, 0.3 part of defoamer, 1 portion of anti-settling agent, 2.5 parts of wilkinites, 10.7 parts of quartz sands, 30 parts of coarse whitings, 8 parts of talcum powder, 0.2 part of synthon, 8 parts of epoxy carbon blacks are sequentially added in container successively, in stirrer, with 1200 revs/min, disperse 15 minutes to mixing;
(2), solidifying agent is prepared according to following preparation method:
36 parts of amine modified firming agents, 0.3 part of dispersion agent, 0.3 part of defoamer, 1 portion of anti-settling agent, 2.5 parts of wilkinites, 3.0 parts of titanium dioxides, 12 parts of quartz sands, 36.7 parts of coarse whitings, 8 parts of talcum powder, 0.2 part of synthon are sequentially added in container successively, in stirrer, with 800 revs/min, disperse 10 minutes to mixing;
(3) the above-mentioned main paint preparing and solidifying agent are mixed by the mass ratio of 2:0.8.
Epoxy resin described in said components is the diphenylol propane tetraglycidel ether epoxy resin that Wuxi epoxy resin factory produces.Epoxy active diluent is the AGE (glycidyl allyl ether) of the new Chemical Manufacture far away in Anhui.Dispersion agent is modified polyurethane solution.Anti-settling agent is the R972 type anti-settling agent of the production of German Degussa.Synthon are the chopped trevira of alkali-free that Hangzhou Jian Qing fibre product company limited produces.Amine modified firming agent is the R-3501 type alicyclic polyamine modified firming agent of the auspicious strange Chemical Manufacture in Guangzhou.The HX-2500 type defoamer that defoamer adopts China to produce.Phenylcarbinol is the phenylcarbinol that Hubei Green Homeland Fine Chemical Co., Ltd produces.Flow agent adopts the BYK306 type flow agent of German Bi Ke chemical production.Described wilkinite is the SD-1 type wilkinite of this production of hamming.Described coarse whiting is the 1083 type coarse whitings that Fujian Sannong Group Co., Ltd. produces.Described quartz sand is the 200 order quartz sands that Foshan Zhen Xinming section produces.Described every kind of component also can adopt similar other type product.
Through the test to the present embodiment, every technical performance index and the experimental data of environment-friendly epoxy seam cream of the present invention are as shown in the table:
Embodiment 3: a kind of environment-friendly epoxy seam cream, by main paint and solidifying agent, by the mass ratio of 2:1.2, mixed, and wherein main paint and solidifying agent are formulated by following component and ratio of weight and number:
Wherein main paint component and ratio of weight and number are as follows:
Wherein curing agent component and ratio of weight and number are as follows:
A kind of preparation method of environment-friendly epoxy seam cream comprises following step:
(1), main paint is prepared according to following preparation method:
26 parts of epoxy resin, 2 parts of epoxy active diluents, 5 parts of phenylcarbinols, 0.3 part of dispersion agent, 0.3 part of defoamer, 1 portion of anti-settling agent, 2.5 parts of wilkinites, 11.7 parts of quartz sands, 26 parts of coarse whitings, 7 parts of talcum powder, 0.2 part of synthon, 8 parts of epoxy carbon blacks are sequentially added in container successively, in stirrer, with 1100 revs/min, disperse 10 minutes to mixing;
(2), solidifying agent is prepared according to following preparation method:
38 parts of amine modified firming agents, 0.3 part of dispersion agent, 0.3 part of defoamer, 1 portion of anti-settling agent, 2.5 parts of wilkinites, 3.0 parts of titanium dioxides, 11 parts of quartz sands, 33.7 parts of coarse whitings, 10 parts of talcum powder, 0.2 part of synthon are sequentially added in container successively, in stirrer, with 600 revs/min, disperse 15 minutes to mixing;
(3) the above-mentioned main paint preparing and solidifying agent are mixed by the mass ratio of 2:1.2.
