CN103497298B - 一种隔热保温无氟聚氨酯泡沫材料 - Google Patents
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Abstract
本发明公开了一种隔热保温无氟聚氨酯泡沫材料,其特征在于由下列重量份的A、B料混合、浇注、反应、熟化制成:A料:过氯乙烯树脂11-16、聚醚多元醇100、脂肪醇聚氧乙烯醚9-13、水3-4、辛酸钾2-3、水2-3、苯骈三氮唑2.0-3.0、云母粉25-35、聚乙烯醇3-4、木质素磺酸钙1-2、纳米铝矾土14-20、聚乙烯吡咯烷酮2-3、改性凹凸棒土6-8;B料:异氰酸酯19-24。本发明化学性质稳定,使用寿命长,采用水和醚做发泡剂,无氟环保,对环境友好;添加改性凹凸棒土,具有较好的阻燃效果,防火安全性能好;本发明具有独特的隔热保温效果和防水效果。
Description
技术领域
本发明涉及一种泡沫,特别是一种隔热保温无氟聚氨酯泡沫材料。
背景技术
聚氨酯泡沫塑料是异氰酸酯和羟基化合物经聚合发泡制成,按其硬度可分为软质和硬质两类,其中软质为主要品种。一般来说,它具有极佳的弹性、柔软性、伸长率和压缩强度;化学稳定性好,耐许多溶剂和油类;耐磨性优良,较天然海绵大20倍;还有优良的加工性、绝热性、粘合性等性能,是一种性能优良的缓冲材料,但价格较高。聚氨酯泡沫塑料一般只用于高档精密仪器、贵重器械、高档工艺品等的缓冲包装或衬垫缓冲材料,也可制成精致的、保护性极好的包装容器;还可采用现场发泡对物品进行缓冲包装。
无氟聚氨酯硬质泡沫作为太阳能热水器中的保温材料,已被国内外业内人士普遍认可,它优异的绝热性能是任何一种高分子材料所不可比拟的,除此之外,它的抗压、防水、阻燃、耐酸碱腐蚀等性能也远比聚苯乙烯、岩棉、珍珠岩等其他保温材料好。
发明内容
本发明的目的是提供一种隔热保温无氟聚氨酯泡沫材料。
为了实现本发明的目的,本发明通过以下方案实施:
一种隔热保温无氟聚氨酯泡沫材料,由下列重量份的A、B料混合、浇注、反应、熟化制成:
A料:过氯乙烯树脂11-16、聚醚多元醇100、脂肪醇聚氧乙烯醚9-13、水3-4、辛酸钾2-3、水2-3、苯骈三氮唑2.0-3.0、云母粉25-35、聚乙烯醇3-4、木质素磺酸钙1-2、纳米铝矾土14-20、聚乙烯吡咯烷酮2-3、改性凹凸棒土6-8;
B料:异氰酸酯19-24。
所述改性凹凸棒土通过以下方法制备:称取下列重量份的原料:凹凸棒土150-155、玉石3-4、玫瑰精油1-2、秸秆灰烬50-55、硅烷偶联剂KH5501-2、碳酸氢钠2-3、季戊四醇三丙烯酸酯2-3、甘油三醋酸酯1-2、交联剂TAC1-2、氢氧化铝3-4;制备方法是将凹凸棒土、玉石放入煅烧炉中,在610-630℃下煅烧3-4小时,取出,与秸秆灰烬、碳酸氢钠混合,研磨至得到300-400目粉末,然后,再加入季戊四醇三丙烯酸酯、氢氧化铝、硅烷偶联剂KH550混合,继续研磨30-45分钟,至充分分散,再加入其它剩余成分,继续研磨30-45分钟后,在1500-1800转/分下搅拌15-30分钟,即得改性凹凸棒土。
本发明所述隔热保温无氟聚氨酯泡沫材料,由以下具体步骤制备而成:
将A料各原料混合,在常温下研磨20-30分钟,得到浆料;再将B料加入A料中,200-300转/分搅拌30-45秒;浇注到模具中自由发泡,获得模坯;然后,连同模具一起将模坯送入隧道式烘箱中,分段升温:40-45℃下,反应15-25分钟;再在55-65℃下,反应10-15分钟;再在75-85℃下,反应5-10分钟;最后在90-100℃下熟化5-7小时。
