CN103388106A - Non-oriented electrical steel plate with high magnetic induction and low iron loss, and manufacturing method thereof - Google Patents

Non-oriented electrical steel plate with high magnetic induction and low iron loss, and manufacturing method thereof Download PDF

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CN103388106A
CN103388106A CN2013102618076A CN201310261807A CN103388106A CN 103388106 A CN103388106 A CN 103388106A CN 2013102618076 A CN2013102618076 A CN 2013102618076A CN 201310261807 A CN201310261807 A CN 201310261807A CN 103388106 A CN103388106 A CN 103388106A
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iron loss
high magnetic
magnetic strength
low iron
steel sheet
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金冰忠
张峰
王波
陈晓
徐琪
刘海
王子涛
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Baoshan Iron and Steel Co Ltd
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Baoshan Iron and Steel Co Ltd
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Abstract

The invention discloses a non-oriented electrical steel plate with high magnetic induction and low iron loss, and a manufacturing method thereof, wherein the weight percentage of the chemical components of the steel plate is as follows: less than or equal to 0.004 % of C, 0.1-1.6% of Si, 0.02-1.0% of Mn, less than or equal to 0.003% of S, 0.1-0.6% of Al, less than or equal to 0.003% of N and less than or equal to 0.0015% of Ti, wherein Si+Al is between 0.2-2.0%, and Mn, Si and Al satisfies the following formula: Mn=K2*Si+K3*Al+a, k2=0.08-0.11, k3=0.17-0.38; a is a constant and the balance is Fe and unavoidable impurities. The non-oriented electrical steel plate with high magnetic induction and low iron loss has 1.70-1.78T of magnetic induction B50 and 3.59-5.5W/kg of iron loss P15/50, has good surface state and is relatively low in manufacture cost without intermediate normalizing or batch annealing, has high magnetic induction, low iron loss and no corrugated defect, and has a magnetic induction B50 0.02T higher and an iron loss P15/50 0.2W/kg lower than those of a normal non-oriented electrical steel plate with same license number.

Description

A kind of high-magnetic induction, low-iron loss non-oriented electromagnetic steel sheet and manufacture method thereof
Technical field
The present invention relates to non-oriented electromagnetic steel sheet and manufacture method thereof; relate in particular to without normalizing or bell furnace process annealing, in apparent good order and condition, low-cost, high magnetic strength, low iron loss non-oriented electromagnetic steel sheet and manufacture method thereof; this non-oriented electromagnetic steel sheet ratio is with the high 0.02T of the conventional non-oriented electromagnetic steel sheet product magnetic strength B50 of the trade mark, and iron loss P15/50 hangs down 0.2W/kg.
Background technology
In recent years, the consumers such as efficient EI iron core, motor, miniature transformer, more and more be subject to people's favor.One of very important reason is, can meet environmental protection, the energy-conservation and needs that effectively reduce the discharging of carbonic acid gas.Meanwhile, along with improving constantly of these consumer over-all propertieies, indirect request is as corresponding raw-material non-oriented electromagnetic steel sheet, to have good magnetic in the guaranteed price advantage, be usually said ultralow iron loss, superelevation magnetic strength, with meet these electricity consumption products to energy-conservation, efficiently in the urgent need to.
Research shows,, in order to obtain good electromagnetic performance, needs chemical composition, the grain-size of improving finished steel plate and the favorable texture of appropriate control steel.Increase silicon, aluminium content in steel; can effectively improve the resistivity of material; and then improve the iron loss of finished steel plate; but the magnetic strength of deteriorated finished steel plate of while; and in normalizing or bell furnace process annealing situation; the finished steel plate surface is easy to produce the corrugated defect, and the outward appearance and the user that affect the finished product use.
Therefore, people often adopt significantly increases silicon in steel, aluminium content,, simultaneously in conjunction with normalizing or bell furnace intermediate annealing process,, effectively to reduce the finished steel plate iron loss, improves the finished steel plate magnetic strength; Utilize induction stirring to improve the slab equiaxial crystal ratio, and obtain finished steel plate in apparent good order and condition.But adopt normalizing or bell furnace process annealing, can significantly increase the manufacturing cost of finished steel plate, extend manufacturing and the delivery cycle of finished steel plate, bring larger difficulty for simultaneously on-the-spot production management, quality control etc.
