CN103360031A - Raw material of Longquan celadon product preparation technology using celadon waste and method thereof - Google Patents
Raw material of Longquan celadon product preparation technology using celadon waste and method thereof Download PDFInfo
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- CN103360031A CN103360031A CN2013102871676A CN201310287167A CN103360031A CN 103360031 A CN103360031 A CN 103360031A CN 2013102871676 A CN2013102871676 A CN 2013102871676A CN 201310287167 A CN201310287167 A CN 201310287167A CN 103360031 A CN103360031 A CN 103360031A
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- celadon
- longquan celadon
- longquan
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
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Abstract
The invention relates to the technical field of material science and aims at providing a raw material of a Longquan celadon product preparation technology using celadon waste and a method thereof. The raw material of a Longquan celadon product preparation technology using celadon waste comprises Longquan celadon blank and Longquan celadon glaze. The method for realizing Longquan celadon product preparation by use of the raw material comprises a step of high-temperature firing. According to the method provided by the invention, the whole preparation flow is simple, no special requirements are imposed on the technology, and the Longquan celadon waste can be processed in bulk without occupying land, thereby saving the raw material of Longquan celadon and reducing the preparation cost; through ultrafine processing, the liquidity, plasticity and body bonding strength of the waste-containing grouting slurry are improved; and by introducing the celadon waste, the characteristics (particularly beauty) of the celadon product are maintained.
Description
Technical field
The invention relates to materials science field, particularly utilize the celadon waste material to prepare raw material and the method thereof of Longquan celadon product process.
Background technology
Longquan celadon is described as " flower of celadon ", and it is verdant sparkling and crystal-clear, moist as beautiful, and is extremely dark on the Chinese culture impact.2009, Longquan celadon went through to list in " human non-material cultural heritage masterpiece register ", and perfect eternal porcelain rhythm of deducing, poem are drawn the south of the River in 2010 World Expos, and it just extensively is that people institute just accepts that dragon's fountain industry celadon is worth.Yet, Longquan celadon is because unique raw material and burn technology for making adopts twice firing, easily produces in process of production cracking, distortion, problem that apparent aesthetic feeling is not strong, large shaped celadon product qualification rate is about 40% only, causes a large amount of useless ceramics and useless base sheet.In addition, the celadon Mineral resources are very rare, and this Sustainable development to celadon brings serious challenge.
The more existing research reports of the recycling of relevant ceramic waste material, relate to a kind of processing method of utilizing ceramic polished waste residue or ceramic waste material to produce the ultra-thin ceramic polished tile such as Granted publication CN100548923C patent of invention, but because the singularity of Longquan celadon raw material and technique there is not yet the open report that the Longquan celadon waste recovery is utilized.
Summary of the invention
Main purpose of the present invention is to overcome deficiency of the prior art, provides a kind of simple flow, cost is low, product performance the are high celadon waste material that utilizes to prepare raw material and the method thereof of Longquan celadon product process.For solving the problems of the technologies described above, solution of the present invention is:
The raw material that utilizes the celadon waste material to prepare the Longquan celadon product process is provided, comprise Longquan celadon blank and Longquan celadon glaze, described Longquan celadon blank is according to weight percent meter, composed of the following components: porcelain stone 30～40%, Zijin soil 40～50%, perlite 8～12%, base substrate waste material 3～5% burns till waste material 6～8%; Described Longquan celadon glaze is according to weight percent meter, and is composed of the following components: quartz 15～25%, feldspar 40～45%, Zijin soil 18～25%, Wingdale 10～15%, useless glaze 3～6%.
