CN103509215A - Chloroprene/tetrafluoroethylene-propylene rubber composite cable sheath material for ships and preparation method thereof - Google Patents
Chloroprene/tetrafluoroethylene-propylene rubber composite cable sheath material for ships and preparation method thereof Download PDFInfo
- Publication number
- CN103509215A CN103509215A CN201310390614.0A CN201310390614A CN103509215A CN 103509215 A CN103509215 A CN 103509215A CN 201310390614 A CN201310390614 A CN 201310390614A CN 103509215 A CN103509215 A CN 103509215A
- Authority
- CN
- China
- Prior art keywords
- parts
- viton
- oxide
- preparation
- sheath material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention discloses a chloroprene/tetrafluoroethylene-propylene rubber composite cable sheath material for ships and a preparation method thereof. The sheath material is prepared from the following raw materials in parts by weight: 60-80 parts of chloroprene rubber, 20-30 parts of tetrafluoroethylene-propylene rubber, 10-15 parts of SIS, 10-15 parts of magnesium hydroxide, 5-10 parts of aluminium hydroxide, 5-10 parts of antimony trioxide, 15-20 parts of carbon black N990, 1-2 parts of zinc oxide, 2-3 parts of magnesium oxide, 8-12 parts of octyl epoxy stearate, 10-15 parts of dihexyl phthalate, 5-10 parts of diisooctyl azelate, 1-2 parts of antiager DNP, 1-2 parts of antiager ODA, 2-3 parts of promoter DPTT, 0.5-1.5 parts of antioxidant 1330, 1-1.5 parts of di(tert-butylperoxyisopropyl)benzene, 5-6 parts of triallyl isocyanurate, 10-15 parts of nanometer attapulgite, 8-12 parts of asbestos powder and 4-8 parts of a composite filling material. The cable material of the invention is excellent in comprehensive performances, excellent in acid-base resistance, oil resistance, thermal aging resistance, weather proofness and the like, also good in flame retardance, extremely less in smoke generating amount during combustion, none in generated toxic gas, none in generated corrosive gas, completely environment-friendly, and widely applicable to cable sheaths for the ships.
Description
Technical field
The present invention relates to a kind of CABLE MATERIALS and preparation method thereof, be specifically related to a kind of neoprene peculiar to vessel/4 third viton compound cable sheath material and preparation method thereof.
Background technology
Shipboard cable claims again marine power cables, is a kind of electric wire of use of electric power, illumination and general control for aquatic buildings such as the river various boats and ships in sea and offshore oil platforms.Although problems such as now widely used shipboard cable has solved fire-retardant, low cigarette, Halogens, acid and alkali-resistance, heat-proof aging, the performance such as weather-proof still have much room for improvement.
Summary of the invention
The object of the present invention is to provide a kind of neoprene peculiar to vessel/4 third viton compound cable sheath material and preparation method thereof, improve the acid and alkali-resistance, heat-proof aging of shipboard cable material, the performance such as weather-proof.