Affected by this; people begin one's study in the relatively-stationary situation of chemical composition; by adding rare earth, calcium containing alloy etc.; non-metallic inclusion in effective removal or reduction steel; by significantly improving the hot rolling slab tapping temperature, and adopt ultrahigh-temperature finish to gauge technology, to improve the favorable texture in finished steel plate;, in the situation that do not adopt normalizing or bell furnace process annealing, effectively improve the electromagnetic performance of finished steel plate.
Achievement in research in the past mainly contains, and TOHKEMY 2007-102930 patent, by significantly improving the hot rolling slab tapping temperature, generally is about 1230~1320 ℃, and with the grain-size, the crystallographic texture that improve hot-rolled sheet, finished steel plate is in apparent good order and condition, and magnetic strength is very high.But after significantly improving for fear of the slab tapping temperature, in heating of plate blank, the operation of rolling, the abundant solid solution of the non-metallic inclusion such as S, N meeting, disperse educt, and then the iron loss of deterioration finished steel plate, this technology has also adopted interpolation 0.005-0.03% calcium containing alloy or rare earth mode cleaning molten steel, and be strict with S, N content must be less than 0.0015%.This has significantly increased to smelt controls difficulty, and tooling cost is very high, and needs special veneer heating apparatus.
Japanese kokai publication hei 3-113287 patent, for avoiding in heating of plate blank, the operation of rolling, the abundant solid solution of the non-metallic inclusion such as S, N meeting, disperse educt, and then the iron loss of deterioration finished steel plate, adopted hot rolling slab low temperature to come out of the stove, then after roughing finishes, adopt the electromagnetic induction rapid heating, effectively to improve finish rolling temperature in, finishing temperature, this technology has been relaxed the control requirement to impurity elements such as S, N, finished steel plate is in apparent good order and condition, and electromagnetic performance is good.Blemish in an otherwise perfect thing be, adopt this technology very high to the device hardware requirement, production cost increases to some extent, and template to control difficulty larger.
TOHKEMY 2003-57657 patent, by strict control finishing temperature, require 950 ℃ or more than, with grain-size, the crystallographic texture that improves hot-rolled sheet.Simultaneously, need to add Sn, the Cu of 0.08-0.5% of 0.02-0.4%, further improve hot-rolled sheet recrystallize effect.Same shortcoming is, add Sn, Cu and can cause production cost significantly to increase, also need to adopt the means such as high temperature coiling, high-temperature final rolling to assist, need special heating of plate blank, rolling equipment, and impurity element S, N equal size are controlled very strict, all require less than 0.0015%.
The paper report that Hunady and Cernik write, strictly control the silicon equivalent weight in steel, improves hot fine rolling process phase transformation effect, then by the cold rolling mode of depressing greatly, control the favorable texture of finished steel plate, draft is up to 91%, and common cold-rolling mill ability does not reach this design requirements far away.
Summary of the invention
The object of the present invention is to provide a kind of high magnetic strength, low iron loss non-oriented electromagnetic steel sheet and manufacture method thereof; finished steel plate is in apparent good order and condition; manufacturing cost is relatively cheap; and without normalizing or bell furnace process annealing; this has high magnetic strength, low iron loss without oriented electric silicon steel; ratio is with the high 0.02T of the conventional non-oriented electromagnetic steel sheet product magnetic strength B50 of the trade mark, and iron loss P15/50 hangs down 0.2W/kg.
The present invention is by suitable silicon, manganese, the aluminum chemistry Composition Design of adoption rate, control the impurity element titanium content in steel, before RH refining liquid steel decarburization end, alloying, adopt the complete deoxidation of ferrosilicon, and adopt Insulation to control hot fine rolling temperature in etc., realized that high magnetic strength in apparent good order and condition, low iron loss non-oriented electromagnetic steel sheet normally produce.Have and control conveniently, easy and simple to handle, with low cost, be easy to realize, and the characteristics such as purity of steel is high, finished steel plate excellent magnetic.Simultaneously, finished steel plate is in apparent good order and condition, need not process through normalizing or bell furnace process annealing.
