CN103387419B - A kind of porcelain Jinsui River and its using method suitable for microwave oven - Google Patents
A kind of porcelain Jinsui River and its using method suitable for microwave oven Download PDFInfo
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- CN103387419B CN103387419B CN201310366575.0A CN201310366575A CN103387419B CN 103387419 B CN103387419 B CN 103387419B CN 201310366575 A CN201310366575 A CN 201310366575A CN 103387419 B CN103387419 B CN 103387419B
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- jinsui river
- porcelain
- ester salt
- microwave oven
- flux
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Abstract
The present invention discloses a kind of porcelain Jinsui River suitable for microwave oven and its using method, including to gold compound, flux, polycarboxylic acids binding agent, the selection of surface agent for fixing, and the optimization to any of the above material addition, after above-mentioned raw materials are mixed according to certain proportioning, Jinsui River is directly decorated and is made in ceramic substrate surface or organizine wire mark brush, form Jinsui River decorative pattern (decalcomania), utensil containing the decorative pattern is used directly for heating in microwave oven, and the integrity and the verity of color of the noble metal decorative pattern in energy holder, therefore there is wide market prospect.
Description
Technical field
The invention belongs to technical field of ceramic material, and in particular to a kind of porcelain Jinsui River and its use suitable for microwave oven
Method.
Background technology
A few days ago, domestic and international daily-use fine and Pengyang china stone producer commonly use Jinsui River as ornament materials.But tradition
The porcelain of Jinsui River decoration has a great defect, and being exactly can not be used in microwave oven.Once microwave oven is opened, it is placed in stove
Porcelain on layer gold strong electric spark is produced under microwave intense radiation, make layer gold be subject to heavy damage, so as to lose yellow brightness.
With the day by day popularization of microwave oven, the demand of microwave porcelain constantly expands.Domestic each porcelain producer is currently using avoidance
Method, i.e., with ceramic whiteware or only with the porcelain of pigment decoration as microwave porcelain, it is to avoid use Jinsui River.This makes China's microwave ceramics
Decorative effect and designs and varieties are all seriously affected, and constrain significantly the international competitiveness of China's microwave porcelain.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of process is simple, synthesis low cost, stable performance and is applied to
Porcelain Jinsui River of microwave oven and its using method.
To solve above technical problem, the technical scheme is that：A kind of porcelain Jinsui River suitable for microwave oven, which is special
Levy is to include following component by weight percentage：
Gold compound 15-35%
Flux 20-40%
Polycarboxylic acids binding agent 20-40%
Surface agent for fixing 1-5%；
The flux by the carboxylate of aluminum, the sulfonate of silicon, cerium sulfuric acid ester salt, the phosphate ester salt of vanadium, zirconium quaternary ammonium salt
Composition；
The preparation method of the polycarboxylic acids binding agent is：Mercaptopropionic acid, sodium peroxydisulfate, isobutanol, magnesium sulfite are added
Polyreaction is carried out 2 hours in 50 DEG C of water, add potassium polyphosphate terminating reaction and obtain co-poly carboxylic acid；Will be described
Co-poly carboxylic acid is cooled to 30 DEG C, adds the pH value that hydrochloric acid adjusts reaction system to be 4～5, that is, obtains polycarboxylic acids binding agent；
The surface agent for fixing is benzoate, stearate.
The gold compound is the carboxylate or sulfonate or sulfuric acid ester salt or phosphate ester salt of gold.
The percentage by weight of the flux is consisted of：The sulfonate 35% of the carboxylate 30%, silicon of aluminum, cerium sulfuric acid ester salt
13%th, the quaternary ammonium salt 7% of the phosphate ester salt 15%, zirconium of vanadium.
The using method in described porcelain Jinsui River, it is characterised in that comprise the steps：
The first step：Gold compound, flux, polycarboxylic acids binding agent, surface agent for fixing are mixed at 60 DEG C according to proportioning
Porcelain Jinsui River is made in conjunction；
Second step：Jinsui River is directly decorated and is made in ceramic substrate surface or organizine wire mark brush
Material surface；
3rd step：Ceramic base material Jing after the decoration of Jinsui River, 750 DEG C of color roastings of Jing are obtained into the ceramic suitable for microwave oven
Product.
