CN103469004A - Leadless copper alloy material - Google Patents

Leadless copper alloy material Download PDF

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Publication number
CN103469004A
CN103469004A CN2013103536891A CN201310353689A CN103469004A CN 103469004 A CN103469004 A CN 103469004A CN 2013103536891 A CN2013103536891 A CN 2013103536891A CN 201310353689 A CN201310353689 A CN 201310353689A CN 103469004 A CN103469004 A CN 103469004A
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Prior art keywords
copper
alloy material
mass percent
lead
impurity
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CN2013103536891A
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CN103469004B (en
Inventor
谢章明
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Zhejiang Yonghe Intelligent Control Technology Co., Ltd
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YORHE FLUID INTELLIGENT CONTROL CO Ltd
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Abstract

The invention provides a leadless copper alloy material, which is composed of the following components by mass percent: 63% of copper, 0.2% of lead, 0.2% of tin, 0.2% of iron, 0.3% of nickel, 0.2% of aluminium, 0.08% of arsenic, no more than 0.4% of inevitable impurities, and the balance being zinc. The invention has the advantages of environmental protection, high safety health coefficient; good thermal forming performance, cutting ability and dezincification resisting performance; good tensile strength and elongation percentage; the invention is especially suitable for producing valve, pipe fitting and various spare and accessory parts in the drinking water system, and is suitable for forging, machining, electroplating, polishing, welding and other technologies.

Description

A kind of Pb-free copper-alloy material
Technical field
The present invention relates to a kind of metallic substance technical field, refer to especially a kind of Pb-free copper-alloy material.
Background technology
At present, good due to performances such as the cutting of copper, stretchings, be widely applied in various industries, is particularly suitable for valve in potable water system, pipe fitting and various spare and accessory parts production thereof, the techniques such as suitable forging, machine add, plating, polishing, welding.Especially the equipment in potable water system, for the consideration of safety and health, necessarily require to use without lead bronze or Pb-free copper-alloy; Require must be less than specified standards without the Pb constituent content in lead bronze or Pb-free copper-alloy.Therefore, various in style without lead bronze on present market, as prior art, publication number is 101250641, patent name is a kind of leadless copper alloy for amiable cutting smithing, the weight percent that it is characterized in that its alloy consists of: Cu:57.5%-59.0%, Fe:0.05%-0.2%, Si:0.3%-0.4%, Bi:0.7%~1.2%, surplus is zinc and inevitable impurity, and Pb :≤0.05, Sn :≤0.2%, Ni :≤0.2%.But the performance of the Bi in current material, Si element meeting material, the Bi element can make material easily ftracture; The Si element affects welding property.
Summary of the invention
The technical problem proposed in order to have solved prior art, the present invention proposes a kind of Pb-free copper-alloy material, and its environmental protection, healthy and safe coefficient are high; The tensile strength of material, anti dezincification character can be high; Welding property, cutting ability and thermoforming performance thereof obviously improve.
Technical scheme of the present invention is achieved in that a kind of Pb-free copper-alloy material, and its mass percent consists of: copper is 60%-68%, lead is 0.01%-0.5%, tin is 0.01%-0.5%, iron is 0.01%-0.3%, nickel is 0.01%-0.6%, aluminium is 0.01%-0.5%, arsenic is 0.01%-0.2%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
Further preferably, its mass percent consists of: copper is 61%-65%, lead is 0.1%-0.5%, tin is 0.1%-0.5%, iron is 0.1%-0.3%, nickel is 0.1%-0.6%, aluminium is 0.1%-0.5%, arsenic is 0.05%-0.2%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
Further preferably, its mass percent consists of: copper is 61%, lead is 0.1%, tin is 0.1%, iron is 0.1%, nickel is 0.1%, aluminium is 0.1%, arsenic is 0.05%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
Further preferably, its mass percent consists of: copper is 63%, lead is 0.2%, tin is 0.2%, iron is 0.2%, nickel is 0.3%, aluminium is 0.2%, arsenic is 0.08%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
Further preferably, its mass percent consists of: copper is 65%, lead is 0.5%, tin is 0.5%, iron is 0.3%, nickel is 0.6%, aluminium is 0.5%, arsenic is 0.1%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
Beneficial effect of the present invention: the Pb-free copper-alloy material that the present invention obtains, mechanical property: tensile strength 330-400MPa, hardness (HV30): 80-110, unit elongation: 35-45%; Processing performance: thermoforming performance 95%, cutting ability 85%; Chemical property: anti dezincification character energy: copper rod is vertically great<=200um laterally.
This Pb-free copper-alloy material environment friendly and healthy and safe coefficient are high, are particularly suitable for valve in potable water system, pipe fitting and various spare and accessory parts production thereof.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
A kind of Pb-free copper-alloy material, its mass percent consists of: copper is 61%, lead is 0.1%, tin is 0.1%, iron is 0.1%, nickel is 0.1%, aluminium is 0.1%, arsenic is 0.05%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
The Pb-free copper-alloy of making according to above-mentioned mass percent, mechanical property: tensile strength 330-400MPa, hardness (HV30): 80-110, unit elongation: 35-45%; Processing performance: thermoforming performance 95%, cutting ability 85%; Chemical property: anti dezincification character energy: copper rod is vertically great<=200um laterally.
This Pb-free copper-alloy material does not affect the negative composition of material property containing Bi, Si, Sb, Ti etc., environmental protection and healthy and safe coefficient are high, are particularly suitable for valve in potable water system, pipe fitting and various spare and accessory parts production thereof.
Embodiment 2
A kind of Pb-free copper-alloy material, its mass percent consists of: copper is 63%, lead is 0.2%, tin is 0.2%, iron is 0.2%, nickel is 0.3%, aluminium is 0.2%, arsenic is 0.08%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
The Pb-free copper-alloy of making according to above-mentioned mass percent, mechanical property: tensile strength 330-400MPa, hardness (HV30): 80-110, unit elongation: 35-45%; Processing performance: thermoforming performance 95%, cutting ability 85%; Chemical property: anti dezincification character energy: copper rod is vertically great<=200um laterally.
This Pb-free copper-alloy material does not affect the negative composition of material property containing Bi, Si, Sb, Ti etc., environmental protection and healthy and safe coefficient are high, are particularly suitable for valve in potable water system, pipe fitting and various spare and accessory parts production thereof.
Embodiment 3
A kind of Pb-free copper-alloy material, its mass percent consists of: copper is 65%, lead is 0.5%, tin is 0.5%, iron is 0.3%, nickel is 0.6%, aluminium is 0.5%, arsenic is 0.1%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
The Pb-free copper-alloy of making according to above-mentioned mass percent, mechanical property: tensile strength 330-400MPa, hardness (HV30): 80-110, unit elongation: 35-45%; Processing performance: thermoforming performance 95%, cutting ability 85%; Chemical property: anti dezincification character energy: copper rod is vertically great<=200um laterally.
This Pb-free copper-alloy material does not affect the negative composition of material property containing Bi, Si, Sb, Ti etc., environmental protection and healthy and safe coefficient are high, are particularly suitable for valve in potable water system, pipe fitting and various spare and accessory parts production thereof.

