CN102928332A - Dynamic corrosion device of high-temperature liquid medium - Google Patents

Dynamic corrosion device of high-temperature liquid medium Download PDF

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Publication number
CN102928332A
CN102928332A CN2012104771644A CN201210477164A CN102928332A CN 102928332 A CN102928332 A CN 102928332A CN 2012104771644 A CN2012104771644 A CN 2012104771644A CN 201210477164 A CN201210477164 A CN 201210477164A CN 102928332 A CN102928332 A CN 102928332A
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crucible
liquid medium
primary tank
mobile jib
magnetic force
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CN2012104771644A
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CN102928332B (en
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黄波
谢中立
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Jiangsu Zhongke Zhichu Technology Co ltd
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HUAINAN ZHONGKE STORED ENERGY TECHNOLOGY Co Ltd
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Abstract

The invention discloses a dynamic corrosion device of a high-temperature liquid medium, and relates to an experimental facility. The dynamic corrosion device comprises a main container, a rotating motor, a magnetic stirring system and a sample rack and is characterized in that the main container is in sealed connection with an upper cover of the device through a flange, a crucible is arranged in the main container, a liquid medium is arranged in the crucible, a heat insulation layer is arranged outside the main container, and a resistance wire is arranged between the thermal insulation layer and the main container; the magnetic stirring system comprises a magnet and a magnetic rotating main rod, a water-cooling pipe is coiled outside the upper cover of the device, and one side of the main container is connected with a smelting box and a storage box respectively through pipelines. According to the dynamic corrosion device, different fluid speeds can be obtained through the rotating speed of the rotating motor, the corrosion experiment of the material can be carried out under different flow speeds, and the flow speed and the temperature are precisely controlled, and meanwhile, vacuum and atmosphere protection design are preformed, and the dynamic corrosion device is suitable for requirements of vacuum environment and requirements of atmosphere protection for the liquid medium with a certain toxicity, and the dynamic corrosion experiment of the high-temperature liquid medium, such as high-temperature oil, molten salt and liquid metal.