In order to achieve the above object, technical scheme of the present invention is as follows:
A kind of high magnetic strength, low iron loss non-oriented electromagnetic steel sheet, the weight percent of its chemical composition is: C :≤0.004%, Si:0.1~1.6%, Mn:0.02~1.0%, S :≤0.003%, Al:0.1~0.6%, N :≤0.003%, Ti :≤0.0015%, and meet Si+A1:0.2~2.0%, Mn, Si, Al meet Mn=k 2* Si+k 3* Al+a, k 2=0.08~0.11, k 3=0.17~0.38, a is constant, a=0~0.7, and all the other are Fe and inevitable impurity.
This high magnetic strength, low iron loss non-oriented electromagnetic steel sheet, in apparent good order and condition, and than the high 0.02T of magnetic strength B50 with the conventional non-oriented electromagnetic steel sheet product of the trade mark, than the low 0.2W/kg of its iron loss P15/50.
High magnetic strength of the present invention, low iron loss, without the manufacture method of oriented electric silicon steel, comprise the steps:
1) smelt, cast:
Smelt, be cast into slab by following chemical composition pre-treatment, converter smelting, RH refining, the chemical component weight percentage composition is: C :≤0.004%, Si:0.1~1.6%, Mn:0.02~1.0%, S≤0.003%, Al:0.1~0.6%, N≤0.003%, Ti≤0.0015%, and meet Si+A1:0.2~2.0%, Mn, Si, Al meet Mn=k 2* Si+k 3* Al+a, k 2=0.08~0.11, k 3=0.17~0.38, a is constant, and all the other are Fe and inevitable impurity.
2) hot rolling:
Slab obtains the normalizing plate after roughing, finish rolling, wherein, the slab tapping temperature is controlled at 1000~1150 ℃, one or more passages of roughing, and adopt the enclosed insulating device between roughing, finishing stand, guarantee finish rolling temperature in 〉=980 ℃.
3) pickling, cold rolling:
The normalizing plate is first carried out pickling, then it is cold rolling to carry out multi-pass, is rolled into the cold-reduced sheet of target thickness, wherein the cold rolling accumulative total draught of multi-pass is 70~81%.
4) annealing, coating:
The cold-reduced sheet that obtains is carried out obtaining described high magnetic strength, low iron loss non-oriented electromagnetic steel sheet after continuous annealing, coating, wherein, first be warmed up to 800~1000 ℃ of insulation 5~60s during continuous annealing, be preferably 10-30s, then the speed of cooling with 3~15 ℃/s slowly cools to 600~750 ℃.
Further, step 1) in, Si, Mn, Al chemical composition design are as follows:
Mn=k 2×Si+k 3×Al+a,k 2=0.08~0.11,k 3=0.17~0.38,a=0~0.7 (1)
Wherein, the k in formula (1) 2, k 3For Si, Al factor of influence, a is constant.
Further, step 1) in, before RH refining liquid steel decarburization end, alloying, adopting the complete deoxidation of ferrosilicon, the interpolation quantity of ferrosilicon is:
M FeSi=k 1* [O] Free/ t steel, k 1=0.1~0.2 (2)
Wherein, [O] FreeWhile for RH refining decarburization, finishing, the free oxygen content in molten steel, k 1For deoxidation constant, be generally 0.1~0.2 ,/t represents per ton.
After ferrosilicon added, molten steel need to carry out 1~2 or 3 with cocycle.
Further, step 4) in, annealing atmosphere is H 2And N 2Mixed gas, and both volume ratios are (30~70): (70~30), dew point≤-25 ℃.
High magnetic strength in apparent good order and condition of the present invention, low iron loss non-oriented electromagnetic steel sheet, the principle of design of its chemical composition is as follows:
Si:0.1~1.6%。Si can improve matrix resistivity, effectively reduces the iron loss of steel.Si content higher than 1.6% the time, can significantly reduce the magnetic strength of steel; And lower than 0.2% the time, do not have again the effect that significantly reduces iron loss.