The technical solution used in the present invention is as follows:
A kind of neoprene peculiar to vessel/4 the third viton compound cable sheath material, raw material by following weight part is made: chloroprene rubber 60-80, 4 third viton 20-30, SIS10-15, magnesium hydroxide 10-15, aluminium hydroxide 5-10, antimonous oxide 5-10, carbon black N990 15-20, zinc oxide 1-2, magnesium oxide 2-3, octyl epoxy stearate 8-12, dihexyl phthalate 10-15, diisooctyl azelate 5-10, antioxidant D NP1-2, anti-aging agent ODA1-2, vulkacit D PTT2-3, oxidation inhibitor 1330 0.5-1.5, dual-tert-butyl peroxy isopropyl base benzene 1-1.5, cyanacrylate 5-6, nano-attapulgite 10-15, asbestos powder 8-12, compounded mix 4-8,
The preparation method of described compounded mix is as follows: a. takes off the raw material of row weight part: diatomite 8-12, wollastonite 6-10, nano titanium oxide 3-5, nanometer silicon carbide 4-8, vinyl three ('beta '-methoxy oxyethyl group) silane 2-3, lanthanum trioxide 2-3, Praseodymium trioxide 1-2, octyl epoxy stearate 10-15, dimethyl silicone oil 3-6, trimethylolpropane trimethacrylate 1-2, clorafin 5-8, brucite powder 3-6, boron rock ground-slag 2-3, accelerant N A-221-2; B, bauxitic clay, wollastonite are calcined to 4-6 hour at 480-520 ℃, be cooled to after room temperature, putting into concentration is that 10-15% hydrochloric acid soln boils 20-30 minute, take out washing to neutral, after drying, pulverizing, mix with nano titanium oxide, nanometer silicon carbide, vinyl three ('beta '-methoxy oxyethyl group) silane, brucite powder and boron rock ground-slag, 3000-5000rpm speed lapping 15-20 minute, crosses 300-400 mesh sieve; C, the powder after sieving is mixed and be get final product with all the other raw materials.
The preparation method of neoprene peculiar to vessel/4 the third viton compound cable sheath material, comprises the following steps:
(1) get chloroprene rubber, viton, magnesium hydroxide, aluminium hydroxide, carbon black N990, magnesium oxide, dihexyl phthalate, antioxidant D NP, nano-attapulgite and add in rubber mixing machine, refine glue 5-8min at 85-90 ℃, blanking, obtains sizing material A;
(2) get 4 third viton, SIS, antimonous oxide, zinc oxide, diisooctyl azelate, anti-aging agent ODA, asbestos powder, compounded mix and add in rubber mixing machine, refine glue 4-6min at 75-85 ℃, blanking, obtains sizing material B;
(3) gained sizing material A, sizing material B and all the other raw materials are together sent in twin screw extruder, carry out mixing, the processing temperature of each section of twin screw extruder is set as respectively: first paragraph 145-155 ℃, second segment 150-160 ℃, the 3rd section of 165-175 ℃, the 4th section of 170-180 ℃, the 5th section of 175-185 ℃, die head temperature 180-190 ℃, finally by air-cooled granulation, obtain required CABLE MATERIALS.
Beneficial effect of the present invention:
CABLE MATERIALS excellent combination property of the present invention, has good acid and alkali-resistance, oil resistant, heat-proof aging, the performance such as weather-proof, simultaneously good flame retardation effect, during burning, the amount of being fuming is considerably less, does not produce toxic gas, does not produce corrosive gases, environmental protection completely, can be widely used in shipboard cable sheath.
Embodiment
A kind of neoprene peculiar to vessel/4 the third viton compound cable sheath material, raw material by following weight (kg) is made: chloroprene rubber 70, 4 third viton 20, SIS10, magnesium hydroxide 12, aluminium hydroxide 8, antimonous oxide 7, carbon black N990 18, zinc oxide 1.5, magnesium oxide 2, octyl epoxy stearate 10, dihexyl phthalate 10, diisooctyl azelate 6, antioxidant D NP1, anti-aging agent ODA2, vulkacit D PTT2, oxidation inhibitor 1,330 0.8, dual-tert-butyl peroxy isopropyl base benzene 1, cyanacrylate 5, nano-attapulgite 10, asbestos powder 10, compounded mix 6,
The preparation method of described compounded mix is as follows: a. takes off the raw material of column weight amount (kg): diatomite 8, wollastonite 10, nano titanium oxide 4, nanometer silicon carbide 6, vinyl three ('beta '-methoxy oxyethyl group) silane 2, lanthanum trioxide 2, Praseodymium trioxide 1, octyl epoxy stearate 10, dimethyl silicone oil 4, trimethylolpropane trimethacrylate 1.5, clorafin 6, brucite powder 4, boron rock ground-slag 2, accelerant N A-22 1.5; B, bauxitic clay, wollastonite are calcined 5 hours at 490 ℃, be cooled to after room temperature, putting into concentration is that 10% hydrochloric acid soln boils 25 minutes, take out washing to neutral, after drying, pulverizing, mix with nano titanium oxide, nanometer silicon carbide, vinyl three ('beta '-methoxy oxyethyl group) silane, brucite powder and boron rock ground-slag, 5000rpm speed lapping 15 minutes, crosses 300 mesh sieves; C, the powder after sieving is mixed and be get final product with all the other raw materials.