The method of utilizing described raw material to realize preparing the Longquan celadon goods is provided, comprises that high temperature burns till, and specifically may further comprise the steps:
Steps A: will burn till waste material and carry out the ultramicronising processing, and make the granularity of burning till waste material between 0.5～2 μ m;
Step B: with the moiety of burning till waste material and other Longquan celadon blanks of processing in the steps A ball mill of packing in proportion, ball milling mixes after adding water, pouring out water after old becomes mud to do, then injection forming repaired biscuit again, obtain work in-process after the drying, the kiln of again work in-process being packed into carries out biscuiting in 800～900 ℃;
Step C: with each moiety of Longquan celadon glaze ball mill of packing in proportion, add the 1wt% dispersion agent, pour out into glaze slip behind the ball milling;
Step D: with the glaze slip that obtains among the step C work in-process of biscuiting among the step B are carried out glazing, then with the kiln of packing into after the work in-process drying after the glazing, the high temperature with 1200～1250 ℃ in reducing atmosphere burns till, and namely finishes the making of Longquan celadon goods.
In the present invention, the ultramicronising in the described steps A is processed and is referred to: roughly grind with the high pressure roll mill first, carry out fine grinding with stirring mill again.
Compared with prior art, the invention has the beneficial effects as follows:
1, whole manufacturing process is simple, and technique is not had special requirement, can process in a large number and land occupation no longer the Longquan celadon waste material, saves Longquan celadon raw material usage quantity, reduces preparation cost;
2, process by ultramicronising, improve the bonding strength of flowability, plasticity-and the base substrate of the slip casting slurry that contains waste material;
3, the introducing of celadon waste material has kept the characteristic, particularly aesthetic property of celadon product.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail:
Comprise Longquan celadon blank and Longquan celadon glaze for the raw material for preparing the Longquan celadon goods with the celadon waste material.
The Longquan celadon blank is according to weight percent meter, and is composed of the following components: porcelain stone 30～40%, and Zijin soil 40～50%, perlite 8～12%, base substrate waste material 3～5% burns till waste material 6～8%.Described base substrate waste material refers to the waste material that produces in the celadon blank forming process.The described waste material that burns till refers in the celadon sintering process because of the waste product that ftractures, distortion produces.
The Longquan celadon glaze is according to weight percent meter, and is composed of the following components: quartz 15～25%, feldspar 40～45%, Zijin soil 18～25%, Wingdale 10～15%, useless glaze 3～6%.Described useless glaze refers to the useless glaze that celadon glazing operation produces.
Utilize described raw material to realize preparing the method for Longquan celadon goods, concrete steps comprise:
Steps A: will burn till waste material and carry out the ultramicronising processing, and make the granularity of burning till waste material between 0.5～2 μ m.The ultramicronising is here processed and is referred to: roughly grind with the high pressure roll mill first, carry out fine grinding with stirring mill again.
Step B: with the moiety of burning till waste material and other Longquan celadon blanks of processing in the steps A ball mill of packing in proportion, ball milling mixes after adding water, pouring out water after old becomes mud to do, then injection forming repaired biscuit again, obtain work in-process after the drying, the kiln of again work in-process being packed into carries out biscuiting in 800～900 ℃.
Step C: with each moiety of Longquan celadon glaze ball mill of packing in proportion, add the 1wt% dispersion agent, pour out into glaze slip behind the ball milling.
Step D: with the glaze slip that obtains among the step C work in-process of biscuiting among the step B are carried out glazing, then with the kiln of packing into after the work in-process drying after the glazing, the high temperature with 1200～1250 ℃ in reducing atmosphere burns till, and namely finishes the making of Longquan celadon goods.
The following examples can make this professional professional and technical personnel's comprehend the present invention, but do not limit the present invention in any way.Dispersion agent among the embodiment adopts PEG1000.
Embodiment 1
The Longquan celadon blank specifically consists of according to weight percent meter: porcelain stone 30%, and Zijin soil 50%, perlite 8%, base substrate waste material 5% burns till waste material 7%.The Longquan celadon glaze specifically consists of according to weight percent meter: quartz 25%, feldspar 40%, Zijin soil 20%, Wingdale 10%, useless glaze 5%.
