Summary of the invention
In order to overcome the defect of above-mentioned prior art, the object of the present invention is to provide many group medium Dynamic Corrosion proving installations and method of testing thereof, can, within same period, estimate the corrosivity of different medium under uniform temp, pressure, shear rate condition; Estimate the corrosivity of same medium under uniform temp, different pressures, different shear rate condition; Estimate the corrosion mitigating effect of corrosion inhibiter in different medium, estimate the relation of corrosion inhibiter effect and density of corrosion inhibitor.
In order to achieve the above object, the object of the present invention is achieved like this:
Many group medium Dynamic Corrosion proving installations, comprise constant temperature oven 1, the circle type that covers of constant temperature oven 1 is uniformly distributed 6 pressure vessels 2, magnetic stirring apparatus 3 and corresponding rotating disk 4 and piece suspension device 5 with pressure have been installed on the lid of pressure vessel 2, temperature sensor 10 and multiport valve 11 have been installed in the centre of constant temperature oven 1, multiport valve 11 is connected with pressure apparatus 7 and 6 pressure vessels 2, pressure vessel 2 also has an independent pressure interface 12, motor 8 is connected with the rotating disk 4 of one of them magnetic stirring apparatus 3, and all magnetic stirring apparatuss 3 connect and transmission by rotating disk 4; Electric lift 9 is for opening up and down the lid of constant temperature oven 1, and self-actuated controller 6 is connected with temperature sensor 10, pressue device 7, motor 8, by temperature, pressure, the rotating speed of computer regulated, demonstration and register system.
Many group medium Dynamic Corrosion proving installations, comprise constant temperature oven 1, and the circle type that covers of constant temperature oven 1 is uniformly distributed 6 pressure vessels 2 and corresponding piece suspension device 5 with pressure, and oil bath delivery pipe and multiport valve 11 have been installed in the middle of constant temperature case lid 1; Multiport valve 11 is connected with pressure apparatus 7 and 6 pressure vessels 2, and pressure vessel 2 also has an independent pressure interface 12; The oil bath delivery line with oil bath pan 9, be connected and its pipeline on pump is installed; The pressure vessel of constant temperature oven 1 bottom covers has installed magnetic stirring apparatus 3 and corresponding rotating disk 4 and leakage fluid dram 13, and motor 8 has been installed; Motor 8 is connected with the rotating disk 4 of one of them magnetic stirring apparatus 3, and all magnetic stirring apparatuss 3 connect and transmission by rotating disk 4; Self-actuated controller 6 is connected with temperature sensor 10, pressue device 7, motor 8, by temperature, pressure, the rotating speed of computer regulated, demonstration and register system.
The method of testing of many group medium Dynamic Corrosion proving installations comprises the following steps:
Step 1, first add certain volume V(mL in pressure vessel 2) test medium, volume V(mL) calculating: V(mL)=65 * S, the surface area cm that S is piece suspension device 5 lacing films with pressure
2.When lacing film while being square, the calculating S=2TL+2KL+2 π rT-2 π r of surface area
2, wherein, the radius that width cm, the r that length cm, the K that thickness cm, the L that T is lacing film is lacing film is lacing film is circular hole on lacing film; When lacing film is circle, the calculating S=2 π r of surface area
2+ 2 π rT+2 π r
1t-2 π r
1 2; Wherein, r is circular lacing film radius cm, r
1for radius cm, the T in garden in the circular lacing film thickness cm that is circular lacing film;
Step 2, heated install lacing film good seal in piece suspension device 5 with pressure after; The pressure of regulating in each pressure vessel 2 by multiport valve 11, the size of pressure is determined according to the pressure of production medium; Regulate stir speed (S.S.) n by self-actuated controller 6, the computing formula of n is: n=7.96 * V * R, and wherein, n is stir speed (S.S.), the r/min of unit; V is the flow velocity according to the field requirement design, the m/s of unit; The diameter that R is rotating disk, unit is mm; After temperature, pressure stability, the ball valve of piece suspension device 5 with pressure is opened, lacing film enters in the solution of test and carries out the corrosion test experiment, after reaching the test duration needed, system stops heating and stirs, and is cooled to after room temperature by the atmospheric valve pressure release, then takes out lacing film and processed according to standard-required.
For measuring the corrosion mitigating effect of different corrosion inhibiter in same medium, add same medium respectively in 6 pressure vessels 2, a blank, 5 add respectively the different corrosion inhibiter of same concentration, carry out the lacing film evaluation according to the above-mentioned requirements starter gear and can obtain the corrosion inhibition rate of 5 corrosion inhibiter in same medium simultaneously.
For the corrosion mitigating effect of measuring in same corrosion inhibiter variable concentrations situation, after adding medium in pressure vessel, a blank, 5 corrosion inhibiter that add respectively variable concentrations, carry out according to the above-mentioned requirements starter gear corrosion inhibition rate that the lacing film evaluation can obtain 5 variable concentrations of corrosion inhibiter simultaneously.