The preparation method of neoprene peculiar to vessel/4 the third viton compound cable sheath material, comprises the following steps:
(1) get chloroprene rubber, viton, magnesium hydroxide, aluminium hydroxide, carbon black N990, magnesium oxide, dihexyl phthalate, antioxidant D NP, nano-attapulgite and add in rubber mixing machine, refine glue 6min at 90 ℃, blanking, obtains sizing material A;
(2) get 4 third viton, SIS, antimonous oxide, zinc oxide, diisooctyl azelate, anti-aging agent ODA, asbestos powder, compounded mix and add in rubber mixing machine, refine glue 4min at 85 ℃, blanking, obtains sizing material B;
(3) gained sizing material A, sizing material B and all the other raw materials are together sent in twin screw extruder, carry out mixing, the processing temperature of each section of twin screw extruder is set as respectively: 150 ℃ of first paragraphs, 160 ℃ of second segments, the 3rd section 170 ℃, the 4th section 175 ℃, the 5th section 180 ℃, 185 ℃ of die head temperatures, finally by air-cooled granulation, obtain required CABLE MATERIALS.
The performance test results of the CABLE MATERIALS making is as follows:
Claims (2)
1. a neoprene peculiar to vessel/4 third viton compound cable sheath material, it is characterized in that, raw material by following weight part is made: chloroprene rubber 60-80, 4 third viton 20-30, SIS 10-15, magnesium hydroxide 10-15, aluminium hydroxide 5-10, antimonous oxide 5-10, carbon black N990 15-20, zinc oxide 1-2, magnesium oxide 2-3, octyl epoxy stearate 8-12, phthalic acid two is ester 10-15, diisooctyl azelate 5-10, antioxidant D NP 1-2, anti-aging agent ODA 1-2, vulkacit D PTT 2-3, oxidation inhibitor 1330 0.5-1.5, dual-tert-butyl peroxy isopropyl base benzene 1-1.5, cyanacrylate 5-6, nano-attapulgite 10-15, asbestos powder 8-12, compounded mix 4-8,
The preparation method of described compounded mix is as follows: a. takes off the raw material of row weight part: diatomite 8-12, wollastonite 6-10, nano titanium oxide 3-5, nanometer silicon carbide 4-8, vinyl three ('beta '-methoxy oxyethyl group) silane 2-3, lanthanum trioxide 2-3, Praseodymium trioxide 1-2, octyl epoxy stearate 10-15, dimethyl silicone oil 3-6, trimethylolpropane trimethacrylate 1-2, clorafin 5-8, brucite powder 3-6, boron rock ground-slag 2-3, accelerant N A-22 1-2; B, bauxitic clay, wollastonite are calcined to 4-6 hour at 480-520 ℃, be cooled to after room temperature, putting into concentration is that 10-15% hydrochloric acid soln boils 20-30 minute, take out washing to neutral, after drying, pulverizing, mix with nano titanium oxide, nanometer silicon carbide, vinyl three ('beta '-methoxy oxyethyl group) silane, brucite powder and boron rock ground-slag, 3000-5000rpm speed lapping 15-20 minute, crosses 300-400 mesh sieve; C, the powder after sieving is mixed and be get final product with all the other raw materials.