Making processes is: will burn till first waste material and use high pressure roll-in mill to grind 4 hours, through stirring levigate mill 6 hours, granularity is 2 μ m after the ultra micro refinement again.Then the moiety of burning till waste material and other Longquan celadon blanks that will process, the ball mill of packing in proportion is take water as ball-milling medium, ball milling 30 hours is poured out water after old and is become mud to do, then injection forming repaired biscuit again, naturally the kiln of packing into after drying, biscuiting is 0.5 hour in 900 ℃.The ball mill of again each moiety of Longquan celadon glaze being packed in proportion adds 1wt% PEG1000, and ball milling was poured out into glaze slip after 36 hours.With the work in-process base substrate glaze slip that obtains of biscuiting, carry out twice glazing at last, the glaze layer thickness is 5mm approximately, Deng the kiln of packing into after the seasoning of glaze layer, high temperature burns till in reducing atmosphere, and firing temperature adopts 1200 ℃, namely make the even structure densification, the Longquan celadon goods that glaze is plump, fine and smooth.
Embodiment 2
The Longquan celadon blank specifically consists of according to weight percent meter: porcelain stone 40%, and Zijin soil 40%, perlite 10%, base substrate waste material 4% burns till waste material 6%.The Longquan celadon glaze specifically consists of according to weight percent meter: quartz 15%, feldspar 42%, Zijin soil 25%, Wingdale 15%, useless glaze 3%.
Making processes is: will burn till first waste material and use high pressure roll-in mill to grind 4 hours, through stirring levigate mill 8 hours, granularity is 1.1 μ m after the ultra micro refinement again.Then the moiety of burning till waste material and other Longquan celadon blanks that will process, the ball mill of packing in proportion is take water as ball-milling medium, ball milling 30 hours is poured out water after old and is become mud to do, then injection forming repaired biscuit again, naturally the kiln of packing into after drying, biscuiting is 1 hour in 800 ℃.The ball mill of again each moiety of Longquan celadon glaze being packed in proportion adds 1wt% PEG400, and ball milling was poured out into glaze slip after 40 hours.With the work in-process base substrate glaze slip that obtains of biscuiting, carry out twice glazing at last, the glaze layer thickness is 5mm approximately, Deng the kiln of packing into after the seasoning of glaze layer, high temperature burns till in reducing atmosphere, and firing temperature adopts 1230 ℃, namely make the even structure densification, the Longquan celadon goods that glaze is plump, fine and smooth.
Embodiment 3
The Longquan celadon blank specifically consists of according to weight percent meter: porcelain stone 35%, and Zijin soil 42%, perlite 12%, base substrate waste material 3% burns till waste material 8%.The Longquan celadon glaze specifically consists of according to weight percent meter: quartz 19%, feldspar 45%, Zijin soil 18%, Wingdale 12%, useless glaze 6%.
Making processes is: will burn till first waste material and use high pressure roll-in mill to grind 6 hours, through stirring levigate mill 8 hours, granularity is 0.5 μ m after the ultra micro refinement again.Then the moiety of burning till waste material and other Longquan celadon blanks that will process, the ball mill of packing in proportion is take water as ball-milling medium, ball milling 24 hours is poured out water after old and is become mud to do, then injection forming repaired biscuit again, naturally the kiln of packing into after drying, biscuiting is 45 minutes in 850 ℃.The ball mill of again each moiety of Longquan celadon glaze being packed in proportion adds 1wt% PEG1000, and ball milling was poured out into glaze slip after 30 hours.With the work in-process base substrate glaze slip that obtains of biscuiting, carry out three glazings at last, the glaze layer thickness is 7mm approximately, Deng the kiln of packing into after the seasoning of glaze layer, high temperature burns till in reducing atmosphere, and firing temperature adopts 1250 ℃, namely make the even structure densification, the Longquan celadon goods that glaze is plump, fine and smooth.