Undertaken by method of testing of the present invention, can obtain accurately the corrosivity of different medium in uniform temp, different shear rate and different pressures situation simultaneously; Can obtain accurately the corrosion mitigating effect of multiple corrosion inhibiter in same medium simultaneously; Can obtain accurately the relation of corrosion inhibiter effect and concentration simultaneously.
Embodiment
Below in conjunction with accompanying drawing, the present invention is done and describes in detail.
With reference to Fig. 1, many group medium Dynamic Corrosion proving installations, comprise constant temperature oven 1, the circle type that covers of constant temperature oven 1 is uniformly distributed 6 pressure vessels 2, corresponding magnetic stirring apparatus 3 and piece suspension device 5 with pressure have been installed on the lid of pressure vessel 2, temperature sensor 10 and multiport valve 11 have been installed in the centre of constant temperature oven 1, multiport valve 11 is connected with pressure apparatus 7 and 6 pressure vessels 2, pressure vessel 2 also has an independent pressure interface 12, motor 8 is connected with the rotating disk 4 of one of them magnetic stirring apparatus 3, all magnetic stirring apparatuss 3 are in transmission connection by rotating disk 4, power is transmitted to another rotating disk according to this by a rotating disk, 6 magnetic stirring apparatuss rotate under the drive of a motor, the lid of constant temperature oven 1 is opened by electric lift 9, self-actuated controller 6 is connected with temperature sensor 10, pressue device 7, motor 8, by temperature, pressure, the rotating speed of computer regulated, demonstration and register system.
Constant temperature oven 1, for heating and the constant temperature of high pressure vessel.
Described pressure vessel 2 has 6, and pressure vessel 2 can be to be threaded with being connected of container cover, can be also that flange connects or fast-open type connects, and pressure vessel 2 is installed in constant temperature oven 1, and circle type is uniformly distributed.
Totally 6 of magnetic stirring apparatuss 3, be arranged on 6 pressure vessels 2.
Rotating disk 4, be arranged on magnetic stirring apparatus, by rotating disk, interconnects and transferring power, and the size of rotating disk can be changed.
Described piece suspension device with pressure 5 has 18, on each pressure vessel, installs 3, and piece suspension device 5 with pressure utilizes the lacing film head in the magnetic-adsorption chamber, removes lacing film head Automatic-falling when magnetic patch and falls in pressure vessel.
A self-actuated controller 6 is connected with constant temperature oven 1, pressue device 7, motor 8, by temperature, pressure, the rotating speed of computer regulated, demonstration and register system.
A pressure apparatus 7, application provides pressure to high pressure vessel 2.
A motor 8, for driving the rotating disk of a magnetic stirring apparatus.
An electric lift 9, for the unlatching up and down of constant temperature oven 1 case lid.
A temperature sensor 10, for measuring and the temperature of controlling constant temperature oven.
A multiport valve 11, connect 6 pressure vessels 2 and pressue device 7, by pressue device 7, to system, provides pressure to regulate.
Independent pressure interface 12 has 6, for the pressure of pressure vessel, regulates.
Fig. 1-1 is Fig. 1 proving installation plan structure schematic diagram of invention, cover circle type at the constant temperature oven of a circle and be uniformly distributed 6 pressure vessels 2, corresponding magnetic stirring apparatus 3 and piece suspension device 5 with pressure have been installed on pressure container cover 2, temperature sensor 10 and multiport valve 11 have been installed in the middle of constant temperature oven, multiport valve 11 is connected with pressure apparatus 7 and 6 pressure vessels 2, pressure vessel 2 also has an independent pressure interface 12, motor 8 drives the rotating disk 4 of one of them magnetic stirring apparatus 3, drive according to this other magnetic stirring apparatuss by rotating disk 4, 6 magnetic stirring apparatuss rotate under the drive of a motor.
With reference to Fig. 2, organize medium Dynamic Corrosion proving installation more, comprise constant temperature oven 1, the circle type that covers of constant temperature oven 1 is uniformly distributed 6 pressure vessels 2 and corresponding piece suspension device 5 with pressure, and oil bath delivery pipe and multiport valve 11 have been installed in the middle of constant temperature case lid 1; Multiport valve 11 is connected with pressure apparatus 7 and 6 pressure vessels 2, and pressure vessel 2 also has an independent pressure interface 12; The oil bath delivery line with oil bath pan 9, be connected and its pipeline on pump is installed, rely on the high temperature oil of pump reciprocation cycle heating with the heated pressure container; Magnetic stirring apparatus 3 has been installed in constant temperature oven 1 bottom on pressure vessel, leakage fluid dram 13, motor 8; Motor 8 is connected with the rotating disk 4 of one of them magnetic stirring apparatus 3, and all magnetic stirring apparatuss 3 are in transmission connection by rotating disk 4, and power is transmitted to another rotating disk according to this by a rotating disk, and 6 magnetic stirring apparatuss rotate under the drive of a motor; Self-actuated controller 6 is connected with temperature sensor 10, pressue device 7, motor 8, by temperature, pressure, the rotating speed of computer regulated, demonstration and register system.