The innovation of the present invention is that Jinsui River obtained in the present invention directly or after organizine wire mark brush makes marble paper can be decorated
In ceramic substrate surface, the ceramic base material is used directly for heating in microwave oven, and can keep Jinsui River decoration figure on base material
The verity of the integrity and color of case, and the Jinsui River is in technological requirement and traditional Jinsui River of the enterprising luggage decorations of ceramic base material
Decoration technology particularly do not require, therefore with wide market prospect.
Specific embodiment
With reference to specific embodiment, the present invention is further detailed explanation.
Embodiment 1
Mercaptopropionic acid, sodium peroxydisulfate, isobutanol, magnesium sulfite are added in 50 DEG C of water carries out polyreaction 2 hours, then
Potassium polyphosphate terminating reaction is added to obtain co-poly carboxylic acid；Described co-poly carboxylic acid is cooled to into 30 DEG C, salt is added
It is 4 that acid adjusts the pH value of reaction system, that is, obtain polycarboxylic acids binding agent；
By the sulfonate 35% of the carboxylate 30%, silicon of aluminum, the phosphate ester salt 15%, zirconium of cerium sulfuric acid ester salt 13%, vanadium
Quaternary ammonium salt 7% is obtained flux after being mixed in proportion.
Gold-sulfonate, flux, polycarboxylic acids binding agent, benzoate are carried out being mixed and made into porcelain at 60 DEG C according to proportioning
Use Jinsui River；
Again Jinsui River is directly decorated and is made in ceramic substrate surface or organizine wire mark brush
Face；
Finally by the ceramic base material Jing after the decoration of Jinsui River, 750 DEG C of color roastings of Jing obtain the ceramic suitable for microwave oven.
Embodiment 2
Mercaptopropionic acid, sodium peroxydisulfate, isobutanol, magnesium sulfite are added in 50 DEG C of water carries out polyreaction 2 hours, then
Potassium polyphosphate terminating reaction is added to obtain co-poly carboxylic acid；Described co-poly carboxylic acid is cooled to into 30 DEG C, salt is added
It is 5 that acid adjusts the pH value of reaction system, that is, obtain polycarboxylic acids binding agent；
By the sulfonate 35% of the carboxylate 30%, silicon of aluminum, the phosphate ester salt 15%, zirconium of cerium sulfuric acid ester salt 13%, vanadium
Quaternary ammonium salt 7% is obtained flux after being mixed in proportion.
Gold-sulfuric acid ester salt, flux, polycarboxylic acids binding agent, benzoate are mixed at 60 DEG C according to proportioning
Porcelain Jinsui River；
Again Jinsui River is directly decorated and is made in ceramic substrate surface or organizine wire mark brush
Face；
Finally by the ceramic base material Jing after the decoration of Jinsui River, 750 DEG C of color roastings of Jing obtain the ceramic suitable for microwave oven.
Embodiment 3
Mercaptopropionic acid, sodium peroxydisulfate, isobutanol, magnesium sulfite are added in 50 DEG C of water carries out polyreaction 2 hours, then
Potassium polyphosphate terminating reaction is added to obtain co-poly carboxylic acid；Described co-poly carboxylic acid is cooled to into 30 DEG C, salt is added
It is 4 that acid adjusts the pH value of reaction system, that is, obtain polycarboxylic acids binding agent；
By the sulfonate 35% of the carboxylate 30%, silicon of aluminum, the phosphate ester salt 15%, zirconium of cerium sulfuric acid ester salt 13%, vanadium
Quaternary ammonium salt 7% is obtained flux after being mixed in proportion.
Gold-phosphate ester salt, flux, polycarboxylic acids binding agent, stearate are mixed at 60 DEG C according to proportioning
Porcelain Jinsui River；
Again Jinsui River is directly decorated and is made in ceramic substrate surface or organizine wire mark brush
Face；
Finally by the ceramic base material Jing after the decoration of Jinsui River, 750 DEG C of color roastings of Jing obtain the ceramic suitable for microwave oven.