Mn:0.02~1.0%。Mn is combined with S and is generated MnS, can effectively reduce the harm to magnetic, improves simultaneously the electrical steel condition of surface, reduces hot-short.Therefore, be necessary to add the Mn content more than 0.02%, and, higher than the Mn content more than 1.0%, easily destroy recrystallization texture, can significantly increase again the manufacturing cost of steel.
Al:0.1~0.6%。Al increases the resistance element, is used for simultaneously the deep deoxidation of electrical steel, and Al content higher than 0.6% the time, can cause the continuous casting difficulty, and magnetic strength significantly reduces; And Al content can significantly reduce the A1N solid solubility temperature lower than 0.1% the time, and causes the magnetic fluctuation of steel.
Si, Mn, Al chemical composition: Si of the present invention, Mn, Al chemical composition relate to and meet formula (1), the basic reason why the present invention limits Mn content is, Mn can enlarge the austenite phase region, makes austenite slack-off to the speed of ferritic transformation, affects the hot rolling stable rolling.In addition, in the situation that Si in steel, Al content are certain, high Mn content also can obviously improve the hot-rolled sheet recrystallization temperature, suppresses the hot-rolled sheet sufficient crystallising.
Below Ti:0.0015%.When Ti content surpasses 0.0015%, the TiN inclusion will be increased greatly, strongly hinder grain growth, worsen the magnetic of steel.
Molten steel through above-mentioned smelting step, at first adopt the RH refining to carry out dark decarburization, molten steel carbon content≤0.004% after decarburization finishes.Then, adopt ferrosilicon to carry out complete deoxidation.For guaranteeing that deoxidation effect is good, after adding ferrosilicon, molten steel need to carry out 1~2 or 3 with cocycle, guarantees that deoxidation products fully floats; Wherein the interpolation quantity of ferrosilicon meets formula (2).
Secondly, the present invention after RH refining decarburization finishes, adopts ferrosilicon to carry out complete deoxidation, rather than strong reductor ferro-aluminum.Because the ferro-aluminum deoxidation products is a bunch shape Al 2O 3, easily be suspended in steel and be difficult for removing, and in follow-up heating of plate blank, operation of rolling fragmentation, size reducing, quantity increases, and suppresses finished steel plate crystal grain-growth in heat treatment process.Due to [O] FreeUsually be controlled at 200~600ppm, good for guaranteeing deoxidation effect, need to add ferrosilicon quantity according to formula (2).Because the ferrosilicon deoxidation products is only SiO 2, the large and globulate of particle, remove than being easier to floating.After adding ferrosilicon, molten steel need to carry out 1~2 or with cocycle, guarantees that deoxidation products fully floats.
Again, the present invention guarantees that by low-cost manufacture method surface quality is good without being orientated steel plate without the corrugated defect.Existing ordinary method is steel plate to be carried out the method for normalizing or cover annealing; but can greatly increase manufacturing cost; and the present invention controls the corrugated defect mainly by optimizing the method for hot rolling technology, therefore in acquisition excellent surface quality, has realized simultaneously low cost.Concrete hot rolling technology is as follows:
After the continuous casting casting finished, slab shove charge successively heated, heats up, after hot rolling slab reheats, the slab tapping temperature need not high temperature, be controlled at 1000~1150 ℃ and get final product, so both can adopt R1, above passage of R2 two frame roughing, broken larger-size column crystal.Intermediate slab between roughing, finishing stand, adopts the enclosed insulating cover to be incubated, to guarantee finish rolling temperature in 〉=980 ℃.Like this, the inner crystal grain of intermediate slab can effectively be grown up, thereby both can effectively improve the texture of finished steel plate, can also eliminate plate face corrugated defect.
Description of drawings
Fig. 1 is the impact of Ti content of the present invention on the finished steel plate magnetic strength;
Fig. 2 is the impact of RH refinement and deoxidation mode of the present invention on nonmetallic inclusionsin steel;
Fig. 3 is the impact of hot fine rolling temperature in of the present invention on production board face quality.