Constant temperature oven 1, for storing the high temperature oil from oil bath pan 9.
Pressure vessel 2 is provided with 6, is arranged in constant temperature oven 1, and circle type is uniformly distributed.
Magnetic stirring apparatus 3 has 6, is arranged on 6 pressure vessels 2.
Rotating disk 4, be arranged on magnetic stirring apparatus, by rotating disk 4, interconnects and transferring power, and the size of rotating disk can be changed.
Piece suspension device 5 with pressure has 18, on each pressure vessel, installs 3, and piece suspension device 5 with pressure utilizes the lacing film head in the magnetic-adsorption chamber, removes lacing film head Automatic-falling when magnetic patch and falls in pressure vessel.
A self-actuated controller 6, be connected with oil bath pan 9, pressue device 7, motor 8, by temperature, pressure, the rotating speed of computer regulated, demonstration and register system.
A pressure apparatus 7, for providing pressure to pressure vessel.
A motor 8, for the rotating disk 4 that drives a magnetic stirring apparatus.
An oil bath pan 9, provide high temperature oil to constant temperature oven 1.
A sensor 10, for measuring and the temperature of controlling oil bath pan 9.
A multiport valve 11, connect 6 pressure vessels and pressue device 7, by pressue device 7, to system, provides pressure to regulate.
Independent pressure interface 12, regulate for the pressure of pressure vessel 2.
A leakage fluid dram 13, be arranged at pressure vessel 2 bottoms, the material for cleaning with emptying pressure vessel 2.
Fig. 2-1 is Fig. 2 proving installation plan structure schematic diagram of invention, covers circle type at the constant temperature oven of a circle and is uniformly distributed 6 pressure vessels and corresponding piece suspension device with pressure 5, and oil bath delivery pipe and multiport valve 11 have been installed in constant temperature case lid centre; Multiport valve is connected with pressure apparatus 7 and 6 pressure vessels 3, and pressure vessel 3 also has an independent pressure interface 12; The oil bath delivery line is connected with oil bath pan 9, relies on the high temperature oil of pump reciprocation cycle heating with the heated pressure container.
Structural representation is looked up in Fig. 2 proving installation bottom that Fig. 2-2 are invention, magnetic stirring apparatus 3 and corresponding rotating disk 4 and leakage fluid dram 13 have been installed on 6 pressure vessels 2 that distribute in the bottom of constant temperature oven 1, motor 8 has been installed, motor 8 drives the rotating disk 4 of one of them magnetic stirring apparatus 3, drive according to this other magnetic stirring apparatuss by rotating disk 4,6 magnetic stirring apparatuss rotate under the drive of a motor.Leakage fluid dram 13 is the material with emptying pressure vessel 2 for cleaning.
The method of testing of many group medium Dynamic Corrosion proving installations comprises the following steps:
Step 1, first will add certain volume V(mL in pressure vessel 2) test medium, V(mL)=65 * S, the surface area cm that S is piece suspension device 5 lacing films with pressure
2; When lacing film while being square, the calculating S=2TL+2KL+2 π rT-2 π r of surface area
2, wherein, the radius that width cm, the r that length cm, the K that thickness cm, the L that T is lacing film is lacing film is lacing film is circular hole on lacing film; When lacing film is circle, the calculating S=2 π r of surface area
2+ 2 π rT+2 π r
1t-2 π r
1 2, wherein, radius cm, r that r is circular lacing film
1for radius cm, the T in garden in the circular lacing film thickness cm that is circular lacing film.
Step 2, start to be heated install lacing film good seal in piece suspension device 5 with pressure after; The pressure of regulating in each pressure vessel 2 by multiport valve 11, the size of pressure is determined according to the pressure of production medium; Regulate stir speed (S.S.) n by self-actuated controller, the computing formula of n is: n=7.96 * V * R, and wherein, n is stir speed (S.S.), the r/min of unit; V is the flow velocity according to the field requirement design, the m/s of unit; The diameter that R is rotating disk, unit is mm; After temperature, pressure stability, the ball valve of piece suspension device 5 with pressure is opened, lacing film enters in the solution of test and carries out the corrosion test experiment, after reaching the test duration needed, system stops heating and stirs, and is cooled to after room temperature by the atmospheric valve pressure release, then takes out lacing film and processed according to standard-required.
For measuring the corrosion mitigating effect of different corrosion inhibiter in same medium, add same medium respectively in 6 pressure vessels 2, a blank, 5 different corrosion inhibiter that add respectively same concentration, carry out the lacing film evaluation according to the above-mentioned requirements starter gear and can obtain the corrosion inhibition rate of 5 corrosion inhibiter in same medium simultaneously.
For the corrosion mitigating effect of measuring in same corrosion inhibiter variable concentrations situation, after adding medium in pressure vessel, a blank, 5 corrosion inhibiter that add respectively variable concentrations, carry out according to the above-mentioned requirements starter gear corrosion inhibition rate that the lacing film evaluation can obtain 5 variable concentrations of corrosion inhibiter simultaneously.