Claims (4)
1. a kind of porcelain Jinsui River suitable for microwave oven, it is characterised in that include following component by weight percentage：
Gold compound 15-35%
Flux 20-40%
Polycarboxylic acids binding agent 20-40%
Surface agent for fixing 1-5%；
The flux is made up of the quaternary ammonium salt of the carboxylate of aluminum, the sulfonate of silicon, cerium sulfuric acid ester salt, the phosphate ester salt of vanadium, zirconium；
The preparation method of the polycarboxylic acids binding agent is：Mercaptopropionic acid, sodium peroxydisulfate, isobutanol, magnesium sulfite are added to into 50
Polyreaction is carried out 2 hours in DEG C water, add potassium polyphosphate terminating reaction and obtain co-poly carboxylic acid；By described poly- carboxylic
Acid copolymer is cooled to 30 DEG C, adds the pH value that hydrochloric acid adjusts reaction system to be 4～5, that is, obtains polycarboxylic acids binding agent；
The surface agent for fixing is benzoate, stearate.
2. porcelain Jinsui River according to claim 1, it is characterised in that：The gold compound is the carboxylate or sulfonate of gold
Or sulfuric acid ester salt or phosphate ester salt.
3. porcelain Jinsui River according to claim 1, it is characterised in that：The percentage by weight of the flux is consisted of：Aluminum
The sulfonate 35% of carboxylate 30%, silicon, the quaternary ammonium salt 7% of the phosphate ester salt 15%, zirconium of cerium sulfuric acid ester salt 13%, vanadium.
4. the using method according to the arbitrary described porcelain Jinsui River of claim 1-3, it is characterised in that comprise the steps：
The first step：Gold compound, flux, polycarboxylic acids binding agent, surface agent for fixing are carried out into mixing system at 60 DEG C according to proportioning
Into porcelain Jinsui River；
Second step：Jinsui River is directly decorated and is made in ceramic substrate surface or organizine wire mark brush
Face；
3rd step：Ceramic base material Jing after the decoration of Jinsui River, 750 DEG C of color roastings of Jing are obtained into the ceramic suitable for microwave oven.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310366575.0A CN103387419B (en) | 2013-08-21 | 2013-08-21 | A kind of porcelain Jinsui River and its using method suitable for microwave oven |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310366575.0A CN103387419B (en) | 2013-08-21 | 2013-08-21 | A kind of porcelain Jinsui River and its using method suitable for microwave oven |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103387419A CN103387419A (en) | 2013-11-13 |
| CN103387419B true CN103387419B (en) | 2017-04-05 |
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| CN201310366575.0A Expired - Fee Related CN103387419B (en) | 2013-08-21 | 2013-08-21 | A kind of porcelain Jinsui River and its using method suitable for microwave oven |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1072670A (en) * | 1992-11-15 | 1993-06-02 | 山东省硅酸盐研究设计院 | Jinsui River |
| CN1363723A (en) * | 2001-10-23 | 2002-08-14 | 南京大学 | Molten gold resisting high-temp sinter and its preparing process |
| CN1858024A (en) * | 2006-04-28 | 2006-11-08 | 冯建光 | Method for preparing imitating gold water |
-
2013
- 2013-08-21 CN CN201310366575.0A patent/CN103387419B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1072670A (en) * | 1992-11-15 | 1993-06-02 | 山东省硅酸盐研究设计院 | Jinsui River |
| CN1363723A (en) * | 2001-10-23 | 2002-08-14 | 南京大学 | Molten gold resisting high-temp sinter and its preparing process |
| CN1858024A (en) * | 2006-04-28 | 2006-11-08 | 冯建光 | Method for preparing imitating gold water |
Non-Patent Citations (2)
| Title |
|---|
| 低温烤烧瓷用金水的研究;邓宇等;《陶瓷工程》;20010630;第3-5页 * |
| 微波瓷用金水的研制;陈建文等;《陶瓷科学与艺术》;20021231;第6-7页 * |
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| CN103387419A (en) | 2013-11-13 |
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