CN103387712B - 一种石墨烯改性的阻燃聚丙烯材料及其制备方法 - Google Patents
一种石墨烯改性的阻燃聚丙烯材料及其制备方法 Download PDFInfo
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- CN103387712B CN103387712B CN201310308938.5A CN201310308938A CN103387712B CN 103387712 B CN103387712 B CN 103387712B CN 201310308938 A CN201310308938 A CN 201310308938A CN 103387712 B CN103387712 B CN 103387712B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/875—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0022—Combinations of extrusion moulding with other shaping operations combined with cutting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0026—Flame proofing or flame retarding agents
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
Dianmeter | 1~5μm |
Thickness | 0.8~1.2nm |
Single layer ratio | >99% |
Purity | >99% |
PP(wt%) | 阻燃剂(wt%) | 石墨烯(wt%) | |
实施例1 | 100 | 0 | 0 |
实施例2 | 75 | 25 | 0 |
实施例3 | 75 | 24.9 | 0.1 |
实施例4 | 75 | 24.5 | 0.5 |
实施例5 | 75 | 24 | 1 |
实施例6 | 75 | 23 | 2 |
实施例7 | 75 | 22.5 | 2.5 |
PP(wt%) | MPP(wt%) | PER(wt%) | 石墨烯(wt%) | |
实施例8 | 75 | 0 | 23 | 2 |
实施例9 | 75 | 19.2 | 3.8 | 2 |
实施例10 | 75 | 17.25 | 5.75 | 2 |
实施例11 | 75 | 15.3 | 7.7 | 2 |
实施例12 | 75 | 11.5 | 11.5 | 2 |
实施例13 | 75 | 7.7 | 15.3 | 2 |
实施例14 | 75 | 5.75 | 17.25 | 2 |
样品 | 拉伸强度 | 弯曲模量 | 悬臂梁缺口冲 | 极限氧指数 | UL-94 | 是否有溶滴 |
/MPa | /MPa | 击强度/kJ·m-2 | % | |||
实施例18 | 27.2 | 986 | 4.2 | 31.6 | V0 | 否 |
实施例19 | 27.8 | 994 | 4.6 | 31.4 | V0 | 否 |
实施例20 | 27.6 | 963 | 4.6 | 31.3 | V0 | 否 |
样品 | PP | 阻燃剂 | 石墨烯 |
对比例1 | PP | MPP与PER质量比3:1 | JCGO-1 |
对比例2 | PP | MPP与PER质量比3:1 | JCGO-2 |
对比例3 | PP | MPP与PER质量比3:1 | P掺杂石墨烯 |
PP(wt%) | APP(wt%) | PER(wt%) | 石墨烯(wt%) | |
对比例4 | 100 | 0 | 0 | 0 |
对比例5 | 75 | 18.75 | 6.25 | 0 |
对比例6 | 75 | 18.675 | 6.225 | 0.1 |
对比例7 | 75 | 18.375 | 6.125 | 0.5 |
对比例8 | 75 | 18 | 6 | 1 |
对比例9 | 75 | 17.25 | 5.75 | 2 |
Claims (9)
Priority Applications (1)
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CN201310308938.5A CN103387712B (zh) | 2013-04-08 | 2013-07-22 | 一种石墨烯改性的阻燃聚丙烯材料及其制备方法 |
Applications Claiming Priority (3)
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CN2013101197099A CN103205058A (zh) | 2013-04-08 | 2013-04-08 | 一种石墨烯改性的阻燃聚丙烯材料及其制备方法 |
CN201310119709.9 | 2013-04-08 | ||
CN201310308938.5A CN103387712B (zh) | 2013-04-08 | 2013-07-22 | 一种石墨烯改性的阻燃聚丙烯材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN103387712A CN103387712A (zh) | 2013-11-13 |
CN103387712B true CN103387712B (zh) | 2014-07-09 |