Description

A kind of high-temp liquid medium Dynamic Corrosion device
Technical field
The present invention relates to a kind of experimental facilities, be specifically related to a kind of high-temp liquid medium Dynamic Corrosion device.
Background technology
When the storage of carrying out the high-temp liquid medium and transportation, need to carry out the material selection to hold-up vessel and transmission pipeline.The corrosion experiment of general high-temp liquid medium is take static state as main, and the material of transmission pipeline selects then to need to consider the relative motion of fluid and material, and relative motion is for the cooperative effect of corrosion.Thereby it is significant for the selecting properly of material to carry out the Dynamic Corrosion experiment.
Summary of the invention
Technical matters to be solved by this invention is to provide a kind of fluid velocity and adjustment that can be implemented under the vacuum seal condition, and realizes the importing of high-temp liquid medium and the high-temp liquid medium Dynamic Corrosion device of derivation.
Technical matters to be solved by this invention realizes by the following technical solutions,
A kind of high-temp liquid medium Dynamic Corrosion device, comprise primary tank, electric rotating machine, magnetic agitation system and specimen holder, it is characterized in that: described primary tank is connected with the device loam cake by flange seal, be provided with crucible in the primary tank, described crucible is fixed on the primary tank bottom by the crucible jig, to prevent that crucible from arbitrarily rocking, described crucible is provided with an aperture, insert thermopair in the aperture, put into liquid medium in the crucible, described primary tank outside is provided with thermofin, between described thermofin and the primary tank resistance wire is housed;
Described magnetic agitation system comprises magnet and magnetic force rotation mobile jib, described magnetic force rotation mobile jib passes the device loam cake, extend in the crucible, and magnetic force rotation mobile jib does not directly contact with device loam cake and crucible, described magnetic force rotation mobile jib upper end is installed magnet and is connected with electric rotating machine, and described magnetic force rotation mobile jib bottom is connected with revolving vane by fixed block, and described specimen holder passes magnetic force rotation mobile jib, place in the crucible, specimen holder is provided with treats laboratory sample;
Described device loam cake outside is wound with water cooling tube, jut in the middle of the described device loam cake is provided with two connectors, a connector connects vacuum pump by pipeline, be provided with vacuum valve between connector and the pipeline, another connector is connected with vacuum and takes into account gas bottle, be provided with Pirani gauge between described vacuum meter and the connector, the pipeline of described gas bottle and connector is provided with an air release, tensimeter and vacuum valve;
One side of described primary tank is connected to respectively fusing case and hutch by pipeline, the export mouth place of pipeline and primary tank is provided with a block, when deriving the high-temp liquid medium, prevent that high-temp liquid from flowing into flange, is respectively equipped with a vacuum valve and abutment ring on the connecting tube of described fusing case and hutch and primary tank.
Adopt being connected of described specimen holder and crucible and rotate cassette and connect, to prevent moving of sample position, head piece is set at the position of not placing sample simultaneously is convenient to the high-temp liquid medium and all derives.
The material of described crucible, magnetic force rotation mobile jib and revolving vane is high temperature resistant, and the solubleness of alloying component in liquid medium is low.
The present invention need to carry out the high temperature corrosion experiment to candidate material during to the selection of high-temp liquid container, pipeline material, especially for pipeline material, needs to obtain the Dynamic Corrosion parameter of material in the high-temp liquid medium, to carry out rational material evaluation.Utilize the principle of magnet rotary actuation, in high-temp liquid, rotate the relative motion that realizes between static sample and the liquid medium at driving screw blade under the vacuum seal condition, and provide vacuum protection by vacuum pump, perhaps utilize inert gas that atmosphere protection is provided.The present invention has carried out the thawing of high-temp liquid medium and has derived storing design simultaneously, is convenient to installation and the taking-up of sample.For fear of the excess Temperature of magnet, the present invention has adopted water cooling tube around the device loam cake, and the gap of swingle with the device loam cake reduced, and reduces the high temperature primary tank for the heat radiation of magnet.