Epoxy resin described in said components is the diphenylol propane tetraglycidel ether epoxy resin that Wuxi epoxy resin factory produces.Epoxy active diluent is the AGE (glycidyl allyl ether) of the new Chemical Manufacture far away in Anhui.Dispersion agent is modified polyurethane solution.Anti-settling agent is the R972 type anti-settling agent of the production of German Degussa.Synthon are the chopped trevira of alkali-free that Hangzhou Jian Qing fibre product company limited produces.Amine modified firming agent is that 18 parts of R-3501 type aliphatic amide family's modified polyamine solidifying agent and 20 parts of R-3501 alicyclic polyamine modified firming agents of the auspicious strange Chemical Manufacture in Guangzhou mix.The HX-2500 type defoamer that defoamer adopts China to produce.Phenylcarbinol is the phenylcarbinol that Hubei Green Homeland Fine Chemical Co., Ltd produces.Flow agent adopts the BYK306 type flow agent of German Bi Ke chemical production.Described wilkinite is the SD-1 type wilkinite of this production of hamming.Described coarse whiting is the 1083 type coarse whitings that Fujian Sannong Group Co., Ltd. produces.Described quartz sand is the 200 order quartz sands that Foshan Zhen Xinming section produces.Described every kind of component also can adopt similar other type product.
Through the test to the present embodiment, every technical performance index and the experimental data of environment-friendly epoxy seam cream of the present invention are as shown in the table:
Test result from the above embodiments: the present invention possesses higher cohesive strength, and harmful substance contents is low, water-fast, acidproof, alkaline-resisting, and there is good application property.
Above-mentioned embodiment is just explained in detail technical scheme of the present invention, and the present invention has more than and is only confined to above-described embodiment, and every any improvement or replacement according to the principle of the invention, all should be within protection scope of the present invention.
Claims (10)
1. an environment-friendly epoxy seam cream, is characterized in that, by main paint and solidifying agent, by the mass ratio of 2:0.8-1.2, is mixed, and wherein main paint and solidifying agent are formulated by following component and ratio of weight and number:
Wherein main paint component and ratio of weight and number are as follows:
Wherein curing agent component and ratio of weight and number are as follows:
2. environment-friendly epoxy seam cream according to claim 1, is characterized in that: described epoxy resin is diphenylol propane Racemic glycidol ether type epoxy.
3. environment-friendly epoxy seam cream according to claim 1, is characterized in that: described epoxy active diluent is glycidyl allyl ether.
4. environment-friendly epoxy seam cream according to claim 1, is characterized in that: described dispersion agent is modified polyurethane solution.
5. environment-friendly epoxy seam cream according to claim 1, is characterized in that: described anti-settling agent is hydrophobic type aerosil; Synthon are the chopped trevira of alkali-free.
6. environment-friendly epoxy type seam cream according to claim 1, is characterized in that: described amine modified firming agent is a kind of or its arbitrary combination of aliphatic amide family polyamines, alicyclic polyamine or its affixture.
7. environment-friendly epoxy seam cream according to claim 1, is characterized in that: it is the defoamer of modified silicon ketone that described defoamer adopts major ingredient.
8. environment-friendly epoxy seam cream according to claim 1, is characterized in that: it is the flow agent of polyacrylic ester interpolymer and fluorine-carbon modified polyacrylate(s) that described flow agent adopts main component.
9. a preparation method for the environment-friendly epoxy seam cream described in any one in claim 1-8, is characterized in that: comprise following step:
(1), main paint is prepared according to following preparation method:
Epoxy resin, epoxy active diluent, phenylcarbinol, dispersion agent, defoamer, anti-settling agent, wilkinite, quartz sand, coarse whiting, talcum powder, synthon, epoxy carbon black are added in container, under the rotating speed of 1000-1200 rev/min, disperse 10-15 minute to mixing;
(2), solidifying agent is prepared according to following preparation method:
Amine modified firming agent, dispersion agent, defoamer, anti-settling agent, wilkinite, titanium dioxide, quartz sand, coarse whiting, talcum powder, synthon are added in container, under the rotating speed of 600-800 rev/min, disperse 10-15 minute to mixing.
10. the preparation method of environment-friendly epoxy seam cream according to claim 9, is characterized in that: described main paint and solidifying agent have been prepared rear packing respectively, during use, the above-mentioned main paint preparing and solidifying agent are mixed by the mass ratio of 2:0.8-1.2.
