CN103387735A - 一种改性阻燃abs树脂及其制备方法 - Google Patents
一种改性阻燃abs树脂及其制备方法 Download PDFInfo
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- CN103387735A CN103387735A CN2013103092195A CN201310309219A CN103387735A CN 103387735 A CN103387735 A CN 103387735A CN 2013103092195 A CN2013103092195 A CN 2013103092195A CN 201310309219 A CN201310309219 A CN 201310309219A CN 103387735 A CN103387735 A CN 103387735A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7461—Combinations of dissimilar mixers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/042—Graphene or derivatives, e.g. graphene oxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/136—Phenols containing halogens
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0022—Combinations of extrusion moulding with other shaping operations combined with cutting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/80—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
- B29C48/83—Heating or cooling the cylinders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2055/00—Use of specific polymers obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of main groups B29K2023/00 - B29K2049/00, e.g. having a vinyl group, as moulding material
- B29K2055/02—ABS polymers, i.e. acrylonitrile-butadiene-styrene polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2063/00—Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0026—Flame proofing or flame retarding agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0089—Impact strength or toughness
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
Dianmeter | 1~5μm |
Thickness | 0.8~1.2nm |
Single layer ratio | >99% |
Purity | >99% |
样品 | ABS(wt%) | TBBP(wt%) | 石墨烯(wt%) |
实施例1 | 100 | 0 | 0 |
实施例2 | 82 | 18 | 0 |
实施例3 | 82 | 17 | 1 |
实施例4 | 82 | 16 | 2 |
样品 | ABS | 阻燃剂 | 石墨烯 |
实施例5 | ABS | 四溴双酚A | JCGO-1 |
实施例6 | ABS | 四溴双酚A | JCGO-2 |
实施例7 | ABS | 四溴双酚A | P掺杂石墨烯 |
样品 | ABS(wt%) | TBBP(wt%) | 石墨烯(wt%) | 聚丁二烯的接枝共聚物(wt%) |
实施例8 | 82.9 | 16 | 0.1 | 1 |
实施例9 | 82 | 16 | 1 | 1 |
实施例10 | 78 | 16 | 5 | 1 |
实施例11 | 73 | 16 | 10 | 1 |
样品 | ABS(wt%) | TBBP(wt%) | 石墨烯(wt%) | 聚丁二烯的接枝共聚物(wt%) |
实施例12 | 87 | 10 | 2 | 1 |
实施例13 | 83 | 14 | 2 | 1 |
实施例14 | 77 | 20 | 2 | 1 |
实施例15 | 73 | 24 | 2 | 1 |
样品 | ABS(wt%) | TBBP(wt%) | 石墨烯(wt%) | 聚丁二烯的接枝共聚物(wt%) |
实施例16 | 82 | 16 | 2 | 0 |
实施例17 | 81 | 16 | 2 | 1 |
实施例18 | 80 | 16 | 2 | 2 |
实施例19 | 78 | 16 | 2 | 4 |
实施例20 | 76 | 16 | 2 | 6 |
实施例21 | 74 | 16 | 2 | 8 |
Claims (10)
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CN103387735A true CN103387735A (zh) | 2013-11-13 |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103804845A (zh) * | 2014-01-28 | 2014-05-21 | 盐城纳新天地新材料科技有限公司 | 一种高强度、高导热abs母粒及其制备方法 |
CN104231588A (zh) * | 2014-09-29 | 2014-12-24 | 中节能太阳能科技(镇江)有限公司 | 一种光伏接线盒盒体材料及其制备方法 |
CN104974462A (zh) * | 2015-07-27 | 2015-10-14 | 苏州荣昌复合材料有限公司 | 一种石墨烯-abs复合阻燃塑料及其制备方法 |
KR20160079529A (ko) * | 2014-12-26 | 2016-07-06 | 연세대학교 산학협력단 | 표면에 인이 도핑된 산화 그래핀을 포함하는 난연제 및 이의 제조방법 |
CN105802015A (zh) * | 2016-04-29 | 2016-07-27 | 宁波宏协承汽车部件有限公司 | 一种阻燃pp汽车用前风挡下卡条材料及其制备方法 |
EP3130630A1 (en) * | 2015-08-12 | 2017-02-15 | Humboldt Universität zu Berlin | Rubber compositions with low content of zinc oxide |