The invention has the beneficial effects as follows: obtain the comparatively accurate fluid field of magnetic agitation by fluid mechanics and numerical simulation, obtain the relative velocity of fluid and sample.Rotating speed by electric rotating machine can obtain different fluid velocities; carry out the corrosion experiment of material under the different in flow rate; and can more accurate coutroi velocity and temperature; can carry out different temperatures; the corrosion behavior of material research under the different in flow rate; simultaneously the present invention has carried out vacuum and atmosphere protection design; be applicable to the vacuum environment requirement or the liquid medium with certain toxicity carried out the requirement of atmosphere protection; the present invention is suitable for high temperature oil; fused salt, the Dynamic Corrosion experiment of the high-temp liquid media such as liquid metal.
Description of drawings
Fig. 1 is structural representation of the present invention;
Fig. 2 is specimen holder structural representation of the present invention.
Embodiment
For technological means, creation characteristic that the present invention is realized, reach purpose and effect is easy to understand, below in conjunction with concrete diagram, further set forth the present invention.
As shown in Figure 1 and Figure 2, a kind of high-temp liquid medium Dynamic Corrosion device, comprise primary tank 19, electric rotating machine 1, magnetic agitation system and specimen holder 16, primary tank 19 is connected with device loam cake 4 by flange seal, be provided with crucible 15 in the primary tank 19, crucible 15 is fixed on primary tank 19 bottoms by crucible jig 18, to prevent that crucible 18 from arbitrarily rocking, crucible 18 is provided with an aperture, insert thermopair 22 in the aperture, put into liquid medium in the crucible 18, primary tank 19 outsides are provided with thermofin 21, between thermofin 21 and the primary tank 19 resistance wire 20 are housed;
The magnetic agitation system comprises magnet 2 and magnetic force rotation mobile jib 17, magnetic force rotation mobile jib 17 passes device loam cake 4, extend in the crucible 15, and magnetic force rotation mobile jib 17 does not directly contact with device loam cake 4 and crucible 15, magnetic force rotation mobile jib 17 upper ends are installed magnet 2 and are connected with electric rotating machine 1, magnetic force rotation mobile jib 17 bottoms are connected with revolving vane 13 by fixed block 14, specimen holder 16 passes magnetic force rotation mobile jib 17, place in the crucible 15, it connects with adopting the rotation cassette being connected of crucible 15, to prevent moving of sample position, head piece is set at the position of not placing sample simultaneously is convenient to the high-temp liquid medium and all derives, specimen holder 28 is installed on the specimen holder 16 which is provided with and treat laboratory sample 11;
Device loam cake 4 outsides are wound with water cooling tube 3, middle jut is provided with two connectors, a connector connects vacuum pump 12 by pipeline, be provided with vacuum valve 5 between connector and the pipeline, another connector is connected with vacuum meter 25 and gas bottle 27, be provided with Pirani gauge 23 between vacuum meter 25 and the connector, gas bottle 27 is provided with an air release 26, tensimeter 24 and vacuum valve 5``` with the pipeline of connector;
One side of primary tank 19 is connected to respectively fusing case 7 and hutch 8 by pipeline, the export mouth place of pipeline and primary tank 19 is provided with a block 9, when deriving the high-temp liquid medium, prevent that high-temp liquid from flowing into flange, be respectively equipped with a vacuum valve 5`, 5`` and abutment ring 6,10 on the connecting tube of fusing case 7 and hutch 8 and primary tank 19.
The material of crucible 15, magnetic force rotation mobile jib 17 and revolving vane 13 is high temperature resistant, and the solubleness of alloying component in liquid medium is low.
The present invention at first opens vacuum valve 5 when work, then open vacuum pump 12 and bleed, and is down to below the 10Pa when vacuum meter 25 records vacuum tightness, begins to heat the medium solid feed in primary tank 19 and the fusing case 7, the cooling system of fetching boiling water simultaneously.(if need atmosphere protection, then close first vacuum valve 5 and vacuum pump 12, open vacuum valve 5```, and open air release 26 to required atmosphere pressure, then close air release 26 and vacuum valve 5```); Case 7 Raws to be dissolved all melt, and after thermopair 22 demonstrations of primary tank 19 reach the melting temperature of medium, slowly open vacuum valve 5`, and high temperature fluid is imported crucible 15.To be importedly close vacuum valve 5` after complete, and take off fusing case 7; When the warming liquid body medium to predetermined temperature, open electric rotating machine 1, simultaneously progressively slowly accelerate to speed of experiment, behind thermopair 22 temperature stabilizations, begin to test timing.
After experiment is finished, close electric rotating machine 1, off resistance silk 20 power supplys, connect storage bin 8, open vacuum valve 5`` and take out storage bin 8 vacuum to 20Pa, then close vacuum pump 12, to storage bin 8 orientation inclination primary tanks 19, liquid medium in the crucible 15 is imported storage bin 8, then close vacuum valve 5``, and take off storage bin 8; After primary tank 19 is down to room temperature, close water cooling tube 3, open flange, Rotary Specimen Rack 16 is taken out it from crucible 15.Take out at last sample 11, carry out sample analysis.
More than show and described ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that describes in above-described embodiment and the instructions just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.