Claims (5)

1. a Pb-free copper-alloy material, it is characterized in that, its mass percent consists of: copper is 60%-68%, lead is 0.01%-0.5%, tin is 0.01%-0.5%, iron is 0.01%-0.3%, nickel is 0.01%-0.6%, aluminium is 0.01%-0.5%, arsenic is 0.01%-0.2%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
2. a kind of Pb-free copper-alloy material according to claim 1, it is characterized in that, its mass percent consists of: copper is 61%-65%, lead is 0.1%-0.5%, tin is 0.1%-0.5%, iron is 0.1%-0.3%, nickel is 0.1%-0.6%, aluminium is 0.1%-0.5%, arsenic is 0.05%-0.2%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
3. a kind of Pb-free copper-alloy material according to claim 1 and 2, is characterized in that, its mass percent consists of: copper is 61%, lead is 0.1%, tin is 0.1%, iron is 0.1%, nickel is 0.1%, aluminium is 0.1%, arsenic is 0.05%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
4. a kind of Pb-free copper-alloy material according to claim 1 and 2, is characterized in that, its mass percent consists of: copper is 63%, lead is 0.2%, tin is 0.2%, iron is 0.2%, nickel is 0.3%, aluminium is 0.2%, arsenic is 0.08%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
5. a kind of Pb-free copper-alloy material according to claim 1 and 2, is characterized in that, its mass percent consists of: copper is 65%, lead is 0.5%, tin is 0.5%, iron is 0.3%, nickel is 0.6%, aluminium is 0.5%, arsenic is 0.1%; Surplus is zinc and inevitable impurity, and impurity≤0.4%.
CN201310353689.1A 2013-08-14 2013-08-14 A kind of Pb-free copper-alloy material Active CN103469004B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105543548A (en) * 2015-12-22 2016-05-04 路达(厦门)工业有限公司 Low-cost unleaded anti-dezincification brass alloy used for casting
EP3050983A1 (en) * 2015-01-28 2016-08-03 Toto Ltd. Brass having improved castability and corrosion resistance
EP2963134B1 (en) 2014-06-23 2018-05-23 Jiangxi Audy Brasswork Inc. Low-lead brass alloy
CN108265195A (en) * 2017-12-22 2018-07-10 宁波金田铜业(集团)股份有限公司 A kind of deep-draw alpha brass and preparation method thereof
CN109468488A (en) * 2018-12-24 2019-03-15 广州海鸥住宅工业股份有限公司 Low lead Anti-dezincificationyellow yellow brass alloy and preparation method thereof
CN109666819A (en) * 2019-01-24 2019-04-23 浙江高澳卫浴有限公司 Unleaded anti-dezincification Cu alloy material and its core assembly obtained