2. the preparation method of neoprene peculiar to vessel/4 the third viton compound cable sheath material as claimed in claim 1, is characterized in that comprising the following steps:
(1) get chloroprene rubber, viton, magnesium hydroxide, aluminium hydroxide, carbon black N990, magnesium oxide, phthalic acid two ester, antioxidant D NP, nano-attapulgite add in rubber mixing machine, at 85-90 ℃, refine glue 5-8min, blanking, obtains sizing material A;
Get 4 third viton, SIS, antimonous oxide, zinc oxide, diisooctyl azelate, anti-aging agent ODA, asbestos powder, compounded mix and add in rubber mixing machine, refine glue 4-6min at 75-85 ℃, blanking, obtains sizing material B;
(2) gained sizing material A, sizing material B and all the other raw materials are together sent in twin screw extruder, carry out mixing, the processing temperature of each section of twin screw extruder is set as respectively: first paragraph 145-155 ℃, second segment 150-160 ℃, the 3rd section of 165-175 ℃, the 4th section of 170-180 ℃, the 5th section of 175-185 ℃, die head temperature 180-190 ℃, finally by air-cooled granulation, obtain required CABLE MATERIALS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310390614.0A CN103509215B (en) | 2013-08-30 | 2013-08-30 | A kind of neoprene peculiar to vessel/4 third viton compound cable sheath material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310390614.0A CN103509215B (en) | 2013-08-30 | 2013-08-30 | A kind of neoprene peculiar to vessel/4 third viton compound cable sheath material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103509215A true CN103509215A (en) | 2014-01-15 |
| CN103509215B CN103509215B (en) | 2016-01-20 |
Family
ID=49892673
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310390614.0A Active CN103509215B (en) | 2013-08-30 | 2013-08-30 | A kind of neoprene peculiar to vessel/4 third viton compound cable sheath material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103509215B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105427918A (en) * | 2016-01-10 | 2016-03-23 | 叶玉浩 | Waterproof wire |
| CN105778266A (en) * | 2016-05-18 | 2016-07-20 | 王维娜 | High-strength oil resistant cable material and preparation method thereof |
| CN106084774A (en) * | 2016-08-29 | 2016-11-09 | 安徽省康利亚股份有限公司 | A kind of outdoor Sun-proof nylon cable material and preparation method thereof |
| CN107325462A (en) * | 2017-05-16 | 2017-11-07 | 安徽瑞鑫自动化仪表有限公司 | A kind of subsurface environment rubber sheath |
| CN107383507A (en) * | 2017-08-21 | 2017-11-24 | 安徽意力电缆有限公司 | A kind of anti-aging Composite rubber cable material |
| CN107828103A (en) * | 2016-10-09 | 2018-03-23 | 芜湖瑞德机械科技有限公司 | Oil-resisting and heat-resisting automobile engine hollow tube and preparation method thereof |
| CN112552626A (en) * | 2020-11-28 | 2021-03-26 | 温州网牌电线电缆有限公司 | Anti-aging cable and processing technology thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1156493A1 (en) * | 2000-05-19 | 2001-11-21 | Sagem Sa | Crosslinkable semi-conductive composition and electrical cable with semi-conductive film |
| CN101613504A (en) * | 2009-07-24 | 2009-12-30 | 青岛中阳消防科技有限公司 | A kind of material and preparation method with temperature sensing cable material of CRT characteristic |
-
2013
- 2013-08-30 CN CN201310390614.0A patent/CN103509215B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1156493A1 (en) * | 2000-05-19 | 2001-11-21 | Sagem Sa | Crosslinkable semi-conductive composition and electrical cable with semi-conductive film |
| CN101613504A (en) * | 2009-07-24 | 2009-12-30 | 青岛中阳消防科技有限公司 | A kind of material and preparation method with temperature sensing cable material of CRT characteristic |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105427918A (en) * | 2016-01-10 | 2016-03-23 | 叶玉浩 | Waterproof wire |
| CN105778266A (en) * | 2016-05-18 | 2016-07-20 | 王维娜 | High-strength oil resistant cable material and preparation method thereof |