Embodiment
Below in conjunction with specific embodiment, technical scheme of the present invention is described in further detail.
The embodiment that the high magnetic strength of the present invention, low iron loss non-oriented electromagnetic steel sheet are made is as follows:
Molten iron, steel scrap, according to the proportioning of the chemical composition shown in table 1, after 300 tons of converter smeltings, adopt floating plug, moving slide board to carry out pushing off the slag.Then, adopt the RH refining to carry out decarburization, deoxidation, alloying, RH refining decarburization is carried out complete deoxidation after finishing, and adjusts Si, Mn, Al content in steel.Molten steel after the continuous casting casting, obtains the strand that 170mm~250mm is thick, 800mm~1400mm is wide.Strand through above-mentioned smelting technology, successively through hot rolling, pickling, cold rolling and annealing process, wherein during hot rolling, the slab tapping temperature is controlled at 1000~1150 ℃, one or more passages of roughing, and adopt the enclosed insulating device between roughing, finishing stand, guarantee finish rolling temperature in 〉=980 ℃; When cold rolling, the cold rolling accumulative total draught of multi-pass is 70~80%; First be warmed up to 800~1000 ℃ of insulation 5~60s during continuous annealing, then the speed of cooling with 3~15 ℃/s slowly cools to 600~750 ℃, finally obtain high magnetic strength, low iron loss non-oriented electromagnetic steel sheet product, its main technologic parameters is as shown in table 2, and its electromagnetic performance is as shown in table 3.
Table 1 unit: weight percent
Si Mn Al Ti C S N Fe/ impurity
Embodiment
1 0.27 0.18 0.27 0.0007 12 29 12 All the other
Embodiment 2 0.30 0.24 0.29 0.0005 16 30 14 All the other
Embodiment 3 0.26 0.32 0.29 0.0013 14 31 13 All the other
Embodiment 4 0.28 0.28 0.28 0.0009 13 32 15 All the other
Embodiment
5 1.27 0.19 0.28 0.0009 14 31 14 All the other
Embodiment 6 1.26 0.23 0.32 0.0012 12 33 10 All the other
Embodiment 7 1.32 0.26 0.29 0.0004 13 32 11 All the other
Embodiment 8 1.31 0.22 0.24 0.0006 14 29 12 All the other
Embodiment 9 1.32 0.58 0.26 0.0007 12 30 13 All the other
Embodiment
10 1.44 0.62 0.38 0.0006 11 31 12 All the other
Comparative Examples 1 0.27 0.36 0.28 0.0028 0.0013 30 13 All the other
Comparative Examples 2 0.26 0.34 0.29 0.0007 0.0015 28 12 All the other
Comparative Examples 3 0.27 0.28 0.32 0.0009 0.0012 33 12 All the other
Comparative Examples 4 1.25 0.27 0.26 0.0008 15 33 13 All the other
Comparative Examples 5 1.28 0.62 0.30 0.0006 14 31 14 All the other
Comparative Examples 6 1.26 0.19 0.28 0.0021 17 32 11 All the other
Comparative Examples 7 1.44 0.48 0.58 0.0009 13 29 12 All the other
Comparative Examples 8 1.38 0.92 0.32 0.0014 12 34 14 All the other
Comparative Examples 9 1.37 0.22 0.29 0.0018 14 33 13 All the other
Comparative Examples 10 1.38 0.24 0.28 0.0008 16 28 12 All the other
Comparative Examples 11 1.40 0.22 0.27 0.0024 15 29 11 All the other
Table 2
Figure BDA00003417822500071
Table 3
The present invention strictly controls the Ti content in molten steel, can effectively avoid in the finished steel plate annealing process, the strongly inhibited effect of the inclusiones such as TiN to crystal grain-growth, thereby can significantly improve the magnetic strength of finished steel plate, the impact of Ti content as shown in Figure 1 on the finished steel plate magnetic strength, as can be known: the finished product magnetic induction performance raises along with the reduction of Ti content.
The impact of RH refinement and deoxidation mode as shown in Figure 2 on nonmetallic inclusionsin steel, as can be known: adopt the ferrosilicon deoxidation, the amount of inclusions in steel will be less than the deoxidation of employing ferro-aluminum.