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6086231A (en) * 1983-10-14 1985-05-15 Nippon Mining Co Ltd High-strength conductive copper alloy
EP1439238A1 (en) * 2003-01-16 2004-07-21 REHAU AG + Co Corrosion resistant brass alloy for parts suitable for use in drinking water service
CN101225487A (en) * 2008-01-15 2008-07-23 胡旭红 Arsenic-containing low-lead brass alloy
CN101331241A (en) * 2005-12-13 2008-12-24 迪尔金属合作两合公司 Copper-zinc alloy and synchronizing ring produced therefrom
CN101638736A (en) * 2009-08-14 2010-02-03 卓美香 Lead-free copper alloy with limited Al and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6086231A (en) * 1983-10-14 1985-05-15 Nippon Mining Co Ltd High-strength conductive copper alloy
EP1439238A1 (en) * 2003-01-16 2004-07-21 REHAU AG + Co Corrosion resistant brass alloy for parts suitable for use in drinking water service
CN101331241A (en) * 2005-12-13 2008-12-24 迪尔金属合作两合公司 Copper-zinc alloy and synchronizing ring produced therefrom
CN101225487A (en) * 2008-01-15 2008-07-23 胡旭红 Arsenic-containing low-lead brass alloy
CN101638736A (en) * 2009-08-14 2010-02-03 卓美香 Lead-free copper alloy with limited Al and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2963134B1 (en) 2014-06-23 2018-05-23 Jiangxi Audy Brasswork Inc. Low-lead brass alloy
EP3050983A1 (en) * 2015-01-28 2016-08-03 Toto Ltd. Brass having improved castability and corrosion resistance
CN105543548A (en) * 2015-12-22 2016-05-04 路达(厦门)工业有限公司 Low-cost unleaded anti-dezincification brass alloy used for casting
WO2017107917A1 (en) * 2015-12-22 2017-06-29 路达(厦门)工业有限公司 Low-cost lead-free dezincification-resistant brass alloy for casting
EP3395970A4 (en) * 2015-12-22 2019-10-30 Xiamen Lota International Co., Ltd. Low-cost lead-free dezincification-resistant brass alloy for casting
CN108265195A (en) * 2017-12-22 2018-07-10 宁波金田铜业(集团)股份有限公司 A kind of deep-draw alpha brass and preparation method thereof
CN109468488A (en) * 2018-12-24 2019-03-15 广州海鸥住宅工业股份有限公司 Low lead Anti-dezincificationyellow yellow brass alloy and preparation method thereof
CN109666819A (en) * 2019-01-24 2019-04-23 浙江高澳卫浴有限公司 Unleaded anti-dezincification Cu alloy material and its core assembly obtained

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Effective date of registration: 20200410

Address after: 317600 Industrial Agglomeration Area of Qinggang Town, Yuhuan City, Taizhou City, Zhejiang Province

Patentee after: Zhejiang Yonghe Intelligent Control Technology Co., Ltd

Address before: Taizhou City, Zhejiang province 317606 Yuhuan County town industrial area

Patentee before: YORHE FLUID INTELLIGENT CONTROL Co.,Ltd.

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