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CN2013101197099A Withdrawn CN103205058A (zh) | 2013-04-08 | 2013-04-08 | 一种石墨烯改性的阻燃聚丙烯材料及其制备方法 |
CN201310308938.5A Active CN103387712B (zh) | 2013-04-08 | 2013-07-22 | 一种石墨烯改性的阻燃聚丙烯材料及其制备方法 |
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Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103205058A (zh) * | 2013-04-08 | 2013-07-17 | 北京航天凯恩化工科技有限公司 | 一种石墨烯改性的阻燃聚丙烯材料及其制备方法 |
CN104140588A (zh) * | 2014-06-10 | 2014-11-12 | 东莞上海大学纳米技术研究院 | 一种多组分无卤阻燃母粒及制备方法 |
CN105273727A (zh) * | 2015-11-25 | 2016-01-27 | 北京旭碳新材料科技有限公司 | 用于阻燃复合材料的组合物和氧化石墨烯阻燃薄膜及其制备方法和应用 |
CN105647549B (zh) * | 2015-11-25 | 2018-02-16 | 北京旭碳新材料科技有限公司 | 一种石墨烯阻燃薄膜及其制备方法和应用 |
CN105802015A (zh) * | 2016-04-29 | 2016-07-27 | 宁波宏协承汽车部件有限公司 | 一种阻燃pp汽车用前风挡下卡条材料及其制备方法 |
CN106009419A (zh) * | 2016-08-09 | 2016-10-12 | 叶伟然 | 一种新型石墨烯消烟阻燃pvc及其制备方法 |
CN106543711B (zh) * | 2016-12-09 | 2019-03-29 | 宜春学院 | 纳米无卤阻燃尼龙6复合材料的制备方法 |
CN107033458A (zh) * | 2017-05-09 | 2017-08-11 | 泰山医学院 | 一种协效阻燃木粉/聚丙烯木塑复合材料及其制备方法 |
CN107245182A (zh) * | 2017-06-21 | 2017-10-13 | 常州碳润新材料科技有限公司 | 一种聚磷酸铵/石墨烯协同阻燃eva发泡材料及其制备方法 |
CN108264685A (zh) * | 2017-12-25 | 2018-07-10 | 温州鑫泰新材料股份有限公司 | 一种改性pp阻燃材料空调吸塑隔热板 |
CN108467547A (zh) * | 2018-04-04 | 2018-08-31 | 宁波福天新材料科技有限公司 | 一种转换器用环保阻燃抗静电聚丙烯组合物及其制备方法 |
TWI732195B (zh) | 2018-05-17 | 2021-07-01 | 利機企業股份有限公司 | 阻燃耐磨的複合材料 |
CN109942959B (zh) * | 2019-04-19 | 2022-01-07 | 陕西理工大学 | 一种聚烯烃-微胶囊阻燃复合材料的制备方法 |
US20220204748A1 (en) * | 2019-05-17 | 2022-06-30 | Sabic Global Technologies B.V. | Process for producing polypropylene composition |
CN110698772A (zh) * | 2019-10-15 | 2020-01-17 | 福州大学 | 一种改性聚磷酸铵/改性氧化石墨烯阻燃跑道颗粒材料 |
EP3885401A1 (en) * | 2020-03-25 | 2021-09-29 | Avanzare Innovacion Tencologica S.L. | Self-sensing flame resistant polymeric materials |
CN114685848A (zh) * | 2020-12-29 | 2022-07-01 | 洛阳尖端技术研究院 | 膨胀型阻燃剂、塑料及其制备方法与应用 |
CN114836023B (zh) * | 2022-04-22 | 2023-07-14 | 福州大学 | 一种阻燃抗静电tpu复合材料 |
CN114874542B (zh) * | 2022-04-29 | 2023-08-08 | 海信空调有限公司 | 无卤阻燃聚丙烯材料及其制备方法、电控盒以及空调 |
CN114914022B (zh) * | 2022-06-13 | 2023-02-28 | 广州市孖宝电缆有限公司 | 一种抗电磁、阻燃电缆 |
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CN103205058A (zh) * | 2013-04-08 | 2013-07-17 | 北京航天凯恩化工科技有限公司 | 一种石墨烯改性的阻燃聚丙烯材料及其制备方法 |
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CN103012953B (zh) * | 2012-10-23 | 2015-06-17 | 台州学院 | 一种阻燃聚丙烯/石墨烯/碳纳米管纳米复合材料及其制备方法 |
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2013
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