At last, it should be noted that above what enumerate only is specific embodiments of the invention.Obviously, the invention is not restricted to above embodiment, a lot of distortion can also be arranged.All distortion that those of ordinary skill in the art can directly derive from content disclosed by the invention or associate all should be thought protection scope of the present invention.
Claims (3)
1. utilize the celadon waste material to prepare the raw material of Longquan celadon product process, comprise Longquan celadon blank and Longquan celadon glaze, it is characterized in that, described Longquan celadon blank is according to weight percent meter, composed of the following components: porcelain stone 30～40%, Zijin soil 40～50%, perlite 8～12%, base substrate waste material 3～5% burns till waste material 6～8%; Described Longquan celadon glaze is according to weight percent meter, and is composed of the following components: quartz 15～25%, feldspar 40～45%, Zijin soil 18～25%, Wingdale 10～15%, useless glaze 3～6%.
2. utilize raw material claimed in claim 1 to realize preparing the method for Longquan celadon goods, comprise that high temperature burns till, it is characterized in that, specifically may further comprise the steps:
Steps A: will burn till waste material and carry out the ultramicronising processing, and make the granularity of burning till waste material between 0.5～2 μ m;
Step B: with the moiety of burning till waste material and other Longquan celadon blanks of processing in the steps A ball mill of packing in proportion, ball milling mixes after adding water, pouring out water after old becomes mud to do, then injection forming repaired biscuit again, obtain work in-process after the drying, the kiln of again work in-process being packed into carries out biscuiting in 800～900 ℃;
Step C: with each moiety of Longquan celadon glaze ball mill of packing in proportion, add the 1wt% dispersion agent, pour out into glaze slip behind the ball milling;
Step D: with the glaze slip that obtains among the step C work in-process of biscuiting among the step B are carried out glazing, then with the kiln of packing into after the work in-process drying after the glazing, the high temperature with 1200～1250 ℃ in reducing atmosphere burns till, and namely finishes the making of Longquan celadon goods.
3. the method for preparing the Longquan celadon goods according to claim 2 is characterized in that, the ultramicronising in the described steps A is processed and referred to: roughly grind with the high pressure roll mill first, carry out fine grinding with stirring mill again.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107021625A (en) * | 2017-05-23 | 2017-08-08 | 张福利 | A kind of bluish white glaze of pottery |
| CN109437836A (en) * | 2018-12-24 | 2019-03-08 | 王晶 | A kind of celadon pen and its preparation process |
| CN112341155A (en) * | 2020-11-27 | 2021-02-09 | 于大鹏 | Method for manufacturing large-size ceramic ware |
| CN112374861A (en) * | 2020-11-27 | 2021-02-19 | 于大鹏 | Method for improving strength of ceramic ware blank |
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| CN1683282A (en) * | 2005-02-23 | 2005-10-19 | 广州晟田化工材料科技有限公司 | Process for producing super thin ceramic polished brick using ceramic polished waste slag or ceramic waste material |
| CN101700971A (en) * | 2009-08-12 | 2010-05-05 | 广东长城集团股份有限公司 | Method for producing petuntse from waste ceramics |
| CN101792303A (en) * | 2009-11-02 | 2010-08-04 | 浙江大学 | Longquan celadon reinforced blank and preparation method of product thereof |
| CN102924049A (en) * | 2012-09-27 | 2013-02-13 | 浙江天丰陶瓷有限公司 | Raw material for low-temperature firing of Longquan celadon and firing method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107021625A (en) * | 2017-05-23 | 2017-08-08 | 张福利 | A kind of bluish white glaze of pottery |
| CN109437836A (en) * | 2018-12-24 | 2019-03-08 | 王晶 | A kind of celadon pen and its preparation process |
| CN112341155A (en) * | 2020-11-27 | 2021-02-09 | 于大鹏 | Method for manufacturing large-size ceramic ware |
| CN112374861A (en) * | 2020-11-27 | 2021-02-19 | 于大鹏 | Method for improving strength of ceramic ware blank |
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| CN103360031B (en) | 2015-07-15 |
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