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| CN201310435281.9A CN103509507B (en) | 2013-09-23 | 2013-09-23 | A kind of environment-friendly epoxy seam cream and preparation method thereof |
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| CN201310435281.9A CN103509507B (en) | 2013-09-23 | 2013-09-23 | A kind of environment-friendly epoxy seam cream and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104263300A (en) * | 2014-09-04 | 2015-01-07 | 三棵树涂料股份有限公司 | Environmental-friendly dry-hanging adhesive and preparation method thereof |
| CN104788901A (en) * | 2015-04-07 | 2015-07-22 | 郑州中德新亚建筑材料有限公司 | Super-fluid epoxy resin grouting material with superior working performance and super-high resistance to freezing and thawing cycle |
| CN106349954A (en) * | 2016-08-29 | 2017-01-25 | 郑丽芬 | Double-component tile-seam filling agent |
| CN106590497A (en) * | 2016-12-21 | 2017-04-26 | 兰州科天环保节能科技有限公司 | Formaldehyde-free aqueous jointing agent and preparation method therefor |
| CN106753122A (en) * | 2016-12-06 | 2017-05-31 | 长江大学 | A kind of epoxy joint glue and preparation method thereof |
| CN106867447A (en) * | 2017-01-19 | 2017-06-20 | 福建沃斯盾建材有限公司 | A kind of joint mixture and preparation method thereof |
| CN107384274A (en) * | 2016-05-16 | 2017-11-24 | 卡本复合材料（天津）有限公司 | A kind of epoxy sealing compound bonded applied to underwater glass fiber composite material seam and preparation method thereof |
| CN108178999A (en) * | 2017-12-26 | 2018-06-19 | 湖南神力铃胶粘剂制造有限公司 | A kind of seam double-component epoxy adhesive and preparation method thereof |
| CN108841288A (en) * | 2018-05-24 | 2018-11-20 | 厦门东顺涂料有限公司 | Aqueous U.S. seam cream |
| CN111040697A (en) * | 2019-12-17 | 2020-04-21 | 佛山科学技术学院 | Flame-retardant adhesive and preparation method thereof |
| CN112300662A (en) * | 2020-11-06 | 2021-02-02 | 福建省高镖建材有限公司 | Anti-cracking coating and preparation method thereof |
| CN114686147A (en) * | 2022-03-10 | 2022-07-01 | 华新水泥股份有限公司 | Bi-component water-based joint material |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263300A (en) * | 2014-09-04 | 2015-01-07 | 三棵树涂料股份有限公司 | Environmental-friendly dry-hanging adhesive and preparation method thereof |
| CN104788901A (en) * | 2015-04-07 | 2015-07-22 | 郑州中德新亚建筑材料有限公司 | Super-fluid epoxy resin grouting material with superior working performance and super-high resistance to freezing and thawing cycle |
| CN104788901B (en) * | 2015-04-07 | 2018-01-09 | 郑州中德新亚建筑材料有限公司 | With the super freeze-thawing resistant circulation epoxy resin grouting material of superior workability superfluidity |
| CN107384274A (en) * | 2016-05-16 | 2017-11-24 | 卡本复合材料（天津）有限公司 | A kind of epoxy sealing compound bonded applied to underwater glass fiber composite material seam and preparation method thereof |
| CN106349954A (en) * | 2016-08-29 | 2017-01-25 | 郑丽芬 | Double-component tile-seam filling agent |
| CN106753122A (en) * | 2016-12-06 | 2017-05-31 | 长江大学 | A kind of epoxy joint glue and preparation method thereof |
| CN106590497A (en) * | 2016-12-21 | 2017-04-26 | 兰州科天环保节能科技有限公司 | Formaldehyde-free aqueous jointing agent and preparation method therefor |
| CN106867447A (en) * | 2017-01-19 | 2017-06-20 | 福建沃斯盾建材有限公司 | A kind of joint mixture and preparation method thereof |
| CN108178999A (en) * | 2017-12-26 | 2018-06-19 | 湖南神力铃胶粘剂制造有限公司 | A kind of seam double-component epoxy adhesive and preparation method thereof |
| CN108841288A (en) * | 2018-05-24 | 2018-11-20 | 厦门东顺涂料有限公司 | Aqueous U.S. seam cream |
| CN111040697A (en) * | 2019-12-17 | 2020-04-21 | 佛山科学技术学院 | Flame-retardant adhesive and preparation method thereof |
| CN112300662A (en) * | 2020-11-06 | 2021-02-02 | 福建省高镖建材有限公司 | Anti-cracking coating and preparation method thereof |
| CN114686147A (en) * | 2022-03-10 | 2022-07-01 | 华新水泥股份有限公司 | Bi-component water-based joint material |
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| CN103509507B (en) | 2016-04-20 |
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