Claims (3)

1. high-temp liquid medium Dynamic Corrosion device, comprise primary tank, electric rotating machine, magnetic agitation system and specimen holder, it is characterized in that: described primary tank is connected with the device loam cake by flange seal, be provided with crucible in the primary tank, described crucible is fixed on the primary tank bottom by the crucible jig, and described crucible is provided with an aperture, insert thermopair in the aperture, put into liquid medium in the crucible, described primary tank outside is provided with thermofin, between described thermofin and the primary tank resistance wire is housed;
Described magnetic agitation system comprises magnet and magnetic force rotation mobile jib, described magnetic force rotation mobile jib passes the device loam cake, extend in the crucible, and magnetic force rotation mobile jib does not directly contact with device loam cake and crucible, described magnetic force rotation mobile jib upper end is installed magnet and is connected with electric rotating machine, described magnetic force rotation mobile jib bottom is connected with revolving vane by fixed block, and described specimen holder passes magnetic force rotation mobile jib, places in the crucible;
Described device loam cake outside is wound with water cooling tube, jut in the middle of the described device loam cake is provided with two connectors, a connector connects vacuum pump by pipeline, be provided with vacuum valve between connector and the pipeline, another connector is connected with vacuum and takes into account gas bottle, be provided with Pirani gauge between described vacuum meter and the connector, the pipeline of described gas bottle and connector is provided with an air release, tensimeter and vacuum valve;
One side of described primary tank is connected to respectively fusing case and hutch by pipeline, and the export mouth place of pipeline and primary tank is provided with a block, is respectively equipped with a vacuum valve and abutment ring on the connecting tube of described fusing case and hutch and primary tank.
2. a kind of high-temp liquid medium Dynamic Corrosion device according to claim 1 is characterized in that:
Described specimen holder connects with adopting the rotation cassette being connected of crucible.
3. a kind of high-temp liquid medium Dynamic Corrosion device according to claim 1 is characterized in that:
The material of described crucible, rotation mobile jib and revolving vane is high temperature resistant.
CN201210477164.4A 2012-11-22 2012-11-22 A kind of dynamic corrosion device of high-temperature liquid medium Active CN102928332B (en)

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CN103454210A (en) * 2013-09-11 2013-12-18 中国科学院金属研究所 Rotary dynamic metal corrosion testing device and using method thereof
CN103487364A (en) * 2013-07-23 2014-01-01 西安石油大学 Testing apparatus and testing method for dynamic corrosion of multiple groups of mediums
CN104297141A (en) * 2014-10-28 2015-01-21 中国科学院合肥物质科学研究院 Axial erosion corrosion test device and method for samples
CN104392755A (en) * 2014-09-24 2015-03-04 中国科学院合肥物质科学研究院 Liquid-state heavy metal oxygen concentration control solid-liquid exchange reaction apparatus under flowing working condition
CN104568725A (en) * 2015-02-16 2015-04-29 核工业理化工程研究院 Low-vacuum liquid-state lithium corrosion test device protected by inert gas
ES2534850A1 (en) * 2014-12-22 2015-04-29 Universidad Complutense De Madrid Equipment and procedure for testing high temperature materials and fluids such as salts, metals, alloys and glass in the molten state (Machine-translation by Google Translate, not legally binding)
ES2534869A1 (en) * 2014-12-22 2015-04-29 Universidad Complutense De Madrid Equipment and procedure for testing high temperature materials and fluids such as salts, metals, alloys or glasses in a molten state in a stirred tank (Machine-translation by Google Translate, not legally binding)
CN104764686A (en) * 2015-03-24 2015-07-08 中国科学院等离子体物理研究所 Device for measuring corrosion of active liquid metal lithium to solid metal materials
CN103398941B (en) * 2013-08-21 2016-01-06 中国科学院合肥物质科学研究院 A kind of bell jar seal liquid heavy metal whirligig
CN105424589A (en) * 2015-12-31 2016-03-23 芜湖东旭光电装备技术有限公司 Material erosion resistance testing device and method
CN105571967A (en) * 2015-11-02 2016-05-11 沈阳工业大学 Method for detecting abrasion resistance and molten metal corrosion resistance of thermal-sprayed coatings
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CN107917871A (en) * 2016-10-11 2018-04-17 中国科学院上海应用物理研究所 The test device and test method of a kind of Corrosion Protection
CN108231224A (en) * 2018-01-17 2018-06-29 中国科学院上海应用物理研究所 A kind of analogy method of nuclear material in molten salt reactor
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JP2012172974A (en) * 2011-02-17 2012-09-10 Suga Test Instr Co Ltd Corrosion testing machine
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CN103487364A (en) * 2013-07-23 2014-01-01 西安石油大学 Testing apparatus and testing method for dynamic corrosion of multiple groups of mediums
CN103487364B (en) * 2013-07-23 2016-08-10 西安石油大学 Many group medium Dynamic Corrosion test devices and method of testing thereof
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