| CN106084774A (en) * | 2016-08-29 | 2016-11-09 | 安徽省康利亚股份有限公司 | A kind of outdoor Sun-proof nylon cable material and preparation method thereof |
| CN107828103A (en) * | 2016-10-09 | 2018-03-23 | 芜湖瑞德机械科技有限公司 | Oil-resisting and heat-resisting automobile engine hollow tube and preparation method thereof |
| CN107841015A (en) * | 2016-10-09 | 2018-03-27 | 芜湖瑞德机械科技有限公司 | A kind of oil-resisting and heat-resisting automobile engine hollow tube and preparation method thereof |
| CN107325462A (en) * | 2017-05-16 | 2017-11-07 | 安徽瑞鑫自动化仪表有限公司 | A kind of subsurface environment rubber sheath |
| CN107383507A (en) * | 2017-08-21 | 2017-11-24 | 安徽意力电缆有限公司 | A kind of anti-aging Composite rubber cable material |
| CN112552626A (en) * | 2020-11-28 | 2021-03-26 | 温州网牌电线电缆有限公司 | Anti-aging cable and processing technology thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103509215B (en) | 2016-01-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103509215B (en) | A kind of neoprene peculiar to vessel/4 third viton compound cable sheath material and preparation method thereof | |
| CN104151739B (en) | A kind of fireproof high-temperature resistant cable material and preparation method thereof | |
| CN103509274A (en) | Oil-resistant cold-resistant ultraviolet-proof polyvinyl chloride/nitrile rubber composite cable material and preparation method thereof | |
| CN102746593B (en) | A kind of Nitrile rubber insulation flat cable material and preparation method thereof | |
| CN103509350B (en) | A kind of cables of nuclear power high-temperature resistant water vapor sheath material and preparation method thereof | |
| CN103509257A (en) | 105 DEG C low-smoke zero-halogen flame-retardant ethylene-propylene-diene monomer cable material and preparation method thereof | |
| CN102977609B (en) | A kind of oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel and preparation method thereof | |
| CN103509349A (en) | Rubber-sheathed cable material for coal mines and preparation method thereof | |
| CN105957631B (en) | A kind of flexible cable and preparation method thereof | |
| CN104151735A (en) | High-strength flame-retardant cable and application thereof | |
| CN104109302A (en) | Aerial insulation cable material | |
| CN104109306A (en) | Optical fiber cable-used insulated cable material and preparation method thereof | |
| CN103509256A (en) | Oil-resistant low-temperature-resistant cable material and preparation method thereof | |
| CN102391567A (en) | Environmentally-friendly polyethylene cable material and preparation method thereof | |
| CN205451840U (en) | Resistant pottery fireproof cable of waiting | |
| CN104961928A (en) | Environment-friendly low-smoke flame-retardant rubber cable material and preparation method thereof | |
| CN102746609B (en) | A kind of eco-type flame retardant compound and preparation method thereof | |
| CN105153601A (en) | Low-temperature-resistant flame-retardant cable for ship | |
| CN104151746B (en) | A kind of environmental protection flame retardant insulating material and application in the cable thereof | |
| CN104804379A (en) | Insulating material for cable | |
| CN102746564A (en) | Modified electric cable material with characteristics of high temperature resistance and corrosion resistance, and preparation method thereof | |
| CN103524907A (en) | Mine cable rubber sheath material and preparation method | |
| CN109456535A (en) | A kind of flame-retardant and fire-resistant wire and cable material and preparation method thereof | |
| CN103509261B (en) | One does not prolong combustion CPE eraser sheath material and preparation method thereof | |
| CN110791043A (en) | Environment-friendly-40-DEG C-resistant polyvinyl chloride sheath material for 5G communication cable and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |