CN103337611B - 一种石墨烯和二氧化钛复合材料的制备方法 - Google Patents
一种石墨烯和二氧化钛复合材料的制备方法 Download PDFInfo
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 79
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 73
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 239000002131 composite material Substances 0.000 title claims abstract description 41
- 239000000463 material Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000000243 solution Substances 0.000 claims abstract description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 11
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000007864 aqueous solution Substances 0.000 claims abstract description 10
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 claims abstract description 6
- 238000002425 crystallisation Methods 0.000 claims abstract description 5
- 230000008025 crystallization Effects 0.000 claims abstract description 5
- 230000008021 deposition Effects 0.000 claims abstract description 3
- 239000011859 microparticle Substances 0.000 claims abstract description 3
- 238000001179 sorption measurement Methods 0.000 claims abstract description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 12
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 3
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 3
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 2
- 238000005259 measurement Methods 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 abstract description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 239000013078 crystal Substances 0.000 description 10
- 238000001069 Raman spectroscopy Methods 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 239000012071 phase Substances 0.000 description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- 239000005357 flat glass Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- NQTSTBMCCAVWOS-UHFFFAOYSA-N 1-dimethoxyphosphoryl-3-phenoxypropan-2-one Chemical compound COP(=O)(OC)CC(=O)COC1=CC=CC=C1 NQTSTBMCCAVWOS-UHFFFAOYSA-N 0.000 description 1
- 241000256844 Apis mellifera Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- CZAYMIVAIKGLOR-UHFFFAOYSA-N [Ni].[Co]=O Chemical compound [Ni].[Co]=O CZAYMIVAIKGLOR-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000000840 electrochemical analysis Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000407 epitaxy Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 238000000101 transmission high energy electron diffraction Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103553017B (zh) * | 2013-10-14 | 2015-09-16 | 南京大学 | 一步制备氟、氮双掺氧化石墨烯的方法和装置 |
CN103825002B (zh) * | 2014-01-29 | 2017-01-04 | 浙江工业大学 | 以二氧化钛为骨架结构包覆磷的复合材料及其应用 |
CN103936065A (zh) * | 2014-03-27 | 2014-07-23 | 南京邮电大学 | 二氧化钛与石墨烯复合纳米材料的制备方法 |
CN105000548B (zh) * | 2014-04-22 | 2018-04-24 | 中国科学院苏州纳米技术与纳米仿生研究所 | 一种新型三维氮掺杂石墨烯复合材料体系的制备方法 |
CN104190395B (zh) * | 2014-08-15 | 2016-02-24 | 中国科学院青海盐湖研究所 | 一种石墨烯/二氧化钛复合材料及其制备方法 |
CN104148045B (zh) * | 2014-08-15 | 2016-02-03 | 中国科学院青海盐湖研究所 | 基于电弧法的石墨烯/二氧化钛复合材料的制备方法 |
CN104577086B (zh) * | 2014-12-17 | 2017-01-04 | 李震祺 | 一种预锂化和石墨烯包覆的介孔SiO负极材料及其制备方法 |
CN105158295A (zh) * | 2015-08-05 | 2015-12-16 | 北京化工大学 | 一种二氧化钛-石墨烯复合湿敏材料的制备方法 |
CN105181755B (zh) * | 2015-08-24 | 2018-11-09 | 大连理工大学 | 氨气传感器及其制备工艺 |
CN105826515A (zh) * | 2016-05-16 | 2016-08-03 | 北京师范大学 | 一种锂离子电池负极材料及其应用 |
CN106328892B (zh) * | 2016-08-30 | 2019-03-26 | 安徽师范大学 | 一种二氧化硅/石墨烯纳米复合材料的制备方法、锂离子电池负极、锂离子电池 |
CN106450234B (zh) * | 2016-12-05 | 2019-04-26 | 新疆维吾尔自治区产品质量监督检验研究院 | 一种球形二氧化钛/石墨烯柔性复合材料的制备方法 |
CN106876670A (zh) * | 2016-12-28 | 2017-06-20 | 广东工业大学 | 一种柔性自支撑的金属氧化物/石墨烯纳米复合膜及其制备方法和应用 |
WO2018164640A1 (en) * | 2017-03-08 | 2018-09-13 | Nanyang Technological University | Electrode, electrochemical cell and methods of forming the same |
CN107199029A (zh) * | 2017-06-08 | 2017-09-26 | 攀枝花学院 | 高效光催化性纳米二氧化钛/石墨烯复合材料的制备方法 |
CN109304183B (zh) * | 2017-07-28 | 2021-06-29 | 中国科学院宁波材料技术与工程研究所 | 处理劣质油料的加氢处理催化剂及其制备方法与应用 |
CN108751168B (zh) * | 2018-06-08 | 2020-10-30 | 常州大学盱眙凹土研发中心 | 一种用于光生阴极防腐的锐钛矿型花状菱形二氧化钛/石墨烯复合材料的制备方法 |
CN108896638B (zh) * | 2018-07-10 | 2020-01-21 | 山东理工大学 | 一种基于二氧化钛掺杂石墨烯负载海参状金钯核壳纳米粒子的免疫传感器的制备方法及应用 |
CN108862266B (zh) * | 2018-07-31 | 2021-11-26 | 辽宁工程技术大学 | 一种氧化石墨烯纳米材料的制备方法 |
CN109301209B (zh) * | 2018-09-27 | 2022-03-18 | 三峡大学 | 一种二氧化钛改性磷/碳复合负极材料的制备方法 |
CN109453679A (zh) * | 2018-10-30 | 2019-03-12 | 江苏理工学院 | 一种掺氮氧化石墨烯二氧化钛复合超滤膜的制备方法 |
CN109786705A (zh) * | 2019-01-17 | 2019-05-21 | 禹城贝尔新材料有限公司 | 一种具有多级碳包覆网络结构的钛酸锂负极材料及其制备方法和应用 |
CN110749572B (zh) * | 2019-10-29 | 2022-04-12 | 广州特种承压设备检测研究院 | 一种石墨烯光纤气体传感器测量***及其测量硫化氢气体的方法 |
CN111454691B (zh) * | 2020-04-14 | 2021-06-08 | 大连理工大学 | 一种石墨烯/非晶二氧化钛纳米棒复合材料、制备方法及其应用 |
CN111584844B (zh) * | 2020-05-20 | 2021-07-06 | 佛山科学技术学院 | 一种二氧化钛纳米复合电极材料及其制备方法 |
CN112725232B (zh) * | 2021-01-04 | 2023-07-14 | 厦门大学 | 一种培养高含量藻蓝蛋白的螺旋藻的培养基和方法 |
CN113948691B (zh) * | 2021-10-15 | 2023-03-10 | 佛山科学技术学院 | 一种二氧化钛复合材料及其作为储能材料的应用 |
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2013
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