CN106633151A (zh) * | 2016-12-29 | 2017-05-10 | 中国科学院合肥物质科学研究院 | 一种泡沫保温材料防火阻燃表面处理剂及其制备方法 |
CN106832771A (zh) * | 2016-12-28 | 2017-06-13 | 广东延春高新材料科技股份有限公司 | 一种阻燃环氧树脂玻璃钢制备方法 |
CN113214591A (zh) * | 2021-04-26 | 2021-08-06 | 湖北凯威高分子材料有限公司 | 一种磷掺杂石墨烯改性abs/pet合金材料及其制备方法 |
CN114921050A (zh) * | 2022-06-17 | 2022-08-19 | 山东亿科化学有限责任公司 | 一种改性abs树脂及其制备方法、改性abs复合材料及其应用 |
Citations (3)
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WO2004048459A1 (en) * | 2002-11-27 | 2004-06-10 | Bromine Compounds Ltd. | Fire retarded styrene polymer compositions |
WO2012170086A1 (en) * | 2011-02-25 | 2012-12-13 | William Marsh Rice University | Sorption and separation of various materials by graphene oxides |
CN102826542A (zh) * | 2012-09-14 | 2012-12-19 | 常州第六元素材料科技股份有限公司 | 一种具有中孔的高比表面活性石墨烯、其制备方法及其用途 |
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2013
- 2013-07-22 CN CN201310309219.5A patent/CN103387735B/zh active Active
Patent Citations (3)
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WO2004048459A1 (en) * | 2002-11-27 | 2004-06-10 | Bromine Compounds Ltd. | Fire retarded styrene polymer compositions |
WO2012170086A1 (en) * | 2011-02-25 | 2012-12-13 | William Marsh Rice University | Sorption and separation of various materials by graphene oxides |
CN102826542A (zh) * | 2012-09-14 | 2012-12-19 | 常州第六元素材料科技股份有限公司 | 一种具有中孔的高比表面活性石墨烯、其制备方法及其用途 |
Non-Patent Citations (3)
Title |
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SHINN-GWO HONG ET AL: "Fire performance and mechanical properties of acrylonitrile-butadiene-styrene copolymer/modified expandable graphite composites", 《FIRE AND MATERIALS》, vol. 36, 21 September 2011 (2011-09-21) * |
张丽等: "石墨烯/ABS树脂复合体系的阻燃性能", 《高分子材料科学与工程》, vol. 29, no. 5, 31 May 2013 (2013-05-31) * |
杨有财等: "EG和DBDPE/Sb2O3同阻燃ABS的阻燃性能及机理研究", 《塑料科技》, vol. 38, no. 4, 30 April 2010 (2010-04-30) * |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103804845A (zh) * | 2014-01-28 | 2014-05-21 | 盐城纳新天地新材料科技有限公司 | 一种高强度、高导热abs母粒及其制备方法 |
CN104231588A (zh) * | 2014-09-29 | 2014-12-24 | 中节能太阳能科技(镇江)有限公司 | 一种光伏接线盒盒体材料及其制备方法 |
KR101665680B1 (ko) | 2014-12-26 | 2016-10-12 | 연세대학교 산학협력단 | 표면에 인이 도핑된 산화 그래핀을 포함하는 난연제 및 이의 제조방법 |
KR20160079529A (ko) * | 2014-12-26 | 2016-07-06 | 연세대학교 산학협력단 | 표면에 인이 도핑된 산화 그래핀을 포함하는 난연제 및 이의 제조방법 |
CN104974462A (zh) * | 2015-07-27 | 2015-10-14 | 苏州荣昌复合材料有限公司 | 一种石墨烯-abs复合阻燃塑料及其制备方法 |
EP3130630A1 (en) * | 2015-08-12 | 2017-02-15 | Humboldt Universität zu Berlin | Rubber compositions with low content of zinc oxide |
WO2017025172A1 (en) * | 2015-08-12 | 2017-02-16 | Humboldt-Universität Zu Berlin | Rubber compositions with low content of zinc oxide |
CN105802015A (zh) * | 2016-04-29 | 2016-07-27 | 宁波宏协承汽车部件有限公司 | 一种阻燃pp汽车用前风挡下卡条材料及其制备方法 |
CN106832771A (zh) * | 2016-12-28 | 2017-06-13 | 广东延春高新材料科技股份有限公司 | 一种阻燃环氧树脂玻璃钢制备方法 |
CN106633151A (zh) * | 2016-12-29 | 2017-05-10 | 中国科学院合肥物质科学研究院 | 一种泡沫保温材料防火阻燃表面处理剂及其制备方法 |
CN113214591A (zh) * | 2021-04-26 | 2021-08-06 | 湖北凯威高分子材料有限公司 | 一种磷掺杂石墨烯改性abs/pet合金材料及其制备方法 |
CN114921050A (zh) * | 2022-06-17 | 2022-08-19 | 山东亿科化学有限责任公司 | 一种改性abs树脂及其制备方法、改性abs复合材料及其应用 |
CN114921050B (zh) * | 2022-06-17 | 2023-06-16 | 山东亿科化学有限责任公司 | 一种改性abs树脂及其制备方法、改性abs复合材料及其应用 |
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