The impact of hot fine rolling temperature in as shown in Figure 3 on production board face quality, as can be known: along with the raising of finish rolling temperature in, the incidence of corrugated defect obviously reduces.
As shown in Table 3,1-11 compares with Comparative Examples, the non-oriented electromagnetic steel sheet product that the present invention obtains, and it is in apparent good order and condition, and than the high 0.02T of magnetic strength B50 with the conventional non-oriented electromagnetic steel sheet product of the trade mark, than the low 0.2W/kg of its iron loss P15/50.

Claims (5)

1. a high magnetic strength, low iron loss non-oriented electromagnetic steel sheet, the weight percent of its chemical composition is: C :≤0.004%, Si:0.1~1.6%, Mn:0.02~1.0%, S :≤0.003%, Al:0.1~0.6%, N :≤0.003%, Ti :≤0.0015%, and meet Si+Al:0.2~2.0%, Mn, Si, Al meet Mn=k 2* Si+k 3* Al+a, k 2=0.08~0.11, k 3=0.17~0.38, a is constant, a=0~0.7, and all the other are Fe and inevitable impurity.
2. high magnetic strength as claimed in claim 1, low iron loss non-oriented electromagnetic steel sheet, is characterized in that, the magnetic strength B50 of described high magnetic strength, low iron loss non-oriented electromagnetic steel sheet is 1.70-1.78T, and iron loss P15/50 is 3.59-5.5W/kg.
3. the manufacture method of high magnetic strength as claimed in claim 1 or 2, low iron loss non-oriented electromagnetic steel sheet, comprise the steps:
1) smelt, cast:
Smelt, be cast into slab by following chemical composition pre-treatment, converter smelting, RH refining, the chemical component weight percentage composition is: C :≤0.004%, Si:0.1~1.6%, Mn:0.02~1.0%, S≤0.003%, Al:0.1~0.6%, N≤0.003%, Ti≤0.0015%, and meet Si+Al:0.2~2.0%, Mn, Si and Al meet Mn=k 2* Si+k 3* Al+a, k 2=0.08~0.11, k 3=0.17~0.38, a is constant, a=0~0.7, and all the other are Fe and inevitable impurity;
2) hot rolling:
Slab obtains the normalizing plate after roughing, finish rolling, wherein, the slab tapping temperature is controlled at 1000~1150 ℃, one or more passages of roughing, and adopt the enclosed insulating device between roughing, finishing stand, guarantee finish rolling temperature in 〉=980 ℃;
3) pickling, cold rolling:
The normalizing plate is first carried out pickling, then it is cold rolling to carry out multi-pass, is rolled into the cold-reduced sheet of target thickness, wherein the cold rolling accumulative total draught of multi-pass is 70~81%;
4) annealing, coating:
The cold-reduced sheet that obtains is carried out obtaining described high magnetic strength, low iron loss non-oriented electromagnetic steel sheet after continuous annealing, coating, wherein, first be warmed up to 800~1000 ℃ of insulation 5~60s during continuous annealing, then the speed of cooling with 3~15 ℃/s slowly cools to 600~750 ℃.
4. the manufacture method of high magnetic strength as claimed in claim 3, low iron loss non-oriented electromagnetic steel sheet, it is characterized in that, step 1) in, before RH refining liquid steel decarburization end, alloying, adopt the complete deoxidation of ferrosilicon, the interpolation quantity of ferrosilicon meets formula (2), and after ferrosilicon adds, and molten steel need to carry out 1~2 or 3 with cocycle;
M FeSi=k 1* [O] Free/ t steel, k 1=0.1~0.2 (2)
Wherein, [O] FreeFree oxygen content while for RH refining decarburization, finishing in molten steel, k 1For deoxidation constant ,/t represents per ton.
5. the manufacture method of high magnetic strength as claimed in claim 3, low iron loss non-oriented electromagnetic steel sheet, is characterized in that step 4) in, annealing atmosphere is H 2And N 2Mixed gas, and both volume ratios are (30~70): (70~30), dew point≤-25 ℃.
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