本发明化学性质稳定,使用寿命长,采用水和醚做发泡剂,无氟环保,对环境友好;添加改性凹凸棒土,具有较好的阻燃效果,防火安全性能好;本发明具有独特的隔热保温效果和防水效果。
具体实施方案
下面通过具体实例对本发明进行详细说明。
一种隔热保温无氟聚氨酯泡沫材料,由下列重量份的A、B料混合、浇注、反应、熟化制成:
A料:各原料重量份为(重量份为公斤):过氯乙烯树脂11、聚醚多元醇100、脂肪醇聚氧乙烯醚9、水3、辛酸钾2、水2、苯骈三氮唑2.0、云母粉25、聚乙烯醇3、木质素磺酸钙1、纳米铝矾土14、聚乙烯吡咯烷酮2、改性凹凸棒土6;
B料:各原料重量份为(重量份为公斤):异氰酸酯19。
所述改性凹凸棒土通过以下方法制备:称取下列重量份(公斤)的原料:凹凸棒土150、玉石3、玫瑰精油1、秸秆灰烬50、硅烷偶联剂KH5501、碳酸氢钠2、季戊四醇三丙烯酸酯2、甘油三醋酸酯1、交联剂TAC1、氢氧化铝3;制备方法是将凹凸棒土、玉石放入煅烧炉中,在610-630℃下煅烧3-4小时,取出,与秸秆灰烬、碳酸氢钠混合,研磨至得到300-400目粉末,然后,再加入季戊四醇三丙烯酸酯、氢氧化铝、硅烷偶联剂KH550混合,继续研磨30-45分钟,至充分分散,再加入其它剩余成分,继续研磨30-45分钟后,在1500-1800转/分下搅拌15-30分钟,即得改性凹凸棒土。
本发明所述隔热保温无氟聚氨酯泡沫材料,由以下具体步骤制备而成:
将A料各原料混合,在常温下研磨20-30分钟,得到浆料;再将B料加入A料中,200-300转/分搅拌30-45秒;浇注到模具中自由发泡,获得模坯;然后,连同模具一起将模坯送入隧道式烘箱中,分段升温:40-45℃下,反应15-25分钟;再在55-65℃下,反应10-15分钟;再在75-85℃下,反应5-10分钟;最后在90-100℃下熟化5-7小时。
所得的材料各功能参数如下:压缩强度(MPa):0.26,氧指数:31,导热系数(W/mK):0.031。
Claims (1)
1.一种隔热保温无氟聚氨酯泡沫材料,其特征在于由下列重量份的A、B料混合、浇注、反应、熟化制成:
A料:过氯乙烯树脂11-16、聚醚多元醇100、脂肪醇聚氧乙烯醚9-13、水3-4、辛酸钾2-3、水2-3、苯骈三氮唑2.0-3.0、云母粉25-35、聚乙烯醇3-4、木质素磺酸钙1-2、纳米铝矾土14-20、聚乙烯吡咯烷酮2-3、改性凹凸棒土6-8;
B料:异氰酸酯19-24;
所述改性凹凸棒土通过以下方法制备:称取下列重量份的原料:凹凸棒土150-155、玉石3-4、玫瑰精油1-2、秸秆灰烬50-55、硅烷偶联剂KH5501-2、碳酸氢钠2-3、季戊四醇三丙烯酸酯2-3、甘油三醋酸酯1-2、交联剂TAC1-2、氢氧化铝3-4;制备方法是将凹凸棒土、玉石放入煅烧炉中,在610-630℃下煅烧3-4小时,取出,与秸秆灰烬、碳酸氢钠混合,研磨至得到300-400目粉末,然后,再加入季戊四醇三丙烯酸酯、氢氧化铝、硅烷偶联剂KH550混合,继续研磨30-45分钟,至充分分散,再加入其它剩余成分,继续研磨30-45分钟后,在1500-1800转/分下搅拌15-30分钟,即得改性凹凸棒土。
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